Professional Documents
Culture Documents
do
Amine and Sulfur
Recovery Units
Gas Treating
Defoamers / Antifoams *
Emulsion Breakers *
Corrosion inhibitors *
HSAS Neutralizers
Antifoulants
Amine Solvents
Acid Gas
Rich Amine
Gas/Liquid
Out
Regenerator
Absorber
Gas/Liquid
In
Why?
Condensed hydrocarbons
corrosion products
oil contamination (FCC)
organic acids
chemical additives
Foaming
Defoamers / Antifoams
Additives that increase the elasticity of the
bubble
allows bubble to expand making the film
unstable
must have low solubility in bulk solution
1 Defoamers are generally only fed when needed.
2 Antifoams can be injected as a preventative.
Foaming or Fouling?
Foaming
Increases amine hold in tower
Increases tower dP suddenly
Fouling
Solids on trays, packing and exchangers
Increases tower dP slowly
Defoamer Injection
FUNNEL
SMALL
VESSEL
CHEMICAL
PUMP
CONTINUOUS INJECTION
Where?
Liquid Treater
Flash Drum
Stripper / Regenerator
organic acids
condensed hydrocarbons
corrosion products
oil contamination (FCC)
chemical additives
Emulsification
Amine solutions have a low
emulsification tendency.
very polar, high surface tension solution
Emulsions occur from contamination.
reduces surface tension
increases viscosity
increases hydrocarbon solubility in amine
phase
Still sounds like foaming ...
Defoamer / Antifoam
amine insoluble
Injection Location
amine solution
Emulsion
oil in amine mixture
amine in oil mixture
Emulsion Breaker
amine insoluble or
oil insoluble
Injection Location
hydrocarbon feed
Acid Gas
Lean Amine
Rich Amine
Gas/Liquid
Out
CI
CP
DF
CP
Regenerator
dP
Absorber
Gas/Liquid
In
CP
CI
CP
CI
Reboiler
Stripper / Regenerator
Hot Lean Piping
Hot Rich Piping
Overhead Condenser
Why?
highest temperature
organic acids
acid gases (CO2)
amine degradation
Corrosion
Clean amine solutions are non-corrosive.
high pH
Corrosion occurs from contamination.
acids, acid gases and chelants (degraded
amine)
phase changes, temperature and velocity
increases with low H2S concentrations
Acidic Contamination
Common Acids
formic acid
acetic acid
oxalic acid
glycolic acid
thiocyanic
thiosulfurous
sulfuric
hydrochloric
Net Problem
Reacts with amine
reduces treating capacity
Heat Stable Salt
Foaming / Emulsions
Corrosion
lowers pH
amine-acid salt corrosive
Strong Acids
Hydrogen Cyanide (HCN)
Formic Acid
(HCOOH)
Acetic Acid (CH3COOH)
Oxalic
(HOOCCOOH)
Thiocyanic
(HSCN)
Other Corrosives
Acid Gases
Carbon Dioxide
very aggressive acid
increase CO2,
corrosion
Hydrogen Sulphide
promotes FeS scale
can reduce corrosion
avoid over stripping!
Amine Degradation
Thermal, oxygen or CO2
diamines chelate iron
organic acids
Ammonium Bisulfide
Concentrates in overhead
control to < 10,000 ppm
purge reflux to SWS
Process Variables
Phase Change
boiling, condensation, flashing
Temperature
Antoine's Equation
reactions rate doubles with each 10C increase
Velocity
physical damage + concentration effect
Corrosion Cycle
1 Corrosion in HOT areas.
Low H2S content
acids more aggressive
acids + amine = chelant
water soluble corrosion product
Corrosion Inhibition
Process Changes
increase amine wt%
restores capacity
increases pH
Chemical Changes
Filming Inhibitor
continuous injection
disperses solids
coats metal
reduce velocity
reduce acid concentrations
control acid
replace / reclaim amine
concentration
neutralize acids
reduce steam rate
remove solids - filtration
Absorbing H2S
Gas is physically and chemically
absorbed by amine.
Amount of gas absorbed
depends on:
Temperature
Pressure
Amount of H2S in amine
4 Possible Variables
1 Increase gas pressure!
Not possible
Pressure set by process
2 Increase amine
circulation rate!
Rate determines how
much not how pure.
3 Reduce temperature!
Reduce Lean Amine
Temperature.
Caution!
Too low a temperature may result in
FOAMING.
At lower temperature:
Amine viscosity increases.
Cold amine may condense feed gas.
(dT=+5C)
Regeneration
1 High Temperature
Reverses absorbtion
2 Steam
Stripping gas
3 Low Pressure
Reduces vapor
pressure
Caution!
1 Hydrocarbons
reduce top temperature, cause foaming.
Action Plan
Reduce H2S in treated gas by:
1
2
3
3
1
2
3
4
5
Amine Losses
Foaming +
Emulsification
condensing hydrocarbon
entrained hydrocarbon
contaminated LPG
solids
Entrainment
too much gas/liquid flow
knock out drum
Solubility
high amine
concentrations
amine type
House Keeping
filter changes
recovered amine
waste
Amine Losses
High Amine Losses Action Plan
1
2
3
4
5
7