1. Các Định Luật Và Phương Thức Khuếch Tán

QT & TB TRUYN KHI
MMH: 605067
B MN: QT & TB CNHH
KHOA:
K THUT HO HC
TRNG: I HC BCH KHOA TP. HCM
NGI SON: PGS.TS. Trnh Vn Dng
22/9/2013
Truywnf khi A
MSMH: 605067
CHNG 1
CAC NH LUAT VA PHNG THC KHUECH
CH TAN
1.1 Khuech tan phan t va nh luat Fick I
1.2 Khuech tan oi lu
1.3 nh luat Fick II
1.4 Cap khoi va he so cap khoi
1.5 Tnh dong mot pha
22/9/2013
Truywnf khi A
MSMH: 605067
CHNG 1
CH TAN
Hai phng thc khuech tan: Khuech tan phan t
Khuech tan oi lu
Khuech tan phan t la g?
c ac trng bang ai lng nao?
22/9/2013
Truywnf khi A
MSMH: 605067
CHNG 1
CH TAN
Mat o dong xac nh bang nh luat Fick I:
dC A
kmol dGA
J MA 2
DAB
DAB gradCA
d
m .s Fd
Mat o dong
Gradien nong o
He so ty le: DAB he so khuech tan phan t
22/9/2013
Truywnf khi A
MSMH: 605067
CHNG 1
CH TAN
He so khuech tan la g?
Xac nh nh the nao?
dG dC kmol kmol / m m
D :

:
m
s
Fd d m .s
3
AB
22/9/2013
Truywnf khi A
MSMH: 605067
CHNG 1
CH TAN
He so khuech tan la ai lng vat ly, phu thuoc vao:
-Ban chat A, B
-ieu kien khuech tan: T
P
-c xac nh bang: thc nghiem
tnh gan ung
22/9/2013
Truywnf khi A
MSMH: 605067
CHNG 1
CH TAN
Trong chat kh:
Cha t k.ta n
Dkh - KK.106,
2
m /s
Cha t k.ta n
Dkh - H2O.109,
2
m /s - 20 C
22/9/2013
N2 NH3 C6H6 H2 Hi n c SO2 CO2 Dietyl ete O2 CH3OH SO3 H2S HCl C2H5OH
13,2 17,0 7,7 61,1
N2 NH3
1,9
1,8
H2
5,3
21,9
10,3 13,8
7,8
17,8
O2 CO2, N2O Cl2 H2S HCl-120C

2,1
1,8
1,6
Truywnf khi A
2,3
13,3
9,4
Cha t k.ta n
Dkh - KK.106,
2
m /s
MSMH: 605067
8,9 13,0
10,2
AC
7,1 20,2 7,8
10,7
CHNG 1
CH TAN
Trong chat kh:
4 ,35 . 10
D AB
1/ 3
A
1
1
M A M B T 1, 5
1/ 3 2
P
vB
Trong o: MA, MB, g/mol;

vA, vB, cm3/mol;
T, K;
P, atm;
22/9/2013
Truywnf khi A
MSMH: 605067
CHNG 1
CH TAN
Trong chat kh:
P
D D
P
A = CxHyOnNm:
22/9/2013
1, 5
V A xVC yV H nVO mV N Z
Truywnf khi A
MSMH: 605067
CHNG 1
CH TAN
Trong chat kh:
Nguyen t
Cl
N1
N2 NII OII Oan OeP OeD OeC OA
v, cm3/nt 27,0 14,8 24,6 3,7 25,6 37,0 10,5 12,0 15,6 7,4 7,4 9,1 9,9 11,0 12,0 8,3
Phan t H2 O2 N2 KK CO CO2 SO2 NO N2O NH3 H2O H2S Cl2 Br2 I2 COS
v, cm3/nt 14,3 25,6 31,2 29,9 30,7 34,0 44,8 23,6 36,4 25,8 18,9 32,9 48,4 53,2 71,5 51,5
22/9/2013
Truywnf khi A
MSMH: 605067
10
CHNG 1
CH TAN
Trong chat long:
Chat hoa tan amoniac glyxerin sacaro ure KCl HNO3 CaCl2 H2SO4 HCl CuSO4 NaCl AgNO3 C2H5OH
t, 0C
Dct-H2O.105,
2
cm /s
22/9/2013
12
10
18,5
1,64
0,63
1,18
20
25
19,5
1,20 1,95 2,4
Truywnf khi A
18
19,2
17
15
12
0,79 1,53 2,56 0,45 1,09 1,19
MSMH: 605067
11
0,84
11
CHNG 1
CH TAN
Trong chat long:
10
200C:
22/9/2013
D
AB
1
1
M
M
A
AB v v
Truywnf khi A
1/ 3
1/ 3
MSMH: 605067
12
CHNG 1
CH TAN
Trong chat long:
D t D 20 1 b t 20
b
22/9/2013
0,2
3
Truywnf khi A
MSMH: 605067
13
CHNG 1
CH TAN
Trong chat long:
He so A, trong dung moi nc
He so B
Long khong
Cac kh C2H5OH CH3OH CH3COOH H2O C2H5OH CH3OH C3H6O
lien hp
1,00
22/9/2013
1,24
1,19
1,27
4,70
Truywnf khi A
2,00
2,00
MSMH: 605067
1,15
1,00
14
CHNG 1
CH TAN
Trong chat long:
oi vi dung dch loang:
H2O
2,6
22/9/2013
D AB 7 , 4 .10
CH3OH
1,9
C2H5OH
1,5
Truywnf khi A
M BT
0,6
vA
C6H6, ete, heptan

1,0
MSMH: 605067
15
CHNG 1
CH TAN
Trong chat ran:
DAB ~ 1010 cm2/s chia lam ba loai: ran
ran xop
ran keo
Nen khuech tan phu thuoc: kch thc;
hnh dang;
s lng tac gia chung;

22/9/2013
Truywnf khi A
MSMH: 605067
16
CHNG 1
CH TAN
Trong chat ran:
Trong gel M > 10000 (Polson):
22/9/2013
Truywnf khi A
9,4.1010T
DAB
0,33
M A
MSMH: 605067
17
CHNG 1
CH TAN
Trong hon hp nhieu cau t:
Hon hp kh:
Hon hp long:
Dihh
1 yi
k yi
j i Dij
1
k y
0
i
j i Dij
1/ 2
1/ 2
Dihh hh xi Dij j
j i
Trong o: ; Dij; xi, yi; y0i; i; i, j ch so;

22/9/2013
Truywnf khi A
MSMH: 605067
18
CHNG 1
CH TAN
1.2 Khuch tn i lu:
Khuch tn i lu l g?
S di chuyen cua vat chat
nh chuyen ong cua moi trng
Khuech tan oi lu thng kha ln;
xay ra khi co ngoai lc;
lun kem theo khuech tan phan t;
nham san bang nong o;
22/9/2013
Truywnf khi A
MSMH: 605067
19
CHNG 1
CH TAN
1.2 Khuch tn i lu:
Khuch tn i lu l g?
Xac nh bang cach nao:
J AX D X
dC A
d
WC
Trong o: DX he so khuech tan xoay: DX = f(Re).
22/9/2013
Truywnf khi A
MSMH: 605067
20
CHNG 1
CH TAN
1.2 Khuch tn i lu:
Mat o dong khech tan tong:
J A J AM J AX DAB DX
CA
DAB
CA
WC
A
Trong moi trng ng yen (W = 0):
J A J AM J AX D AB
22/9/2013
Truywnf khi A
C A
MSMH: 605067
21
CHNG 1
CH TAN
1.3 nh luat Fick II:
Xet mot nguyen to the tch dV = dxdydz
toa o 0xyz
Lp cn bng vt cht:
- theo ba phng x, y, z;
dz
Mx
dx
- xy ra bng c khuch tn: phn t;

i lu;
22/9/2013
Truywnf khi A
dy
Mx+dx
x
MSMH: 605067
22
CHNG 1
CH TAN
1.3 nh luat Fick II:
w gradC D C
C
Trong mi trng ng yn:
Khi qu trnh n nh:
D C
w gradC D C
Khi n nh trong mi trng ng yn:qu trnh n nh:
C
22/9/2013
2C
x 2
2C
y 2
Truywnf khi A
2C
z 2
MSMH: 605067
23
CHNG 1
CH TAN
1.4 Cap khoi va he so cap khoi:
Cap khoi la g?
y
dGi dFd
y*
y ybm
x
x bm
x*
y x
22/9/2013
Truywnf khi A
MSMH: 605067
24
CHNG 1
CH TAN
He so cap khoi la g?
y
dG i

dFd
y*
y ybm
x
x bm
x*
y x
22/9/2013
Truywnf khi A
MSMH: 605067
25
CHNG 1
CH TAN
Xac nh he so cap khoi:
Sh
A Rem Scn
D
F C
D
D
Sh A Rem Scn
Xac nh theo ly thuyet: thuyet mang

thuyet tham thau
thuyet lp bien khuech tan
thuyet thiet lap be mat mi
thuyet xoay ao be mat phan pha
22/9/2013
Truywnf khi A
MSMH: 605067
26
CHNG 1
CH TAN
Xac nh he so cap khoi:
Xac nh theo s tng t: truyen ien
truyen nhiet
truyen ong lng
22/9/2013
Truywnf khi A
MSMH: 605067
27
CHNG 1
CH TAN
No Ten goi
Ky
hieu
1 Sherwood Sh
2 Reynold Re
3
Schmit
Sc
Peclet
Pe'
Fourier Fo'
Bio
22/9/2013
Bi'
Bieu thc
Ty so gia dong cap va

D
dong dan
w w Ty so gia lc quan tnh va

lc ma sat

Ty so trng toc o va
D D
trng nong o
w
Ty so gia dong oi lu va
ReSc
D
dong dan
D
2
2
D1
Ty so dong cap ngoai va

dong dan trong
Truywnf khi A
Yngha
Ghi chu
ac trng cho cho cap khoi Con goi la chuan

be mat phan pha
so Nu'
ac trng cho cho che o thuy
ong lc cua dong pha
ac trng cho tnh chat vat ly Con goi la chuan
cua dong pha
so Pr'
ac trng cho s khuay tron Goi la chuan so
cua dong pha
Peclet TK
ac trng cho tnh khong on Con goi la chuan
nh cua qua trnh
so Fo TK
ac trng cho qua trnh van Con goi la Bio
chuyen qua be mat phan pha truyen khoi
MSMH: 605067
28
CHNG 1
CH TAN
1.5 Tnh dong mot pha:
a) Tnh toc o hoa tan:
dM
*
C C f
d
2
0
0
d 0

*
*
0
2 ShDC
4 DC
b) Tnh thiet b boc hi:
22/9/2013
Truywnf khi A
MSMH: 605067
29
CHNG 1
CH TAN
22/9/2013
Truywnf khi A
MSMH: 605067
30
CHNG 1
CH TAN
M L C R C V p bm p f p bm p H
22/9/2013
Truywnf khi A
MSMH: 605067
31

1. Các Định Luật Và Phương Thức Khuếch Tán

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1. Các Định Luật Và Phương Thức Khuếch Tán

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Copyright:

Available Formats

QT & TB TRUYN KHI

O2 CO2, N2O Cl2 H2S HCl-120C

7,1 20,2 7,8

Trong o: MA, MB, g/mol;

N2 NII OII Oan OeP OeD OeC OA

1,20 1,95 2,4

0,79 1,53 2,56 0,45 1,09 1,19

C6H6, ete, heptan

s lng tac gia chung;

Trong o: ; Dij; xi, yi; y0i; i; i, j ch so;

Trong o: DX he so khuech tan xoay: DX = f(Re).

Trong moi trng ng yen (W = 0):

Xet mot nguyen to the tch dV = dxdydz

- xy ra bng c khuch tn: phn t;

Trong mi trng ng yn:

Khi qu trnh n nh:

Khi n nh trong mi trng ng yn:qu trnh n nh:

Xac nh theo ly thuyet: thuyet mang

Ty so gia dong cap va

Ty so dong cap ngoai va

ac trng cho cho cap khoi Con goi la chuan

b) Tnh thiet b boc hi:

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