H

H
H

H
H

O
H

O
O

H
N

O
O
H

H
H

HO

2+

H H

3+

H
H

H
H

H
O
S

H
+

O
H

H
HH

HBr

H
N
H
H
H
H H

4+

N
H

H H
H

H
H

H
H

H
H

HH

H
H

OH
O As OH

Na
HO

NH
I

Na

CH3

CH3
NH2

OH

+HO

Na

O
OH
+

Na

N
N
HBr
HBr
OH HO

OH +
Na

Deoxyribonucleic acid short-hand:

5-ACTGGG-3
3-TGACCC-5
HO
OH
N
P
H
O
O
N
H
O

O
P

OH

NH H
HO

NH

O
H

NH

O
P

OH

O
N

O
P

N
NH H

HO

O
H

NH

P
O

OH

O
N

O
P

H3C

N
NH H

HO

NH

P
O

OH

H
O
N

O
H

O
H
HO

O
P

NH H

NH
H

NH H

CH3

P
O

OH

H
O

H
N
O
HO

OH

N
O

H
O

HO

O
H

O
P

HO

OH

H
H
H

H
H

H
H H

H H

H H
H
H

H
H
H
H

HH

01/Mar/2013 10:33:29 ACD/CNMR (v.6.07)

27[143.99]

35

36
28[97.71]

25[144.11]

29[152.73]

Na
Na

68

31[48.69]

24[94.74]

HO

32[48.87]

OH

26[105.14]

22

70

NH
37

45

30
33[26.11]

40[182.10]

38[167.76]

42[38.98]

OH

20

23

16[128.70]

C H3

41

As

C H3

44[13.59]

39

21

43[19.23]

34[12.37]

15[127.09]

17[127.09]

14[107.09]

18[107.09]

13[156.06]

NH2
19

OH
8

7[72.38]

9[41.40]

1[39.20]

Na

HO

48

71

46
47[173.90]

62

49[57.90]

12

72

53

54[57.90]

H Br

Na
3[22.52]

Na

60[57.90]

57[57.90]50

2[34.12]
OH

5[22.52]

65
61[173.90]

51[51.50]52[51.50]

11
10[177.95]

6[34.12]

OH

59

69

67H Br
58[173.90]
OH 66
64

55[173.90]

HO

63

56

4[26.95]

120
115
110
105

(55;58;47;61)

100
95
90
85
80
75
70
65
60
55
50
45
40
35
30

(10)
(40)

(16)
(38)

(13)

(29)

(25)

(26)
(18;14)

(28)
(24)

(7)

(49;60;57;54)

(32)

(1)

(4)
(33)
(3;5)

(44)
(34)

25
20
15
10
5
0

150

100

50

01/Mar/2013 10:45:24 ACD/HNMR Predictor (v.6.08)

H H

H
H
H

HH

HH

H H
H
H

H
H

HH

0.84, 0.29
0.91, 0.29
0.30

0.20

1.43, 0.12
1.47, 0.11

0.10
1.36, 0.07
1.62, 0.06
1.94, 0.05
1.98, 0.05
1.97, 0.04
2.15, 0.02
2.21, 0.0000
0.00

10