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ISSUES TO ADDRESS...
• What are the classes and types of composites?
• What are the advantages of using composite
materials?
• How do we predict the stiffness and strength of the
various types of composites?
Chapter 16 - 1
Composite
• Combination of two or more individual
materials
Chapter 16 - 2
Terminology/Classification
• Composite:
-- Multiphase material that is artificially
made.
• Phase types:
-- Matrix - is continuous
-- Dispersed - is discontinuous and
surrounded by matrix
Chapter 16 - 3
Terminology/Classification
• Matrix phase: woven
-- Purposes are to: fibers
- transfer stress to dispersed phase
- protect dispersed phase from
environment
-- Types: MMC, CMC, PMC 0.5 mm
cross
metal ceramic polymer section
view
• Dispersed phase:
-- Purpose:
MMC: increase sy, TS, creep resist. 0.5 mm
CMC: increase KIc Reprinted with permission from
D. Hull and T.W. Clyne, An
PMC: increase E, sy, TS, creep resist. Introduction to Composite Materials,
2nd ed., Cambridge University Press,
-- Types: particle, fiber, structural New York, 1996, Fig. 3.6, p. 47.
Chapter 16 - 4
Classification of Composites
Chapter 16 - 5
Classification: Particle-Reinforced (i)
Particle-reinforced Fiber-reinforced Structural
• Examples:
- Spheroidite matrix: particles: Adapted from Fig.
cementite 10.19, Callister &
steel ferrite (a) Rethwisch 8e. (Fig.
(ductile) (Fe C) 10.19 is copyright
3 United States Steel
(brittle) Corporation, 1971.)
60 mm
Adapted from Fig.
- WC/Co matrix: particles: 16.4, Callister &
cemented cobalt WC Rethwisch 8e. (Fig.
16.4 is courtesy
(ductile, (brittle,
carbide tough)
: hard)
Carboloy Systems,
Department, General
Electric Company.)
600 mm
Adapted from Fig.
16.5, Callister &
- Automobile matrix: particles: Rethwisch 8e. (Fig.
tire rubber rubber carbon 16.5 is courtesy
Goodyear Tire and
(compliant) black Rubber Company.)
(stiff)
0.75 mm Chapter 16 - 6
Classification: Particle-Reinforced (ii)
Particle-reinforced Fiber-reinforced Structural
Prestressed concrete
- Rebar/remesh placed under tension during setting of concrete
- Release of tension after setting places concrete in a state of compression
- To fracture concrete, applied tensile stress must exceed this
compressive stress
150
0 20 40 60 80 10 0 vol% tungsten
(Cu) (W)
• Application to other properties:
-- Electrical conductivity, se: Replace E’s in equations with se’s.
-- Thermal conductivity, k: Replace E’s in equations with k’s.
Chapter 16 - 8
Classification: Fiber-Reinforced (i)
Particle-reinforced Fiber-reinforced Structural
• Fibers very strong in tension
– Provide significant strength improvement to the
composite
– Ex: fiber-glass - continuous glass filaments in a
polymer matrix
• Glass fibers
– strength and stiffness
• Polymer matrix
– holds fibers in place
– protects fiber surfaces
– transfers load to fibers
Chapter 16 - 9
Classification: Fiber-Reinforced (ii)
Particle-reinforced Fiber-reinforced Structural
• Fiber Types
– Whiskers - thin single crystals - large length to diameter ratios
• graphite, silicon nitride, silicon carbide
• high crystal perfection – extremely strong, strongest known
• very expensive and difficult to disperse
– Fibers
• polycrystalline or amorphous
• generally polymers or ceramics
• Ex: alumina, aramid, E-glass, boron, UHMWPE
– Wires
• metals – steel, molybdenum, tungsten
Chapter 16 - 10
Longitudinal
direction
Fiber Alignment
Adapted from Fig. 16.8,
Callister & Rethwisch 8e.
Transverse
direction
(a) fracture
surface
Chapter 16 - 13
Classification: Fiber-Reinforced (v)
Particle-reinforced Fiber-reinforced Structural
• Critical fiber length for effective stiffening & strengthening:
fiber ultimate tensile strength fiber diameter
sf d
fiber length shear strength of
2c fiber-matrix interface
• Ex: For fiberglass, common fiber length > 15 mm needed
• For longer fibers, stress transference from matrix is more efficient
Short, thick fibers: Long, thin fibers:
sd sd
fiber length f fiber length f
2 c 2c
c = composite
f = fiber
m = matrix
Chapter 16 - 15
Composite Stiffness:
Transverse Loading
• In transverse loading the fibers carry less of the load
c = composite
f = fiber
m = matrix
Chapter 16 - 16
Composite Stiffness
Particle-reinforced Fiber-reinforced Structural
Chapter 16 - 17
Composite Strength
Particle-reinforced Fiber-reinforced Structural
2l
2. When l < lc
l c
s cd *
Vf s m (1Vf )
d
Chapter 16 - 18
Composite Production Methods (i)
Pultrusion
• Continuous fibers pulled through resin tank to impregnate fibers with
thermosetting resin
• Impregnated fibers pass through steel die that preforms to the desired shape
• Preformed stock passes through a curing die that is
– precision machined to impart final shape
– heated to initiate curing of the resin matrix
Chapter 16 -
Composite Production Methods (ii)
• Filament Winding
– Continuous reinforcing fibers are accurately positioned in a predetermined
pattern to form a hollow (usually cylindrical) shape
– Fibers are fed through a resin bath to impregnate with thermosetting resin
– Impregnated fibers are continuously wound (typically automatically) onto a
mandrel
– After appropriate number of layers added, curing is carried out either in an
oven or at room temperature
– The mandrel is removed to give the final product
Adapted from Fig. 16.15, Callister & Rethwisch 8e.
[Fig. 16.15 is from N. L. Hancox, (Editor), Fibre
Composite Hybrid Materials, The Macmillan
Company, New York, 1981.]
Chapter 16 -
Classification: Structural
Particle-reinforced Fiber-reinforced Structural
• Laminates -
-- stacked and bonded fiber-reinforced sheets
- stacking sequence: e.g., 0º/90º
Adapted from
- benefit: balanced in-plane stiffness Fig. 16.16,
Callister &
Rethwisch 8e.
• Sandwich panels
-- honeycomb core between two facing sheets
- benefits: low density, large bending stiffness
face sheet
adhesive layer
honeycomb
resistance w/SiC
whiskers
10 -10
s(MPa)
20 30 50 100 200 Chapter 16 - 22
Summary
• Composites types are designated by:
-- the matrix material (CMC, MMC, PMC)
-- the reinforcement (particles, fibers, structural)
• Composite property benefits:
-- MMC: enhanced E, s, creep performance
-- CMC: enhanced KIc
-- PMC: enhanced E/r, sy, TS/r
• Particulate-reinforced:
-- Types: large-particle and dispersion-strengthened
-- Properties are isotropic
• Fiber-reinforced:
-- Types: continuous (aligned)
discontinuous (aligned or random)
-- Properties can be isotropic or anisotropic
• Structural:
-- Laminates and sandwich panels
Chapter 16 - 23
ANNOUNCEMENTS
Reading:
Core Problems:
Self-help Problems:
Chapter 16 - 24