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1502_400 HI-TEMP KO-19 AEROSOL MSDS 20211105
1502_400 HI-TEMP KO-19 AEROSOL MSDS 20211105
Product Identifier
Product name HI-TEMP KO-19 (Aerosol)
Synonyms Not Available
Proper shipping name AEROSOLS
Chemical formula Not Applicable
Other means of identification Not Available
Relevant identified uses of the substance or mixture and uses advised against
Alcohol ethoxylates (AE) are used in many types of consumer and industrial products like, e.g., laundry detergents, all-purpose cleaning agents,
dishwashing agents, emulsifiers, and wetting agents. Alcohol alkoxylates (AA) are used as weakly foaming and foam-mitigating surfactants in
household cleaning agents, dishwashing agents and cleaning agents designed for the food industry. Other applications of AA include textile
lubricants, agricultural chemicals, and rinse aid formulations
Relevant identified uses
Alcohol ethoxylates (AE) are nonionic surfactants composed of a hydrophobic alkyl chain (fatty alcohol) which is combined with a number of
ethoxylate, or ethylene oxide, units via an ether linkage. Alcohol alkoxylates (AA) normally contain both ethylene oxide (EO) and propylene oxide
(PO) in their hydrophilic moiety, whereas butylene oxide (BO) is less frequently used. The abbreviation AA has been used to designate nonionic
surfactants with a hydrophilic part containing PO (or BO), frequently in combination with EO.
Once connected and if the message is not in your prefered language then please dial 01
Label elements
Hazard pictogram(s)
Hazard statement(s)
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HI-TEMP KO-19 (Aerosol)
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
84133-50-6 10-30 alcohols C12-14 secondary ethoxylated
67-63-0 10-30 isopropanol
68476-85-7. 10-30 hydrocarbon propellant
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HCIS; 3. Classification drawn from Regulation (EU) No 1272/2008 - Annex VI; 4.
Classification drawn from C&L; * EU IOELVs available
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HI-TEMP KO-19 (Aerosol)
Extinguishing media
Alcohol stable foam.
Dry chemical powder.
BCF (where regulations permit).
Carbon dioxide.
Water spray or fog - Large fires only.
SMALL FIRE:
Water spray, dry chemical or CO2
LARGE FIRE:
Water spray or fog.
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HI-TEMP KO-19 (Aerosol)
Environmental precautions
See section 12
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HI-TEMP KO-19 (Aerosol)
Control parameters
Emergency Limits
Ingredient TEEL-1 TEEL-2 TEEL-3
isopropanol 400 ppm 2000* ppm 12000** ppm
hydrocarbon propellant 65,000 ppm 2.30E+05 ppm 4.00E+05 ppm
Exposure controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can
be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection.
Appropriate engineering The basic types of engineering controls are:
controls Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically
"adds" and "removes" air in the work environment. Ventilation can remove or dilute an air contaminant if designed properly.
Personal protection
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HI-TEMP KO-19 (Aerosol)
NITRILE+PVC A up to 20 x ES - AX-3 P2 -
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HI-TEMP KO-19 (Aerosol)
Material is highly volatile and may quickly form a concentrated atmosphere in confined or unventilated areas. The vapour may displace and
replace air in breathing zone, acting as a simple asphyxiant. This may happen with little warning of overexposure.
WARNING:Intentional misuse by concentrating/inhaling contents may be lethal.
The odour of isopropanol may give some warning of exposure, but odour fatigue may occur. Inhalation of isopropanol may produce irritation of
the nose and throat with sneezing, sore throat and runny nose.
There is strong evidence to suggest that this material can cause, if swallowed once, very serious, irreversible damage of organs.
Overexposure to non-ring alcohols causes nervous system symptoms. These include headache, muscle weakness and inco-ordination,
giddiness, confusion, delirium and coma.
Not normally a hazard due to physical form of product.
Considered an unlikely route of entry in commercial/industrial environments
Isoparaffinic hydrocarbons cause temporary lethargy, weakness, inco-ordination and diarrhoea.
Ingestion Swallowing 10 millilitres of isopropanol may cause serious injury; 100 millilitres may be fatal if not properly treated. The adult single lethal dose is
approximately 250 millilitres. Isopropanol is twice as poisonous as ethanol, and the effects caused are similar, except that isopropanol does not
cause an initial feeling of well-being. Swallowing may cause nausea, vomiting and diarrhea; vomiting and stomach inflammation is more
prominent with isopropanol than with ethanol. Animals given near-lethal doses also showed inco-ordination, lethargy, inactivity and loss of
consciousness.
Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal or may
produce serious damage to the health of the individual.
There is strong evidence to suggest that this material, on a single contact with skin, can cause very serious, irreversible damage of organs.
Skin exposure to isoparaffins may produce slight to moderate irritation in animals and humans. Rare sensitisation reactions in humans have
occurred.
Skin Contact Spray mist may produce discomfort
Most liquid alcohols appear to act as primary skin irritants in humans. Significant percutaneous absorption occurs in rabbits but not apparently in
man.
Open cuts, abraded or irritated skin should not be exposed to this material
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HI-TEMP KO-19 (Aerosol)
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects. Examine the skin
prior to the use of the material and ensure that any external damage is suitably protected.
511ipa
There is some evidence to suggest that the material may cause mild but significant inflammation of the skin either following direct contact or after
a delay of some time. Repeated exposure can cause contact dermatitis which is characterised by redness, swelling and blistering.
If applied to the eyes, this material causes severe eye damage.
Instillation of isoparaffins into rabbit eyes produces only slight irritation.
Eye Not considered to be a risk because of the extreme volatility of the gas.
Isopropanol vapour may cause mild eye irritation at 400 parts per million. Splashes may cause severe eye irritation, possible burns to the cornea
and eye damage. Eye contact may cause tearing and blurring of vision.
Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.
This material can cause serious damage if one is exposed to it for long periods. It can be assumed that it contains a substance which can
produce severe defects.
There has been some concern that this material can cause cancer or mutations but there is not enough data to make an assessment.
Substance accumulation, in the human body, may occur and may cause some concern following repeated or long-term occupational exposure.
There is limited evidence that, skin contact with this product is more likely to cause a sensitisation reaction in some persons compared to the
general population.
Chronic Constant or exposure over long periods to mixed hydrocarbons may produce stupor with dizziness, weakness and visual disturbance, weight loss
and anaemia, and reduced liver and kidney function. Skin exposure may result in drying and cracking and redness of the skin.
Main route of exposure to the gas in the workplace is by inhalation.
Prolonged or repeated skin contact may cause degreasing, followed by drying, cracking and skin inflammation.
Long term, or repeated exposure of isopropanol may cause inco-ordination and tiredness.
Repeated inhalation exposure to isopropanol may produce sleepiness, inco-ordination and liver degeneration. Animal data show developmental
effects only at exposure levels that produce toxic effects in adult animals. Isopropanol does not cause genetic damage.
There are inconclusive reports of human sensitisation from skin contacts with isopropanol.
TOXICITY IRRITATION
HI-TEMP KO-19 (Aerosol)
Not Available Not Available
TOXICITY IRRITATION
TOXICITY IRRITATION
hydrocarbon propellant
Inhalation(Rat) LC50; 658 mg/l4h[2] Not Available
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise
specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
Polyethers (such as ethoxylated surfactants and polyethylene glycols) are highly susceptible to being oxidized in the air. They then form complex
mixtures of oxidation products.
Animal testing reveals that whole the pure, non-oxidised surfactant is non-sensitizing, many of the oxidation products are sensitisers. The
oxidization products also cause irritation.
Humans have regular contact with alcohol ethoxylates through a variety of industrial and consumer products such as soaps, detergents and other
cleaning products. Exposure to these chemicals can occur through swallowing, inhalation, or contact with the skin or eyes. Studies of acute
ALCOHOLS C12-14 toxicity show that relatively high volumes would have to occur to produce any toxic response. No death due to poisoning with alcohol ethoxylates
SECONDARY ETHOXYLATED has ever been reported. Studies show that alcohol ethoxylates have low toxicity through swallowing and skin contact.
Animal studies show these chemicals may produce gastrointestinal irritation, stomach ulcers, hair standing up, diarrhea and lethargy.
Both laboratory and animal testing has shown that there is no evidence for alcohol ethoxylates (AEs) causing genetic damage, mutations or
cancer. No adverse reproductive or developmental effects were observed.
Tri-ethylene glycol ethers undergo enzymatic oxidation to toxic alkoxy acids. They may irritate the skin and the eyes. At high oral doses, they may
cause depressed reflexes, flaccid muscle tone, breathing difficulty and coma. Death may result in experimental animal. However, repeated
exposure may cause dose dependent damage to the kidneys as well as reproductive and developmental defects.
Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-allergic condition
known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of highly irritating compound. Main
criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic individual, with sudden onset of persistent
asthma-like symptoms within minutes to hours of a documented exposure to the irritant. Other criteria for diagnosis of RADS include a reversible
airflow pattern on lung function tests, moderate to severe bronchial hyperreactivity on methacholine challenge testing, and the lack of minimal
lymphocytic inflammation, without eosinophilia. RADS (or asthma) following an irritating inhalation is an infrequent disorder with rates related to
the concentration of and duration of exposure to the irritating substance.
Isopropanol is irritating to the eyes, nose and throat but generally not to the skin. Prolonged high dose exposure may also produce depression of
ISOPROPANOL
the central nervous system and drowsiness. Few have reported skin irritation. It can be absorbed from the skin or when inhaled. Intentional
swallowing is common particularly among alcoholics or suicide victims and also leads to fainting, breathing difficulty, nausea, vomiting and
headache.
The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of
vesicles, scaling and thickening of the skin.
The substance is classified by IARC as Group 3:
NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.
HYDROCARBON
inhalation of the gas
PROPELLANT
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HI-TEMP KO-19 (Aerosol)
ALCOHOLS C12-14
SECONDARY ETHOXYLATED
No significant acute toxicological data identified in literature search.
& HYDROCARBON
PROPELLANT
Toxicity
Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite
V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment
Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing
of equipment wash-waters.
Wastes resulting from use of the product must be disposed of on site or at approved waste sites.
When released in the environment, alkanes don't undergo rapid biodegradation, because they have no functional groups (like hydroxyl or carbonyl) that are needed by most
organisms in order to metabolize the compound.
However, some bacteria can metabolise some alkanes (especially those linear and short), by oxidizing the terminal carbon atom. The product is an alcohol, that could be next oxidised
to an aldehyde, and finally to a carboxylic acid. The resulting fatty acid could be metabolised through the fatty acid degradation pathway.
For Petroleum Hydrocarbon Gases:
Environmental Fate: Petroleum hydrocarbon gases are primarily produced in petroleum refineries, or in gas plants that separate natural gas and natural gas liquids. This category
contains 99 petroleum hydrocarbon gas substances, the majority of which never reach the consumer. Petroleum hydrocarbon gases do not contain inorganic compounds, (e.g.
hydrogen sulfide, ammonia, and carbon monoxide), other than asphyxiant gases; the low molecular weight hydrocarbon molecules are primarily responsible for the hazard associated
with these gases.
Atmospheric Fate: All components of these gases will evaporate to the air where interaction with hydroxyl radicals is an important fate process. Substances in refinery gases that
evaporate to air may undergo indirect, gas-phase oxidation reaction with hydroxyl radicals and this is an important fate process for these substances.
For High Boiling Point Ethylene Glycol Ethers: Koc: 10; log Kow: -1.73 to +0.51 @ 20 C. Henry's Law Constant: 3.54 E-14 to 3.67 E-13 m3 atm/mol @ 25 C. These chemicals form a
category based on similar structural, physiochemical and toxicological properties. Triethylene- and tetraethylene- glycol ethers represent typical members of the category.
Environmental Fate: All have high boiling points, low volatility and high water solubility. Higher molecular weight species and surrogates may be solids at ambient temperatures.
Atmospheric Fate: Triethylene glycol butyl ether (TGBE), tetraethylene glycol methyl ether (TetraME) and tetraethylene glycol butyl ether (TetraBE) have atmospheric
photodegradation half-lives of 2.5, 2.4 and 2.0 hours, respectively.
For petroleum distillates:
Environmental fate:
When petroleum substances are released into the environment, four major fate processes will take place: dissolution in water, volatilization, biodegradation and adsorption. These
processes will cause changes in the composition of these UVCB substances. In the case of spills on land or water surfaces, photodegradation-another fate process-can also be
significant.
As noted previously, the solubility and vapour pressure of components within a mixture will differ from those of the component alone. These interactions are complex for complex
UVCBs such as petroleum hydrocarbons.
For Isopropanol (IPA):
log Kow: -0.16- 0.28;
Half-life (hr) air: 33-84;
Half-life (hr) H2O surface water: 130;
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HI-TEMP KO-19 (Aerosol)
Bioaccumulative potential
Ingredient Bioaccumulation
isopropanol LOW (LogKOW = 0.05)
Mobility in soil
Ingredient Mobility
isopropanol HIGH (KOC = 1.06)
Labels Required
Marine Pollutant
Class 2.1
Transport hazard class(es)
Subrisk Not Applicable
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HI-TEMP KO-19 (Aerosol)
Transport in bulk in accordance with MARPOL Annex V and the IMSBC Code
Product name Group
alcohols C12-14 secondary
Not Available
ethoxylated
isopropanol Not Available
hydrocarbon propellant Not Available
Safety, health and environmental regulations / legislation specific for the substance or mixture
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HI-TEMP KO-19 (Aerosol)
ECHA SUMMARY
Ingredient CAS number Index No ECHA Dossier
alcohols C12-14 secondary
84133-50-6 Not Available Not Available
ethoxylated
Harmonisation (C&L
Hazard Class and Category Code(s) Pictograms Signal Word Code(s) Hazard Statement Code(s)
Inventory)
1 Skin Irrit. 2; Aquatic Chronic 2 GHS09; GHS07; Wng H315; H411
2 Skin Irrit. 2; Aquatic Chronic 2; Eye Irrit. 2; Flam. Liq. 3; STOT SE 3 GHS09; GHS07; Wng; GHS02 H315; H411; H319; H226; H335
Harmonisation Code 1 = The most prevalent classification. Harmonisation Code 2 = The most severe classification.
Pictograms Hazard
Harmonisation (C&L
Hazard Class and Category Code(s) Signal Word Statement
Inventory)
Code(s) Code(s)
GHS02; H225; H319;
1 Flam. Liq. 2; Eye Irrit. 2; STOT SE 3
GHS07; Dgr H336
Flam. Liq. 2; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3;
STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3;
STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3;
GHS02; Dgr; H225; H319;
STOT SE 3; STOT SE 3; STOT SE 1; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3;
GHS08; H336; H335;
STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3;
2 GHS05; H370; H302;
STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3;
GHS06; H312; H331;
STOT SE 3; STOT SE 3; Acute Tox. 4; Acute Tox. 4; Acute Tox. 3; STOT SE 1; STOT SE 3; STOT SE
GHS03 H340; H314
3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3;
STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; STOT SE 3; Skin Corr. 1B; Eye Dam. 1; STOT SE 3;
STOT SE 3; STOT SE 3; STOT SE 3
Harmonisation Code 1 = The most prevalent classification. Harmonisation Code 2 = The most severe classification.
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HI-TEMP KO-19 (Aerosol)
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification
committee using available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or
other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
end of SDS