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FINAL PROJECT
NUMERICAL METHOD
CASE 11
GROUP 11

DIVIANI PUTRI G NUR INDAH SHIFANI M. ADI WICAKSONO AGUS WAHYUDI


102317002 102317004 102317005 102317006
CASE 11
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Rate of reaction (Data literatur)

where
• K1 is equilibrium constant of first reaction

• p1 = partial pressure of ethyle benzene partial pressure component


• P2=partial pressure of styrene  
Pi = x Ptot
• P3= partial pressure of hydrogen
DATA
PROPERTIES

Initial feed (ethyl benzene): CATALYST DATA


0.00344 kmol/s
• 𝜌𝑐=2137 kg/m3
V PBR : 10.0 m3
P total : 2.4 atm
• ϕ= 0.4
Fsteam :Fethylbenzene= 14.5:1
Finert=0.00344 x 1000 x 14.5
= 0.04988
R=8.314 j/mol K
SPECIFIC HEAT (CP)
cp depend on temperature T ref AT 298,15 K
Enthalpy Each Component
(at 298,15K)
• H°f ethylbenzene = 29920 j/mol H°0 reaction1= Hf2+Hf3-Hf1
H° 0reaction 2= Hf4+Hf5-Hf1
• H°f styrene = 147360; H°0freaction 3= Hf6+Hf7-Hf3-
Hf1
• H°f hydrogen =0
• H°f butane =82930
• H°f ethylene = 52510 enthalphy reaction:
• H°f toluene =50170
• H°f metane = -74520
• H°f steam = -241818
Selectivity of styrene to benzene
toluene
  𝑠𝑡 = 𝑟 1
𝑆
𝐵𝑇 𝑟 2+𝑟 3
Design reactor
 
• Design equation
 
𝑑𝐹
=𝑟𝐴 Place Your Picture Here
𝑑𝑉
• Ethyl benzene = -r1-r2-r3;
• styrene = r1;
• hidrogen = r1-r3;
• benzene = r2;
• ethylene = r2;
• toluene = r3;
• methane = r3;
ENERGY BALANCE
Energy balance of multiple reaction in adiabatic PBR

Where Ua=0

𝑑𝑇  ((r1∗Hr1)+(r2∗Hr2)+(r3∗Hr3))∗(298− T)
=
𝑑𝑉 )/((Fi∗cpi)+(F(1)∗cp1)+(F(2)∗cp2)+(F(3)∗cp3)+(F(4)∗cp4)+(F(5)∗cp5)+(F(6)∗cp6)+(F(7)∗cp7));  
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TEMPERATURE 1300 K Dengan


V=50m3
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TEMPERATURE 1100 K Dengan


V=10m3
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TEMPERATURE 930 K Dengan


V=10m3
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TEMPERATURE 800 K Dengan


V=10m3
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