Professional Documents
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2010
SPECIAL ISSUES
80
Milena Pani
BELGRADE
2010.
80
, ,
2010.
/ PUBLISHER
11000 , 9,
Geographical institute Jovan Cviji SASA
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25.05.2009. /
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. / Prof. dr Milutin Ljeevi
. / Prof. dr Dejan Filipovi
/ LANGUAGE EDITING
/
/ TECHNICAL EDITOR
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/ COVER DESIGN
/ Dejan Atanasovski
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20.
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, (La Grega et al,
2001). ,
(,
, 2000):
- : , , ,
;
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, , ;
- : , .
13
,
,
. ,
, , , , , ,
, .
, ,
, ,
, ,
, ,
.
(Household Hazardous Waste)
, ,
(, , ,
),
(http://www.epa.gov/garbage/hhw.htm). ,
, , , ,
, , , (La Grega et al, 2001). ,
,
( 1),
(Dorian, 1988). -
,
,
,
(La
Grega et al, 2001).
,
, ,
.
EPA1,
1000 kg
, (La Grega et al,
2001).
( 1.): ,
,
( -,
1
14
, 85%
), ,
(, , 2000; La Grega et al, 2001).
1.
Table 1. Prticipation of hazardous waste from household and commercial sector
40,0%
30,1%
16,4%
,
7,5%
,
2,5%
3,5%
Izvor: , , 2000
, (, ,
)
.
,
.
, , ,
, ,
, .
,
,
20. EPA, , 2
(Pichtel, 2005).
,
,
- ,
,
,
.
2
Medical Waste Tracking Act 1988.
1991. ,
(Pichtel, 2005).
15
,
,
,
.
,
, - .
,
.
20. -
,
-. ,
,
, .
91/689/EC ,
( I);
( II) ( III).
(
2).
, 91/689/EC
, -
.
16
2.
Table 2. Properties of wastes which render them hazardous
21-55C
21C;
,
,
,
: , European Waste Katalogue (2002)
-,
.
,
17
,
, , .
, ,
EPA, (La
Grega et al., 2001). ,
, Solid Waste Disposal Act 1965.
, . Resource
Conservaton and Recovery Act (RCRA)3 ,
: ,
, ,
: 1) ,
, ; 2)
,
, ,
.
, RCRA-,
: 1) ; 2)
; 3) ; 4)
4.
,
.
3
RCRA ,
EPA .
, .
:
.
, (Watts, 1998:13-14).
4
C,
, (1)
, , ; (2)
; (3)
, ,
. .
(4)
, (EPA,
2001).
18
(http://www.epa.gov/epaoswer/hotline/training/defsw.pdf).
,
, :
, ,
(Watts, 1998). ,
(Blackman, 2001):
-
;
- ;
-
;
- ,
.
.
.
,
(Watts, 1998):
( 3)
,
(Watts,
1998). EPA
(Blackman,
2001):
- ,
;
-
.
19
3. ()
Table 3. US Hazardous waste characteristics
- , ,
24% , 60C;
-
, ,
;
-
;
- ;
- pH 2.0 12.5;
-
6.36 mm/;
- ;
- ;
-
;
- ,
;
- , pH 2 - 12.5,
;
-
;
-
;
- ,
;
- ,
Tohicity Characheristic Leaching Procedure (TCLP),
,.
31
8 .
, .
,
.
: Watts, 1998
,
,
.
,
,
,
.
20
,
.
,
. 1994.
5 6,
-
.
,
(2002) 20
.
. ,
91/689/C
(*).
:
1. , , ,
;
2. , , ,
, ;
3.
, , ;
4. , ;
5. ,
;
6. ;
7. ;
8. , ,
, ;
9. ;
10. ;
11.
;
12.
;
13. ;
5
21
14.
15.
16.
17.
, ;
, , ;
;
(
);
18. /
(
,
);
19.
, off-site
;
20. ( ,
),
.
,
, - . EPA
,
, 3
(http://www.epa.gov/epaoswer/osw/hazwaste.htm):
1. ;
2. ;
3. ;
, .
.
F. EPA ,
, , ,
,
(La Grega et al, 2001).
, (Blackman, 2001).
. :
22
, , ,
, , ,
, ,
, , , ,
, , ,
(La Grega et al, 2001).
, , , ,
(,
, 2000).
( )
,
( U),
(La Grega et al,
2001). ,
, , (DDT) (Blackman, 2001).
, EPA ,
, ,
(, , 2000).
,
, e
, .
, .
,
(),
()
.
,
( )
23
,
,
.
(, ,
) ,
,
. ,
creadle-to-grave ,
, .
, -
RCRA-,
(Blackman, 2001):
1. (LQG) 1000 kg
1 kg 7 ;
2. (SQG) 1000 kg,
100 kg , 1 kg
;
3. ( ) (CESQG)
100 kg 1 kg
;
,
RCRA Hazardous Waste Reporting System,
.
, , Toxic Release Inventory
600
(McGlinn, 2000). ,
,
(Blackman, 2001).
, -,
,
( ),
7
EPA
,
. F P.
24
, ( ).
. ,
, -.
- -
,
, ,
.
,
, ,
.
,
, -.
, 30-80%
,
25% 68-76% (, 2001).
, ,
,
,
,
.,
,
(, 1999).
, - 36
(, 1999).
(, , , , , , , ,
, , , , , , ,
, ),
(25%),
(13%),
(13%),
(10%), (8%),
. ,
1%
25
, ,
(, 2001).
4. e
- -
Table 4. The total amount of hazardous waste in EU and US
1992
423 000
1994
513 000
1995
577 000
1996
606 000
1990
66 000
1992
99 000
1995
248 000
1996
230 000
1990
3 246 000
1991
3 387 000
1995
2 708 000
1996
3 401 000
1990
1 040 000
1992
1 513 000
1993
1 520 000
1994
890 000
1995
868 000
1996
959 000
1997
1 271 000
1994
3 394 353
1990
2 936 000
1992
2 452 000
1993
2 077 000
1991
1993
1995
2003
30 000 000
RCRA
26
e
,
( 4).
20. ,
, /
(, 1999).
-
,
.
, 4,
,
.
,
,
(McGlinn, 2000).
,
, ,
.
,
,
, .
, ,
, (, ,
2000).
, on-site, ,
off-site
cradle-to-grave (La Grega et al., 2001).
,
,
, .
,
, 90 ,
27
,
(Watts, 1998; Pichtel, 2005):
- (, 8
), , (
hazardous waste);
-
.
;
- .
,
.
180 ( 270
),
6000 kg ,
(Pichtel, 2005).
,
.
, , , ,
,
.
,
,
. ,
. , -
,
(Liu, 2000).
EPA ,
, , ,
.
,
, ,
.
28
,
, .
,
, ,
(McGlinn, 2000). ,
,
.
,
, ,
(
).
,
.
: , ,
, ,
,
(, , 2000).
1997. ,
98,6% ,
80% . 1,4%
, 20%
(Blackman, 2001).
. ,
,
, ,
,
.
,
, , ,
,
.
29
RCRA- (),
(Blackman, 2001):
-
, , ;
-
,
;
- ,
.
, ,
-,
(Blackman, 2001):
,
Uniform Hazardous Waste Manifest,
.
EPA,
,
(Blackman, 2001).
Uniform Hazardous Waste
Manifest,
,
.
,
, , ;
;
;
.
,
, (Blackman,
2001). ,
(Pichtel, 2005). ,
,
,
.
, EPA
30
.
,
, , , , ,
.
,
,
,
, .
,
.
,
-, ,
,
,
(, ,
2000). ,
,
10 ,
(Blackman, 2001).
,
, , ,
.
,
.
,
(Pichtel, 2005):
, , ;
,
(23 );
, ,
;
(),
;
31
,
;
, EPA;
, ;
, Uniform Hazardous
Waste Manifest
.
,
,
.
. ,
, , 1957.
ADR,
(Jovanovi, 2004).
,
, 9 ( 5).
1
1
1
2
3
4.1
4.2
4.3
5.1
5.2
6.1
6.2
7
8
9
: Jovanovi, 2004
5.
Table 5. The classes of dangerous goods
,
,
32
1: a (:
Fig. 1. Table advisories for transport vehicles marking (ADR)
ADR)
,
. ,
( , ,
) ( 1).
(2 3 )
( 6), (4 )
.
6.
Table 6. Basic and addition danger on table advisories
2
3
4
5
6
8
0
1
2
3
5
6
9
: Jovanovi, 2004
33
,
, X ,
,
(Jovanovi, 2004).
,
,
,
.
,
, ,
,
.
.
,
.
Assante-Duah Nagy (2001)
:
-
;
- ,
;
-
;
-
;
-
;
- ;
- ,
;
- ,
, ;
34
,
;
- ,
.
,
OECD-9.
,
OECD ,
,
(, , 2000).
, ,
,
,
( ,
,
),
(Toovi i dr,
1998). ,
. ,
(Mihajlov, Petkovi, 1998).
, 1992.
OECD-
,
,
.
(Krueger, 1999).
OECD-
.
9
35
, ,
,
259/93/C10
.
OECD-,
-
,
.
,
,
(Krueger, 1999).
1995. -,
, 1.665.500 , 85%
-, 8% OECD-,
, -, , , 6%
.
OECD- ,
,
. , .
16.000 1%
, , ,
(, 1999).
,
.
75% - ,
20% .
, ,
, , .
,
, ,
10
Council Regulation 259/93/C on Supervision and control of shipments of waste within, into
and out of the European Community
36
.
,
, ,
.
,
,
, ,
(Blackman, 2001).
,
, ,
(Adeleke, 2001).
, ( 2),
,
,
(Blackman, 2001; Soesilo, Wilson, 1995).
,
,
.
2.
Fig 2. The waste hierarchy
37
, ,
,
,
, , .
(La Grega et al, 2001):
,
, (,
, 2000).
11,
.
,
,
(Pichtel,
2005).
,
,
,
cradle-to-grave. -
RCRA-,
,
.
, RCRA
,
.
, ,
, .
11
38
,
,
,
.
, ,
,
.
, EPA
, .
,
, ,
,
. ,
,
, ( ),
,
,
(Pichtel, 2005).
,
,
.
,
, ,
.
,
, ,
.
,
39
. ,
, ,
,
.
,
, ,
, ,
.
,
, .
,
,
(, ,
2006). ,
,
.
:
,
,
, .
, ,
(EPA, 1997; Miloevi et al,
2009).
,
(Pichtel, 2005).
,
(EPA, 1997).
40
,
,
, ,
.
,
. ,
(1)
(2) ,
.
,
.
,
,
.
,
, ,
.
,
:
;
; ;
( ). ,
.
,
,
,
,
, EPA
,
61
(Pichtel, 2005).
,
41
,
. ,
,
.
, ,
. ,
.
, ,
,
.
,
, .
,
.
,
.
-
:
, , , , ,
, , .
.
20 ,
,
, ,
.
42
,
:
;
; ,
(Theodore, Reynolds, 1987).
.
, .
,
. , ,
,
. ,
.
,
, ,
.
, , .
(Jaki, Ili, 2000; La Grega et al, 2001).
/
,
.
,
,
.
,
,
.
43
, .
,
. ,
,
.
,
, ,
(),
()
(Wiles, 1988; Jaki, Ili, 2000).
, ,
, ,
(http://glossary.eea.europa.eu/EEAGlossary/C/
Chemical_treatment_of_hazardous_waste).
, ,
(
), ()
(Pichtel, 2005).
, .
, ,
,
,
(, , 2000).
,
( 7),
, :
,
.
44
7.
Table 7. Common chemical treatment processes for hazardous waste
- ,
.
/
.
: Pichtel, 2005
, pH
.
,
. pH
2-12.5, , 6-8,
(Pichtel, 2005; Blackman, 2001; , , 2000).
,
,
. ,
,
.
, , ,
.
, ,
,
.
(Pichtel, 2005).
,
, ,
.
45
,
.
,
(Pichtel 2005). ,
( 8).
8.
Table 8. Commonly used oxidizing and reducing agents
: Pichtel, 2005
,
,
. ,
,
, pH
. ,
: , .
, .
(, , 2000).
. ,
ex-situ, ,
(Blackman,
2001).
,
,
,
46
. ,
, ,
. 1900. -
,
, , ,
(La Grega et al, 2001).
, ,
,
, , ,
,
(Blackman, 2001).
,
, , ,
,
(, ,
2000). , EPA
,
, ,
,
, .
(Jilani, 2004):
;
;
.
,
:
, - , ,
, pH, , ,
.
, ,
.
,
,
(Jilani, 2004). ,
,
,
47
(, ,
2000).
( )
,
(, , , .), (PCB, DDT .).
, ,
4-15 3-6 .
,
,
. , ,
, (Blackman, 2001).
, ,
,
. ,
, ,
: ;
,
; .
,
, .
, ,
, , (Pichtel,
2005; Blackman, 2001)
, ,
,
.
, , , ,
(, , 2000).
, , ,
, ,
(Pichtel, 2005).
, ,
, (
48
) (Blackman, 2001).
(http://www.wau.boku.
ac.at/fileadmin/_/H81/H813/IKS_Files/Lehre/Archiv/813359_0607/5_incinerati
on_hazardous.pdf ):
;
;
( CO2,
,...)
( ).
(Theodore, Reynolds, 1987).
( )
.
,
,
, ,
.
,
.
(http://www.epa.gov/epaoswer/hotline/training/incin.txt):
;
;
.
(, , 2000):
;
;
;
;
;
49
.
,
, 90% .
, ,
.
,
. ,
.
,
,
.
,
(, , 2000).
, ,
, ,
( )
,
. , ,
,
, ,
(Pichtel, 2005).
,
(Theodore, Reynolds, 1987):
;
, , ;
;
,
.
50
,
,
.
, ,
(, , 2000).
, ,
, 648 C 1694 C,
,
(Blackman, 2001).
, ,
,
. ,
, ,
(, , 2000).
, ,
,
, ,
.
,
(La Grega et al., 2001).
,
,
,
.
,
, ,
,
.
, .
,
.
,
,
: 25-30%
,
(, , 2000).
, .
51
:
,
.
,
425-760 C
.
99.9999% (Shah, Schulz, Daiga, 1988).
,
,
(, , 2000):
;
:
1. ;
2. (NaCl, FeCl2, Zn, Pb);
3. , .
,
,
, ,
,
.
,
, .
, , ,
,
.
,
, - 1997. ,
1400 , 1999. , 1205 (Kiel, Zabel,
2001).
, ,
52
.
, Superfund12
,
-,
(, ,
, .
, ,
.
,
.
,
,
: , , , ,
,
,
.
, ,
,
,
(La Grega et al., 2001).
,
(Watts, 1996).
12
1980. , - Comprehensive Response,
Compensation and Liability Act (CERCLA Superfund),
.
Superfund EPA,
. 25
, EPA ,
,
,
. ,
,
,
(http://www.epa.gov/superfund/25anniversary/index.htm).
53
,
.
(La Grega et al, 2001):
,
.
:
; ,
, ;
;
;
.
,
.
.
( )
.
,
,
,
.
,
.
,
.
,
,
.
,
.
, ,
(La Grega et al., 2001; Watts, 1996):
54
,
;
;
;
,
.
,
.
,
.
,
, .
,
(, , )
(
, ) (Watts, 1996).
,
,
.
(Wetzel, 1988).
55
, ,
(, , 2000; Watts, 1996):
in-situ
,
, .
, (Miloevi i dr, 1998).
: ,
/, .
ex-situ
, ,
.
, ,
(Miloevi i dr, 1998).
: ,
, ,
, ,
,
/.
,
,
, x-situ ,
,
, ,
. in-situ
,
,
,
(Watts, 1996).
,
,
, ,
,
56
, . ,
,
,
(Miloevi i dr,
1998).
,
(Kiel, Zabel, 2001).
EPA
.
, ,
cradle-to-grave,
( ) , ,
,
. ,
,
, ,
.
20%
, ,
(, , 2000).
2001. , -
69% .
, ,
. -, () (
) 16 ,
1,4 (Pichtel,
2005).
,
:
, ,
.
,
57
.
,
,
.
,
.
,
,
. , ,
, , ,
.
,
.
, ,
, ,
.
-, 1999/31/C ,
, ,
,
,
,
.
,
.
, ,
,
.
, ,
58
,
.
.
,
,
. -
1999/31/C
,
,
,
.
, ,
.
:
,
;
;
, ,
;
.
-, EPA
. RCRA-
,
.
CFR-13 (Subpart N Landfills)
, ,
,
, ,
13
59
, ,
,
,
,
, .
,
,
(Wright, Ross, Tagawa, 1988).
,
,
, (Watts, 1998).
, ,
,
. ,
,
,
,
(Pichtel, 2005).
,
,
, .
,
.
25-
24 (Wright, Ross, Tagawa, 1988).
,
: , ,
. ,
,
,
. EPA
14,
( , , ),
.
,
14
60
,
, .
, e ,
e
,
.
,
, ,
,
.
,
,
,
,
.
50-80% (Wright,
Ross, Tagawa, 1988).
,
.
,
:
,
,
; ,
,
.
.
.
61
, : 1)
, ,
,
; 2)
(Wright, Ross, Tagawa, 1988).
,
, ,
.
,
. ,
, (,
, 2000):
;
;
;
;
.
,
(Watts, 1998).
,
(
).
,
.
(), ,
,
.
62
()
(), (Pichtel, 2005).
,
, ,
,
(Pichtel, 2005).
(La Grega et al, 2001).
,
(, , 2000). ,
,
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, ,
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( 3).
3.
(: , , 2000)
Fig. 3. Scematic of a hazardous waste landfill
. ,
63
(),
.
,
,
( ).
.
,
,
.
,
(Pichtel, 2005).
,
20. RCRA-,
.
(Soesilo,
Wilson, 1995). Land
Disposal Restrictions Program (LDR) EPA, ,
,
.
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(Pichtel, 2005).
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, (30 cm)
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(61 cm)
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mm;
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;
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(61 cm)
.
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(La Grega et al, 2001).
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(La Grega et al, 2001).
66
4.
(: , , 2000)
Fig. 4. Closing phase of hazardous waste landfill
,
, ,
. ,
()
,
.
,
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, .
,
(Pichtel, 2005).
,
67
(Blackman,
2001).
,
5 ,
. ,
. 2001. , -
473 I , 123 (26%)
, 350 (73%) (EPA, 2001).
. ,
( 50%
), (25%), (12%),
(5%), (1%) (Warner, 1988).
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Techniques) BREF (Best Available Techniques REFerence Document).
IPPC
,
( ,
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),
15
70
- .
BAT, :
()
,
-, je
-,
BREF-16
(http://www.europeansealing.com/publications/BREF_note.htm).
BREF-,
-
IPPC- . ,
, ,
(http://eippcb.jrc.ec.europa.eu/).
16
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IPPC- (European IPPC Bureau) .
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.
75/442/C ( )
91/689/C , ,
.
:
(http://www.wasteonline.org.uk/resources/Wasteguide/mn_legislation_european
_euaffect.html).
75/442/C ( )
, 1975.
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1978.
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3
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(Grupa
autora., 2004).
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(Grupa autora, 2003).
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, , ,
,
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.
,
, -
74
75
.
84/631/C
-.
,
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. 84/63//
1994. 94/31/ 166/2006.
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,
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77
, ,
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1989).
75/442/C 91/689/C,
,
.
259/93/C
1994. ,
,
OECD
.
, (
).
(http://www.ncte.ie/environ/waste.htm).
1013/2006, 1379/2007
669/2008 (
).
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) (, 2002). ,
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2002). ,
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( 1983.
" " 1986. .), ,
,
,
(Krueger, 1999).
1989. UNEP1 , 1992.
(20
), ,
170 (http://www.basel.int/ratif/convention.htm).
,
,
1
(The United Nations Environmental
Programme)
78
79
, OECD2, UNEP-, ,
. OECD
,
OECD-. ,
,
,
.
. , UNEP
,
OECD-
(Krueger, 1999),
.
OECD
, 1984.
84/631/
,
, ,
(http://www.ncte.ie/environ/waste.htm).
,
69 , , 1993.
259/93/
. Nj
.
UNEP 20.
,
,
,
,
. ,
Cairo Guidelines and Principles for the Environmentally Sound Management of
Hazardous Wastes,
2
(Organization for Economic Cooperation and
Development)
80
, (Krueger, 1999).
,
, ,
.
,
,
.
,
,
. 1
,
. 2
, 3
(Krueger, 1999).
8 9,
(
3)
(
1 3).
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, 3,
(http://www.basel.int/convention/basics.html).
,
(Krueger, 1999). , ,
,
3
80
81
, UNEP
.
,
, ,
(
).
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. 1995.
,
( )
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. , ,
,
69
(http://www.basel.int/ratif/ban-alpha.htm).
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,
(2000-2010. ), :
;
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;
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,
(Grupa
autora, 2003).
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OECD-
,
, ,
82
,
.
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- (http://www.ec.gc.ca/wmd-dgd/default.asp?lang=En&n)
86013F77-1). 4,
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,
OECD-.
,
.
OECD-
,
,
,
(Krueger, 1999).
,
,
, , OECD
,
,
1992.
C(92)39/FINAL OECD-
(http://www.ec.gc.ca/wmddgd/default.asp?lang=En&n=86013F77-1). ,
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(POPs) ,
, , ,
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2004, 50
. , 152
, , 147 .
84
,
,
, (Grupa
autora, 2003).
,
, ( , 1995). ,
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: , ,
, ,
( , 2003).
12
,
, :
1. Aldrin
,
;
2. Hlordan
;
3. DDT ,
II
,
.
;
4. Dieldrin ,
.
5. Dioksin
,
,
. ,
, , ;
6. Endrin
, ,
;
7. Furani
, PCB;
84
85
8. Heptahlor
, ,
;
9. Heksahlor benzen (HCB)
.
,
;
10. Mireks
,
, ;
11. Polihlorovani bifenili (PCBs)
,
, ,
,
,
( ., 1995);
12. Toksafen ,
, , .
,
,
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,
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,
21,
.
, ,
, 2025.
86
( , 2003). ,
(polihlorovani dibenzo-p-dioksini dibenzo-p-furani; heksahlor benzen;
PCBs),
,
.
20. ,
,
1985.
1987. .
1989.
(PIC),
2004.
. UNEP-, (Klaus Topfer)
,
,
(http://www.fao.org/newsroom/en/news/2004/37667/index.html).
:
,
;
,
,
.
,
PIC
.
39 ( 3) ,
86
87
24 , 4 11
. 27 ,
(http://www.pic.int/home.php?type=t&id=5&sid=16).
,
. 9
,
( ) . ,
,
,
(Grupa autora, 2003).
(http://www.pic.int/home.php?type=t&id=5&sid=16):
-
;
-
;
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-
;
-
PIC,
.
,
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.
,
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, .
,
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. ,
,
, , ,
Waste Management Act (2002),
Federal Waste Management Plan, .
, , ,
, , ,
,
-
.
, ,
, ,
,
,
(http://www.umweltbundesamt.at/en/ueberuns/). 1990. .,
,
,
. ,
(, 1999):
89
,
;
,
;
,
(,
), ;
o .
,
, ,
.
,
.
,
Waste Management Act (1990-2007),
(6th Report on
the State of the Environment in Austria, 2002):
, ,
;
;
(, , , ,
);
,
;
.
, ,
,
-.
, ,
,
(Federal Waste Management Plan, 2006):
90
;
,
;
,
, ,
, ,
.
(2006) ,
1992, 1995, 1998. 2001. ,
,
, .
- (. ,
),
,
,
(http://www.Bundesabfallwirtschaftsplan.at/article/articleview/52746/1/13192/).
,
,
.
1999. (Federal Waste Management plan,
2001) 49
, 54
( 2004, ).
5 ,
(
),
2 .
,
( 9),
,
90
91
.
9.
Table 9. Hazrdous waste structure in Austria
(
/)
0.9
3.2
7.5
()
20.0
4.1
,
3.8
,
2.3
2.2
4.6
: 7th State of the Environment Report, 2004
, 19992004,
, (7th State of the Environment Report, 2004):
138.000 1999. ,
398 kg
;
1999. : (, ,
.) 75.000 , -
21.000 ;
10%
100.000 ,
-
, 1997.
,
240.000 (1998) 1
(2001).
19932002. ,
( 1). ,
,
.
92
1400000
1200000
1000000
800000
600000
400000
200000
0
1993
1994
1995
1996
1998
1999
2000
2001
2002
1.
(: , 2002; 7th State of the Environment Report, 2004)
Graph.1. Hazardous waste in Austria (in tons)
,
,
. , 1996. ,
60% ( 1999),
(6th Report on the State of the
Environment in Austria, 2002).
,
-
(94/904/) 1998. .
(668 )
322 ,
(, 1999). 2001.
, 1.200.000 ,
,
,
920.000 .
1999. ,
( 10).
, 1. 2009. ,
,
,
92
93
,
, ,
,
(, 2002).
,
20. ,
, Waste Management Act Federal Waste
Management Plan,
,
. ,
,
.
, 1
,
:
, ,
,
.
94
,
,
, 2000. 194 (
),
1.2 ( 1).
,
(6th Report on the State of the Environment in Austria,
2002). ,
.
, 2002. Waste Management Act
,
. 2004.
0.8
,
.
, ,
(Federal Waste Managament Plan, 2006).
,
,
() .
, ,
,
,
(, 1999).
, ,
,
OECD- 7
. ,
- 259/93/EEC
-
OECD- .
94
95
1.
Sketch. 1. Geographical rearrangement of TSD facilites in Austria
(: 6th Report on the State of the Environment in Austria 2002)
, 1989. ,
Act on the Remediation of Contaminated Sites,
.
,
.
,
, ,
,
.
e
, -,
-.
,
,
. ,
96
, ,
,
, ,
,
.
96
97
, ,
,
,
-. ,
,
.
,
,
,
(http://www.environ.ie/en/Environment/Waste/):
1990.
, ,
.
,
.
1992.
,
2,
, ,
,
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.
, ,
,
.
1994. ,
, .
.
.
1996. Waste Management Act,
P
98
, .
,
-.
,
.
,
Environmental Protection Agency Act (1992),
(P),
:
,
,
;
,
,
;
;
;
;
, ,
98
99
;
,
;
,
;
, ,
,
;
.
,
,
,
(
10 ) ,
,
.
2008
2012. :
;
,
;
, , ,
,
.
,
. ,
,
,
100
,
,
.
,
(, 2007).
, :
,
,
;
,
;
,
;
( );
.
1996. , ,
: on-site,
off-site, , ,
(, 1999).
,
National Waste Report.
Waste
Management Act 1996 je
91/689/.
,
,
. ,
(, , ).
,
(
) (, 1999).
100
101
19902006.
, ( 11). 1992.
, , ,
1995. .
,
. ,
,
. 1998. ,
29%, ,
, ( 21.5% 1996.
),
15% (, 2001).
11.
Table 11. Hazardous waste in Ireland
1990
66 000
1992
99 000
1995
248 000
1996
229 634
1998
296 017
2001
258 000
2004
307 778
2006
284 184
: , 2002; P Ireland, 2007
,
, 2006.
8% 2004. , 10%
2001. .
, 2002. ,
, ,
,
, ,
, , ,
(, 2007).
,
, , 29 888 (2006. ),
(P, 2001).
,
102
20082015,
.
2006
2004
2001
1998
1996
0
100000
200000
300000
2.
Graph 2. Industrial hazardous waste in Ireland
(: , 2007)
,
, ,
.
,
19962006. ( 2),
, , .
( 3),
(62%
), , (8%),
(7%) , (6%)
(, 2007).
102
103
3.
Graph 3. Most important hazardous waste generators
19962006. .,
( 12, 4),
,
.
,
(P,
2007).
12. 1996-2006 ( )
Table 12. Options for hazardous waste management 1996-2006 (in tons)
1996
1998
2001
2002
2003
2004
2005
2006
141.151 131.738 95.565
86.328
88.409
On-site
33.470
39.055
48.013
55.952
60.872
Off-site
51.727
99.598 115.366 109.545 180.678 165.498 146.811 134.904
: , 2007; R, 2001.
n-site 19962006. ,
2004. ,
. off-site
, , ,
, 17% 20012004.. 9% 20042006. .
,
.
104
,
, 2003. ,
,
(, 2007).
8% ,
,
(, 2007).
180000
160000
140000
tone
120000
100000
80000
60000
40000
20000
0
1996
1998
2001
2004
2006
4.
Graph 4. Comparison of different options of hazardous waste management
2006. .,
, 47,5% (
) (
) .. 31%
n-site IPPC
(, ,
), 21%
( 15 ,
) (, 2007).
,
,
, ,
104
105
.
,
,
,
. , ,
,
.
,
( 2)
. 2006. ,
, ,
,
.
106
2.
Sketch. 2. Hazardous waste recovery and disposal facilities in Ireland
(: EPA, 2001)
106
107
,
,
.
, ,
, ,
-, ,
e ,
, .
,
,
,
(http://www.azo.hr/default.aspx?art=146).
, ,
, , ,
,
, .
:
,
.
, ,
,
, ,
,
, .
, 2002. ,
,
, ,
( ),
.
,
,
108
.
, ,
: ,
( ),
(http://www.azo.hr/default.aspx?art=146).
-
-,
2000. , (NN 178/04,
111/06, 60/08),
,
.
,
(NN
50/05, 39/09)
.
(NN MU 3/94)
(NN 69/06, 17/07, 39/09).
,
(NN 130/05)
(NN 85/07).
(NN
46/02),
,
,
, .
, ,
,
,
,
.
:
;
;
108
109
;
;
;
;
;
;
.
,
-,
20072015, ,
.
20072012
:
,
;
;
;
;
.
. ,
,
.
. ,
,
. , 8 ,
. ,
, 200 kg,
4 .
110
,
13.2 ( 13), 2.97 per
capita. , ,
,
. ,
,
,
, , ,
, .
13.
Table 13. Estimates of the annual amount of waste
1.2
2.6
1.6
-
7.1
0.1
0.2
0.4
13.2
: , 2005
,
, ( ),
,
,
(NN50/05, 39/09).
,
,
,
,
.
110
111
70000
60000
50000
40000
30000
20000
10000
0
2001
2002
2003
2004
2005
5. (2001-2005)
Graph 5. Reported hazardous waste quantities (2001-2005)
(: Plan gospodarenja otpadom u Republici Hrvatskoj 2007-2015)
, -
,
,
, ,
, .
,
( 5),
213.000 ,
.
, ,
- ,
. ,
47 ,
( 3) 43
( 4),
.
, .
112
3.
Sketch 3. Facilities for hazardous waste collection and storage
(: Plan gospodarenja otpadom u Republici Hrvatskoj 2007-2015)
:
, ;
, ; ;
/; .
,
.
,
,
,
.
,
,
,
.
112
113
4.
Sketch 4. Facilities for hazardous waste treatment
(: Plan gospodarenja otpadom u Republici Hrvatskoj 2007-2015)
, ( 1994.
). 2004. 2005. , 12.805 , ,
13.157 ,
, 2005. ,
,
.
:
, , , ,
.
,
,
,
, ,
.
.
,
, ,
.
,
,
. ,
,
,
.
, ,
,
.
, ,
,
(Djordjevic, Panic, 2007). ,
. ,
,
.
,
2000. ,
,
, .
,
, . ,
. ,
115
, -
, ,
. ,
,
.
.
.
-
,
, ,
, ,
(
) ( ).
( 30)
,
. ,
, (Grupa autora, 2004).
(. 135/04, 36/09),
1,
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. :
,
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,
.
116
,
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5 ,
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, ,
;
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o
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. 60/09);
o
(. , . 55/01);
o
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. 41/10);
o ,
,
(. , . 113/05, 6/07,
8/10)
, ,
,
,
;
117
,
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, .113/05);
o
(. , . 5/10).
(. , . 66/91, 83/92, 53/93, 67/93, 48/94, 53/95)
:
o
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29 11
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, . 84/05);
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. 84/05);
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, . 84/05);
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101/05), :
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, . 79/91).
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21/99, 44/99, 68/02; . , . 36/09)
, ,
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, . 36/09)
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SUMMARY
How are human needs suddenly began to grow, and intensive development
of science and technology made them freely meet, there was a production of
significant quantities of different types of waste, which features in the beginning
were not fully known. Detection of a large number of new artificial materials
especially applicable in industrial production, resulting in the generation of
specific types of waste - hazardous waste, its characteristics and long-term
seriously threaten human health, other living organism and the environment in
general. It is for the aforementioned reasons, it is necessary to consider the
whole issue related to hazardous waste, that is, become familiar with its
characteristics, behavior in nature, where at the beginning of massive
uncontrolled delayed, subdivisions, which includes, anthropogenic processes
that generate and grade the severity of the expected consequences .
Industrialized countries that were due to accelerated industrialization first met
with the aforementioned problem, have initiated detailed studies that have
produced a series of rules and principles defined in the form of legal provisions
governing the operation of hazardous waste management system. This system,
also called the system of cradle-to-grave, encompasses all phases of his
generation, or generation of hazardous waste, through collection, transportation,
storage, treatment and final disposal. For the proper functioning of each phase
and the behavior of the participants in this complex system, it is necessary to
establish an appropriate legislative, institutional and planning framework and
mechanisms for their implementation, thus reducing the risk of potential adverse
effects.
Hazardous waste management system is an organized approach of
continuous direct and control the same from the moment of its creation,
collection, storage, treatment and final disposal. It is characterized by extreme
complexity, due to very pronounced risk of his release and penetration into the
environment, which directly affected all living organisms and environmental
quality. Guidelines for sustainable management, regulating the responsibilities
of all stakeholders mentioned system and prescribe for each phase individually.
Generation of hazardous waste is a particularly problematic phase because of the
complex organization of the system for monitoring the quantitative and
qualitative variations within a general trend of the waste generated, and the
establishment of effective mechanisms to control the generators themselves,
especially when it comes to industrial plants, which bear great responsibility for
future the fate of waste generated. As a logical continuation, after the generation
of hazardous waste, usually lead to its temporary storage, which involves storing
hazardous waste on its way to the facility for treatment and final disposal. Due to
the accumulation of large quantities of hazardous waste in one place, this phase
represents a major challenge in the sense of order to prevent possible accidents.
SUMMARY
157
For this reason, the constant control, not only by the direct responsible parties,
but also by the competent authorities of a state. Further functioning of the
management of hazardous wastes usually involves its removal from the plant for
its treatment, which significantly increases the risk of accidents and threat to
population and environment in wider areas, along routes that are used. In order
to partially or completely neutralized characteristics of hazardous waste have
been developed various forms of treatment, possibly followed and disposal in
landfills that are specially equipped for the said function. Today, after a long
experience in the pursuit of a system of hazardous waste as more aligned with
high ecological standards have been created more options for managing
hazardous waste relating to the promotion of technologies that generate less
waste, substitution of hazardous substances less hazardous, recycling and reuse
existing hazardous waste and the like. This situation resulted in the
establishment of new technological standards have further improvements to
measure very short intervals, and further progress in this field is inevitable. Like
many developing countries, the Republic of Serbia started with a serious change
in the field of environmental protection, which resulted in separation of a
number of serious problems that require a special approach to the resolution.
How is the current practice of hazardous waste ocenjana as extremely poor and
completely unsustainable in the future to Serbia's EU flows, it became clear that
the crucial changes are necessary. First of all, we started the construction of a
new regulatory system must be fully adapted to EU standards, the institutional
framework that should enable the implementation of all provisions prescribed
and planned basis to be Put the short-and long-term objectives in establishing a
system of hazardous waste. The competent authorities must have open
communications and cooperation among themselves and with the responsible
parties and the public who are the unavoidable future system. In this sense, it is
necessary to implement adequate training and then continuous control, which
will ensure the implementation of established principles for managing hazardous
waste.
In addition to these changes, the extent to which the work began, the
problem must be mentioned non-availability of network facilities for hazardous
waste management, ie, lack of facilities for some form of treatment or disposal
of hazardous waste. It is clear that a country with its industrial production and
the desire to preserve environmental quality, is unable to support such an
approach, but it has accelerated its approach to the creation and construction.
This begins with the realization of one of the basic principles presented in the
EU directives, which points to the necessity of self-sufficiency of each Member
State in addressing hazardous waste on its territory. Of course, it is clear that
introduced changes involve significant financial investment and to a large extent
on the economic strength of a country, which can be partly alleviate a good
assessment of real needs and a clear definition of short and long term goals. This
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