2

. 04

04

03
.1 Va=0mL pH>7
.
.2
.2.1 :

) CH 3 NH 2 ( aq ) + H 3O + CH 3 NH 3+ ( aq ) + H 2O (l

.2.2 :
VE=25mL

pHE=6

.2.3 :
+

H 3O VE
10 25
A
H 3O + VE = CBVB CB =
= CB
= 5.102 mol.L1
A
V
50
1

m = M .n m = M .CB .V m = 31 5.102 500.103 = 7, 75.10 1 g = 775mg

.3

+
3

CH 3 NH ( aq ) +

) OH ( aq

) CH 3 NH 2 ( aq ) + H 2O (l

x
xq

xq

xq

xmax

xmax

xmax

CBVB

CBVB xq

CBVB xmax

pH : SB ) 11,7 pH ( Va=0
CBVB xmax = 0 xmax = CBVB
xq = OH .VB
q

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2\1

. 04

OH .VB OH
q
q
=
=
CBVB
CB

1014
= pH = 10 pH 14
10
10 pH 14
10 14 +11,7
=
= 0,1
CB
5.10 2

xmax

Ke
= K e = OH H 3O OH
q
q
q
H 3O +

xq

= 1 .

.4
.4.1 :

CH 3 NH 2 (aq) + H 3O + (aq) CH 3 NH 3+ (aq) +

) H 2O(l

x=0

xq

------

---

C AVA

CBVB

xq

C AVA xq

CBVB xq

VA<VE H3O+ :
= 10 pH pK A .4.2

[CH 3 NH 2 ]q

= pH pK A

CH 3 NH 3+
q

CBVB xq

xq

[CH 3 NH 2 ]q
CH 3 NH 3+
q

CBVB xq
=

VA + VB
xq

VA + VB

log

[CH 3 NH 2 ]q
+
3

CH 3 NH
q

[CH 3 NH 2 ]q
CH 3 NH 3+
q

pH = pK A + log

CBVB xq

= [CH 3 NH 2 ]q
VA + VB

CH NH + = xq
3 q
3
VA + VB

CBVB
CBVB
= xq
1 + 10 pH pK A
[CH 3 NH 2 ]q
CH 3 NH 3+
q

= xq
1+

5.102 50.103
: xq = 1,10.103 mol : pH=10,8 VA=10,0mL
10,8 10,7
1 + 10
x
=1 .
= q = 1,1 .4.3
xmax

.4.4

1
1
K = pK A = 10 pK A K = 1010,7 = 5.1010
KA
10

+
3

=
q

CH 3 NH
q
[CH 3 NH 2 ]q H 3O +

=K

K>104 K . 4.3
.5
.5.1 :

H 2O CH 3 NH 3+ . Cl H 3O CH 3 NH 2.

= 10 pH E pK A .5.2

[CH 3 NH 2 ]E
+
3

CH 3 NH
E

= 10610,7 = 2.105

[CH 3 NH 2 ]E
+
3

CH 3 NH
E

[CH 3 NH 2 ]E CH 3 NH 3+ . 5.1
E

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2\2

= xq