, .

: , 3224
:
: ,
: 19/11/14
: 26/11/14
:


.

,
.


CH3COOH (
) .

.

,
.

( )
.
, KNO3 0,001 M
. (=l/A l
A )
=L/L

:
)- - :
a)
)2
)
)4 200ml. 2
. 10ml.

). , KNO3 0,001 M, CH3COOH 0,1

200 ml .
0.01 .
CaVa=CtVt Vt=200ml, Ca=0,1M,
Ct=0.01M=C1
Va = CtVt/Ca = (200ml x 0,1 M )/(0.001 M) = 20ml = V1
3 :
C2= 0.006 M (V2=12ml)
C3=0.003 M (V3=6ml)
C4=0.001 M (V4=2ml)
)
) 25

C . .
) ,
, 24C ,
.
) KNO3 0.001 ,
KNO3
,
, (1)
) , 1,2,3,4
CH3COOH , .
)
24C.

-:
- 3 L= 390S,
3 (

= 1000L/C) (1)
.
3: = 141.77 cm2xS/mol
=1000L/C L = (Cx)/1000 = (0,001 mol/cm3 x 141.77 cm2 x
S/mol)/1000
L = 1.418 x 10-4 S/cm

 (1) L = L x K K = L/L = (1.418 x 10-4

S/cm)/382.7 x 10-6 S = 0.371 cm-1
- .
L1=440 S, L2=301S, L3=235S, L4=121S. :
LH2O=7.3S
a)
:
L1 = L1 LH2O = 440 S 7.3S = 432.7 S.
b) L
(1),
.
L1 = L1 x K = 432.7 S x 0.371 cm-1 = 160.5 S/cm
c)
= 1000L/C. 1 = 1000L1/C1 1 = (1000 x 160.5
S/cm )/0.01 M 1 = 16.05 S/(cm x M)
d) .
- 1: ,
KNO3, ,
, ,

.
a/a

C(M)

L (S)

L
L
(S/(cm x
(S)
(S/cm) M))
H2O
7.3
KNO3
0.001
390
382.7
141.8
141.8
1
0.010
440
332.7
160.5
16.05
2
0.006
301
293.7
109.0
18.16
3
0.003
235
227.7
84.48
28.16
4
0.001
121
113.7
42.18
42.18
-

1
1
c

( 4)
0 K a ( 0 ) 2
1/ C
.
2: 4 ,
, 1/ C.
a/a

C (M)

(S/(cm x
M))

1/ ( (cm x
M)/S)

C (S/cm)

1
2
3
4

0.010
0.006
0.003
0.001

16.05
18.16
28.16
42.18

0.0623
0.0551
0.0355
0.0237

0.1605
0.1090
0.0845
0.0422

1: 1/
C

y=ax+b : y = 0.343x + 0.010
a = 0.074 b = 0.008
(4). 1/ = 1/ 0 + C/(Ka20)
1/0 = 0.010 Ka20 = 0.343.
1/0 = 0.010 0 = 100 S/(cm x M)
Ka20 = 0.343 Ka = 0.343/ 1002 = 3.43 x 10-5
Ka CH3COOH 1.7 x 10-5
% :
.%= [(1.7 x 10-5 3.43 x 10-5)/1.7 x 10-5 ] x 100% =
101.7%

 :
1)

.


(10-3 10-4)
.

25C 24C.
2)
(4) (1)

. (

).
3)




.
4)
,
,

.
5) O


(

.).

:
- ..-..,
V, 2011 ,.45-51
-Handbook of Chemistry and Physics, 73rd Edition,.8-39