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Glass Manufacturing
Glass Manufacturing
• Quartz is crystalline
SiO2:
(soda glass)
Adapted from Fig. 12.11,
Callister, 6e.
Glass
• Glass composition determines properties
• noncrystalline
fiberglass 55 16 15 10 4 MgO
• Glasses:
--do not crystallize
--spec. vol. varies smoothly with T
--Glass transition temp, Tg
F A
dv dy dv dy
shear stress
velocity change with dis tan ce
http://www.pilkington.com/pilkington/corporate/english/education/float+process/default.htm
The Floating part
• Molten glass, at approximately 1000ºC, is poured
continuously from a furnace onto a shallow bath of molten
tin.
• It floats on the tin, spreads out and forms a level surface.
• Thickness is controlled by the speed at which solidifying
glass ribbon is drawn off from the bath.
• After annealing (controlled cooling) the glass emerges as a
'fire' polished product with virtually parallel surfaces.
HEAT TREATING GLASS
• Annealing:
--removes internal stress caused by uneven cooling.
• Tempering:
Chemical
--puts surface of glass part into compression
tempering is
--suppresses growth of cracks from surface scratches. also possible.
--sequence:
before cooling surface cooling further cooled
cooler compression
hot hot tension
cooler compression
Fabricating Glass in other shapes
GLASS
FORMING
• Pressing:
Pressing
Gob
operation
Parison
mold
• Blowing:
Adapted from Fig. 13.7, Callister, 6e. (Fig. 13.7 is adapted from C.J. Phillips,
Glass: The Miracle Maker, Pittman Publishing Ltd., London.)
‘Crizzling’
• Prolongued exposure to chemical attack
can lead to local microcracks, ‘Crizzling.’
• Eventually leads to failure.
Ceramic History
• In 221 BC during the Qing Dynasty, Qin Shi Huang was the
Emperor in reign. The Terra Cotta Army was built as a way
of creating an illusion of strength and manpower.
• Discovered in 1974.
en.wikipedia.org/wiki/Terracotta_Army
7000 ‘soldiers’ thus far discovered