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Introduction: Semiconductor
Materials that permit flow of
electrons are called conductors (e.g.,
gold, silver, copper, etc.).
Materials that block flow of
electrons are called insulators (e.g.,
rubber, glass, Teflon, mica, etc.).
Materials whose conductivity falls
between those of conductors and
insulators are called
semiconductors.
Semiconductors are “part-time”
conductors whose conductivity can
be controlled.
Cont’d….
Germanium(Ge) and Silicon(Si) are example of
semiconductor materials that are neither
conductor nor insulators.
Their electrical conductivity is between that of a
conductor and insulator.
When isolated germanium and silicon atoms
have four valence electrons(i.e. electrons in the
outer orbit).
Doping
For a semiconductor material to have the
properties needed to work in electronic
components, impurities are usually added.
The impurities cause the material to conduct
currents in certain ways.
The addition of an impurity to a semiconductor is
called doping.
Sometimes the impurity is called a dopant.
Donor impurities
When an impurity contains an excess of electrons, the
dopant is called a donor impurity.
Adding such a substance causes conduction mainly by
means of electron flow, as in a metal like copper.
When a substance with pentavalent impurities such as
phosphrus,arsenic or antimony is added to a
semiconductor, the material conducts by means of
electron flow.
The excess electrons are passed from atom to atom when
a voltage exists across the material
A material with a donor impurity is called an N type
semiconductor, because electrons have negative charge.
Acceptor impurities
If an impurity has a deficiency of electrons, the
dopant is called an acceptor impurity.
When a substance with trivalent impurities such
as aluminium, boron, gallium, or indium is added
to a semiconductor, the material conducts by
means of hole flow.
A hole is a missing electron.
A material with an acceptor impurity is called a
P-type semiconductor, because holes have
positive charge.
Majority and Minority charge carriers
Charge carriers in semiconductor materials are either:-
electrons, which have a unit negative charge, or
holes, having a unit positive charge.
In any semiconductor material, some of the current is in
the form of electrons passed from atom to atom in a
negative-to-positive direction.
Some current occurs as holes that move from atom to
atom in a positive-to-negative direction.
In an N-type semiconductor, most of the current flows as
electrons passed from atom to atom.
The flow of current in a P-type material is better imagined
as a flow of electron absences, not electrons.
Cont’d….
The absences, called “holes,” move in a direction
opposite that of the electrons.
When the two types of material are brought together, the
P-N junction develops properties that make the
semiconductor materials truly useful as electronic
devices.
The N-type semiconductor is represented by the short,
straight line in the symbol, and is called the cathode.
The P-type semiconductor is represented by the arrow,
and is called the anode.
Diode
A diode is a two- terminal electronic component
that conducts current primarily in one direction.
This effect is used for rectification when the
positive part of an AC-signal can pass while a
negative part is blocked.
It has low (ideally zero) resistance in one
direction, and high (ideally infinite) resistance in
the other.
Diode
A diode is a semiconductor device which conducts
only in one direction.
A diode has two different terminals.
The positive electrode is called anode and the
negative electrode is called cathode.
Symbol of diode
What's a diode made from?
Diode is made from Semiconductors
The energy levels of a semiconductor can be
modified so that a material (e.g. silicon or
germanium) that is normally an insulator will
conduct electricity.
Material Example Resistivity (𝞨-cm)
Conductor Copper 1.56x
Semiconductor Silicon -
Insulator Ceramics -
How do we turn a semiconductor into a
conductor?
By doping it!
Doping is a process where impurities are added to
the semiconductor to lower its resistivity.
Silicon has 4 electrons in its valence level
We add atoms which have a different number of
valence shell electrons, 3 or 5 to a piece of silicon.
Phosphorus(P), Arsenic(As), Antimony(Sb) have 5
valence electrons
Boron(B), Aluminum (Al), Indium(In) have 3
valence electrons
Cont’d…..
N-type silicon:
• Adding atoms which have 5 valence electrons
makes the silicon more negative.
• The majority carriers are the excess electrons.
P-type silicon
• Adding atoms which have 3 valence electrons
makes the silicon more positive.
• The majority carriers are "holes".
• A hole is the lack of an electron in the valence
shell.
Cont’d….
Anode Cathode