INTERNATIONAL Iso STANDARD 247 "oes Rubber — Determination of ash Coutcheue — Déteminaton dy tux do concros etonoe murder Teoasr zo) e180 2008180 247:2006(€) he PF ney tn anbeieayptce maconcewA ao h mab or vane nn one being a sates artemakl hoe Sons ee Pers oasis Evy eae on ete rae aunts bzaty so mart nase rattan yo sun aren inl Seva is r Gten fhatoe rmetmentnaen pga nein whut pemiazon ewig om other 180 a Pe adres Dow oF s0caynpt cnc, Eel openiaion ‘io wets 1 ‘o1s02n06-rgremes10 247:2006(€) Foreword {80 (the intsnatonal Organization for Standardization) is & word feeraton of ratlonal santas bods {050 member bode). Tho work of preparing Ineatonal Standards ie normal eared ou ough ISO technica camnies, Each Member bea ntostes a abject or whch echnical come hasbeen, ‘satoned has te ight be rpresortedon hat eommites temaons organizations, goverment sna ‘on-govrnmerta nan wih ISO, aot pt inne wok, 90 colaborsos sos wit Oe rmatonal lsctotectiou Gammiston (IEC) 2 all mata of aacrotachncalsancadeaton, Intrnatonal Standards are cated in secordarce with the ules gen i the ISONEC Dec, Fart 2. “The man tack of technical commits Isto prepare International Standards. Oral national Senders {opted by the ‘cchries| commas are escustag fo the mamber bodes fr vl. Pusleton as an Irtrnatonal Standard roauresspproval ya ast 75 af he amber bees casing aol. ‘Atontion i drawn tothe possbity hat some ofthe slamants ft dcumant maybe the suc of paint ‘ahs. 180 cal net be had rpanstie or aang any ol uch patent gts 180 247 was prepared by Tecnica Commitee ISOITC 45, Rubber and ubberproduets,Subconriee SC 2 Tsing and ana. “This tour ation cancels and replaces th this esen (SO 247-1890, whch hasbeen raved update tho normative loansINTERNATIONAL STANDARD 150 247:2006(€) Rubber — Determination of ash 1 Scope ‘Thisntarnatonal Standard specs two maths foe he detarinaton of as rom raw bere, sompoundes ‘bears and vleanzales, The raha are aplebl ora, compoundes ot vasanzed nat fhe M, ‘Grand tamil deca n180 1629, xcept. = Matt shalnot be used fe the detention ash om compounded or vuleanizes bbe containing ‘one, bromine oriedne = nod shat be sed or compounded or vulcanizad rubbers centaning one, bene or en. al nt bo used for encomgouneed rubber — Lithium ane tuoi camgounds may asc wih ites cris fo frm vlale compounds, ging mash ‘eauts Plelinenerules sha thle be Used fr aching yore conaning ahd ikutrpaymerced “Ti nlematonal Standard das nat over he nterpreaton ofthe ash resus 4 to the nrg ceric Content ofa compound or warzats. This Is the espera cf the erat wo has to be aware ol the Sahavou of ober aves a slave tempat, ‘Te wo method of ashing do not ave dencl ecu in allease, and Nis ncescary tsa nth tat report ‘namabed of ashing empojes. 2 Normative references “Te fling referenced documents ave ndapensabie forthe application of this document For dated ‘elrence, ole elon sed ape Fo’ undated tates thal eon he eernoeddosument (ietudng any monament) apples. 150.248, Raber, rw — Determraton of laser contnt 180 1629, Rubber and tees — Nomenctanre 180 1795, Rubber aw natural and aw yntete— Sampling and ator preparative procsdiee 3 Principle 34 Method & |Awolpied ast porns heated cue evra ga burner. Alor expulsion ol hevoaiedecompostion product he ruil I ranalved to a mule umace wheres hested unt al he eatonacooke mater Na Een ut of and congint mas stained 82 Method 8 ‘Awoljid tat orton hestedn acute nth proton of ste ai, rt by means of ges bua and ‘nan nama urace unl al te carbonaceous mato has been Gut of and conta mass eased180 247:2006(6) 4 Reagent 4.1, Sure eid (or metned Bony), analyte ads, p= 1,84 fon 5 Apparatus Crdnerybortry apparatus, ls tho flowing 5.4 Crucible, of ecula,sica or patnum, of capacty approximately 0 on For raw nhl ubbers is pom use 2 cucble of minimum expacy 26 on? per gam eat orton 52 Hestesletant, thermally insulating board, 100mm sare an of hckressapproxanstaly an wth ‘cena hoot avammodal he eu (6, Abou we-hkas fe crue shal projet blow th bar 55.2 Bunson burr, snl ype of gas buna. 54 Mute furnace, fed wth fue and wih proion for conliag hea ow trough te furnace. (is fay a achiev by agustng the dor opening) A Yonperaurecorfobng deve Is rauled ain & lenpertue of 80 "C+ 25"C or 9500 28". 6 Preparation of the test portion 6.1 Tost portions ofa natural rer sal be et fom the homopenizd piece propses in acardance wth TSO 1765, Tot patane ofa enthato rubbers shal bo cut fn te died ubter sbtaned shar carn cut the determination of vlalxmater content mn accardae with SO 24, 6.2 Testporions of weber compounds shal be comminutd by hand 15.3 Testportons of ucanzao chat be shestodor urbod ona mo comin by han {6.4 Care salle akon o ensure ta et portions of rther compounds ar vlcanlzate ars epresenatho ‘he sample 7 Procedure 7A Method A Heats clean empty erate (6:1) of appropri sie for about 30min in ho mule umace (6.4), masine at 50°62 25°C. allow fo ool io ambentampertrein a descent and wah fhe noses mg Take a tee poron of about 3 gota utber or 9198 go compounded naer or vleanzat, scaring tothe mass ‘aso bo expecta, and woigh th nearest 0.1 m9 Place word test orton inthe crucble maurad Ininehoe ine neat ‘satan bora reuting oar 2). eat hecrudbe gent wi he burner (3) n ‘hood for proper verti, aking cre nate ruber doos rat its any rater eet do apurirg ot fring, rape he above proosdre wh aes porto, “man the rubs as decomposed to a chared mass, aul incoase the hoa rom He burner nt me Volale deconposion products havo been suvstaralyexpolba ee a dy erbenaceous reside remains, “anal he eu ands conants othe mufefurace, mand a 580°C = 25° (eo, however the Nol) leaving the door othe furnace sig open 1 prvi sufcien af oxilze he carton Conn heating unt te carbon is comply oxidize ard a oan ashe cbainos. Remove rsa and Ieconens rom ha turmsea, allow lo colts arisen aperture nthe dasealr ana waigh fhe noses (11mg. Then hat the custo and scorns agin fr about 30min he mut furnace, malted at '805C 425°C for 980°C 25°C — see Nab), allow fo cel amb empeatue tho sosexator tnd r-woih 1 fe nerest 61 mg. This aes shal nate om he previous mace by more han mg ah she 1th emu sn for compounas and wikaizte. His 2 so 08 apenas180 247:2006(6) requtoentis nt uted repet ne heating, cooling and sighing procedure unt ine erence teen Ko ‘Srecescve welgungs mots his equement NOTE Fo conpnind sn naarzateg, sport of 50°25“ may bese 72 Method 8 Hota clean amply crue (6:1) of eprops er bout 90min in tha mute urace (6.4), msn a 950°C = 25°C, alamo coalio amber iomperntio n'a dstosntor and welgh fhe nearest mg Take {oat potion a abou go 8g ote compoune o vlcaniate ana wig fo he nest Gt mg Pace best Doren inthe cuae ana per about 38 er? ot conceniated sure acd (4.1) over it 20 hat ne rub is employ wot. Plas tha erie an ts contents i the hol nt Reser, erly inating board (52) ana heat andy ith ho tumor 9 hoo fo proper vento. ung the al ean, th stu avs excessively witha he ame o sid posi lcs of aerial {nen te reaction becomes more gone, increase the eat rom he bua unl he cass sutte aad ls Velaized and ary careanacoos resid omaine Treatr he cell and canons ote fle umace Iansined et 880°C + 25°C, and haat or about 1 nntall he crbonis completly oxdaed ara coan ash Ie cbanoa. Remove the cule ana contents rom to Iunace aot o ooo 9 aman tempest ‘esleator and walgh toto nearest 0 mg. Than hea he sul ans contents aga or abet 90 minh ‘emule fumace, mantaned st 950°C 28 C, ala coat ambient temperate Inte Sanco nd reowacgh the naaree 1g Ive mass ters rom he pravcus mate by more han 1% rave ote amount of ash rept he hast, cooing and weigh posed uth lleranesbatveen Wo socaeavewoighingeelaes han lays {ote amour of ash ‘mg Iso mas, nga, of tho ts orton; 1m te the mass, n grams of te empty ruc; ‘mg Is tho mas, in grams, oto crue and ash 9 Test report “The lest opt shal nud ho flowing partes 8) alla roquied or hal donteaton of he pace or sao tse 1b) a toronco otis tomatonal Standar ©) tha mathed employed —mathod Aor meth 4) the temperature use, anne reason rs coie 950°C was uted for method 12} the ash detrmined or te product esta, as percentage by mas; 4) the deo of ets 180 00 ara sees a180 247:2006(6) tes 03.080