1

AIGTS04/XIIP/XIIIIV16

Date : 13/04/2016

HINTS&SOLUTIONS

AIGTS#4

PHYSICS
91.

(2)
gliquid = 7 gcontainer

T2
T1

0.50=1

absolute
g
7
= l =
apparant g l g c 6
92.

(1)
Bycooling'slaw(T1

T2
T1 =0.5

T2)

dT T1 + T2

Ts
=
dt 2

300
T1 =0.5

Ts =temp.ofsurrounding
60oC 50oCin10min.

3000
=T1 =600K
5

(50-60)
50+ 60

= K
Ts _______(1)
10min
2

(42-50)
50+ 42

= K
Ts ________(2)
10min
2

(1) (2)
10 (55Ts) 5
=
=
8 (46Ts) 4
93.

94.

95.

96.

97.

1
10
1
b= 1 b=101=9
n
h =

Ts =10oC
(1)
ByKirchhoff'slawatjunction
H1 =H2 +H3________(1)
H1 =

KADT (3K)A(50)
=
l
l

H3 =

KADT K( A)(150)
=
l
l

H1 =H3
(3)
PV=nRT
aV2=nRT
a(2V)dV=nR(DT)
2aV2=nRDT
2[nR(200)]=nRDT
[DT=400]
(3)
T2=27oC=300K
0.4=1

T2
T1

T2
T1 =0.6
(T1=500K)
25%of40%=10%
nowefficiency=50%

ChangeinT1 = DT1 =100K

(4)
DQ= DU+ Dw
DU=0
DQ= DW
DQ1> DQ2> DQ3>0
(2)

Q1

Q2

T1

T2

W=10J

b=
98.
[PV= aV2=nR(200)]

Q1
Q1
9=
Q1 =90J
W
10

(1)
VT=constant
PV=nRT
PV2 =constant
n=2
C=

C=

C=

R
R

g - 1 n 1

R
R

5
1 2-1
3
3R
3R2R R
R=
=
2
2
2

PVn =constant

99.

AIGTS04/XIIP/XIIIIV16

(4)

103.

(4)
forcompoundpendulum

P
2P0
P0

T=2p

4T0

2 R
2MR 2
2sec=2p
= 2p
g
mg(R)

T0
V0

2V0

2R

4 = 4p g
2

PoVo=nRTo
C=CV +

100.

R
R
R

=
1-n g - 1 n 1

104.

X3 =4sin(wt+

A2=4

V T

A2sin45=4

1
2

T]
1
2
0

initially V

1
2
0

3V

T0
T1

T1 = 3T0

Resultantamplitude
= (6)2 +(8)2 + 2(6)(8)cos90o

2Mv
3 2

3
1
PV= Mv2forall
2
2

105.

=10m
(3)
y=

A
2

v=Awatmeanposition

(4)

5R
(10)
Q=nCpdT=(1)
2
7R
(5)
Q1 =nCp dT=(1)
2
Q 2 5
=
Q1
7
Q1 =

A1=2
1

(4)
PV=

T0__________________(1)

Finally (3V0) T1__________________(2)

(1) (2)
1
2
0

45o

A2cos45=(4)
2
=4
1
2

102.

A3=4

[PV=nRT]

1
2

101.

(4)
X1 =2sinwt
X2 =4 2sin(wt+ )
4

DQ=ncdT
=(n)(2R)(3T)
=6nRT=6PoVo
(4)
P2V=constant

R=0.5m

3R R
+
=(2R)
2
2

I
mgl

7
Q
10

V1 = w A2 y2
2
V1 = w A

=wA

A2
4

3
3
=v
4
2

106.

AIGTS04/XIIP/XIIIIV16

(4)
Bygraph
F=8N x=2m

109.

X= 5 2sin2pt +5 2cos2pt

F
N
=k=springconstant=4 m
x
T=2p

(3)
x=

+5 2sin 2pt+
X= 5 2sin2pt

m
0.01
=2p
k
4

2p p
T=
=
= 0.314 sec
20 10
107.

A
2

2
2
R= A1 + A2 + 2A1A2 cos

110.
111.

3 1
v = 2 v
4l1 2l

1
2

3
4l1 v=2(300)

1
k[20103]2
2

0.032
=k
(20 10-3)2
fromequation(1)

0.032 10-2
2010-3
F=

20 10-3 20 10-3
2
3
N=1.5N
2

=
108.

(3)

P.E.

(K.E.)=

1
2 2
1 2 2 2 mw y

mw (A y )= 2
2
n

112.

l1 =

3 330 33
=
m
4 600 80

l1 =

33
100cm
80

l1=41.25cm
(2)
I0 =60

nA
=y
1+n

Df =

Df=

Df =

n
A

1
+
n

2p

Dx

2pf
2p
Dx=
Dx
v
v

f
2p(400)
(0.28)
448

Df =

W
m2

f =400Hz:v=448m/sec
Pathdiff.= Dx=0.28m
Dx=(0.28)m

nA2 y2n = y2

y=

1
v
2l

1(O.T.)C.O.P =1(O.T)O.O.P.
_____________(1)

8p
p
(28)=
448
2

I=I0 +I0+ 2 I0I0 cos

I=120

W
m2

p
2

( 2 )(5 2)=20cm

(4)[Adiabatic]
(3)
f =300Hz=

PEU=U0+ kx2

0.04=0.01+

A2 +A2 + 0 =

R=

A=20103 m

A
F=kx=k
2

(1)

p
2

113.

AIGTS04/XIIP/XIIIIV16

(1)
Forstationarywave

115.

(3)
I=

px

y=5cos

sin(100pt)
25

I
Loudness=10log10
I0

px

Amplitudeofstationarywave=5cos

25

I
12
-12 =10log10 [10 ]
10

=10log10

px
=0(fornode)
5cos
25
116.

px
=cos(2n+1)p
2
25

400p
P
W
=
2 =1
m
4
p
(
10
)
A

Loudness=1210dB
(1)

cos

px
x=(2n+1)p
2
25
x=(2n+1)

114.

Mg=FB
(10)3r(g)=(10)2(6)(g)(rw)

25
2

node occur at
n=0x=12.5cm
117.
n=1x=37.5cm
n=2x=62.5cm
n=3x=87.5cm
Sox=25cmisrightAnswerwherenodewillnotoccur
(3)
Inunisonf1 :f2 =1:1
f=

1 T
2l u

Evergydensity=
=

1
(stress)(strain)
2

1
Y(strain)2
2

=(1011)

f =500Hz
Method=2
f1 : f2=1:1

f+5=

(1)

2 10-3
1

= 21011
4

Df
1 (2)

f
2 100

1 T
2l u

(100)(6)(10)(1)
=0.6g/cm3
(103)(10)

1 Dl

= Y
2 l

Df

1 DT
100
100=
f
2 T

f=

r =

410-6
16

105
=2.5104J/m3
4

=
(no.ofbeats=5)

118.

1 T1
2l u

f
T
100
=
=
f +5
102
102
T
100

(2)
(rgh)oil =(rgh)water
roil(147.3mm)=(1000)(135mm)
roil =

119.
120.

1000 135
147.3

roil =916.4969kg/m3
(4)
(4)
Radiusofcommonsurface

f
10
=
f +5 10.1

1 1 1
=
r
r1 r2

10.1 f =10 f +50

0.1 f =50
f =500Hz

1 1 1
=
r 3 4
r=12cm

121.

122.

AIGTS04/XIIP/XIIIIV16

Let upto the same phase point phase change in

pendulumwithtimeperiod7sbe qwhileothercovers
phase(p + q)

(4)
As about velocity of flow of liquids and about their
densitiesnothingismentioned,thereforeanyconclusion
can'tbemade.
(2)

2p
t_________(1)
3
2p
q =
t_________(2)
3
n

then p + q =

Solvingeq (1)and(2)
h

t=
126.
av

formaximumheight,
Rateofenteringvolume=Rateofleavingvolume
a=av

123.

a=a 2 gh
a2 =a22gh
h a a2
(4)

127.

dx

128.

Areaofplates=(0.1)2 =0.01m2
Velocitydv=0.1m/s
f=0.002N
h=0.01Poise

0.01
=0.001decapoise
0.1
hAdv
F=
dx
0.1
0.002=0.0010.01
dx
dx=0.0005m

(2)

pt
2 pt
sin2
y=0.2 cos
2
2

2
2
Cos
q
sin
q
=
Cos2q
Q
2pt
y=0.2cos
2
125.

y=0.2cos pt
SHMwithamplitude=0.2m
(1)

p
2

Phasediff.b/wacceleration&displacemetis
f2 = p
f2 = 2f1
(3)
(i)gravitationalforceremainsconstant
(ii)viscousforceincreasesexponentially
(iii)Netforceactingontheballincreasesexponentially
withtime
(1)
Volumeofbodyimmersedinthewater
=

2
p(8)3
3

\ bouyant force acting on body

2
p(8)3103g[FB =Vsg]
3

h=

124.

(1)
InSHM,phasedifferenceb/wdisplacementandvelcoity
is f1 =

0.1m

21
s
8

forequilibriumFB =Weightofbody

2 3 3
4
p8 10 g= p [8363]rg
3
3
129.

Solving,weget
r =865kg/m3
(3)
ds=

130.

dQ
T

here,dQ=0[adiabaticprocess]
ds=0
S=Constant
(4)
LetA=crosssectionalAreaofcylinder
foradibatic process
T.Vg1 =constt
g1
T1V
=T2Vg1
1
2

formonatomic g =
2

5
3
2

T1(A.L1)3 =T2(A.L2)3
2

T1 L2 3
=

T2 L1

AIGTS04/XIIP/XIIIIV16

131.

(1)

134.

(3)
2nd harmonicofanopenpipeis

dH 1

dt l

f1 =

dH

dt 1 l2 2r 2
= =
=
dH
l1 pr p

dt 2
132.
133.

Now,as thispipeisclosedtoobtainresonanceagain
frequencyis slowlyincreaseduptof2

5v
v
which is just greater than
& is
4l
l

\ f2 =

possible frequency

(4)
(3)
hereK= p

2p

135.

(2)
For no beat to be observed.

=p

5
4

f2 = f1

\ n=5

Q y=3cos(100 pt px)

2v v
= __________(1)
2l l

f p' = fs'

l =2cm

176(vs v) 165(vs +v)

(vs 22) =
vs
176(330-v ) 165
=
(330+v)
33022
330
Solvingwegetv=22m/s

Chemistry
136. (1)

136. (1)

P1 P2
=
T1 T2

P1 P2
=
T1 T2

100
101
=
T
T + 1

100
101
=
T
T + 1

T=100K
137. (3)
Initalconc.
Conc.atEq.

T=100K
137. (3)
X+
1
1x
1.25

2Y
2Z
1.5
1
1+2x+0.5
1.52x 1+2x x=0.25
2
0.5

0.5 0.5
Kc =
= 0.05
1.25 2 2
138. (4)
Equation(2)
1
= (Equation(1))
4

X+

izk. lkUnzrk
1
lkE; ij lkUnzrk1x
1.25
Kc =

2Y
2Z
1.5
1
1+2x+0.5
1.52x 1+2x x=0.25
2
0.5

0.5 0.5
= 0.05
1.25 2 2

138. (4)

lehdj.k (2)
=

1
(lehdj.k(1))
4

1/4

K 2 =
K1

1/4

K 2 =
K1

= K1-1/4

= K1-1/4
139. (2)
139. (2)
140. (1)
Since Keq is decreased on increasing the temperature 140. (1)
rkieku c<+kus ij Keq dk eku de gks tkrk gS vr% vfHkf;k
thereforereactionisexothermic.

"ek{ksih gksxhA

AIGTS04/XIIP/XIIIIV16

141. (3)
A

B+C

KP1 =

a 2P1
1- a
2E

KP2 =
KP1
KP2

141. (3)
A
KP1 =

4a 2P2

a 2P1
1- a 2
2E

KP2 =

1- a 2

B+C

KP1

P1
4P2

KP2

4a 2P2
1- a 2

P1
4P2

9
P
= 1
1 4P2

9
P
= 1
1 4P2

P1
36
=
P2
1

P1
36
=
P2
1

142. (2)
n1T
1 =n2T
2

142. (2)
n1T
1 =n2T
2

2
1300= T2
5
T2=750K
=477C
143. (2)

2
1300= T2
5
T2=750K
=477C
143. (2)

T
T
v
M
M
Since both T and M are constant therefore vrms will be
T rFkkM nksuksa
sameinbothcontainers.
144. (4)
144. (4)
v

P + an
(Vnb)=nRT
T

v2

P + an (Vnb)=nRT
T
2

At high pressures
P(Vnb)=nRT
PVPnb=nRT

Z =1+

nkc ds mPp ekuksa ij

P(Vnb)=nRT
PVPnb=nRT
PV

=Z

nRT

PV
Pb
= 1
nRT RT

Z =1+

147.
148.
149.
150.

(3)
(4)
(3)
(1)

Pb
RT

145. (2)
146. (2)
O

PV

= Z

nRT

PV
Pb
= 1
nRT RT

Pb
RT

145. (2)
146. (2)

fu;r gS vr% vrms nksuksa ik=ksa esa leku gksxkA

PO
O
O P
O
O
P
O P

PO
O P
O
O
P
O P
O

147.
148.
149.
150.

(3)
(4)
(3)
(1)

AIGTS04/XIIP/XIIIIV16

151. (4)
Cyclicsilicates
152. (1)
Duetoabsenceofvacanddorbitalsinvalenceshellof
Catom,H2Omolecules willnot attackthereforeCCl4 is
not hydrolysed.
153. (1)
N3 nitrideion
154. (3)
155. (2)
2PCl5 +H2SO4 2POCl3 + SO 2 Cl 2 +2HCl
Sulphuryl
chloride

156. (2)
157. (2)
P4 +3NaOH+3H2O PH3 +3NaH2PO2
Cl2 +2NaOH(Dil) NaCl+NaClO+H2O
3Cl2 +6NaOH(conc.) 5NaCl+NaClO3 +3H2O
4S+6NaOH Na2S2O3 +2Na2S+3H2O
158. (3)
SO2 >NH3 >HCl>CO2 >CH4 >O2 >N2 >H2
159. (1)
P =

nRT 0.1 0.082 300

=
V
1

151. (4)

pf; flfydsV
152. (1)

dkcZu ds la;ksth dks"k esa fjDr d d{kdksa dh vuqifLFkfr ds

dkj.k H2O dk vke.k lEHko ugh gS vr% CCl4 ty vi?kfVr
ugha gksrkA
153. (1)
N3 nitrideion
154. (3)
155. (2)
2PCl5 +H2SO4 2POCl3 + SO 2 Cl 2 +2HCl
Sulphuryl
chloride

156. (2)
157. (2)
P4 +3NaOH+3H2O PH3 +3NaH2PO2
Cl2 +2NaOH(Dil) NaCl+NaClO+H2O
3Cl2 +6NaOH(conc.) 5NaCl+NaClO3 +3H2O
4S+6NaOH Na2S2O3 +2Na2S+3H2O
158. (3)
SO2 >NH3 >HCl>CO2 >CH4 >O2 >N2 >H2
159. (1)
P =

nRT 0.1 0.082 300

=
V
1

=2.46atm
=2.46atm
160. (3)
160.
(3)
PV=nRTistherelationbetweenstatevariablestherefore
PV =nRT voLFkk pjksa ds e/; lEcU/k n'kkZrk gS vr% ;g
it does not depend on path of the process.
ize ds iFk ij fuHkZj ugh djrk A
161. (3)
162. (2)
161. (3)
162. (2)
Kp = PCO2 =0.012bar
Kp = PCO2 =0.012bar
=0.012105 Pa
=1.2103 Pa=1.2kPa

=0.012105 Pa
=1.2103 Pa=1.2kPa

163. (4)
NH3(g) + H2S(g)
0.5
0
atEq.
0.5+x x
0.67
0.17
Kp =0.670.17
=0.11

163. (4)

NH4HS(s)

0.5+2x=0.84
x=0.17

NH4HS(s)

NH3(g) + H2S(g)
0.5
0
atEq.
0.5+x x
0.67
0.17
Kp =0.670.17
=0.11

164. (3)
SO3H

164. (3)
SO3H

NH2
165. (3)

NH2
165. (3)
100 times

100 times

108 MHCl
106 MHCl
Dilution

108 MHCl
106 MHCl
Dilution

[H+]=108 +107 (fromH2O)

=1.1107
\ pHwillbelittlelessthan7

[H+]=108 +107 (fromH2O)

=1.1107
\ pH dk eku 7 ls FkksMk+ de gksrk gSA

0.5+2x=0.84
x=0.17

AIGTS04/XIIP/XIIIIV16

166. (4)

166. (4)
pH=12i.e.[OH]=102

10 -2
=510-3 M
2
Ksp =[Ba2+][OH]2
=(5103)(102)2
=5107
167. (1)
\ [Ba2+]=

[H+ ] =

10-3 x + 10-5x+ 10-6x 10-3

=
=3.3104 M
3x
3

168. (2)

pH=12i.e.[OH]=102
10 -2
=510-3 M
2
Ksp =[Ba2+][OH]2
=(5103)(102)2
=5107
167. (1)
\ [Ba2+]=

[H+ ] =

168. (2)

KE av =

3 RT
2 NA

KE av =

3 8.3 300

2 6 1023
=6.21021 J

169. (4)
170. (2)

3 RT
2 NA

3 8.3 300

2 6 1023
=6.21021 J

=
169. (4)
170. (2)

rH2
rO2

10-3 x + 10-5x+ 10-6x 10-3

=
=3.3104 M
3x
3

PH2

MO2

rH2

PO2

MH2

rO2

PH2

MO2

PO2

MH2

1 32
4 2

1 32
4 2

1
1

1
1

171. (3)
pKb =10 i.e.pKa =4
pH=pKa +log

B -
HB

171. (3)
pKb =10 i.e.pKa =4
pH=pKa +log

1
= 4 +log
1
=4

172. (1)
[Ca(OH)2]=

1
= 4 +log
1
=4

172. (1)
0.5
M
2

0.05
= 0.05 M
2
pOH=log5 log102
=0.7+2=1.3
pH=141.3=12.7
173. (3)
IP>Ksp
(Ag+)[Br]>51013
0.05[Br]=51013
[Br]=1011 M
MolesofKBr=Mv(l)
=1011 1
11
Mass=10 120
=1.2109 gm

[OH]=2

B -
HB

[Ca(OH)2]=

0.5
M
2

0.05
= 0.05 M
2
pOH=log5 log102
=0.7+2=1.3
pH=141.3=12.7
173. (3)
IP>Ksp
(Ag+)[Br]>51013
0.05[Br]=51013
[Br]=1011 M
KBr ds eksy =Mv(l)
=1011 1
11
nzO;eku=10 120
=1.2109 gm

[OH]=2

10

AIGTS04/XIIP/XIIIIV16

174. (2)
SnS2
Sn4+ +2S2
4+
Ksp =[Sn ][S2]2
175. (2)
Videal=222.4
=44.8L
Vobs=22.4103m3=22.4L

174. (2)
SnS2
Sn4+ +2S2
4+
Ksp =[Sn ][S2]2
175. (2)
Videal=222.4
=44.8L
Vobs=22.4103m3=22.4L

Vobs
22.4
=
= 0.5
Z= V
44.8
ideal

Vobs
22.4
=
= 0.5
Z= V
44.8
ideal

176. (2)
176. (2)
P4+3NaOH+3H2O PH3+3NaH2PO2
P4+3NaOH+3H2O PH3+3NaH2PO2
177. (2)
177. (2)
SaltofNH4OHandHClwillbeweaklyacidic,therefore
NH4OH rFkk HCl dk yo.k nqcZy vEyh; gksxk vr% pH<7.
pH<7.
178. (1)
178. (1)
K
1
K
1
K neut =
= a
K neut =
= a
Kh Kw
K
K
h

10 -4
-14

10
179. (3)
0.05MHCl
[H+]=0.05=5102
pH=1.3

0.05NH2SO4

10

= 10

0.05
MH2SO4
2

0.05
[H+]= 2
=0.05M \ pH=1.3
2
180. (3)

10 -4
10-14

= 1010

179. (3)
0.05MHCl
[H+]=0.05=5102
pH=1.3
0.05NH2SO4

0.05
MH2SO4
2

0.05
[H+]= 2
=0.05M \ pH=1.3
2
180. (3)

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