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JEE Mains Chemistry Model Paper 3

CHEMISTRY
41. If the shortest wavelength of H atom in Lyman series is x, the longest wavelength in the Balmer series of He+ would be x 5x (a) (b) 4 9 9x 36 x (d) (c) 5 4 Which of the following equilibrium will shift left on increasing temperature. H2(g) + 1/2O2(g) (i) H2O(g) (ii) CO2(g) + C(s) CO(g) (iii) C(s, diamond) C(s, graphite) (a) Only (i) (b) Both (i) and (ii) (c) Only (iii) (d) None of these Which of the following solution has the highest solubility of AgBr? (a) 10 3 M NaBr (b) 10 3 M NH4OH (c) Pure water (d) 10 3 M HBr The kinetic energy of two moles of N2 at 27C is (a) 5491.6 J (b) 6491.6 J (c) 7482.6 J (d) 8882.4 J A galvanic cell is composed of two hydrogen electrodes of which cathode is a standard hydrogen electrode. In which of the following solutions should the other half cell be immersed to get maximum EMF? (a) 0.1 M C6H5CO2H (b) 0.1 M CH3CO2H (c) 0.1 M HCO2H (d) 0.1 M H2C2O4 If equal volumes of 1 M KMnO4 and 1 M K2Cr2O7 solutions are allowed to oxidise Fe(II) to Fe(III) in acidic medium, then Fe(II) oxidised will be (a) more by KMnO4 (b) more by K2Cr2O7. (c) equal in both the cases. (d) cant be determined. Which one of the following will have the highest coagulating power for a ferric hydroxide solution? (a) NaCl (b) BaCl2 (c) K2CrO4 (d) K3[Fe(CN)6]

42.

43.

44. 45.

46.

47.

48.

The number of neutrons accompanying the formation of 54X139 and 38Sr94 from the absorption of slow neutron by 92U235 followed by nuclear fission is (a) 0 (b) 2 (c) 1 (d) 3 Achiral stereoisomers, which have chiral centres and possess a symmetry plane are called (a) d (b) l (c) d and l (d) meso For the following,

49. 50.

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www.myengg.com CH3Cl CH3CH2Cl (CH3)2CHCl (CH3)3CCl (a) (c) 51.

o o o o

JEE Mains Chemistry Model Paper 3 ;

o

CH 3 + Cl

H1

CH 3 CH 2 + Cl ;

H2
H3
o
o

(CH3)2CH+ + Cl ;

(CH 3 ) 3C + Cl ;
H3 >
o

H4
(b) (d)

The correct order of enthalpies of ionization is

H1 > H 2 > H1 > H 2 >

H4 H4
o

H1 < H 2 < H1 > H 2 <

o o

H3 <
o

H4
o

H3 <

H3 < H4

The reaction of CH3CH=CH (a) CH3CHBrCH2

OH with HBr gives mainly OH

(b) CH3CH2CHBr

om

OH

(c) CH3CHBrCH2

Br

g. c

(d) CH3CH2CHBr

Br

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www.myengg.com 52.

JEE Mains Chemistry Model Paper 3

Consider the following reaction:

H3C CH CH CH3 + Br D CH3

.

X + HBr
.

(a) H3C CH CH CH2

D
.

(b) H3C CH C CH3

D
.

CH3

CH3

(c) H3C C CH CH3

D CH3

(d) H3C CH CH CH3

CH3

53.

When cinnamic acid is nitrated, the incoming electrophile ( NO 2 ) goes at (a) ortho position only (c) meta position only (b) para position only (d) both ortho and para positions

54.

55.

56.

58.

59.

60.

57.

OH NH2 Which of the following compounds has colour but no unpaired electrons? (a) KMnO4 (b) K2MnO4 (c) MnSO4 (d) MnCl2 Molar heat capacity of water in equilibrium with ice at constant pressure is (a) zero (b) infinity 1 1 (c) 40.45 kJ K mol (d) 75.48 kJ K 1 mol 1 The standard enthalpy of formation of water is numerically equal to (a) zero (b) standard molar enthalpy of combustion of hydrogen. (c) sum of standard molar enthalpies of formation of H2 and O2. (d) 2 HO H An aqueous solution of 6.3 g oxalic acid dihydrate is made up to 250 ml. The volume of 0.1 N NaOH required to completely neutralize 10 ml of this solution is (at mass : C = 12, O = 16, H = 1) (a) 40 ml (b) 20 ml (c) 1 ml (d) 4 ml Which of the following groups activate the ring when directly attached (a) NO2 (b) COOH (c) OH (d) both OH and COOH Which of the following is least basic

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Which of the following carboxylic acids undergoes decarboxylation easily? (b) C6H5 CO COOH (a) C6H5 CO CH2 COOH (c) C6H5 CH COOH (d) C6H5 CH COOH

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JEE Mains Chemistry Model Paper 3

O
(a) (b) (c) (d)

N H

N H

N H

R
61.

(c) Ph 63.

OH

(d)

64.

65.

The Cannizzaro reaction is not given by (a) Trimethylacetaldehyde (c) Benzaldehyde The d orbital involved in sp3d hybridisation is (a) dxy

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The PPP bond angle in P4 molecule is (a) 60 (c) 90

67.

68.

An organic compound with molecular formula, C7H8O dissolves in NaOH and gives a characteristic colour with FeCl3. On treatment with bromine, it gives a tribromoderivative, C7H5OBr3. The compound is (a) benzyl alcohol (b) o methyl phenol (c) m methyl phenol (d) p methyl phenol 69. P2O5 is a (a) reducing agent (b) oxidising agent

66.

Which of the following species of ammonical solution of sodium acts as a reducing agent? (a) sodium atom (b) solvated electron (c) solvated sodium ion (d) sodium hydride Maximum value of paramagnetic behaviour is shown by (a) [Fe(CN)6]3 (b) [Sc(CN)6]3 (c) [Cr(CN)6]3 (d) [Co(CN)6]3

(c) dxz

g. c
(b) 30 (d) 120 (b) Acetaldehyde (d) Formaldehyde (b) d x 2 (d) d z 2
y2

om
OH

(C) R Compound (C) in the above reaction is: (a) hydroxy acid (b) amino alkanol (d) (c) 62. Which alcohol is most reactive towards acylation CH3 (b) (a) OH

C=O

HCN

(A)

NH3

(B)

Hydrolysis

amino acid amino hydroxy acid

CH3 OH

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JEE Mains Chemistry Model Paper 3

70.

71.

(c) buffer (d) none of these If a nuclear reaction takes place by 2 parallel paths such as 1 B A 2 C then the decay constant for the complete decay will be (a) 1, 2 (b) 1/ 2 (d) 1 + 2 (c) 1 Which among CH4.SiH4, GeH4 is most volatile? (a) CH4 (b) SiH4 (c) GeH4 (d) SnH4
1. BH3/THF 2. H2O2.OH

72.

(A), compound (A) is

74.

75.

CH3 C CH=CH2

76.

77. 78. 79.

CH3 (a) 1,1,1 Trimethyl 2 propene (b) 3,3 Dimethyl 1 butene (c) 3,3,3 Trimethyl 1 propene (d) 2,2 Dimethyl 3 butene When a solution of benzoic acid (a weak monobasic acid) is titrated with NaOH, the pH of the solution is 4.2, when half the acid is neutralized. Dissociation constant of the acid is (Anti log 0.8 = 6.31) (a) 6.31 10 5 (b) 3.2 10 5 (c) 6.31 10 4 (d) 6.42 10 4 Which of the following is not a polymer? (a) SiO2 (b) Teflon (c) Neoprene (d) Isoprene Mutation of DNA occurs due to changes in the sequence of one of the following (a) Bases (b) Ribose units (c) Phosphate units (d) Sugar units An organic compound X is boiled with KOH when it evolves a gas, which gives white precipitate with MgSO4 solution. The compound X also gives salicyclic acid on warming with phenol. X is likely to be (a) C6H5Cl (b) CCl4 (c) CHCl3 (d) C6H5OH

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73.

(a) Pentanol (b) 2 pentanol (c) Pentane (d) 1,2 pentan di ol Oxidation state of Cr in CrO5 is (a) +5 (b) +3 (c) +6 (d) +10 Which of the following is the life saving mixture for an asthma patient? (a) Mixture of helium and oxygen. (b) Mixture of neon and oxygen. (c) Mixture of xenon and nitrogen. (d) Mixture of argon and oxygen. IUPAC name of the following compound is CH3

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JEE Mains Chemistry Model Paper 3

CHCl3 KOH

80.

NH2

Cl

(X)

H3O+ 300 K

(Y)

In the above sequence (Y) is (a) Cl (c) CN

COOH OH

(b) Cl (d) Cl

OH NH2

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