B GIO DC V O TO

D B I HC NM 2009

D B

Thi gian lm bi: 90 pht, khng k thi gian pht .

(60 cu trc nghim)

( thi c 06 trang)

MN: HA HC- KHI A

M thi 860
H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cho bit khi lng nguyn t (theo vC) ca cc nguyn t:
H = 1; He= 4 ; C = 12; N = 14; O = 16; F=19; Ne=20; Na = 23; Mg = 24; Al = 27;
S = 32; Cl = 35.5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Br = 80;
Ag = 108;Ba =137.
I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40):
Cu 1: Cho mt lung kh CO i qua ng s ng m gam Fe2O3 nung nng. Sau mt thi
gian thu c 10.44 gam cht rn X gm Fe, FeO, Fe2O3 v Fe3O4 . Ha tan ht X trong
dung dch HNO3 c, nng thu c 4.368 lt NO2 (sn phm kh duy nht iu kin
chun). Gi tr ca m l
A. 12
B. 24
C. 10.8
D. 16
Cu 2: t chy hon ton mt hn hp A (glucz, anehit fomic, axit axetic) cn 2.24
lt O2 (iu kin chun). Dn sn phm chy qua bnh ng dung dch Ca(OH) 2, thy khi
lng bnh tng m gam. Gi tr ca m l
A. 6.2
B. 4.4
C. 3.1
D. 12.4
Cu 3: Tng s ht ca mt nguyn t X l 28. X l
A. O
B. N
C. F
D. Ne
+
Cu 4: Bit Cu c s hiu nguyn t l 29. Cu hnh electron ca ion Cu l
A. [Ar]3d104s1
B. [Ar]3d94s1
C. [Ar]3d9
D.[Ar]3d10
Cu 5: Cho phng trnh ho hc:
Al + HNO3 Al(NO3)3 + NO + N2O + H2O (Bit t l th tch N2O: NO = 1 : 3)
Sau khi cn bng phng trnh ho hc trn vi h s cc cht l nhng s nguyn, ti
gin th h s ca HNO3 l
A. 66
B. 60
C. 64
D. 62
Cu 6: a mt hn hp kh N2 v H2 c t l 1: 3 vo thp tng hp, sau phn ng thy
th tch kh i ra gim 1/10 so vi ban u. Tnh thnh phn phn trm v th tch ca
hn hp kh sau phn ng.
A. 20%, 60%, 20%
B. 22.22%, 66.67%, 11.11%
C. 30%, 60%, 10%
D. 33.33%, 50%, 16.67%
Cu 7: Dy gm cc cht no sau y u c tnh lng tnh ?
A. Al, NaHCO3, NaAlO2, ZnO, Be(OH)2
B. H2O, Zn(OH)2, CH3COONH4, H2NCH2COOH, NaHCO3
C. AlCl3, H2O, NaHCO3, Zn(OH)2, ZnO
D. ZnCl2, AlCl3, NaAlO2, NaHCO3, H2NCH2COOH

Trang 1/6 M thi 860

Cu 8: C 4 dung dch trong sut , mi dung dch ch cha mt cation v mt loi anion.
Cc loi ion trong c 4 dung dch gm: Ca2+, Mg2+, Pb2+, Na+, SO42-, Cl-, CO32-, NO3-.
l 4 dung dch g?
A. BaCl2, MgSO4, Na2CO3, Pb(NO3)2
B. BaCO3, MgSO4, NaCl, Pb(NO3)2
C. BaCl2, PbSO4, MgCl2, Na2CO3
D. Mg(NO3)2, BaCl2, Na2CO3, PbSO4
Cu 9: Khi nhit phn hon ton 100 gam mi cht sau: KClO3 (xc tc MnO2), KMnO4,
KNO3 v AgNO3. Cht to ra lng O2 t nht l
A. KClO3
B. KMnO4
C. KNO3
D. AgNO3
Cu 10: Pht biu no sau y l ng:
A. Photpho trng c cu trc mng tinh th nguyn t, photpho c cu trc polime
B. Nitrophotka l hn hp ca NH4H2PO4 v KNO3
C. Thy tinh lng l dung dch m c ca Na2SiO3 v K2SiO3
D. Cacbon monooxit v silic ioxit l oxit axit
Cu 11: Cho cc kim loi: Cr, W , Fe , Cu , Cs . Sp xp theo chiu tng dn cng t
tri sang phi l
A. Cu < Cs < Fe < W < Cr
B. Cs < Cu < Fe < W < Cr
C. Cu < Cs < Fe < Cr < W
D. Cs < Cu < Fe < Cr < W
Cu 12: Ho tan 5.4 gam bt Al vo 150 ml dung dch A cha Fe(NO 3)3 1M v
Cu(NO3)2 1M. Kt thc phn ng thu c m gam rn. Gi tr ca m l
A. 10.95
B. 13.20
C. 13.80
D. 15.20
Cu 13: A l hn hp kh gm SO2 v CO2 c t khi hi so vi H 2 l 27. Dn a mol hn
hp kh A qua bnh ng 1 lt dung dch NaOH 1.5a M, sau phn ng c cn dung dch
thu c m gam mui. Biu thc lin h gia m v a l
A. m=105a
B. m=103.5a
C. m=116a
D. m=141a
Cu 14: Sc V lt CO2 ( iu kin chun) vo 200 ml dung dch X gm Ba(OH)2 1M v
NaOH 1M . Sau phn ng thu c 19.7 gam kt ta, gi tr ca V l
A. 2.24 v 4.48
B. 2.24 v 11.2
C. 6.72 v 4.48
D. 5.6 v 11.2
Cu 15: Ho tan ht m gam Al2(SO4)3 vo nc c dung dch A. Cho 300 ml dung
dch NaOH 1M vo A, thu c a gam kt ta. Mc khc, nu cho 400 ml dung dch
NaOH 1M vo A, cng thu c a gam kt ta. Gi tr ca m l
A. 21.375
B. 42.75
C. 17.1
D. 22.8
Cu 16: A l hn hp cc mui Cu(NO3)2, Fe(NO3)2, Fe(NO3)3, Mg(NO3)2. Trong O
chim 9.6% v khi lng. Cho dung dch KOH d vo dung dch cha 50 gam mui A.
Lc kt ta thu c em nung trong chn khng n khi lng khng i thu c m
gam oxit. Gi tr ca m l
A. 47.3
B. 44.6
C. 17.6
D. 39.2
Cu 17: Cho a mol bt km vo dung dch c ha tan b mol Fe(NO3)3. Tm iu kin lin
h gia a v b sau khi kt thc phn ng khng c kim loi.
A. a 2b
B. b > 3a
C. b 2a
D. b = 2a/3
Cu 18: t chy hon ton 4.872 gam mt Hirocacbon X, dn sn phm chy qua bnh
ng dung dch nc vi trong. Sau phn ng thu c 27.93 gam kt ta v thy khi
lng dung dch gim 5.586 gam. Cng thc phn t ca X l
A. CH4
B. C3H6
C. C4H10

D. C4H8

Trang 2/6 M thi 860

Cu 19: in phn 2 lt dung dch hn hp gm NaCl v CuSO4 n khi H2O b in

phn hai cc th dng li, ti catt thu 1.28 gam kim loi v ant thu 0.336 lt kh (
iu kin chun). Coi th tch dung dch khng i th pH ca dung dch thu c bng
A. 12
B. 13
C. 2
D. 3
Cu 20: Cho t t 150 ml dd HCl 1M vo 500 ml dung dch A gm Na2CO3 v NaHCO3 th
thu c 1.008 lt kh (iu kin chun) v dung dch B. Cho dung dch B tc dng vi dung
dch Ba(OH)2 d th thu c 29.55 gam kt ta. Nng mol ca Na 2CO3 v NaHCO3 trong
dung dch A ln lt l:
A. 0.18M v 0.26M
B. 0.21M v 0.18M
C. 0.21M v 0.32M
D. 0.2M v 0.4M
Cu 21: Cho 3.2 gam Cu tc dng vi 100ml dung dch hn hp HNO 3 0.8M v H2SO4 0.2M,
sn phm kh duy nht l kh NO. S gam mui khan thu c l
A. 7.90
B. 8.84
C. 5.64
D. 10.08
Cu 22: Hy cho bit, phn ng no sau y HCl ng vai tr l cht oxi ha?
A. Fe + KNO3 + 4HCl FeCl3 + KCl + NO + 2H2O
B. MnO2 + 4HCl MnCl2 + Cl2 + 2H2O
C. Fe + 2HCl FeCl2 + H2
D. NaOH + HCl NaCl + H2O
Cu 23 : Cho hn hp kim loi Mg, Zn, Fe vo dung dch cha AgNO3 v Cu(NO3)2.. Sau khi
phn ng xy ra hon ton thu c dung dch X gm 3 mui v cht rn Y gm ba kim loi. Ba
mui trong X l
A. Mg(NO3)2, Fe(NO3)3, AgNO3
B. Mg(NO3)2, Zn(NO3)2, Cu(NO3)2
C. Mg(NO3)2, Zn(NO3)2, Fe(NO3)3
D. Mg(NO3)2, Zn(NO3)2, Fe(NO3)2
Cu 24: Cho 6.4 gam dung dch ru A c nng 71.875% tc dng vi lng d Na thu
c 2.8 lt H2 iu kin chun. S nguyn t H c trong cng thc phn t ru A l
A. 4
B. 6
C. 8
D. 10
Cu 25: Cho cc cng thc phn t sau : C3H7Cl , C3H8O v C3H9N. Hy cho bit s sp xp
no sau y theo chiu tng dn s lng ng phn ng vi cc cng thc phn t ?
A. C3H7Cl < C3H8O < C3H9N
B. C3H8O < C3H9N < C3H7Cl
C. C3H8O < C3H7Cl < C3H9N
D. C3H7Cl < C3H9N < C3H8O
Cu 26: Cho 2.46 gam hn hp gm HCOOH, CH3COOH, C6H5OH, H2NCH2COOH tc
dng va vi 40 ml dung dch NaOH 1M. Tng khi lng mui khan thu c sau khi phn
ng l
A. 3.52 gam
B. 6.45 gam
C. 8.42 gam
D. 3.34 gam
Cu 27: Dy cc cht u lm mt mu dung dch thuc tm l
A. Etilen, axetilen, anehit fomic, toluen
B. Axeton, etilen, anehit axetic, cumen
C. Benzen, but-1-en, axit fomic, p-xilen
D. Xiclobutan, but-1-in, m-xilen, axit axetic
Cu 28: t chy 1.6 gam mt este E n chc c 3.52 gam CO2 v 1.152 gam H2O.
Nu cho 10 gam E tc dng vi 150ml dung dch NaOH 1M , c cn dung dch sau phn
ng thu c 16 gam cht rn khan . Vy cng thc ca axit to nn este trn c th l
A. CH2=CH-COOH
B. CH2=C(CH3)-COOH
C. HOOC(CH2)3CH2OH
D. HOOC-CH2-CH(OH)-CH3
Cu 29: Cht bo A c ch s axit l 7. x phng ho 10 kg A, ngi ta un nng n
vi dung dch cha 1.420 kg NaOH. Sau khi phn ng xy ra hon ton trung ho hn
hp, cn dng 500ml dung dch HCl 1M. Khi lng x phng (kg) thu c l
A. 10.3425
B. 10.3435
C. 10.3445
D. 10.3455

Trang 3/6 M thi 860

Cu 30: Dy ch cha nhng amino axit c s nhm amino v s nhm cacboxyl bng
nhau l
A. Gly, Ala, Glu, Tyr
B. Gly, Val, Tyr, Ala
C. Gly, Val , Lys, Ala
D. Gly, Ala, Glu, Lys
Cu 31: Cho 29.8 gam hn hp 2 amin n chc k tip tc dng ht vi dung dch HCl,
lm kh dung dch thu c 51.7 gam mui khan. Cng thc phn t 2 amin l
A. CH5N v C2H7N
B. C2H7N v C3H9N
C. C3H9N v C4H11N
D. C3H7N v C4H9N
Cu 32: Cho cc cht : amoniac (1) ; anilin (2) ; p-nitroanilin (3) ; p-metylanilin (4) ;
metylamin (5) ; imetylamin (6) . Hy chn s sp xp cc cht trn theo th t lc baz
tng dn .
A . (3) < (2) < (4) < (1) < (5) < (6)
B . (2) > (3) > (4) > (1) > (5) > (6)
C . (2) < (3) < (4) < (1) < (5) < (6)
D . (3) < (1) < (4) <(2) < (5) < (6)
Cu 33: Thy phn 34.2 gam mantz vi hiu sut 50%. Sau tin hnh phn ng
trng bc vi dung dch thu c. Khi lng Ag kt ta l
A. 43.2 gam
B. 32.4 gam
C. 21.6 gam
D. 10.8 gam
Cu 34: C 45.75 gam cao su buna-S phn ng va ht vi 20 gam brom trong CCl4. T l mt
xch butaien v stiren trong cao su buna-S l
A. 1 : 3
B. 1 : 2
C. 2 : 3
D. 3 : 5
Cu 35: Cho cc cht sau : axetilen, axit fomic, fomanehit, phenyl fomat, glucz,
anehit axetic, metyl axetat, mantz, natri fomat, axeton. S cht c th tham gia phn
ng trng gng l
A. 8
B. 7
C. 5
D. 6
Cu 36: nhn bit ba l mt nhn: phenol, stiren, ancol benzylic, ngi ta dng mt
thuc th duy nht l
A. Nc brom
B. Dung dch NaOH
C. Na
D. Ca(OH)2
Cu 37: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3.75. Dn X qua Ni nung nng,
thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l
A. 40%
B. 50%
C. 25%
D. 20%
Cu 38: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l:
A. CH3CHO, C2H5OH, C2H5COOCH3.
B. C2H4(OH)2, CH3OH, CH3CHO.
C. CH3CHO, C6H12O6 (glucoz), CH3OH.
D. CH3OH, C2H5OH, CH3CHO.
Cu 39: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2(anilin),
C6H5OH (phenol), C6H6(benzen), CH3CHO. S cht trong dy phn ng c vi nc brom l
A. 5
B. 6
C. 7
D. 8
Cu 40: Ru X, anehit Y, axit cacboxylic Z c cng s nguyn t H trong phn t, thuc
cc dy ng ng no n chc mch h. t hon ton hn hp 3 cht ny (c s mol bng
nhau) thu c t l mol CO2:H2O=11:12 . Vy cng thc phn t ca X, Y, Z l:
A. CH4O, C2H4O, C2H4O2
B. C2H6O, C3H6O, C3H6O2
C. C3H8O, C4H8O, C4H8O2
D. C4H10O, C5H10O, C5H10O2
II. PHN RING [10 cu] :Th sinh ch c lm mt trong hai phn (phn A hoc B)
A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50)
Cu 41: Cho cc dung dch sau: Na2CO3, NaOH v CH3COONa c cng nng mol/l v c
cc gi tr pH tng ng l pH1, pH2 v pH3. S sp xp no ng vi trnh t tng dn pH.
A. pH3 < pH1 < pH2
B. pH3< pH2 < pH1
C. pH1 < pH3 < pH2
D. pH1 < pH2 < pH3
Trang 4/6 M thi 860

Cu 42: Cho 13.8 gam axit A tc dng vi 16.8 gam KOH , c cn dung dch sau phn ng thu
c 26.46 gam cht rn. cng thc cu to thu gn ca A l
A. C3H6COOH
B. C2H5COOH
C. CH3COOH
D. HCOOH
Cu 43: Chn pht biu ng:
A. Tnh oxi ha ca Ag+ > Cu2+ > Fe3+ > Ni2+ > Fe2+
B. Tnh kh ca K > Mg > Zn > Ni > Fe > Hg
C. Tnh kh ca K > Fe > Cu > I- > Fe2+ > Ag
D. Tnh oxi ha ca Ag+ > I2 > Fe3+ > Cu2+ > S2Cu 44: Cn ti thiu bao nhiu gam NaOH (m1) v Cl2 (m2) phn ng hon ton vi 0.01
mol CrCl3. Gi tr ca m1 v m2 ln lt l
A. 3.2 v 1.065
B. 3.2 v 0.5325
C. 6.4 v 0.5325
D. 6.4 v 1.065
Cu 45: Ch dng mt thuc th phn bit cc kim loi sau: Mg, Zn, Fe, Ba?
A. Dung dch NaOH
B. Dung dch H2SO4 long
C. Dung dch HCl
D. Nc
Cu 46: t chy hon ton 1 mol ancol no A cn 3.5 mol O2. Cng thc phn t ca A l
A. C2H6O
B. C2H6O2
C. C3H8O3
D. C3H6O2
Cu 47: Cho 0.1 mol cht X ( CH6O3N2) tc dng vi dung dch cha 0.2 mol NaOH un nng
thu c cht kh lm xanh giy qu tm m v dung dch Y. C cn dung dch Y thu c m
gam rn khan. Gi tr ca m l
A. 8.5
B. 12.5
C. 15
D. 21.8
Cu 48: Ho tan 19.2 gam Cu vo 500 ml dung dch NaNO 3 1M, sau thm vo 500ml dung
dch HCl 2M . Kt thc phn ng thu c dung dch X v kh NO duy nht, phi thm bao
nhiu ml dung dch NaOH 1M vo X kt ta ht ion Cu2+
A. 600
B. 800
C. 400
D. 120
Cu 49: Thy phn hon ton mt lng mantoz, sau cho ton b lng glucoz thu c
ln men thnh ancol etylic th thu c 100 ml ancol 460. Khi lng ring ca ancol l
0,8gam/ml. Hp th ton b kh CO2vo dung dch NaOH d thu c mui c khi lng l
A. 106 gam
B. 84.8 gam
C. 212 gam
D. 169.6 gam
Cu 50: Hirat ho 3.36 lt C2H2 ( iu kin chun) thu c hn hp A ( hiu sut phn ng
60%) . Cho hn hp sn phm A tc dng vi dung dch Ag 2O/NH3 d thu c m gam cht
rn. Gi tr ca m l
A. 19.44
B. 33.84
C. 14.4
D. 48.24
B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60)
Cu 51: Xt phn ng thun nghch sau:
SO2(k) + NO2(k) SO3(k) + NO(k).
Cho 0.11(mol) SO2, 0.1(mol) NO2, 0.07(mol) SO3 vo bnh kn 1 lt. Khi t cn bng ha hc
th cn li 0.02(mol) NO2. Vy hng s cn bng KC l
A. 18
B. 20
C. 23
D. 0.05
Cu 52: Cho Na d tc dng vi a gam dung dch CH3COOH. Kt thc phn ng, thy khi
lng H2 sinh ra l
A. 10%

11a
. Vy nng C% dung dch axit l
240

B. 25%

C. 4.58%

D. 36%

Trang 5/6 M thi 860

Cu 53: Cho 0.1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy
ng ng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32.4 gam
Ag. Hai anehit trong X l
A. CH3CHO v C2H5CHO.
B. CH3CHO v C3H5CHO.
C. HCHO v CH3CHO.
D. HCHO v C2H5CHO.
Cu 54: Dy gm cc kim loi u tc dng c vi dung dch FeCl3 l:
A. Fe, Mg, Cu, Ag, Al
B. Fe, Zn, Cu, Al, Mg
C. Cu, Ag, Au, Mg, Fe
D. Au, Cu, Al, Mg, Zn
Cu 55: Cn bao nhiu a mol K2Cr2O7 v b mol HCl iu ch c 3.36 lit Cl2 iu kin
chun. Gi tr a v b ln lt l:
A. 0.05 v 0.7
B. 0.05 v 0.35
C. 0.1 v 0.7
D. 0.1 v 0.35
Cu 56: Ha tan hon ton hn hp gm FeS2 0.24 mol v Cu2S vo dung dch HNO3 va
thu c dung dch X (ch cha hai mui sunfat) v V lt kh NO duy nht . Gi tr ca V l
A. 34.048
B. 35.84
C. 31.36
D. 25.088
Cu 57: nhn bit cc kh: CO2, SO2, H2S, N2 cn dng cc dung dch:
A. Nc brom v NaOH
B. NaOH v Ca(OH)2
C. Nc brom v Ca(OH)2
D. KMnO4 v NaOH
Cu 58: t chy hon ton 1 mol ancol no A cn 2.5 mol O2. Cng thc phn t ca A l
A. C2H6O
B. C2H6O2
C. C3H8O3
D. C3H6O2
Cu 59: Cho 20 gam hn hp 3 amin no n chc l ng ng k tip c t l mol tng ng l
1: 10 : 5, tc dng va vi dung dch HCl thu c 31.68 gam hn hp mui. Tng s ng
phn ca 3 amin trn l
A. 7
B. 14
C. 28
D. 16
Cu 60: Ln men m gam glucz vi hiu sut 90%, lng CO 2 sinh ra hp th ht vo nc
vi trong thu c 15 gam kt ta v khi lng dung dch gim 5.1 gam. Gi tr m l
A. 20.25
B. 22.5
C. 30
D. 45
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