TEST - 11

DATE : 09-03-2013

COURSE NAME : VIKAAS (JA) & VIPUL (JB)

TARGET : JEE (IITs) 2014

COURSE CODE : CLINIC CLASSES
CHEMISTRY
(GOC : ELECTRONIC EFFECTS)

HINTS & SOLUTIONS

1. (B)
Sol. Order of +I = (CH3)3 C > (CH3)2 CH > CH3 CH2 > CH3.

Cl
Sol.

2. (D)
Sol. Self explanatory.
3.

Cl

>

CH3

CH3

(B)
(D)

>

p-d back bonding

effect of two CH3

Sol. N (CH3)3 > N H3 >

7.

17. (BD)

Sol. Heat of hydrogenation

1
stability of alkene

delocalisation +I
+I effect of three CH3

16. (AB)

6. (A)
Sol. D or H will show hyperconjugation.
(B)

CH3
CH3

CH3

5. (D)
Sol. Those species which more H then it will show maximum
hyperconjugation.

8.

>

Cl

CH
4.

CH 2

Sol. On the basis of electronic effect.

18. (ABC)

(D)

Sol. On the basis of electronic effect.

9.

(C)

Sol.

Sol.

hyperconjugation and delocalisation with +I effect.

It shows hyperconjugation.

19. (ACD)
10. (D)

20. (AB)

11. (B)

21. (CD)
Sol. (A) 2

(B) 1

(C) 4

(D) 6

12. (C)
22. (BC)
13. (C)
Sol. (I) +m effect of O and hyperconjugative effect of 2-CH3 groups.
(II) is a simple 2carbocation
(III) +m effect of O and hyper conjugation of one CH3 groups.
(IV) is a simple 1carbocation.
14. (A)
Sol. Negative charge and lone pair on adjacent atom will increase
potential energy and decrease stability.
15. (B)

RESONANCE

SOL090313 - 1