Analytical Chemistry

1. Exactly 750.0 mL of a solution that contained 480.4 ppm of Ba(NO3)2

were mixed with 200.0 mL of a solution that was 0.03090 M in Al2(SO4)3.
A. What mass of solid BaSO4 was formed?
B. What was the molarity of the unreacted reagent [Al2(SO4)3 or
Ba(NO3)2 ]?
2. What mass of MgNH4PO4 precipitated when 200.0 mL of a 1.000%
(W/V) solution of MgCl2 were treated with 40.0 mL of 0.1753 M Na3PO4
and an excess of NH4
+
? What was the molarity of the excess reagent
(Na3PO4 or MgCl2) after the precipitation was complete?
3. Exactly 25.0 mL of a 0.3757 M solution of Na3PO4 were mixed with
100.0 mL of 0.5151 M HgNO3.
A. What mass of solid Hg3PO4 was formed?
B. What is the molarity of the unreacted species (Na3PO4 or HgNO3)
after the reaction was completed?
4. What volume of 0.01000 M AgNO3 would be required to precipitate all
of the I
-
in 200.0 mL of a solution that contained 24.32 ppt KI?
5. What mass of solid PbCl2 (278.10 g/mol) is formed when 200 mL of
0.125 M Pb
2+
are mixed with 400mL of 0.175 M Cl
-
?

BS Mining Engineering 1