CHEMISTRY

th
12 JEE

SOLUTIONS

VIDYAPEETH
S E L E C T I O N H O G A Y A H I N S E
 VIDYAPEETH
Solutions
DPP-1 (JLC/001)
[Concentration Terms]
1. Which of the following is an example of 6. A solution is obtained by mixing 200g
gaseous solution? of 30% and 300g of 20% solution by
(A) Camphor in nitrogen gas
weight. What is the percentage of solute
(B) Solution of hydrogen in palladium
(C) Chloroform mixed with nitrogen in the final solution?
gas (A) 50%
(D) Both (A) & (C) (B) 28%

2. In an amalgam of mercury with sodium, (C) 64%

solvent is (D) 24%
(A) Mercury
(B) Sodium
7. What will be the mole fraction of
(C) Amalgam
(D) None of these ethanol in a sample of spirit containing
85% ethanol by mass?
3. The molarity of 9.8 % (w/w) H2SO4 (A) 0.69
solution is (d = 1.02 g/cc)
(B) 0.82
(A) 1.02 M
(B) 2.04 M (C) 0.85
(C) 1 M (D) 0.60
(D) 4.12 M

4. The molarity of 900 gm of water is 8. The molarity of H2SO4 solution, which

(A) 50 M has a density 1.84 g/cc at 35°C and
(B) 55.5 M contains 98% by weight is-
(C) 5 M
(A) 1.84 M
(D) Cannot be calculated
(B) 18.4 M
5. What is the mole fraction of glucose in (C) 20.6 M
10% W/W glucose solution? (D) 24.5 M
(A) 0.01 (B) 0.02
(C) 0.03 (D) 0.04

(2)
9. What is molarity of K+ in aqueous 10. When a saturated solution of sugar is
solution that contains 17.4 ppm of heated it
K2SO4 (174 g mol-1)? (A) Remains saturated
(A) 2 × 10–2 M (B) Becomes unsaturated
(B) 2 × 10–3 M (C) Becomes supersaturated
(C) 4 × 10–4 M (D) Achieves equilibrium state
(D) 2 × 10–4 M

(3)
 DPP-2 (JLC/002)
[Concentration Terms]
1. What is the molarity of 4.9% (w/w) 6. 25 ml of 3.0 M HNO3 are mixed with 75 ml
H3PO4 solution by mass (density of of 4.0 M HNO3. If the volumes are additive,
the molarity of the final mixture would be-
H3PO4 = 1.22 g/ml)? (A) 3.25 M (B) 4.0 M
(A) 0.61 M (B) 4.9 M (C) 3.75 M (D) 3.50 M
(C) 1.22 M (D) 1 M
7. A 5.2 molal aqueous solution of
2. −
The concentration of NO ions when methyl alcohol, CH3OH, is supplied.
3
What is the mole fraction of methyl
equal volumes of 0.1 M AgNO3 and alcohol in the solution?
0.1 M NaCl are mixed together is (A) 1.100 (B) 0.190
(A) 0.05 M (B) 0.25 M (C) 0.086 (D) 0.050
(C) 0.1 M (D) 0.2 M
8. A solution of ethanol in water is 10% by
3. A 5-molar solution of H2SO4 is diluted volume. If the solution and pure ethanol have
densities of 0.9866 g/cc and 0.785 g/cc
from 1 L to 10 L. What is the molarity respectively . The percent by weight is nearly
of the solution? (A) 7.95 %
(A) 0.25 (B) 1 (B) 17 %
(C) 2 (D) 0.5 (C) 9.86 %
(D) 16.2 %
4. The density of a solution prepared by 9. A compound H2X with molar weight of
dissolving 120 g of urea (mol. Mass = 80g is dissolved in a solvent having
60 u) in 1000g of water is 1.15 g/mL. density of 0.4 gml–1. Assuming no
The molarity of this solution is- change in volume upon dissolution, the
molality of a 3.2 molar solution is-
(A) 0.50 M (B) 1.78 M (A) 6
(B) 7
(C) 1.02 M (D) 2.05 M
(C) 8
(D) 9
5. The molality of 1 M NaNO3 solution is
(d = 1.25 g/ml) 10. An aqueous solution contains 28%
(A) 0.8 m (w/W) KOH solution, if density of
(B) 0.858 m solution is 1.25g/mL, if mole fraction of
(C) 1.6 m KOH is Y then find out the value of
18Y.
(D) 1 m

(4)
 DPP-3 (JLC/003)
[Henry's Law & it’s Applications]
1. The solubility of gas in a liquid increase 5. The value of Henry’s law constant for
with some gases at 293 K is given below.
(A) Increase of temperature Arrange the gases in the increasing order
(B) Amount of liquid taken of their solubility.
(C) Decreases in temperature He : 144.97 kbar, H2 : 69.16 kbar,
(D) Reduction of gas pressure N2 : 76.48 kbar, O2 : 34.86 kbar
(A) He < N2 < H2 < O2
2. Four gases like H2, He, CH4 and CO2 has (B) O2 < H2 < N2 < He
Henry’s constant values (KH) are 69.16, (C) H2 < N2 < O2 < He
144.979, 0.413 and 1.67. The gas which is (D) He < O2 < N2 < H2
most soluble in liquid is-
(A) He (B) CH4 6. Henry’s law constant for molality of
(C) H2 (D) CO2 methane in benzene at 298 K is 4.27 ×
105 mm Hg. The mole fraction of
3. Henry’s law constant for the solubility methane in benzene at 298 K under 760
of N2 gas in water at 298 K is 1.0  105 mm Hg is
atm. The mole fraction of N2 in air is (A) 1.78 × 10–3 (B) 17.43
0.6. The number of moles of N2 from air (C) 0.114 (D) 2.814
dissolved in 10 moles of water at 298 K 7. H2S is a toxic gas used in qualitative
and 5 atm pressure is analysis. If solubility of H2S in water at
(A) 3.0  10−4 STP is 0.195m, what is the value of KH?
(B) 4.0  10−5 (A) 0.0263 bar
(C) 5.0  10−4 (B) 69.16 bar
(D) 6.0  10−6 (C) 192 bar
(D) 289 bar
4. Henry’s constant of four gases A, B, C
and D in water are 40.3, 1.67, 0.413 and 8. How much oxygen is dissolved in 100
0.611 bar at 298 K and 1 atm. The gas mL water at 298 K if partial pressure of
which has maximum solubility in water oxygen is 0.5 atm and KH = 1.4 × 10–3
at 298 K and 1 atm is mol/L/atm?
(A) A (A) 22.4 mg
(B) B (B) 22.4 g
(C) C (C) 2.24 g
(D) D (D) 2.24 mg

(5)
9. When a gas is bubbled through water at
298 K, a very dilute solution of gas is
obtained. Henry’s law constant for the
gas is 100 k bar. If gas exerts a pressure
of 1 bar, the number of moles of gas
dissolved in 1 litre of water is
(A) 0.555
(B) 55.55 × 10–5
(C) 55.55 × 10–3
(D) 5.55 × 10–5

10. According to William Henry’s the

solubility of a gas in liquid depen is on
the pressure of the gas. If 'm' is the
molality of the gas and 'P ' is its
pressure, then which of the following
plot is in accordance with the law?

log m

(A)

log P

log m

(B)

log P

log m

(C)

log P

log m

(D)

log P

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 DPP-4 (JLC/004)
[Vapour Pressure of Liquid - Liquid Solutions,
Ideal solution and non ideal solutions]
1. If liquids A and B form an ideal 6. An ideal solution has two components A
solution, the and B. If A is more volatile than B and
(A) Enthalpy of mixing is zero also PAO  PT , then the correct relation
(B) Entropy of mixing is zero
between mole fraction of A in liquid (X)
(C) Free energy of mixing is zero
and vapour (Y) phase is :
(D) Free energy as well as the entropy
(A) XA = YA
of mixing are each zero
(B) XA  YA
2. The mixture that forms maximum (C) XA  YA
boiling azeotrope is:
(A) Water + Nitric Acid (D) Nothing can be said
(B) Ethanol + Water
(C) Acetone + Carbon disulphide 7. For water Ethanol solution, how many
(D) Heptane + Octane statements are correct?
(i) VP observed = VP calculated
3. Which pair from the following will not (ii) V mix = 0
form an ideal solution (iii) H mix < 0
(A) CCl4 + SiCl4
(iv) S mix > 0
(B) H2O + C4H9OH
(C) C2H5Br + C2H5I (v) G mix <0
(D) C6H14 + C7H16
8. Two liquids A and B form ideal
4. Positive deviation from Raoult’s law is solutions. At 300 K, the vapour pressure
shown by which of the following of solution containing 1 mole of A and 3
mixtures? mole of B is 550 mm Hg At the same
(A) Benzene and toluene temperature, if one more mole of B is
(B) CHCl3 and Acetone added to this solution, the vapour
(C) Ethanol and Water
pressure of the solution increases by 10
(D) HCl and Water
mm Hg The vapour pressure of A and B
in their pure states (in mm Hg) are
5. Raoult’s law is not valid in
respectively
(A) Non-ideal solution showing
(A) 400, 600
positive deviation
(B) Non-ideal solution showing (B) 500, 500
negative deviation (C) 600, 400
(C) Mixture of two immiscible liquid (D) None of these
(D) All of these

(7)
9. At a given temperature, total vapour 10. Two liquid A and B form ideal solution,
pressure (in Torr) of a mixture of The vapour pressure of liquid A and B is
volatile components A and B is given by 200mm and 300mm Hg respectively.
P = 240 + 120 XB Hence, vapour The total vapour pressure (P) of binary
pressure of pure A and B respectively ideal solution may be
(in Torr) are – (A) 150 mm
(A) 120, 75 (B) 334.5mm
(B) 120, 195 (C) 185.2mm
(C) 240, 360 (D) 240 mm
(D) 75, 45

(8)
 DPP-5 (JLC/005)
[Colligative Properties: Relative Lowering of Vapour Pressure,
Elevation of boiling point]
1. Which of the following is incorrect? 5. If relative decrease in vapour pressure is
(A) Relative lowering of vapour 0.4 for a solution containing 1 mol NaCl
pressure is independent of the in 3 mol of H2O, then % ionization of
nature of the solute and the solvent.
NaCl is
(B) The relative lowering of vapour
pressure is a colligative property (A) 60%
(C) Vapour pressure of a solution is (B) 80 %
lower than the vapour pressure of (C) 40 %
the solvent. (D) 100 %
(D) The relative lowering of vapour
pressure is directly proportional to 6. The vapour pressure lowering caused by
the original pressure. the addition of 100g of sucrose (molecular
mass = 342) to 1000g of water if the
2. ‘A’ gram of non-volatile, non-electrolyte
(molar mass M) is dissolved in 200 ml vapour pressure of pure water at 25oC is
of unknown solvent (density = 1.25 23.8 mm Hg
gm/ml molal elevation constant is Kb). (A) 1.25 mm Hg
Elevation in boiling point of this (B) 0.125 mm Hg
solution can be given by
(C) 1.15 mm Hg
M 4 KbA
(A) (B) (D) 0.012 mm Hg
Kb M
KbA KbM 7. When 10 g of a non-volatile solute is
(C) (D)
4M 4A dissolved in 100 g of benzene, it raises
boiling point by 1oC then molecular
3. The mass of a non-volatile solute of mass of the solute is
molar mass 40 gmol-1 that should be
(kb for C6H6 = 2.53 K kg mol–1)
dissolved in 114 g of Octane to lower its
vapour pressure by 20% is (A) 223g/mol
(A) 10 g (B) 11.4 g (B) 233g/mol
(C) 9.8 g (D) 12.8 g (C) 243g/mol
(D) 253g/mol
4. If the elevation in boiling point of a
solution of 10 g of solute (mol. wt. = 8. When mercuric iodide is added to an
100 g) of 100 g water is ∆Tb, the
aqueous solution of KI the
ebullioscopic constant of water is
(A) Boiling point increases
(A) 10 (B) 100 ΔTb (B) Boiling point decreases
Tb (C) Freezing point decreases
(C) ΔTb (D) (D) Osmotic pressure increases
10

(9)
9. If X gram of glucose is dissolved in 10. At 100o C the vapour pressure of a
180g of water to reduce is vapour solution of 6.5 g of a solute in 100 g
pressure by 20% then find the value of water is 732 mm. If kb = 0.52, the
X/10. boiling point of this solution will be
(A) 102 oC (B) 103 oC
(C) 101 oC (D) 100 oC

(10)
 DPP-6 (JLC/006)
[Colligative Properties : Depression in freezing point,
Osmosis and Osmotic Pressure]
1. Kf, molal depression constant or 6. A solution containing 62 g ethylene glycol
cryoscopic constant, does not depend on in 250g water is cooled to –10°C. If Kf for
(A) Nature of solvent water is 1.86K kg mol–1, the amount of
(B) Amount of solvent water (in g) separated as ice is :
(C) Freezing point of solvent (A) 48 (B) 32
(D) (H)fusion of solvent (C) 64 (D) 16

2. Osmotic pressure is 0.0821 atm at 7. Study the following figure and choose the
temperature of 300 K. Find concentration correct option
in mole/litre
(A) 0.033 (B) 0.066
(C) 0.33 × 10-2 (D) 3

3. The freezing point of equimolal aqueous

solutions will be highest for–
(A) C6H5NH3Cl (anilinium chloride)
(B) Ca(NO3)2
(C) La(NO3)3
(D) C6H12O6 (glucose)
4. For an aqueous solution, freezing point is
−0.186 oC. Elevation of the boiling point
of the same solution is (kf = 1.86 K kg
mol-1 and Kb = 0.52 K kg mol–1).
(A) 0.186 oC (B) 0.052 oC
(C) 1.86 oC (D) 5.12 oC
5. When mercuric iodide is added to the
aqueous solution of potassium iodide, the
(A) freezing point is raised
(B) freezing point does not change
(C) freezing point is lowered.
(D) boiling point does not change
(A) There will be no movement of any
solution across the membrane
(B) Solvent of BaCl2 will flow towards
the NaCl solution
(C) NaCl will flow towards the BaCl2
solution
(D) The osmotic pressure of 0.1 M NaCl
is equal to the osmotic pressure of
0.05 M BaCl2, assuming complete
dissociation of the electrolyte.
8. How many grams of sucrose (M. wt. =
342) should be dissolved in 100 g water in
order to produce a solution with a 105.0°C
difference between the freezing point and
the boiling temperatures? (Kf = 1.86°C/m,
Kb = 0.51°C/m) Nearest Integer

(11)
9. Freezing point of an aqueous solution is 10. 75 g ethylene glycol is dissolved in 500
−0.186 o C . Elevation of boiling point of gram water. The solution is placed in a
same solution would be : refrigerator maintained at a temperature of
263.7 K. What amount of ice will separate
(K b = 0.512 and K f = 1.86 K molality −1)
out at this temperature?
(A) 0.186 oC
(Kf water = 1.86 K molality -1)
(B) 0.0512 oC
(A) 300 g
(C) 0.092 oC
(B) 200 g
(D) 0.237 oC
(C) 178 g
(D) 258 g

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 DPP-7 (JLC/007)
[Abnormal Molar Masses, Van't Hoff Factor,
Degree of dissociation and association]
1. Observe the following abbreviations πobs = 5. The van’t Hoff factor (i) for a dilute’
observed colligative property πcal = aqueous solution of Na2SO4 is :
theoretical colligative property assuming (A) 1+  (B) 1 − 
normal behaviour of solute. Van’t Hoff (C) 1 + 2 (D) 1 − 2
factors (i) is given by
(A) i = obs  cal 6. A 0.001 molal solution of [Pt(NH3)4Cl4] in
(B) i = obs + cal water had a freezing point depression of
0.0054°C. If Kf for water is 1.80, the
(C) i = obs − cal
correct formula for the above compound
obs assuming its complete dissociation is
(D) i =
cal (A) [Pt(NH3)4Cl3]Cl
(B) [Pt(NH3)4Cl2]Cl2
2. The vant’s Hoff factor for 0.1 M Ba(NO3)2 (C) [Pt(NH3)4Cl]Cl3
solution is 2.74. The degree of dissociation (D) [Pt(NH3)4Cl4]
is
(A) 91.3% (B) 87% 7. 0.04 M Na2SO4 solution is isotonic with
(C) 100% (D) 74% 0.1 M glucose at the same temperature.
What is the apparent degree of
3. Phenol dimerises in benzene having van’t dissociation of Na2SO4?
Hoff factor 0.54. What is the degree of (A) 0.25 (B) 0.50
association? (C) 0.75 (D) 0.85
(A) 1.92 (B) 0.98
(C) 1.08 (D) 0.92 8. We have three aqueous solution of NaCl
labelled as ‘A’. ‘B’ and ‘C’ with
4. When 20 g of naphthoic acid (C11H8O2) is concentration 0.1 M, 0.01 M and 0.001 M,
dissolved in 50 g of benzene (Kf = 1.72 K respectively. The value of van’t Hoff
kg/mol) a freezing point depression of 2 K factor for these solution will be in the
is observed. The van’t Hoff factor (i) is order
(A) 0.5 (A) iA  iB  iC
(B) 0.2 (B) iA  iB  iC
(C) 1.0
(C) iA = iB = iC
(D) 3.0
(D) iA  iB  iC

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9. Calculate the apparent degree of ionization 10. The depression in freezing point observed
of an electrolyte MX2 in water, if the for a formic acid solution of concentration
observed molar mass of the solute by 0.5 mL L–1 is 0.0405°C. Density of formic
measuring elevation in boiling point is acid is 1.05 g mL–1. The Van’t Hoff factor
65.6 g (Normal molar mass of the solute of the formic acid solution is nearly :
= 164 g). (Given for water kf = 1.86 K kg mol–1)
(A) 75% (A) 0.8
(B) 85% (B) 1.1
(C) 65% (C) 1.9
(D) 25% (D) 2.4

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 DPP-8 (JLC/008)
[Abnormal Molar Masses, Van't Hoff Factor,
Degree of dissociation and association]
1. Van’t Hoff factor of aqueous acetic acid 5. The Van’t Hoff factor for a 0.1 M
solution is Al2(SO4)3 solution is 4.20. The degree of
(A)  1 (B)  1 dissociation is
(C) = 1 (D) 0 (1) 80% (2) 90%
(3) 78% (4) 83%
2. The value of observed and calculated
molecular weights of silver nitrate are 6. The lowering of vapour pressure of
92.64 and 170 respectively. The degree 0.1M aqueous solutions of NaCl, CuSO4
of dissociation of silver nitrate is and K2SO4 are:
(A) 60 % (B) 83.5% (1) All equal
(C) 46.7% (D) 60.23% (2) In the ratio of 1 : 1 : 1.5
(3) In the ratio of 3 : 2 : 1
3. If 0.1 M solutions of each electrolyte are (4) In the ratio of 1.5 : 1 : 2.5
taken and if all electrolytes are
completely dissociated, then whose 7. K2HgI4 is 40% ionised in aqueous
boiling point will be highest? solution, The value of its van’t Hoff
(A) Glucose factor (i) is :
(B) KCl (A) 1.6
(C) BaCl2 (B) 1.8
(D) K4[Fe(CN)6] (C) 2.0
(D) 2.2
4. Consider the following three aqueous
solution of CH3COOH 8. The osmotic pressure of a dilute solution
I − 0.1 m of an ionic compound XY in water is
II − 0.01m four times that of a solution of 0.01 M
III − 0.001m BaCl2 in water. Assuming complete
dissociation of the given ionic
If i1, i2 and i3 represents the value of
ompounds in water, the concentration of
van’t Hoff factor for solution I, II and III
XY (in mol L–1) in solution is :
respectively, the correct order of i1, i2
(A) 4×10–2
and i3 is.
(B) 6×10–2
(A) i1  i2  i3 (B) i1  i2  i3
(C) 4×10–4
(C) i2  i1  i3 (D) i1  i3  i2 (D) 16×10–4

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9. Molal depression constant for a solvent 10. Molecules of benzoic acid (C6H5COOH)
is 4.0 K kg mol–1. The depression in the dimerise in benzene. ‘w’ g of the acid
freezing point of the solvent for 0.03 dissolved in 30g of benzene shows a
depression in freezing point equal to 2K.
mol kg–1 solution K2SO4 is :
If the percentage association of the acid
(Assume complete dissociation of the to form dimer in the solution is 80, the w
electrolyte) is:
(A) 0.18K
(Given that Kf = 5K kg mol–1, Molar
(B) 0.24K mass of benzoic acid = 122g mol–1)
(C) 0.12K
(A) 2.4 g (B) 1.0g
(D) 0.36K
(C) 1.5g (D) 1.8g

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