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Ideal Gas Equation

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Universal gas constant
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Ideal gas equation in terms of density
I
Question
For an ideal gas if the Molar mass of a gas is 32g/mol find the density of a gas if
the pressure is 4 atm at 27ᵒC
Combined ideal gas equation
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Question
At 27ᵒC and 1atm a gas has a volume of 5L what will be the volume at 177ᵒC
and 1.5 atm [ JEE Mains 2016]
2. For a given mass of gas if pressure is reduced to half and temperature is doubled
then volume of a gas will become
3. The density of O2 is lowest at [ JEE Mains ]
(a) 2atm and 273 K
(b) 1atm and 273 K
(c) 1 atm and 293 K
(d) 2 atm and 293 K
Dalton law of partial pressure
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Questions :
Find the partial pressure of each gas when 6 gm of H2 and 44g of CO2 are mixed in a
container at 10 atm Total pressure
2. Find fraction of total pressure exerted by each gas when 16g of SO2 is mixed with 56g. Of
N2 in the container [ JEE MAINS 2018]
2. Equal weight of 1 gm of ethane and hydrogen are mixed in an empty container at 25 ᵒc The
fraction of total pressure exerted by hydrogen gas is [ JEE Mains 1993]
Grahm’s Law of diffusion
Rate of diffusion is defined as number of moles or volume of gas diffused in unit
time
Questions
1. The rate of diffusion of He , CH4 and SO4 gas
2. The rate of diffusion of unknown gas is 1.73 times smaller than rate of
diffusion of O2 find the molar mass of unknown gas [ IIT JEE]
Meaning of rate of diffusion
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Question
1. 20 ml of O2 is diffuse in 10 sec find the volume of H2 gas diffuse in 20 sec
2. If 24 g of H2 gas is diffuse in 5sec find the mass of O2 diffuse in 5 sec [ JEE
MAINS 2013]
3. A football bladder contains 4:1 mole ratio ( n1 : n2) of H2 and O2 find the
composition by weight ( w1: w2) effusing out of punctured ball
[ JEE Mains ]
Kinetic theory of gas
Posulates :
1. molecules of same gas are identical to each other ( shape , size, mass)
2. All the collision of gas molecule and with the walls of container are elastic in nature
3. Molecules are random motion in straight line
4. The pressure of gas is due to collision of molecule with the wall of container
5. Kinetic energy of a gas only depend on temperature
6. The volume of gas molecule is negligible as compared to total volume of
a gas
7. There is no intermolecular force of attraction between the molecules
Calculation of Kinetic energy for an ideal gas
Question:
1. Find the Kinetic energy of a ideal gas if the temperature is increase by 100
2. Find the kinetic energy of 1 molecule at 50ᵒ C
Different kind of velocity for gas molecule

Most Probable velocity:

Average speed
Root mean square speed velocity
1. The temperature at which oxygen molecules have the same root mean square speed as helium
atoms have at 300 K is : [ 1986 JEE ]
(Atomic masses : He = 4 u, O = 16 u)
(1) 1200 K
(2) 600 K
(3) 300 K
(4) 2400 K

2. By how many folds the temperature of a gas would increase when the root mean Square velocity
of the gas molecules in a container of fixed volume is increased from 5×10 4 cm/s to 10×104 cm/s?
(1) Four
(2) three
(3) Two
(4) Six
3. The average velocity of gas molecule at 27ᵒ C is 0.3m/s The average velocity at
927ᵒ C will be [1989 JEE]
A. 0.6 m/s
B. O.3 m/s
C. 0.9 m/s
D. 3 m/s
Maxwell distribution curve

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