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Cathodic Protection
Cathodic Protection
Protection
ME 472-061 Corrosion Engineering I
ME, KFUPM
Dr. Zuhair M. Gasem
Dr. Z. Gasem
ME 472-061
KFUPM
References:
Dr. Z. Gasem
ME 472-061
KFUPM
Corrosion Cell on a
Metal Surface
H+
H2
H+
Fe2+
H+
H+
Cathode
Anode
Fe2+
Metal
Electron Flow
H+
H+
Dr. Z. Gasem
ME 472-061
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Electrolyte
H2
H+
H2
H+
H2
H+
H2
H+
H H
H+ H+
H+
H+
H+ H+
H+ H+
H
Fe2+
e e
e e
H+
H+
e ee e e e
e e
e
e
e
Dr. Z. Gasem
ME 472-061
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Before CP:
ianode = icathode
= icorr
E = Ecorr
After CP:
icorr = ia
icathode = ic
iapp = ic ia
E = ECP
ECP
Dr. Z. Gasem
ME 472-061
KFUPM
ianode = icathode = iL
E = Ecorr
After CP:
icorr = ia
icathode = ic = iL
iapp = ic ia
E = ECP
ECP
Dr. Z. Gasem
ME 472-061
KFUPM
Cathodic Protection
CP makes the structures potential more negative which promotes cathodic
reactions and slows anodic reaction
Increases icathode
Decreases ianode
Need to supply iapp = icathode - ianode
Where CP is used?
CP is often applied to coated structures, with the coat providing the
primary form of corrosion protection and the CP system acts as a
supporting protection.
The main applications of CP include:
Buried pipeline
Acids storage tanks
Offshore steel structures such as platforms and oil rigs
Ships
Concrete structures exposed to seawater such as bridges
Dr. Z. Gasem
ME 472-061
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CP of Buried Pipelines
Before CP is applied:
Dr. Z. Gasem
ME 472-061
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CP of Buried Pipelines
After CP is applied:
The structure to be protected becomes the cathode
The anode is an external electrode:
Amore active metal (sacrificial anode)
An inert anode with impressed DC current (Impressed
current)
The soil is the electrolyte
Ionic current flow b/w the anode and the cathode in the
external surfaces
Electrons flow between the anode and cathode through an
insulated copper wire.
e-
cathode
+ve ions
current in
electrolyte
Sacrificial
anode
Dr. Z. Gasem
ME 472-061
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CP of Buried Pipelines
10
Sources of current
Dr. Z. Gasem
ME 472-061
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O2+2H2O+4e- 4OH-
In neutral seawater
O2+2H2O+4e- 4OH-
Anode reactions
At active anode in
sacrificial anode CP system
(Mg, Al, Zn)
M M+n + ne-
11
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ME 472-061
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CP of pipelines
12
Protection Criteria
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ME 472-061
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How
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ME 472-061
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Protection Criteria
14
Reference Electrodes
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ME 472-061
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Common
Cu/CuSO4 in soil
AgCl in seawater
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ME 472-061
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Potential Protection
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ME 472-061
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Corrosion condition
-0.5 to -0.6
Intense corrosion
-0.6 to -0.7
Corrosion
-0.7 to -0.8
Slow corrosion
-0.8 to -0.9
Cathodic protection
-0.9 to -1.1
Overprotection
-1.1 to -1.4
Severe overprotection
(disbonding of coatings,
hydrogen blistering, HE)
17
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ME 472-061
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Dr. Z. Gasem
ME 472-061
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Structure
19
Bottom Externals,
Isolated Buried Casings
Marine structures
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ME 472-061
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Soil Corrosivity
The soil particles are covered with thin surface film of moisture with
dissolved salts and gases.
The total volume of soil consists of solid particles and pores filled
with moisture and air.
Soils with a high proportion of sand have very limited storage
capacity for water whereas clays are excellent in retaining water
Air in the pores contains 10-20 times as much CO2 as atmospheric
air.
Soils with high moisture content, high electrical conductivity, high
acidity, and high dissolved salts will be most corrosive.
Soil Corrosivity
Dr. Z. Gasem
ME 472-061
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Dr. Z. Gasem
ME 472-061
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Soil Corrosivity
22
Soil
Corrosivit
resistivity y Rating
(ohm cm)
>20,000
Essentially
noncorrosive
10,000 to
20,000
Mildly
corrosive
5,000 to
10,000
Moderately
corrosive
1,000 to
5,000
Corrosive
<1,000
Very
corrosive
Dry sand
Clay with
saline
water
(sabkha)
Soil Corrosivity
Dr. Z. Gasem
ME 472-061
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Seawater
Resistivity
Electrolyte
23
Progressively Less
Corrosive
10,000
Resistivity
(ohm-cm)
Mildly Corrosive
Seawater (Gulf)
Raw water
Drinking water
16
200-2000
2000-5000
2,000
1,000
500
Ohm-cm
Moderately Corrosive
Corrosive
Very Corrosive
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Environment
Initial CP Applied
Initial CP
current CP current current
Applied
CP current
Moving
seawater
325375
75-105
32-54
11-16
Stagnant
seawater
160270
45-75
11-32
5-11
soil
43-54
11-16
5.4-11
1.1-0.54
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ME 472-061
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Example
26
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Coatings in CP Systems
27
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ME 472-061
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Disadvantages
29
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Metal
-1.75
-1.6
-1.1
-1.1
-0.8
-0.5 to -0.8
-0.2 to -0.5
-0.5
-0.5
-0.2
-0.2
-0.2
-0.2
+0.3
30
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ME 472-061
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Sacrificial anodes
31
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ME 472-061
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Sacrificial anodes
60 inch in length
4 Kg
32
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This method is done by placing four pins at equal distances from each other.
A current is passed through the two outer pins using a power supply.
the voltage across the two inner pins is measured using a voltmeter.
the resistance can be calculated using Ohm's law (Resist = V/I).
Soil resistivity = 191.2*V/I*d (d in feet) ohm-cm,
where R is the soil resistance and d is the pin spacing in feet.
Power
supply
voltmeter
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ME 472-061
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ME 472-061
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Sacrificial Anode
36
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Dr. Z. Gasem
ME 472-061
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ED = Eanode Ep + Epolar
ED = driving potential
Eanode = anode potential
Ep = protection potential
Epolar = change in potential
of anode due to current
flow (polarization); usually
taken as 0.1 V
ED
38
Driving Potential
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39
Example:
Dr. Z. Gasem
ME 472-061
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Sacrificial Anodes
40
Mg
Zn
Al
Theoretical
capacity
Actual
capacity
Efficiency
2200
(A*hr)/Kg
1232
810
2980
780
2640
50-60%
>90%
>90%
potential
-1.1
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ME 472-061
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Electric Circuit
I
Battery
Resistor
R total
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Rab
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1.
2.
3.
Ra = /(2La)*(ln(8La/Da) -1)
Ra = 1000/(2*150)*(ln(8*150/15)-1) = 3.6
Dr. Z. Gasem
ME 472-061
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Anodes distribution
44
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ME 472-061
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Design Example
45
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ME 472-061
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ME 472-061
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Anodes
Aluminum
alloy anode
AA-036348
47
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ME 472-061
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ICCP
Dr. Z. Gasem
ME 472-061
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Components of ICCP
system
A transformer: to
reduce the voltage
from high to low
voltage
A rectifier to convert
AC to DC
A current distributor
(junction box)
Anodes with backfills
49
Reactions
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ME 472-061
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In neutral seawater
O2+2H2O+4e- 4OH-
O2+2H2O+4e- 4OH-
Cathode
anode
Dr. Z. Gasem
ME 472-061
KFUPM
Disadvantages
51
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ME 472-061
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An
Components of ICCP
external power source
AC transmission lines
A solar power system
Anodes
52
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Anode
Coke-to-earth
Resistance
Anode to
coke
resistance
Soil
Coke
breeze
Anodes in ICCP
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Material
Consumption rate
(Kg/(A*yr)
applications
Platinized niobium
(inert)
Platinized Ti (inert)
8x10-6
Seawater,
concrete,
==
Graphite (inert)
0.1-1
Scrap steel
7-9
Soil,
Potable water
Marine, soil
1-0.25
Marine, soil
8x10-6
Dr. Z. Gasem
ME 472-061
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Applications
55
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ME 472-061
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Buried pipelines
56
Well Casing
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ME 472-061
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Remote
Surface
Anode
Bed
Junction
Box
Producing Zone
Rectifier
Perforations
57
ICCP Design
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ME 472-061
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1.
2.
3.
4.
5.
6.
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60
CP Power off
300 mV
time
Dr. Z. Gasem
ME 472-061
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3. Current distribution
Variation of electrolyte
resistivity b/w anode
and cathode (largest
current flows along
least resistant path)
Defects in coatings:
current concentrates
at defects
61
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Stray Currents
Subway system
Interference with
another CP system
Welding equipment
Electrical power
transmission lines
62
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ME 472-061
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4. Number of Required
Anodes
N = Y*C*I/W
N =
anodes
Y =
I =
C =
W =
63
5. Resistance calculation
Dr. Z. Gasem
ME 472-061
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Dwights
anode:
Ra = /(2La)*(ln(8La/Da) -1)
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ME 472-061
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F : Adjusting Factor
65
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The
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ME 472-061
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= 2000*0.184/483 = 0.76
Total R= 0.76+0.24=1
E = I*R=1*36.1 = 36.1 V
Hence, use a DC power with a minimum current
supply of 40 A and a minimum voltage of 40 V (1600
Watt rating).