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No 13

A producer gas has the following composition by volume :


CO

23,0%

CO2

4,4%

O2

2,6%

N2

70,0%
T =70F, P = 750 mm Hg

a.

CO

23,0%

CO2?

CO2

4,4%

O2..?

O2

2,6%

N2.?

N2

70,0%

Calculate the cubic feet of the gas at 70 and 750 mm Hg pressure, per
pound of carbon present

Answer :
Basis of calculation : 100 lb-mol of gas
Lb-mole
CO

CO2

23
4,4

Weight

lb-mole

Weight,Lb

28

lb-mole

23 lb-mole x 28 = 644 lb
44

44 lb-mole x 28 =

193 lb
O2

2,6

lb-mole

32

N2

70

lb-mole

28

2,6 lb-mole x 32 = 83,2 lb


70 lb-mole x 28 = 1960 lb

+
2880,2 lb

Basis 100 lb C =
2C + O2

100
12

= 8,3 lb-mol
2CO

23
2

23

23

C + O2

lb-mole

CO2

4,4 4,4

4,4

lb-mole

Total C = 23 + 4,4 = 27,4 lb-mol x 12 = 328 lb


70F = 530R
1 lb-mol = 359,04 Cu ft
100 lb-mol = 35904 Cu ft
the cubic feet of the gas at 70 and 750 mm Hg pressure, per pound of
carbon present
V2

= V1 x

P1
P2

= 35904 cu ft x

b.

T2
T1
760 mm Hg
750 mm Hg

530 R
492 R

= 119,2 cu ft

Calculate the volume of the air, at the condition of part a , required for
the combustion of 100 cu ft of the gas at the same condition if it is
desired that the total oxygen present before combustion shall be 20 %
in exess of that theoretically required

Answer :
O2 exess

lb-mol gas =

100+ 20
100
100
27,4
=

CO

= 1,2 lb-mol

x lb-C
100
27,4

= 23 x lb-mol gas

x 8,3 = 30,29 lb-mol

= 23 x 30,29 = 696,67
2CO + O2

2CO2

696,67

348,335

696,67

lb-mol

O2 untuk pembakaran = 20 % in exess


= 1,2 x 348,335 = 418,002 lb-mol
O2 yang ada

= 2,6 x 30,29 = 78,754 lb-mol

O2 yang disupplay

= 339,248 lb-mol

N2 yang disupplay =

78
21

x 339,248 = 1276,2187 lb-mol

Udara disupplay = O2 yang disupplay + N2 disupplay


= 339,248 lb-mol + 1276,2187 lb-mol
= 1615,4667 lb-mol
Vudara =

n RT
P

1615,4667 x 0,000073021 x 530


0,986

Vudara / 100 ft3 gas =

c.

100
119,2

= 63,38 cu ft3

x 63,38 = 53,179 cu ft3

Calculate the percentage composition by volume of the gases leaving


the burner of part b , assuming complete combustion

Answer :
Komposisi gas saat lb-mol gas = 30,29 lb-mol
CO

23,0 x 30,29

= 496,67

CO2

4,4 x 30,29

= 133,276

O2

2,6 x 30,29

= 78,754

N2

70,0 x 30,29

= 2120,3

2829 lb-mol
Maka
CO2 = 133,276 + 696,67

= 823,946

= 19,20%

O2 = 418,002 348,335

= 69,667

= 1,62%

N2

= 2120,3 + 1276,2187 = 3396,5187


4290,1317

= 79,18%
100%

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