CONFIDENTIAL*/SULIT*

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962/1

EXCEL 2

CHEMISTRY (KIMIA)

JABATAN PELAJARAN SABAH EXCEL 2 2011

Instructions to candidates: DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE TOLD TO DO SO. There are fifty questions in this paper. For each question, four suggested answers are given. Choose one correct answer and indicate it on the multiple-choice answer sheet provided. Read the instructions on the multiple-choice answer sheet carefully. Answer all questions. Marks will not be deducted for wrong answers. Arahan kepada calon: JANGAN BUKA KERTAS SOALAN INI SEHINGGA ANDA DIBENARKAN BERBUAT DEMIKIAN Ada lima puluh soalan dalam kertas ini. Bagi setiap soalan, empat cadangan jawapan diberikan. Pilih satu jawapan yang betul dan tandakan jawapan itu pada helaian jawapan aneka pilihan yang dibekalkan. Baca arahan pada helaian jawapan aneka pilihan itu dengan teliti. Jawab semua soalan. Markah tidak akan ditolak bagi jawapan yang salah. ______________________________________________________________________________ This question paper consists of 13 printed pages. (Kertas soalan ini terdiri daripada 13 halaman bercetak.) 962/1 CONFIDENTIAL*SULIT*

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Section A Four suggested answers labeled A, B, C, and D are given for each question. Choose one correct answer. 1. Mass spectrometers separate isotopes of different elements based on their A mass B electric charge C mass divided by electric charge D abundance The electronegative of five elements are given below : Element Electronegative P 0.7 Q 1.1 R 1.6 S 2.6 T 1.7

2.

Which of the following bonds has the lowest ionic character? A PS B QT C PQ D RT 3. The modern periodic table is given by A Mendeleev B Einstein C Bohr D Moseley The transition of an electron from a 4s orbital to 1s orbital in hydrogen atom causes A a Balmer line B a Lyman line C increases in kinetic energy of electron D conversion of H+ to H atom A 5.82 g of silver coin is dissolved in nitric acid when sodium chloride is added to the solution. All the silver is percipitated as AgCl. Percipitate weighs 7.20 g. What is the percentage of silver in the coin? A 98.2% B 93.1% C 86.4% D 82.3% An element X has the outer ground state electronic configuration ns2 np5. Which statement about X is incorrect? A Compared to other elements in its period, X has a relatively low first ionisation energy. B X forms an X1 ion. C X forms diatomic molecules. D X is in group 17.

4.

5.

6.

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7. The Pauli Exclusion Principle limits the number of electrons that can occupy an orbital to A 1 B 2 C 3 D 4

8.

Which of the following best explains this phenomenon? A Heating the gas reduces its pressure. B Heating the gas decreases its density. C Heating the gas decreases its molecular motion. D Heating the gas reduces the frequency of the gas molecules collisions. 9. Which of the following is an example of nuclear fusion? A Hydrogen-1 and hydrogen-2 combine to form helium-3. B Polonium-210 decays into lead-206 and an alpha particle. C Carbon-14 breaks down into a beta particle and nitrogen-14. D Uranium-235 and a neutron produce barium-141, krypton-92, and three neutrons. The state of hybridisation of sulphur in SO2 is same as that of sulphur in A SCl2 B SO3 C SO42 D SF4 Which of the following statement is correct? A Polarisation of an anion is maximum by high charged cation. B Small sized cation minimises the polarisation. C Small anion brings about a large degree of polarisation. D A small anion undergoes a high degree of polarisation. A mixture of iron and steam is allowed to reach equilibrium at 800 K: 3Fe(s) + 4H2O(g) Fe3O4(s) + 4H2(g) The equilibrium pressures for hydrogen and steam are 3.5 kPa and 2.4 kPa

10.

11.

12.

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respectively. The equilibrium constant, Kp, for the reaction is A 4.5 B 1.45 C 9.0 D 6.0 13. Hydrogen and carbon dioxide react as represented by the equation: H2(g) + CO2(g) CO(g) + H2O(g) When 4 mol of hydrogen and 0.9 mol of carbon dioxide were used for this reaction, 0.1 mol of CO2 was found in the equilibrium mixture. Calculate Kc for the experiment. A 0.2 B 2.2 C 0.8 D 2.0 In the following reaction, H2O(l) + NH3(g) water acts as a A Bronsted-Lowry acid B Bronsted-Lowry base C conjugate acid D conjugate base NH4+(aq) + OH(aq)

14.

15.

Iodine reacts with propanone in the presence of dilute acids as represented by the following equation: I2 + CH3COCH3 HI + ICH2COCH3 The graph of the concentration of iodine in the reaction mixture measured at regular time intervals is given as follows

Based on the graph, which of the following statements is true of the reaction above? A The rate of reaction is inversely proportional to [I2]. B The rate-determining step in the reaction mechanism is independent of I2. C The reaction is first order with respect to I2. D The half-life of the reaction is a constant. 16. The table below shows the result of an experiment for the reaction at 25 C. X(aq) + Y(aq) Z(aq)

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What is the rate equation for the reaction? A Rate = k [X]3 [Y]2 B Rate = k [X]3 [Y] C Rate = k [X]2 [Y] D Rate = k [X] [Y] 17. How many electrons are required to deposit 6.35g of copper at the cathode in the electrolysis of aqueous copper (II) sulphate? [Relative atomic mass of Cu = 63.5, L = Avogrado number] A 6.35L B L__ 6.35 C D Lx 6.35 63.5 L x (2 x 6.35) 63.5

18

The solubility of the Group 2 sulphates decrease with increasing proton number of the Group 2 elements because A. The lattice energy of the sulphates decreases B. The second ionization energy of the sulphates decreases C. The ionic character of the sulphates increases D. The hydration energy of the cations decreases

19

The substance formed when excess aqueous sodium hydroxide is added to aqueous aluminum sulphate is A. [Al(OH)3Cl3] B. [Al(H2O)2(OH)4]C. [Al(OH)6]3D. [Al(H2O)6]3+ Which one of the following properties decreases on descending Group 14 of the Periodic Table? A. The acidity of the oxides B. The stability of the +2 oxidation state C. The electric conductivity of the elements D. The ionic character of the oxides

20

21

Which of the following best explain the decreasing thermal stability of the +4 oxidation state on going down the Group 14 elements? A. The metallic property of the elements increases B. The size of the atoms increases C. The ionization energy increases D. The screening effect increases

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22 In which of the following compound stated below , nitrogen exhibits the highest oxidation state? A. NH3 B. N2O5 C. HNO2 D. N2H4

23.

The structural formula of ethyl 2-methylpropanoate is

CH 3 O O C CH 2 CH 3 O C O CH 2 CH 3

H3 C

C H CH 3

H3 C

C H

O
C

H2 C CH 3

CH 2

C O
O C O H C CH 3 CH 3

CH 2 CH 3

CH 3 CH 2

24.

Refer to the following reaction sequence:

COCH3 Step 1

COCH 3 Step 2 NO 2

CH(OH)CH 3

NO 2 Step 3

CH

CH 2 Step 5 NHCOCH 3

CH

CH 2 Step 4 NH 2

CH

CH 2

NO 2

Which one of the following types of reaction is not involved in the above

7
sequence? A acylation B oxidation C reduction D dehydration 25. Refer to the following reaction sequence:

COCH3 Step 1

COCH 3 Step 2 NO 2

CH(OH)CH 3

NO 2 Step 3

CH

CH 2 Step 5 NHCOCH 3

CH

CH 2 Step 4 NH 2

CH

CH 2

NO 2

Which one of the following types of reaction mechanism is not involved in the above sequence? A electrophilic addition B electrophilic substitution C additionelimination D elimination

26. Hydrolysis of the ester, CH3COOCH2CH2CH3, produces ethanoic acid. In an experiment, 2.04 g of the ester was used and 0.90 g of ethanoic acid was produced. What is the percentage yield of ethanoic acid? A 44 B 59 C 75

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D 90

27. An excess of methanol was mixed with 12 g of ethanoic acid and an acid catalyst. At equilibrium the mixture contained 8 g of methyl ethanoate. The percentage yield of ester present was A 11 B 20 C 54 D 67 28. Refer to the following reaction sequence:

COCH3 Step 1

COCH 3 Step 2 NO 2

CH(OH)CH 3

NO 2 Step 3

CH

CH 2 Step 5 NHCOCH 3

CH

CH 2 Step 4 NH 2

CH

CH 2

NO 2

Which one of the following would be the most appropriate to carry out Step 2? A H2/Ni B Sn/HCl C LiAlH4 D Fe/HCl 29. When gas X reacts with Y, a mixture of CH2BrCH2Br and CH2BrCH2OH are produced. X and Y are probably X Y A ethene bromine water B ethene sodium bromide solution

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C D HBr (g) Br2 vapour ethene ethene

30.

Consider the following reaction: X + CH3Cl Cl X

The benzene derivative reacts slower than benzene. X is most likely to be the A 31. Cl atom group B SO3H group C CH3CH2 group D NO2

The compound C3H7Br undergoes a series of reactions as show below. KCN in ethanol C3H7Br Boil What is the product Y? A C CH3CH2CH2CN CH3CH2CH2CH2 NH2 B D CH3CH2CH2NH2 CH3CH2CH2COOH X 150 C H2/ Pt Y

32.

Which of the following does not occur when Freon-12 (CF2Cl2) molecules collide with ozone molecules in the stratosphere? A C CF2Cl2 CFCl2 + F Cl + O3 O2 + ClO B D CF2Cl2 CF2Cl + Cl ClO + O Cl + O2

33.

22.5 cm3 of 0.4 moldm-3 bromine water is needed to react completely with an aqueous solution of phenol. The relative molecular mass of phenol is 94. What is the mass of phenol in the given solution? A 0.141 g *B 0.282 g C 0.564 g D 0.846 g

34.

Phenylmethanol is shaken with excess deuterium oxide (D2O ). How many hydrogen atoms per molecule of phenymethanol will be replaced by the deuterium atom? A 1 B 3 C 5 D 8

35.

Ethanal differs from other aldehydes in its reaction with which of the following reagents? A B C Fehlings solution Alkaline iodine solution Acidified potassium dichromate(VI) solution

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D Hydrogen in the presence of a nickel catalyst.

36.

An organic compound. P has the formula shown below.

=O Compound P A B C D 37. is an aromatic compound. can be reduced to a primary alcohol. undergoes oxidation to form a carboxylic acid. gives a yellow precipitate with 2,4-dinitrophenylhydrazine.

When compound X is oxidized with acidified potassium dichromate (VI), compound Y is formed. Both compound X and Y contains the same number of carbon atoms per molecule. When X reacts with Y under suitable conditions, a compound with a sweet fruity smell is produced. X is most likely to be A propanal B propanoic acid C propan-1-ol D butan-2-ol

38. Which reagent will react with both ethanol and phenol? A B C D Bromine water Sodium hydroxide Ethanoyl chloride Acidified potassium manganate (VII) solution

39. A substance, amigdalin present in almond gives it a distinctive delicious flavour when hydrolysed to form compound X. Compound Y and Z will be produced by continuous hydrolysis of X. The reaction scheme is shown below. C6H5 Hydrolysis Amigdalin + Z C OH continuous hydrolysis Y

H CN Compound X What could Y and Z be respectively? A B C D C6H5CH(OH)COOH and NH3 C6H5CH2OH and NH3 C6H5COOH and NH3 C6H5OH and CH3CN

40. Which of the following reagents is unsuitable to be used to differentiate the two compounds?

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O C6H5 C H A B C D Iodoform test Tollens reagent Fehlings solution Mass spectrometer Section B For each of the questions in this section one or more of the three numbered statements 1 to 3 may be correct. Decide whether each of the statements is or is not correct. The responses A to D should be selected on the basis of the following. A 1 only is correct B 1 and 2 are correct C 2 and 3 only are correct. D 1 , 2, and 3 are correct. and O C6H5 - C CH3

41. Which of the following statements are correct? In crystalline solids, particles are held rigidly together by strong attractive 1 forces in a three dimensional orderly structure called the lattice structure 2 3 In amophous solids the particles are not arranged in an orderly fashion All solids are denser than liquids

42. Which of the following species do not have a tetrahedral shape? 1 2 3 PH4+ ICl4 XeF4

43. Which of the following statements are true for hydrogen bonding? 1 2 3 It is cause for the high melting of water It is responsible for ice being less dense than water It is responsible for the high enthalpy of vaporisation of water

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A 1 only is correct B 1 and 2 are correct C 2 and 3 only are correct. D 1 , 2, and 3 are correct.

44. The diagram below shows the vapour pressure-composition graph for the ideal mixture of benzene and toluene at 20oC.

Which of the following statements is true of a mixture which contains 40 % of benzene at 20oC? 1 2 3 The partial vapour pressure of benzene is 4.0 kPa The partial vapour pressure of toluene is 1.8 kPa The partial vapour pressure of the mixture of benzene and toluene is 13 kPa

45. The e.m.f of the cell

Pt(s) / H2(g) , H+(aq) // Zn2+ (aq) / Zn (s)

depends on the 1 2 3 46. pressure of the hydrogen gas. concentration of the H+ ions. concentration of the Zn2+ ions

Which of the following statements about PbCl4 are correct? 1 2 3 Its molecule is tetrahedral in shape It is a liquid at room temperature It readily decomposes to Pb and Cl2 on heating

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A 1 only is correct B 1 and 2 are correct C 2 and 3 only are correct. D 1 , 2, and 3 are correct.

47.

In which of the following reactions does ammonia react as a base? Formation of a blue precipitate when ammonia gas is bubbled through 1 aqueous copper(II) sulphate(VI) 2 3 Reaction of ammonia gas with excess chlorine to form nitrogen trichloride Formation of a dark blue solution when excess aqueous ammonia is added to solid copper(II)hyroxide

48.

Malic acid , HOOCCH(OH)CH2COOH is found in apples. Which of the following is true about malic acid? 1 2 3 It has one chiral centre It has a secondary alcohol It form esters with ethanoic acid or with ethanol

49.

Ethyl butanoate is used as an artificial pineapple flavoring. Which of the following pairs can be used to produce the ester? 1 2 3 CH3CH2CH2COOH and CH3CH2OH CH3CH2CH2COCl and CH3CH2OH CH3CH2COOH and CH3CH2CH2OH

50. Which of the following react with both phenylamine and aminocyclohexane? 1 2 3 Ethanoyl chloride Bromine water Sodium hydroxide