N HCl

no Volume boraks V HCL 380.47

1 10 20.5 381.3701 Mol boraks =
2 10 21.5
N boraks
N HCl 1 = 0.0973 0.0973
N HCl 2 = 0.0928 0.0928
N HCl rata2 = 0.0951

N NaOH
V larutan = 0.5
No V HCl V NaOH Berat NaOh = 4.0599
1 25 14 Mr NaOH = 40
2 25 13.5 mol NaOh = 0.1015
Molaritas = N 0.2030
N NaOH 1 = 0.1698
N NaOH 2 = 0.1761 Faktor Normlts = 1.1740
N NaOH rata2 = 0.1729

Membuat Larutan Asam Asetat dlm Berbagai konsentrasi

Asam asetat 1 N
Asam Asetat 0.8 N =
Berat CH3COOH
Menghitun g Suhu rata2
T rata2 = 42.6667 C

Adsorpsi Asam Asetat

V NaOH 0,2 N
No C CH3COOH. N V As Astt. mL Berat arang, gram
sebelum Sesudah
1 1 5 10.0884 26.4 22.9
2 0.8 5 10.0694 19.9 18
3 0.6 5 10.0012 15.7 13.1
4 0.4 5 10.0164 10 8.5
5 0.25 10 10.0691 12 10.6
6 0.15 15 10.0598 11.5 9.8
7 0.1 25 10.027 14.7 11.6

Mencari Hub ato Persamaan Xa V Ca

1. Metode Langmuir
Xa =

No Y = 1 / Xa X = 1/ Ca X.Y X2
 1 27.7838 1.2628 35.0844 1.5946
2 51.0843 1.6065 82.0678 2.5809
3 37.0780 2.2074 81.8470 4.8727
4 64.3661 3.4020 218.9762 11.5739
5 69.3266 5.4561 378.2528 29.7690
6 57.0397 8.8522 504.9299 78.3623
7 31.1779 12.4644 388.6125 155.3605
jumlah 337.8563 35.2515 1689.7707 284.1140

A= -0.109282557006792

B= 48.8155280546873

No Y percobaan X Y persamaan Kesalahan relatif

1 27.7838 1.2628 48.6775 75.2012%
2 51.0843 1.6065 48.6400 4.7848%
3 37.0780 2.2074 48.5743 31.0058%
4 64.3661 3.4020 48.4437 24.7372%
5 69.3266 5.4561 48.2193 30.4462%
6 57.0397 8.8522 47.8481 16.1144%
7 31.1779 12.4644 47.4534 60.0217%
242.3115%

Kesalahn relatif rata2 metode Langmuir = 34.6159%

2. Metode freundlich Metode Freund

0.9000
No Xa Ca Y = ln Xa X =0.8000
ln Ca XY
1 0.0360 0.7919 -3.3245 0.7000 -0.2333 0.7756
CA

2 0.0196 0.6225 -3.9335 0.6000 -0.4741 1.8647

0.5000
3 0.0270 0.4530 -3.6130 0.4000 -0.7918 2.8609
4 0.0155 0.2939 -4.1646 0.3000 -1.2244 5.0990
5 0.0144 0.1833 -4.2388 0.2000
-1.6967 7.1922
0.1000
6 0.0175 0.1130 -4.0437 0.0000 -2.1807 8.8181
7 0.0321 0.0802 -3.4397 0
-2.5229 0 00
8.6780 00 00
0 00 0 00 00 00 00
0.-9.1239 . . . 0.
0.1621 2.5378 -26.7578 20 4035.288560 8 10

A= 7.95787145859173 XA
B= 6.54981034262279

no X Ypersamaan Y percobaan Kesalahn rta2

1 -0.2333 4.6932 -3.3245 241.1722%
2 -0.4741 2.7772 -3.9335 170.6048%
3 -0.7918 0.2485 -3.6130 106.8789%
4 -1.2244 -3.1936 -4.1646 23.3151%
M
0.9000
0.8000
0.7000
 M
5 -1.6967 -6.9526 -4.2388 64.0214%
6 -2.1807 -10.8037 -4.0437 167.1702% 0.9000
7 -2.5229 -13.5269 -3.4397 293.2571% 0.8000
0.7000
1066.4198%
0.6000
Kesalahan relatif rata2 = 152.3457%
0.5000

CA
0.4000
3. Metode BET 0.3000
No Y Percobaan
X X2 XY 0.2000
1 181.7853 0.8674 0.7524 157.6850 0.1000
0.9000 2 483.9561 0.9045 0.8182 437.7493 0.0000
0.8000 0.0150 0.0200 0.025
3 186.8159 0.8344 0.6962 155.8782
0.7000
4 364.7415 0.8500 0.7225 310.0303
0.6000
5 524.9012 0.8833 0.7803 463.6627
0.5000
Column H
CA

0.4000
6 328.8173 0.8522 0.7262 280.2095
0.3000 7 116.6656 0.7891 0.6227 92.0626
0.2000 2187.6829 5.9810 5.1185 1897.2776
0.1000
A= 0.0000 3420.8193
0.0100 0.0150 0.0200 0.0250 0.0300 0.0350 0.0400 Metode Langmuir
B= -2610.3023
XA 0.9000
No Y percobaan Y persamaan Kesalahn
0.8000relatif
1 181.7853 356.99924254 0.7000 96.3851%
2 483.9561 483.90606436 0.0103%
0.6000
3 186.8159 244.01184619 30.6162%
0.5000
4 364.7415 297.39405799 18.4644%
CA

5 524.9012 411.42136757 0.4000 21.6193%

6 328.8173 304.83062166 0.3000 7.2948%
7 116.6656 89.119686421 0.2000 23.6110%
198.0012%
0.1000
0.0000
Kesalahan rata2 = 28.2859% 0.0200 0.0210

XA
 No N awal N akhir V CH3COOH akhir (V2
3.8047 1 1.00 0.80 250.00
0.0100 2 1.00 0.60 250.00
3 1.00 0.40 250.00
0.1995 4 1.00 0.25 250.00
5 1.00 0.15 250.00
6 1.00 0.10 250.00

t CH3COOH 60

Normalitas
CA 0 CA Xa
0.9129 0.7919 0.0360
0.6882 0.6225 0.0196
0.5429 0.4530 0.0270
0.3458 0.2939 0.0155
0.2075 0.1833 0.0144
0.1326 0.1130 0.0175
0.1017 0.0802 0.0321
 Xa Ca
0.0205 0.7919
0.0206 0.6225
0.0206 0.4530
0.0206 0.2939
0.0207 0.1833
0.0209 0.1130
0.0211 0.0802

Metode Freundlich
X2
0.0544
0.2247
0.6270
1.4991 Column H
2.8789
4.7553
00 0 0 0 00
00 0 00 6.36490 00 0 00 00
0. . . 0 . .
4 60 80
16.4044
10 12
0

XA

Xa Ca
109.2024 0.7919 0.0360
16.0743 0.6225 0.0196
1.2821 0.4530 0.0270
0.0410 0.2939 0.0155
Metode BET
0.9000
0.8000
0.7000
 Metode BET
0.0010 0.1833 0.0144
0.9000 2.032E-05 0.1130 0.0175
0.8000 1.3346E-06 0.0802 0.0321
0.7000
0.6000
0.5000
Column H
0.4000
0.3000
0.2000
0.1000
0.0000
0.0150 0.0200 0.0250 0.0300 0.0350 0.0400 0.0450
XA

de Langmuir

Xa Ca
0.0183 0.7919
0.0196 0.6225
0.0206 0.4530
0.0191 0.2939
Column H
0.0184 0.1833
0.0189 0.1130
0.0420 0.0802

0.0210 0.0220

XA
V CH3COOH yg diambil (V1) Aquadest yang ditambahkan
200.0000 50.0000
150.0000 100.0000
100.0000 150.0000
62.5000 187.5000
37.5000 212.5000
25.0000 225.0000
t Konversi
0 6.1785
30 69.869
60 72.6266 Grafik Waktu vs Konversi
90 74.6566
80
70
60
50

Konversi ( % )
40
30
20
10
0
0 10 20 30 40 50 60 70 80 90 100
t ( menit )
Waktu vs Konversi

Column C

50 60 70 80 90 100
menit )