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PRESENTATION…
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CONSTANT PRESSURE
IN TRODUCTION TO CONSTANT PRESSURE

 A constant pressure calorimeter measures the change in enthalpy of

a reaction occurring in a liquid solution.
 In that case the gaseous pressure above the solution remains
constant, and we say that the reaction is occurring under conditions
of constant pressure.
CONSTANT PRESSURE PROCESS

 An isobaric process occurs at constant pressure .since the pressure

is constant, the force exerted is constant and the work done is given
as p v.
 An isobaric expansion of a gas requires heat transfer to keep the
pressure constant,
PROCESS;

 Since the pressure is constant, the force exerted is constant and

the work done is given as PΔV. An isobaric expansion of a gas
requires heat transfer to keep the pressure constant. An isochoric
process is one in which the volume is held constant, meaning that
the work done by the system will be zero.
FORMULA:
HEAT CAPACITY AT CONSTANT PRESSURE

 For an ideal gas at constant pressure, it takes more heat to achieve the same temperature
change than it does at constant volume. At constant volume all the heat added goes into
raising the temperature. At constant pressure some of the heat goes to doing work.
 Q = nCPT
 For an ideal gas, applying the First Law of Thermodynamics tells us that heat is also equal
to:
 Q = Eint + W
 At constant pressure W = PV = nRT
T-S DIAGRAM:
P-v DIAGRAM :
 BOYLE’S LAW:

 Boyles Law Formula. Boyle's Law, an ideal gas law which states that the volume of an
ideal gas is inversely proportional to its absolute pressure at a constant temperature. The
law applies only to ideal gases which allow only pressure and volume to change.
CHARLE’S LAW;

 Charles' Law is a special case of the ideal gas law. It states that the volume of a fixed
mass of a gas is directly proportional to the temperature. This law applies to ideal gases
held at a constant pressure, where only the volume and temperature are allowed to
change.
Charle’S law:

Vi/Ti = Vf/Tf

where
Vi = initial volume
Ti = initial absolute temperature
Vf = final volume
Tf = final absolute temperature
DERIVATION…