ALCOL BEO

1. Goi ten

3-methyl-4-heptanol

2,3-butandiol

2-methyl-1,2,3-propantriol 2-methylglycerin

3-penten-2-ol

2-butyn-1,4-diol

1,2-propandiol
2

2. Viet cong thc:

2,2-dimethyl-1,3-butandiol trimethylcarbinol Alcol tert-amylic

Isopropyl tert-butylcarbinol

2-methyl-3-butyn-2-ol

4,4-dimethyl-1-penten-3-ol

methylisobutylcarbinol

Alcol allylic

7. T CH3CH2CH2OH ieu che CH3CH2-O-CH(CH3)2

8. ieu che cac dung moi

a.
CH3CH2ONa
ClCH2CH2OH

CH3CH2OCH2CH2OH

Na

CH3CH2OCH2CH2ONa
ClCH2CH2OH

b.
C6H5ONa
ClCH2CH2OH

CH3CH2 O CH2CH2 O CH2CH2OH

C6H5OCH2CH2OH

Na

C6H5OCH2CH2ONa
ClCH2CH2OH

C6H5 O CH2CH2 O CH2CH2OH

c.
CH2 CH2 OH OH
O

HO CH2CH2 O CH2CH2 OH
5

9. ieu che 2-pentanol t 1-pentanol

10. T 1,2-dibromobutan ieu che 2-butanol

11. ieu che ethyl acetat t cac chat vo c

12. T ethanol ieu che methyldiethylcarbinol

13. Viet s o chuyen hoa ch dung tac nhan vo c a. T propylen thanh dimethylisopropylcarbinol

10

13. b. T butylen thanh 3,4-dimethyl-3-hexanol

11

14. T propylen va ethylen ieu che methylisopropylcarbinol

12

14. T propylen va ethylen ieu che dimethylethylcarbinol

13

15. Dung chat ban au la acetylen ieu che a. butanol

HC CH
1) 2)

Na

C2H5Br

HC C C2H5

H2/Ni

CH3CH2CH2CH3
NaOHdd

Cl2/as

CH3CH2H2CH2OH

CH 3CH 2CH 2CH 2Cl

Hoac:

14

b. propanol
HC CH
1) 2)

Na CH3I

HC C CH3

H2/Ni

CH3CH2CH3

Cl2/as

CH3CH2CH2Cl
NaOH dd

CH3CH2H2OH

Hoac:

15

16. Hp chat carbonyl nao khi tac dung LiAlH 4 cho cac alcolsau:

benzaldehyd

Alcol benzylic

acetophenon

methylphenylcarbinol

cyclohexanon

cyclohexanol

16

17. Viet phan ng cua butanol vi

17

18. Hoan thanh chuoi phan ng va goi ten san pham

3-methyl-1-buten A

2-iodo-3-methylbutan B

D C 2,3-dihydroxy-2-methylbutan 2-methyl-2,3-butandiol 2-methyl-2-buten

18

19. T chat vo c ieu che

a. 2-butanol

CaC2

b. triethylcarbinol

19

20. Viet phan ng ieu che trinitroglycerin, neu ng dung

trinitroglycerin Gian mach, tr au that ngc

20

21. C che phan ng kh nc testosterol trong moi trng acid

H3COH H H3C O
+

CH3
H3O+

H 3C O

OH H H3C
H+

OH H 3C 2 H
H2O

H 3C

H
+

CH3
+

H
H+

CH3

21