Chapt 10 Q# 33, 35, 37, 39, 43, 44

Tuesday, April 13, 2010

5:54 PM

33. Forces
a. Dispersion
b. Dipole-dipole and dispersion
c. Hydrogen bonding and dispersion
d. Ionic
e. Dispersion
f. Dipole-dipole and dispersion
g. Ionic
35. Greater IMF
a. OCS (dipole-dipole and dispersion instead of dispersion only)
b. SeO2 (both have dipole-dipole and dispersion.but Se makes a larger molecule)
c. H2NCH2CH2NH2 (more hydrogen bonding due to additional N instead of C)
d. H2CO (dipole-dipole and dispersion instead of dispersion only)
e. CH3OH (hydrogen bonding instead of just dipole-dipole)
37. Boiling Points
a. n-pentane is not as compact as neopentane, meaning that it has a greater surface
area for interactions among molecules and therefore greater dispersion forces
b. HF experiences hydrogen bonding which is the strongest type of IMF whereas HCl's
largest IMF is dipole-dipole
c. LiCl experiences ionic forces which are stronger than dipole-dipole and dispersion
forces of HCl
d. n-hexane is a larger molecule and therefore experiences greater dispersion forces
39. Properties
a. Highest bp - HBr - is the only polar molecule and it experiences dipole-dipole forces
b. Highest fp - NaCl - ionic forces are the strongest
c. Lowest vapor pressure - I2 - has the greatest dispersion forces
d. Lowest fp - N2 - only dispersion forces
e. Lowest bp - CH4 - smallest molecule and therefore lowest dispersion forces
f. Highest bp - HF - hydrogen bonding while others only dipole-dipole
43. H2O2 experiences a larger amount of hydrogen bonding than water. In addition, because
the molecule is larger there is also a greater likelihood that they tangle in one another
increasing viscosity
44. Each molecule is non-polar and therefore only experiences dispersion forces. The larger
the molecule, the greater the dispersion forces. Size of the molecules are:
CO2 < CS2 < CSe2

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