| |

| | ts reac
products
n
RT
E E
o
tan
log
303 . 2

=
| |
| | ts reac
products
n
RT
E E
o
tan
ln

=
+
2
1
ln
2
H
o
a
RT
E E ( )
2
ln 1 ln
2
+

=
H
o
a
RT
E E
( )( )
+

=
H
o
a
RT
E E ln 2
2
| | | |
+ +
= =
H H
a a pH log 303 . 2 ln
pH
RT
E E
o

+ =
303 . 2
+

=
H
o
a
RT
E E log
303 . 2
+
=
H
o
g
a E E log 0592 . 0
m m a a
H
+
= = =
m E E
o
g
log 0592 . 0 log 0592 . 0 =

m 511 . 0 log =

m m E E
o
g
log 0592 . 0 03025 . 0 + =
m E m E
o
g
03025 . 0 log 0592 . 0 + = +
o
g
E

+
H
a


-
m
o
g
E

+
H
a


-





















-
-
-

-
-
-
I z z A
+
= log
m 511 . 0 log =

( )
q p
q p
q p q p
m a
m a
+


+

=
=
1

( ) ( ) | |
q p
q p
qm pm m
+

=
1
| |
q p q p
m q p m
+

=
1
( )
q p
q p
+
+
=
1




0.0071659M
1000
1
41
2 . 204
06 . 0
,
=
|
.
|

\
|
|
|
.
|

\
|
=
|
.
|

\
|
=
mL
L
mL
g
V
MM
mass
M
mol
g
NaOH L
KHP
NaOH

M .
M . M .
M M
Ave
,NaOH ,NaOH
NaOH
008683645 0
2
0102014 0 0071659 0
2
2 1
=
+
=
+
=


( )
mol mol
molNaOH
molHCl
mL
L
mL . mol
molNaOH
molHCl
MV mol
HCl
L
mol
HCl
NaOH HCl
0.00462
1
1
1000
1
6 . 14 008683645 0
1
1
=
|
.
|

\
|
|
.
|

\
|
=
|
.
|

\
|
=

0.00462g
458 . 36 0.00013
=
=
=
HCl
mol
g
HCl
HCl HCl HCl
mass
mol mass
MM mol mass

( )
mL
g
solution
mL
g
mL
g
solution
mL
g
solution
O H
water
solution
solution
g g
g g
mass
mass
0.998074
99704 . 0 1.00103734 99704 . 0
64 . 9
9.65
99704 . 0
03 . 15 67 . 24
03 . 15 68 . 24
2
=
= |
.
|

\
|
=

|
|
.
|

\
|

=
|
|
.
|

\
|
=

9.981g
10 0.998074
=
=
=
aliqout
mL
g
aliqout
aliqout
aliqout
aliqout
mass
mL mass
V mass



g mass
g g mass
mass mass mass
water
water
HCl aliqout water
976 . 9
000462 . 0 981 . 9
=
=
=

( )
kg
g mol
g
water
HCl
HCl
g
kg
g
.
g
mass,kg
MM
mass,g
m 0.01271
1000
1
976 . 9
458 36
0.00462
=
|
|
.
|

\
|

|
|
.
|

\
|
=
|
.
|

\
|
=

o
g
E

( )
( ) | |
0.530
0592 . 0
0.00087 log 0592 . 0 0.0001360 1973 . 0
log
0592 . 0
log 0592 . 0
log
=

=

=

anti
m E E
anti
o
g

+
H
a
0.0004617 0.00087 0.530 = =
=
+
+
H
H
a
m a