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Part A - Chemistry
1)
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2)
A mixture of formic acid and oxalic acid is heated with conc. H 2 SO4 . The
gaseous product is passed into KOH solution where the volume decreases by
1/6th. The molecular proportion of the organic acids, formic acid and oxalic acid
in the mixture is
3)
4:1
1: 4
1: 2
2: 1
4)
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water) and containing 68.5% Hz by volume find the volume of H2, measured at
STP, which will dissolve in 1L of water.
5)
18 mL
12 mL
23 mL
121 mL
A mixture of 0.50 mole of H 2 and 0.50 mole of SO2 is introduced into a 10.0
L container at 25C, The container has a 'pinhole' leak. After a period of time the
partial pressure of H 2 in the remaining mixture
6)
3.7g of an oxide of a metal was heated with charcoal. The liberated CO2 was
absorbed in caustic soda solution and weighed 1.0 g. If the specific gravity of the
metalis 0.095, the exact atomic weight of the metal is
a) 170.B
b) 32.7
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c) 67.37
d) 65.4
7)
oxide ions, one eighth of tetrahedral voids are occupied by divalent ions (A2+),
while one half of the octahedral voids are occupied by trivalent ions (B3+). What is
the formula of the oxide?
a) A3B2O4
b) A2B2O4
c) AB2O5
d) AB2O4
8)
disulphide ( l ) are - 393.3, -293.72 and - 1108.76 kJ/mol respectively. The standard
heat of formation of carbon disulphide ( l ) is
a) -128.02kJ
b) + 128.02kJ
c) - 218.42 kJ
d) + 218.42 kJ
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9)
10)
increase in Ecell ?
a) Pt (H2) | H+ (Ag)
b) Ag, AgCI| CI-(aq)
c) PtlQuinhydrone| H+ (aq)
d) Ag | Ag+(aq)
11)
d) CH3
12)
13)
v
1840
b)
1840
v
c) 1840 v
d) v
14)
The molecular mass of each N2 and CO is 28. If 0.5 L of N2 at 27C and 700
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15)
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16)
a)
b)
c)
d)
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17)
Product is purple complex having structure.
a)
b)
c)
d) None of the above
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18)
19)
(ii)
(iii)
d) 3.5
20)
21)
were added. The remaining acid required 20 mL of 0.5 N NaOH for complete
neutralisation. The normality of the acid solution is
22)
a)
0.9 N
b)
0.45 N
c)
0.225 N
d)
1.45 N
A metal crystallizes into two cubic phases, face centred cubic (FCC) and
body centred cubic (BCC) whose unit cell lengths are 3.5 and 3.0 respectively.
Calculate the ratio of the densities of FCC and BCC,
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a) 1.67
b) 1.26
c) 6.23
d) 1.04
23)
How much ethyl alcohol, C2H5OH, must be added to 1.00 L of water so that
24)
25)
26)
27)
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28)
1
2
The standard enthalpy change for the reaction H2(g)+ O2(g) H2O(g), is
H = - 248.8 kJ. It truly suggests, that
a) 248.8 kJ of energy is evolved when reaction is processed at 1 atm
pressure and 298 K temperature.
b) 248.8 kJ of energy is evolved irrespective of reaction conditions
(pressure and temperature)
c) the reaction 2H2 + O2 2H2O evolves same amount of energy 248.8
kJ
d) The reaction is
1
2
29)
dissolved in 800 g of water, the solution freezes at - 1.16C. What is the molecular
formula of the solute? ( k f = 1.86C/m)
a) CH2O
b) C2H4O2
c) C3H6O3
d) C4H8O8
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30)
For the reaction 3BrO- BrO3 + 2Br-, in alkaline solution, the value of the
second order (in BrO-) rate constant at 80C in the rate law for ( [BrO-] / t) was
found to be 0.056L mol-1 s-1. Then, [BrO
3 ]/ t is
a) 0.019 L mor1 s-1
b) 0.112 L mol-1 s-1
c) 0.168 Lmol-1 s-1
d) 0.056 L mol-1 s-1
Part C Physics
31)
After 8s, a stone is released from the balloon. The stone will
A
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32)
A projectile is moving at 60m/s at its highest point, where it breaks into two
equal parts due to an internal explosion. One part moves vertically up at 50m/s
with respect to the ground. The other part will move at
33)
110m/s
120m/s
130m/s
10(61) m/s
with the vertical, and rebounds with a speed v, at an angle with the vertical.
The coefficient of restitution between the particle and the floor is e. The
magnitude of v is
A
eu
(1-e)u
u(sin2 + e2cos2)
u(e2sin2+cos2)
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34)
A block of mass m is pushed towards a movable wedge of mass m and
height h, with a velocity u. All surfaces are smooth. The minimum value of u for
which the block will reach the top of the wedge is
35)
(2gh)
(2gh)
(2gh(1+1/))
(2gh(1-1/))
moving in the xy plane. Starting from the origin, the particle is taken along the
positive x-axis to the point (a, 0), and then parallel to the y-axis to the point (a, a).
The total work done by the force on the particle is
A
-2ka2
2ka2
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36)
-ka2
ka2
A rod of length l slides down along the inclined wall as shown in figure. At
the instant shown in figure, the speed of end A is v, then the speed of B will be
37)
(v sin)/cos
(v sin)/sin
(v cos)/cos
(v cos)/cos
In the figure, shown the plank is being pulled to the right with a constant
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38)
Two point masses of 0.3kg and 0.7kg are fixed at the ends of a rod of length
1.4m and of negligible mass. The rod is set rotating about an axis perpendicular to
its length with a uniform angular speed. The point on the rod through which the
axis should pass in order that the work required for rotation of the rod is
minimum, is located at a distance of
A
39)
Speed of a planet in an elliptical orbit with semi major axis a about sun of
40)
2 1
GM
r a
1 1
GM
r a
1 2
GM
r a
GMr
2a 2
suspended, with its length vertical, from a fixed point by a mass less spring, such
that it is half-submerged in a liquid of density at equilibrium position. When the
cylinder is given a small downward push and released it starts oscillating vertically
with small amplitude. If the force constant of the spring is k, the frequency of
oscillation of the cylinder is
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41)
1/2 (k-Ag/M)1/2
1/2 (k+Ag/M)1/2
1/2 (k+gL2/M)1/2
1/2 (k+Ag/Ag)1/2
A uniform rod of length 2.0m specific gravity 0.5 and mass 2kg is hinged at
one end to bottom of a tank of water (specific gravity = 1.0) filled up to a height of
1.0 m as shown in figure. Taking the case 0o the force exerted by the hinge on
the rod is (g = 10m/s2)
10.2 N upwards
4.2N downwards
8.3N downwards
6.2N upwards
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42)
It has capillary tube of length l and radius r fitted horizontally at bottom. If the
coefficient of viscosity of water is then time required in which the level will fall
to a height H/2 is (density of water is )
43)
lr2/4A ln(2)
4lr4/gAln(1/2)
8lA/gr4ln(2)
4Hl/gr4ln(2)
Two pulses in a stretched string, whose centres are initially 8cm apart, are
moving towards each other as shown in the figure. The speed of each pulse is
2cm/s. After 2s total energy of the pulse will be
zero
purely kinetic
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44)
purely potential
overtone frequency of an open organ pipe. Further nth harmonic of closed pipe is
also equal to the mth harmonic of open pipe, where n and m are
45)
5, 4
7, 5
9, 6
7, 3
2/5 R
5/2 R
10/3 R
6/7 R
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46)
from the surface and partly refracted into the slab. The reflected and refracted
rays are mutually perpendicular. The incident ray makes an angle i with the
normal to the slab. The refractive index of the slab is
47)
tan-1(i)
cot-1(i)
sin-1(i)
cos-1(i)
the centre of the screen. If S1CS2 = and is the wavelength, the fringe with will
be
A
2/
/2
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48)
49)
k Q/r2
(n-1) k Q/r2
n/(n-1) k Q/r2
(n-1)/n k Q/r2
smooth narrow tunnel through its centre. A small particle with negative charge,
initially at rest far from the sphere, approaches it along the line of the tunnel,
reaches its surface with a speed v, and passes through the tunnel. Its speed at the
centre of the sphere will be
A
2v
1.5v
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50)
In an isolated parallel-plate capacitor of capacitance C, the four surfaces
have charges Q1, Q2, Q3 and Q4, as shown. The potential difference between the
plates is
51)
(Q1+Q2+Q3+Q4)/2C
(Q2+Q3)/2C
(Q2-Q3)/2C
(Q1+Q4)/2C
dielectric slab. The capacitor is connected to a cell and the slab is taken out.
A
52)
A particle of charge per unit mass is released from origin with velocity v =
v0 i in a magnetic field
B B0 k
And
B0
for
for
3 v0
2 B0
3 v0
2 B0
3 v0
3
v0 t
2 B0 2
B0
3 v0
v0 t
2 B0
3B0
v
3 v0
0 t
2 B0 2 3B0
vt
3 v0
0
2 B0 2
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53)
Two long parallel wires are at a distance 2d apart. They carry steady equal
currents flowing out of the plane of the paper as shown. The variation of the
magnetic field B along the line XX is given by
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54)
CR
CR ln (2)
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55)
L/(R ln (2))
LR
A copper rod of mass m slides under gravity on two smooth parallel rails l
distance apart and set at an angle to the horizontal. At the bottom, the rails are
joined by a resistance R. There is a uniform magnetic field perpendicular to the
plane of the rails. The terminal velocity of the rod is
mgRcos/B2l2
mgRsin /B2l2
mgRtan /B2l2
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56)
Binding energy per nucleon of 1H2 and 2He4 are 1.1eV and 7.0 MeV
57)
20.8MeV
16.6MeV
25.2MeV
23.6MeV
Difference between nth and (n + 1)th Bohrs radius of H atom is equal to its
58)
Magnetic field at the centre (at nucleus) of the hydrogen like atoms (atomic
n3/Z5
n4/Z
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59)
Z2/n3
Z3/n5
A star initially has 1040 deuterons. It produces energy via the processes 1H2
60)
106s
108s
1012s
1016s
different instants, the quantity time. If now their present activities are A1 and A2
respectively the their age difference equals
2A
T
ln 1
ln 2
A2
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A1
A2
T ln
A
T
ln 2
ln 2 2A1
T ln
A2
2A1
Part A - Mathematics
61) The equation of one of the planes through origin which is parallel to the
line x-1/2 = y+3/-1 = z+1/-2 and at a distance 5/3 from it is
A
2x + 2y + z = 0
3x + 2y + 2z = 0
x 2y + 2z = 0
None of these
62) An unbiased die is tossed to until a number greater than 4 appears. The
probability that an even number of tosses is needed is
A
2/5
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63)
1/5
2/3
3a 1 b 2 3b 1 c2 3c 1
abc
Where a, b, c > 0 is
64)
125
25
27
None of these
Let |z i| + |z + i| = k, if k = 0, then
A
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65) How many ways are there to arrange the letter of the word FATHER with
vowels in alphabetical order.
A
480
240
360
120
66) In a triangle ABC, a: b: c = 4:5:6. The ratio of radius of the circum circle to
that of the in circle is
A
16:7
16:9
15:11
15:13
67) Tangents are drawn to the ellipse x2 + 2y2 = 2, then the locus of the midpoint of the intercept made by the tangents between the coordinate axes is
1
1
2 1
2
2x 4 y
1
1
2 1
2
4x 2 y
x2 y 2
1
2 4
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x2 y 2
1
4 2
68) The slope of common tangent to the ellipse x/a + y/b = 1 and the circle
x + y = r must be
r2 a2
r 2 b2
r 2 b2
r2 a2
r2 a2
r 2 b2
r 2 b2
a2 r2
69) If one of the diagonals of a square is along the lines x = 2y and one of its
vertices is (3, 0), then its sides through this vertex are given by the equations
A
y + 3x + 9 = 0, 3y x + 3 = 0
y + 3x 9 = 0, 3y x 3 = 0
y 3x + 9 = 0, 3y + x 3 = 0
y 3x 9 = 0, 3y + x + 3 = 0
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70)
71)
2xetan-1y = e2tan-1y + k
xe2tan-1y = e2tan-1y + k
xetan-1y = e-1y + k
(x-2) = ketan-1y
f (x 2 ) f x
is
lim
x 0 f x f 0
A
-1
72) The equation of the circle having radius 3 and touching the circle x2 + y2
4x 6y 12 = 0 at (- 1, - 1) is
2
2
a) 5x 5 y 8x 14 y 16 0
2
2
b) 5x 5 y 8x 14 y 32 0
2
2
c) 5x 5 y 8x 14 y 4 0
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2
2
d) 5x 5 y 8x 14 y 4 0
73)
rxa
bxa
and
r.c
0,
where
a.b
0,
then
r is equal to
Let
b
ta where t is a scalar
A
a
c
B
C
ac
None of these
74) Consider an A.P. with first term a and the common difference d. Let Sk
denote the sum of the first K terms. Let Skx/sx is independent of x, then
A
a =d/2
a =d
a = 2d
None
75) The equation of the line passing through the point (1, 2, -4) and
perpendicular to the two lines x-8/3 = y+9/-16 = z-10/7 and x-15/3 = y-2/8 = z-8/-5
is
A
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76) The points of contact Q and R of tangent from the point P (2, 3) on the
parabola y = 4x are
A
77) The equation of bisector of that angle between the lines x + y + 1 = 0 and 2x
3y 5 = 0 which contains the point (10, -20) is
A
None of these
78)
1
1
f t 1for t 0,1 and0 f t for
2
2
3
1
g 2
2
2
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79)
0 g 2
3
2
3
5
g 2
2
2
2/3
4/3
80) A spherical iron ball 10cm in radius is coated with a layer of ice of uniform
thickness that melts at a rate of 50cm/min. When the thickness of ice is 5cm,
then the rate at which the thickness of ice decrease is
A
1/36 cm/min
1/18 cm/min
1/54 cm/min
5/6 cm/min
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82)
all values of p
83) Given P(x) = x4 + ax3 + bx2 + cx + d such that x = 0 is the only real root of P(x)
= 0. If P(-1) < P(1), then in the interval [-1, 1]
A
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84)
If
1 sin 2
cos 2
4sin 4
sin 2
1 cos 2
4sin 4 0
2
2
sin
cos
1 4sin 4
0
Such that
85)
7
12
7 11
,
24 24
7 11
,
12 12
None of these
, then is
If in a triangle ABC,
cos A cos B + sin A sin B sin C = 1,
then a : b : c is equal to
86)
1: 1: 2
1: 1: 3
1: 2 : 1
1: 3 : 1
7 5 3
, ,
11 9 7
3 7 5
, ,
7 11 9
3 5 7
, ,
7 9 11
5 7 3
, ,
9 4 7
87)
a 1 a 1 a 1
b 1 b 1 a 1
c 1 c 1 a 1n 2
a
If b
c
b 1
b 1
c 1
c 1
n 1
0,
n
any integer
88) If the mean deviation of number 1, 1+d, 1+2d,,1+100d from their mean
in 255, then the d is equal to
A
10.0
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20.0
10.1
20.2
90)
at least 1000
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