One Year Phase Test: Narayana

NARAYANA
One Year Phase Test

BATCH: SCCP 4501
for
IIT-JEE, 2005
PHASE - I
CHEMISTRY
Code: OYPTC 02
Time: 2 Hours
Maximum Marks: 60
Note:
i)
Attempt all questions.
ii)
Separate answers are to be given on the separate pages.
iii)
Use of logarithmic table is NOT PERMITTED.
iv)
Use of calculator is NOT PERMITTED.
Useful Data:
Gas Constant
Avogadro's Number
Plancks constant
1 Faraday
1 calorie
1 amu
1 eV
Atomic No:
Atomic Masses:
=
8.314 J K1 mol1
=
0.0821 Lit atm K1 mol1
=
1.987 2 Cal K1 mol1
Na =
6.023 1023
h
=
6.625 1034 J s
=
6.625 1027 erg s
=
96500 Coulomb
=
4.2 Joule
=
1.66 1027 kg
=
1.6 1019 J
H = 1, D = 1, Li = 3, Na = 11, K = 19, Rb = 37, Cs = 55, F = 19, Ca = 20, He = 2, O = 8, Au = 79, Ni = 28
He = 4, Mg = 24, C = 12, O = 16, N = 14, P = 31, Br = 80, Cu = 63.5, Fe = 56, Mn = 55, Pb = 207, Au = 197,
Ag = 108, F = 19, H = 2, Cl = 35.5, Sn = 118.6, Na = 23
Name of the Candidate:
Batch Number
OYPT-Ph-I-CH-2
NARAYANA IIT ACADEMY

South Delhi Centre:
47B, Kalu Sarai, New Delhi - 110 016.

Ph.: 51828300/01/02, 30946351
2/40, Adjacent Central Market, West Punjabi Bagh,
New Delhi - 110 026.
Ph.: 55479790, 30946351
West Delhi Centre:
SECTION A
1.
Two substance A and B are present to the extent that the concentration of A is four times than
that of B. If half life of A is 5 min and that of B is 15 min. Find the time when A and B will
have the same concentration.
(1)
2.
The initial pressure of cyclopropane

(C3H6) in a 500 cc vessel was 702.6 mm Hg at 500 K.
(2)
Calculate the concentration of cyclopropane that remained after 720 sec., if the specific
reaction rate constant for its isomerization was 5.95 10-4 sec -1.
3.
When 1M CH3COOH is reacted with 1 M NaOH solution at 25, then what is the pH of the
solution ?
4.
A teacher enters a classroom from front door while student from back door. There are 13
equidistant rows of benches in the classroom. The teacher releases N2O from the front while
the student releases the weeping gas (C 6H10OBr) from the last bench. At which row will the
student start laughing and weeping simultaneously?
5.
If the value of activation energy is decreased by 20 Kcal at 298 k, then what will be the effect
on the equilibrium constant ?
6.
The
vander Waals constant
for
gases
N 2,
O2,
O3
and
He
are
5 104 , 4 10 3 , 2 10 2 and 4 10 5 in dm3 per mole respectively, then arrange these gases in
increasing order of their compressibility.
7.
What will be the effect on the equilibrium constant for the exothermic reaction on increasing
the temperature?

South Delhi Centre: 47B, Kalu Sarai, New Delhi - 110 016. Ph.: 51828300/01/02, 30946351
West Delhi Centre: 2/40, Adjacent Central Market, West Punjabi Bagh, New Delhi - 110 026. Ph.: 55479790, 30946351
OYPT-Ph-I-CH-3
8.
For the following parallel chain reaction,

4B
1 102 s 1
A
2 103 s 1
5C
then find out the overall half-life of A.
9.
0.635g of a cupric salt is dissolved in water and excess of KI is added in the solution and the
M
2
liberated iodine requires 25 ml Na 2S2O3 where it converts into S4 O6 . What is the % of
5
copper in the salt?
10.
3.16 g of KMnO4 is completely reacting with 56 ml H2O2 in acidic medium, then what is the
volume strength of H2O2 ?
SECTION B
11.
The equilibrium constant K for the reaction

2NH
N +3H
2
is 1.64 10 at 400 C and 1.44 10 at 500 C. Calculate the heat of formation of NH in

this temperature range. [log 0.0878 = 1.056]
12.
A solution was prepared by mixing 200 mL of 0.125 M propionic acid with 100 mL of 0.25
M KOH. What was the pH of the solution ? ( Ka = 1.34 105 ). [log 4.3 = 0.6334]

OYPT-Ph-I-CH-4
13.
A 1st order reaction is 50% complete in 30 min at 270C and in 10 min at 470C. Calculate the
(i) Rate constant for reaction at 270C and 470C.
(ii) Energy of activation for the reaction.
(iii) Energy of activation for the reverse reaction if heat of reaction is 50 KJ mol1
[log3 = 0.4771]
14.
A solution of weak acid was titrated with base NaOH. The equivalence point was reached
when 36.12 mL of 0.1M NaOH have been added. Now 18.06 mL of 0.1 M HCl were added to
titrated solution, the pH was found to be 4.92. What is Ka of acid?
[antilog (4.92)=1.2105]
15.
A mixture of H2C2O4 and NaHC2O4 with impurities weighing 2.82 gm was dissolved in water
and the solution made upto 1L. 10 mL of this solution required 3.0 mL of 0.1N NaOH
solution for complete neutralization, and 10 mL of same solution in hot dil. H 2SO4 medium
required 4 mL of 0.02 M KMnO4 for complete neutralization. Calculate the amount of
H2C2O4 and NaHC2O4 in the mixture.
N
HCl using phenolphthalein
10
indicator required 25 ml HCl to 1st end point. At this stage methyl orange was added and
addition of acid was continued. The IInd end point was reached after further addition of 5 mL
of the acid. Calculate the amount of Na2CO3 and NaOH in one litre of the solution?
6.
25 mL of a mixture of NaOH + Na 2CO3 when titrated with
1
7.
What amount of activation energy (in kcal) is needed for 10 3% molecule to cross over the
activation barrier at 27C?
18.
Equal moles of A2(g) and B2(g) are introduced into a sealed container and heated to certain
temperature where following equilibria was established:
(i) A2(g) + B2(g)
kp = 2
2AB(g),
OYPT-Ph-I-CH-5
(ii) A2(g) + 3B2(g)

2AB3 (g)
If partial pressure of ClF and ClF 3 at equilibrium are 8 atm and 4 atm respectively. Calculate
Kp for the second equilibrium reaction.
19.
For the following sequential chain reaction,

2
5
A
k1 10
min B k 2 10 min C
then what will be the concentration of C at time, t = 69.3 minutes. Given that the initial
concentration of A is = 1 M
20.
The value of C p / C v for O3 is 7/6 at very high temperature where all degree of freedom
assumed to be excited. Then predict that the structure of O3 will be linear or non-linear.
NARAYANA
One Year Phase Test
BATCH: SCCP 4501
for
IIT-JEE, 2005
PHASE - I
CHEMISTRY
SOLUTIONS
SECTION A
1.
[A]0 = 4 [B]0 , [A]t = [B]t

0.693
0.693
kA =
kB =
15
5
4[B
0.693 2.303
0]
log
5
t
[B]t
...(1)

OYPT-Ph-I-CH-6
[B ]
0.693 2.303
log 0
15
t
[B]t
[B0 ] = x
let
[B]t
...(2)
Dividing eqn. (1) by (2) we get x =2

Putting the value of x =2 in eqn (2)we get t = 15 min
2.
Number of moles of C3H6 initially = n =

702.6 500
760 0.082 1000 500
n = 0.0112 moles
2.303
0.0112
log
5.95 10-4 =
720
0.0112 x
x = 1.5 10-2 mol / L
PV
RT
n=
3.
CH3COONa + H2 O
CH3 COOH + NaOH
CH3COO
CH3COOH + OH
(1 - )c
c
c
2
Kw
c
Kh =
Ka (1 )
10 9
= 2 0.5
1.8
1 109
=
0.11108
1.8 0.5
[OH ] = 0.11 104 = 0.33 104

pH = 8.96.
Kh =
4.
R N2O
R C6 H10OBr
M C6 H11OBr
M N 2O
x
179
13 x
44
x=4
5.
No. effect on equilibrium constant because H will remain constant.
6.
He < N2 < O2 < O3
7.
On increasing the temperature of the exothermic reaction, the equilibrium constant will
decrease because the equilibrium will shift towards the backward direction.
K overall k1 k 2
= 102 + 103 s1
= 1.1102 s 1
8.

OYPT-Ph-I-CH-7
t1/ 2
0.693
0.693
s
k
1.110 2
69.3
s 6.3s
11
9.
From question, n-factor of Na2S2O3 = 1

M
5
required m mole of Na2S2O3 = 25 ml
5
Meq. of Na2S2O3 = 5 = Meq. of I2 reacted

= Meq. of KI reacted
= Meq. of Cu+2 reacted.
Wt. of Cu+2 in the copper salt (n-factor of Cu+2 = 1)

5
63.5g
1000
= 0.3175g
% of Cu+2 in the copper salt
0.3175
100 = 50%
0.6315
10.
Let the Volume strength of H2O2 = x

n-factor of KMnO4 in acidic medium = 5
m eq of KMnO4 = m eq. of H2O2

3.16
x
1000 56
158 / 5
5.6
x = 10.
SECTION B
11.
K2
H 1 1
K1 2.303R T1 T2
1
0.144
H
1
log
3
1.64 2.303 1.987 10 673 773
log
H = 25.14/2 kcal /mole

= 12.57 kcal /mole
12.
C2H5COO + H2O
OH + C2H5COOH
(Ka = 1.34 105)
Kw
11014
0.746 109
Kh =
K a 1.34 10 5
On applying following equation we get concentration
2C
Kh =
(1 )
Concentration = 0.025 moles / litre
= 0.043 10-4
log [OH- ] = pOH
OYPT-Ph-I-CH-8
= 6.966
pH = 14 6.966 = 7.034.
13.
For 1st order reaction, K =
0.693
t 1/ 2
0.693
2.31102 min1
30
0.693
6.93 102 min1
at 470C K2 =
10
K 2 E a [T2 T1 ]
(ii)
Now, 2.303 log10
K1 R T1T2
Ea = 43850 J mol1
= 43.85 KJ mol1
(iii) For a reaction E a F.R E a B.R = H
43.85 - E a B.R = - 50.0
(i) at 270C K1 =
E a B.R = 43.85 + 50.0 = 93.85 KJ mol1
14.
For complete neutralization,

Meq. of acid = Meq. of NaOH
= 36.12 0.1 = 3.612
HA + NaOH NaA + H2O
3.612
3.612
0
0
0
0
3. 612
3. 612
Now 1. 806 Meq. of HCl (18.06 0.1) are added to this solution containing 3.612 Meq.
of NaA
NaA +
HCl
NaCl +
HA
Meq. before reaction 3. 612
1. 806
0
0
Meq. after reaction 1. 806
0
1. 806
1. 806
The solution has HA and NaA and thus, acts as buffer
1.806
pH = - log Ka + log
1.806
4. 92 = - log Ka
Ka= 1.2 10-5
15.
Let
H2C2O4 = x gm
NaHC2O4 = y gm
For I titration: (of 1L mixture) (Acid Base Titration)
eq. of H2C2O4 + eq. of NaHC2O4 = eq. of NaOH used for 1000 mL.
y 3 0.1
x

100
45 112 1000

x
y
0.03
. . . . . (i)
45 112
For II titration:
(Redox titration)
x
y
4 0.02 5
100
M

112
1000
45
2
OYPT-Ph-I-CH-9
x
y
0.04
45 56
Calculating x and y by (i) and (ii)
X = 0.9 gm, y = 1.12 gm
. . . . . (ii)
16.
Let NaOH = a gm.

Na2CO3 = b gm.
b
1
a
40 106 1000 = 10 25
1
b
106 1000 10 5
a = 1.6gm., b = 2.12 gm.
17.
Fraction of molecules crossing over the activation energy is,

Ea
103
e RT
100
E
105 e RTa
ln 105
Ea
RT
2.303 log 10 5
Ea
RT
Ea
RT
E a 2.303 5 RT
2.303 5 2 300
2.303 3 kcal 6.909 kcal.
2.303 ( 5)
18.
Let the initial pressure of F2(g) is P0 atm, therefore initial pressure of Cl2(g) is P0 atm.
Now,
(i)
Cl2(g) + F2(g)
2ClF(g), Kp = 2
t = 0 P0
P0
0
P0 x y
P0 x 3y
2x = 8 atm
For,
(ii)
Cl2(g) + 3F2(g)
2ClF3(g)
t = 0 P0 x
P0 x
0
At eq. P0 x y
P0 x 3y
2y = 4
Q 2x = 8
x = 4 atm
2y = 4
y = 2 atm
st
From question, for 1 equilibrium,
2
PClF
k p1 2
PF2 .PCl2
(8) 2
(P0 4 2) (P0 4 3 2)
(P0 6)(P0 10) 32
2
P02 16 P0 28 0
OYPT-Ph-I-CH-10
P02 14 P0 2 P0 28 0
P0 (P0 14) 2(P0 14) 0
(P0 2)(P0 14) 0
P0 2 or, 14
P0 14 atm
Q P0 2 atm ,
Now, k pII
(2y) 2
(4) 2
atm 2
3
3
(P0 x y) (P0 x 3y)
8 4
1
atm 2
32
19.
k1 k 2
So, the sequential reaction converts into with the slowest step
A k1 C
t = 0, [A]0
0
t = t1, [A]0 x x
[A]0
Now, k1t ln
[A]0 x
1
69.3 10 2 ln
1 x
1
0.693 ln
1 x
1
ln 2 ln
1 x
1
1
1
2
x M [C]t M
1 x
2
2
20.
If O3 be non-linear, then its rotational degree of freedom would be = 3.

Let the rotational degree of freedom of O3 = n
then for O3 molecule, transtational degree of freedom = 3
rotational degree of freedom = n
vibrational degree of freedom = 6 n.
R
R
C v (total) 3 h (6 n) R
2
2
R
R
R
C p (total) 3 n (6 n) R
2
2
2
R
R
C p 3 2 n 2 (6 n) R R
r
R
R
Cv
3 n (6 n) R
2
2
7 3 n 2(6 n) 2
r
6
3 n 2(6 n)
7
3 n 12 2n
7n
6 3 n 12 2n 2 15 n
n=3
OYPT-Ph-I-CH-11
O3 is a non-linear molecule.


One Year Phase Test: Narayana

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NARAYANA

One Year Phase Test

Attempt all questions.

Separate answers are to be given on the separate pages.

Use of logarithmic table is NOT PERMITTED.

Use of calculator is NOT PERMITTED.

Name of the Candidate:

NARAYANA IIT ACADEMY

47B, Kalu Sarai, New Delhi - 110 016.

West Delhi Centre:

The initial pressure of cyclopropane

NARAYANA IIT ACADEMY

For the following parallel chain reaction,

then find out the overall half-life of A.

The equilibrium constant K for the reaction

is 1.64 10 at 400 C and 1.44 10 at 500 C. Calculate the heat of formation of NH in

NARAYANA IIT ACADEMY

25 mL of a mixture of NaOH + Na 2CO3 when titrated with

(ii) A2(g) + 3B2(g)

For the following sequential chain reaction,

[A]0 = 4 [B]0 , [A]t = [B]t

NARAYANA IIT ACADEMY

Dividing eqn. (1) by (2) we get x =2

Number of moles of C3H6 initially = n =

[OH ] = 0.11 104 = 0.33 104

No. effect on equilibrium constant because H will remain constant.

He < N2 < O2 < O3

NARAYANA IIT ACADEMY

From question, n-factor of Na2S2O3 = 1

Meq. of Na2S2O3 = 5 = Meq. of I2 reacted

Wt. of Cu+2 in the copper salt (n-factor of Cu+2 = 1)

Let the Volume strength of H2O2 = x

m eq of KMnO4 = m eq. of H2O2

H = 25.14/2 kcal /mole

For 1st order reaction, K =

E a B.R = 43.85 + 50.0 = 93.85 KJ mol1

For complete neutralization,

Let NaOH = a gm.

Fraction of molecules crossing over the activation energy is,

If O3 be non-linear, then its rotational degree of freedom would be = 3.

NARAYANA IIT ACADEMY

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