GENERAL CHEMI S TRY

2:

ENTHALPY
 WHAT IS
ENTHALPY?
 ENTH A LP Y
I t is d e fin e d a s th e s u m o f th e in te rn a l e n e rg y
a n d the p r o d u c t of the p r e s s u r e an d volume.

H = U + P V

SUM o f INTERNAL ENERGY a n d th e PRO DUC T O F PRESSURE AND V O LUM E

.
 ENTH A LP Y
Δ = ΔU + PΔ
H V

C ha nge
C ha nge in
W or k d one
in b y the
enthalpy i nt ern al
system
( Heat a d d e d or energy
re m o v e d fro m
th e s y s t e m )
ENTH A LP Y
W = - PΔ
V

ΔU = Q + W
ΔU = Q - PΔ
V
+ PΔ
ΔH = Q - PΔ V
V
Δ H = Qp
 ENTH A LP Y
Th e h e at i s ab so r b e d o r gi v e n o f f b y a
sy st e m u n d e r t h e c o n d i t i o n constant
o f pressure.

I f ΔH i s > 0 = E N D O TH E R M IC
If ΔH = EXOTHERMIC
is < 0
 P R OB LEM
An ideal gas e x p a n d s f r o m a v o l u m e of 6
d m ³ t o 16 d m ³ against c o n s t a n t e x t e r n a l
p r e ssu r e o f 2 . 0 2 6 x 10 ⁵ N/ m ². Fi n d
t h e e n t h a l p y change i f ΔU is 418 J.
 P R E P A R E D BY:

FROILAN MANGULABNAN II
STEVEN INALIGO
LLIANE RHAFAEL
LEODONES11 S TE M -
PEACE
 S U B M I T T E D TO:

MR. BENIGNO
LORENZO
THANK YOU FOR
LISTENING!