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- Alkanes
1
Organic Chemistry
Organic Chemistry involves the study of Carbon
based compounds of which there are millions and
many more yet to be made
4
Formation of Carbons 4 covalent bonds
7
Structural Formulas
A single line represents one pair of
electrons (a single bond).
Molecular formula
Becomes: CH4O, C4H10, C2H4O2
10
Molecular Shape
When carbon is bonded to 4 other atoms carbon is at
the center of a tetrahedron and the 4 other atoms are
located at the corners.
This is known
As a
Tetrahedron
If there are 3 Cs
Bonded to each other
Then there are 3 joined
tetrahedrons 11
Vocabulary Interlude
Hydrocarbons: organic compounds
containing only Carbon and Hydrogen.
Straight chain: All internal C bonded to only 2
other Cs
Ex: c-c-c-c-c-c-c
Branched: One or more int. C bonded to 3 or 4
other Cs
Ex: c-c-c-c-c-c-c-c c
| | |
c c c-c-c
|
c
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Vocabulary
13
Vocabulary
Homologous Series: a group of
compounds with related structures and
properties.
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Primary Categories of Hydrocarbons
CH3-CH2-CH2 Hexane!
CH2-CH2-CH3
Is it a branched or straight chain hydrocarbon?
19
Properties of Alkanes
Physical Properties
Mol. M.P. B.P.
Change systematically
Formula
with the number of Cs
CH4 -182 -162
C2H6 -183 -89
As the number of Cs C3H8 -188 -42
In a homologous C4H10 -138 -0.5
series increases, the C5H12 -130 36
b.p. & m.p. increases. C6H14 -95 69
C7H16 -91 98
(Due to increasing Intermolecular force C H -57 126
8 18
in the form of temporary dipoles)
C9H20 -54 151 20
SIMPLE HYDROCARBONS
Draw the structural formula, condensed
structural formula and molecular formula
for the following:
propane
Octane