CC CHUYN LUYN THI CP TC H-C 2016

HA HU C

CHUYN 4: ESTE - LIPIT

A. TM TT L THUYT
ESTE
I. Khi nim Cng thc tng qut
1. Khi nim:
-OH
R - COOH
R - COO - R ' (este)
'
+OR

(R l gc H-C hoc H; R l gc H-C)

2. Cch t cng thc tng qut:
- CTPT tng qut (dng cho phn ng t chy este)
+ Este no, n, h: CnH2nO2 (n2)
+ Este n, khng no,mch h: CnH2n+2-2aO2 (n3, a 2)
+ Este n chc: CxHyO2 (x2, y2x)
+ Este bt k: CxHyOz (x2, y2x)
- CTCT tng qut (dng cho phn ng thy phn este)
+ Este n chc: R-COO-R
(R l gc H-C hoc H; R l gc H-C)
+ Este to bi axit a chc v ancol n chc:
R-(COOR)x (x l s nhm -COOH)
+ Este to bi axit n chc v ancol a chc:
(RCOO)x-R
(x l s nhm -OH)
+ Este to bi axit a chc v ancol a chc:
Rx-(COO)x.y-Ry (x l s nhm OH, y l s nhm COOH).
II. ng phn Danh php
1. ng phn
* Cch vit ng phn este n chc dng: R-COO-R
+ B1: Cho R l H c dng HCOOR
+ B2: Chuyn tng cacbon t R sang R n khi R ch cn 1
cacbon.
+ B3: Vit y cu to ca cc gc R v R nu c.
* Lu : cng vi CTPT ca este ta cn c ng phn n chc
ca axit cacboxylic.
2. Danh php: (este n chc RCOOR)
Tn este = Tn gc R + Tn gc axit cacboxylic tng ng
(ui at)
III. L tnh
- Nhit si thp hn axit v ancol tng ng do khng c lin
kt H gia cc phn t este vi nhau. (este < ancol < axit)
- Hu nh khng tan trong nc do khng c lin kt H vi cc
phn t nc.
IV. Phn ng thy phn
a) Thu phn trong mi trng axit axit cacboxylic v ancol

LIPIT CHT GIT RA

I. Cht bo: l trieste ca glixerol v cc axit bo (axit
monocacboxylic c s chn nguyn t C t 12 n 24C,
khng phn nhnh) gi l triglixerit hay triaxylglixerol
* Cng thc chung: (RCOO)3C3H5 (R l gc ca
axit bo)
* Mt s axit bo thng gp:
+ Axit bo no:
Axit stearic (C17H35COOH), axit panmitic
(C15H31COOH).
+ Axit bo khng no:
Axit oleic (C17H33COOH), axit linoleic (C17H31COOH).
* Phn ng thu phn trong mt axit
H ,t 0

3RCOOH +
(RCOO)3C3H5 + 3H2O

C3H5(OH)3
* Phn ng x phng ho
t
(RCOO)3C3H5 + 3NaOH
3RCOONa +
C3H5(OH)3
* Phn ng cng H2 i vi cht bo lng cht
bo rn
0

t
(C17H33COO)3C3H5 + 3H2
(C17H35COO)3C3H5
1
R -COO-CH 2
0

* Cng thc cu to:

R 2 -COO-CH

R 3 -COO-CH 2
(R1, R2, R3 c th ging hoc khc nhau)
T n axit bo khc nhau v glixerol to ra ti a
[n2(n+1)/2] trieste.
* Ch s axit v ch s x phng ha ca cht bo
+ Ch s axit ca cht bo l s mg KOH dng
trung ha lng axit t do c trong 1 gam cht bo.
+ Ch s x phng ha ca cht bo l tng s mg
KOH cn trung ha ht lng axit t do v x phng
ha ht lng este c trong 1 gam cht bo.
II. Cht git ra tng hp
1. X PHNG l hn hp mui natri (kali) ca cc
H 2SO4 ,d
RCOOR + H2O
RCOOH + ROH
axit bo; thnh phn ch yu ca x phng l mui
Phn ng thun nghch.
natri ca axit panmitic (C15H31COOH) v axit stearic
b) Thu phn trong mi trng kim mui ca axit
(C17H35COOH)
cacboxylic v ancol (phn ng x phng ha )
2. KHI NIM V CHT GIT RA TNG HP
RCOOR + NaOH RCOONa + ROH
l cc cht c tc dng ty ra nh x phng (bt git
tng hp hay x phng bt); Mui natri ca axit
Phn ng mt chiu.
oexyl benzen sunfonic, C12H25C6H4SO3Na (natri
V. iu ch

oexyl benzen sunfonat)

a) i vi este RCOOR thng thng c iu ch t
axit cacboxylic v ancol tng ng.
3. TC DNG GIT RA CA X PHNG &
H 2 SO4 ,t o
CHT GIT RA TNG HP

RCOOR' + H 2 O
RCOOH + R'OH

+ X phng & cht git ra tng hp c tnh hot ng

b) i vi este ca phenol (RCOOC6H5) c iu ch t phenol v
b mt cao. Chng c tc dng lm gim sc cng b
anhidric ca axit tng ng.
Trang 1

CC CHUYN LUYN THI CP TC H-C 2016

HA HU C

(CH3CO)2O + C6H5OH CH3COOC6H5 + CH3COOH

c) i vi vinyl axetat (CH3COOCH=CH2) c iu ch t axit
axetic (CH3COOH) v axetilen (CH CH).
CH3COOH + CHCH CH3COOCH=CH2

mt ca cc vt bn du m bm trn da, vi ... cc

vt bn c phn chia thnh nhng phn nh sau b
cun tri theo nc.
+ Khng nn dng x phng git trong nc cng (
l nc c cha nhiu ion Ca2+ v Mg2+) do c s to
thnh kt ta ca cc mui Ca2+ v Mg2+.
VI. Mt s vn m rng
* Este ca axit fomic HCOOR cn c phn ng trng bc.
+ Cht git ra tng hp c th dng trong nc
* Este ca phenol RCOOC6H5 + 2MOH RCOOM + C6H5OM
cng.
+ H2O
+ Nu x phng
* Este ca ancol khng bn (c lin kt i gn vo nhm COO ):
Cht bo + 3NaOH x phng + glixerol
RCOOCH=R khi thu phn anehit
* Nhn xt:
- Nu R l H khi thy phn to ra cc sn phm u trng gng.
mcht bo + mNaOH = mx phng + mglixerol
- Nu R H khi thy phn to ra sn phm c 1 cht trng gng.
* Mt hp cht hu c n chc A c cng thc CnH2nO2 nu A
- Tc dng vi Na, NaOH (hoc lm tan vi: CaCO3) A l
axit cacboxylic CTCT: RCOOH
- Ch tc dng vi NaOH khng tc dng vi Na A l este
- Tc dng c vi NaOH A l este hoc axit
1 sn phm duy nht
* Nu Este + NaOH
hoc m rn = meste + mNaOH.
Th l este vng. V d:

B. TRC NGHIM
L THUYT
Cu 1: Tng s cc hp cht hu c c cng thc phn t C4H8O2 s phn ng c vi NaOH l
A. 4
B. 5
C. 6
D. 7
Cu 2: Este X c CTPT C5H10O2. X tham gia phn ng trng bc. Vy s CTCT ca X l
A. 2
B. 3
C. 4
D. 5
Cu 3: Tng s hp cht hu c no, n chc, mch h, c cng cng thc phn t C5H10O2, phn ng c vi dung
dch NaOH nhng khng c phn ng trng bc l
A. 4
B. 5
C. 8
D. 9
Cu 4: Pht biu ng l
A. Phn ng gia axit v ancol c mt H2SO4 c l phn ng mt chiu.
B. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v ancol.
C. Khi thu phn cht bo lun thu c C2H4(OH)2.
D. Phn ng thu phn este trong mi trng axit l phn ng thun nghch.
Cu 5: Nhn nh no sau y khng ng?
A. Tn este RCOOR gm: tn gc hirocacbon R + tn anion gc axit (ui at).
B. Nu thay nguyn t H nhm COOH ca axit cacboxylic bng gc hirocacbon th c este.
C. Phn ng thu phn este trong kim l phn ng 1 chiu v gi l phn ng x phng ho.
D. Este c nhit si thp hn so vi axit v ancol c cng s nguyn t C v este c khi lng phn t nh hn.
Cu 6: Nhng bin php phn ng thu phn este c hiu sut cao v nhanh hn l
A. Tng nhit ; tng nng ancol.
B. Dng OH- (xc tc); tng nhit .
+
C. Dng H (xc tc); tng nng ancol.
D. Dng H+ (xc tc); tng nhit .
Cu 7: Cho cc cht: axit propionic (X); axit axetic (Y); ancol etylic (Z) v metyl axetat (T). Dy gm cc cht c sp xp
theo chiu tng dn nhit si l
A. T, Z, Y, X.
B. Z, T, Y, X.
C. T, X, Y, Z.
D. Y, T, X, Z.
Cu 8: Este no sau y khng thu c bng phn ng gia axit v ancol?
A. etyl axetat
B. metyl acrylat
C. allyl axetat
D. vinyl axetat

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CC CHUYN LUYN THI CP TC H-C 2016

HA HU C

Cu 9: Cho cc cp cht: (1) CH3COOH v C2H5CHO; (2) C6H5OH v CH3COOH; (3) C6H5OH v (CH3CO)2O; (4)
CH3COOH v C2H5OH; (5) CH3COOH v CH CH; (6) C6H5COOH v C2H5OH. Nhng cp cht no tham gia phn ng
este ho?
A. (1), (2), (3), (4), (5). B. (2), (3), (4), (5), (6).
C. (2), (4), (5), (6).
D. (3), (4), (5), (6).
Cu 10: Hp cht thm X thuc loi este c cng thc phn t C8H8O2. X khng th iu ch t phn ng ca axit v
ancol tng ng v khng tham gia phn ng trng gng. X l
A. C6H5COOCH3.
B. CH3COOC6H5.
C. HCOOCH2C6H5.
D. HCOOC6H4CH3.
Cu 11: Hp cht X c cng thc phn t CnH2nO2 khng tc dng vi Na, khi un nng X vi axit v c c 2 cht Y1
v Y2. Bit Y2 b oxi ho cho metanal cn Y1 tham gia phn ng trng gng. Vy gi tr ca n l
A. 1.
B. 2.
C. 3.
D. 4.
Cu 12: Hai cht hu c X, Y c cng cng thc phn t C3H4O2. X phn ng vi NaHCO3 v phn ng trng hp, Y
phn ng vi NaOH nhng khng phn ng vi Na. Cng thc cu to ca X, Y ln lt l
A. C2H5COOH, CH3COOCH3.
B. C2H5COOH, CH2 = CHCOOCH3.
C. CH2 = CHCOOH, HCOOCH = CH2.
D. CH2 = CH CH2COOH, HCOOCH = CH2.
Cu 13: Hp cht hu c X n chc cha (C, H, O) khng tc dng vi Na nhng tc dng vi dung dch NaOH theo t
l mol 1:1 hoc 1:2. Khi t chy 1 mol X thu c 7 mol CO2. Cng thc cu to ca X l
A. C2H5COOC4H9.
B. HCOOC6H5.
C. C6H5COOH.
D. C3H7COOC3H7.
Cu 14: Cho cc cht: etyl axetat, etanol, axit acrylic, phenol, phenylamoni clorua, phenyl axetat. Trong cc cht ny, s
cht tc dng c vi dung dch NaOH l
A. 3.
B. 4.
C. 5.
D. 6.
Cu 15: Cho cc ng phn mch h C2H4O2 tc dng ln lt vi: NaOH, Na, AgNO3/NH3 th s phng trnh phn
ng xy ra l
A. 3.
B. 4.
C. 5.
D. 6.
Cu 16: Cho hn hp cc cht hu c n chc c cng thc phn t C3H6O2 tc dng ht vi NaOH thu hn hp sn
phm hu c Y. Cht no di y khng c trong Y?
A. CH3COONa
B. HCOONa
C. C2H5COOH
D. C2H5OH
Cu 17: Trong cc cht: xiclopropan, benzen, stiren, metyl acrylat, vinyl axetat, imetyl ete, s cht c kh nng lm mt
mu nc brom l
A. 5
B. 4
C. 6
D. 3
Cu 18: Thu phn este C4H6O2 trong mi trng axit thu c hn hp 2 cht u tham gia phn ng trng gng.
Cng thc cu to ca este l
A. HCOOCH2CH=CH2
B. HCOOC(CH3)=CH2
C. CH2=CHCOOCH3
D. HCOOCH=CHCH3
Cu 19: Cho cht X tc dng vi 1 lng va dd NaOH, sau c cn dd thu c cht rn Y v cht hu c Z. Cho
Z tc dng vi AgNO3/NH3 c cht hu c T. Cho cht T tc dng vi NaOH li thu c cht Y. Cht X c th l
A. HCOOCH = CH2.
B. HCOOCH3.
C. CH3COOCH = CHCH3.
D. CH3COOCH = CH2.
Cu 20: Thy phn este X trong mi trng axit thu c hai cht hu c A v B. Oxi ha A to sn phm l cht B.
Cht X khng th l
A. etyl axetat
B. vinyl axetat
C. etilen oxalat
D. isopropyl propionat.
Cu 21: Thu phn este Z trong mi trng axit thu c hai cht hu c X v Y (MX < MY). Bng mt phn ng c th
chuyn ho X thnh Y. Cht Z khng th l
A. metyl propionat
B. metyl axetat
C. etyl axetat
D. vinyl axetat
Cu 22: E l hp cht hu c ch cha mt loi nhm chc, cng thc phn t C10H18O4. E tc dng vi dung dch NaOH
un nng cho ra hn hp ch gm mui natri ca axit aipic v ancol Y. Y l ancol c cng thc phn t:
A. CH4O
B. C2H6O
C. C3H6O
D. C3H8O
Cu 23: Hp cht hu c mch h X c cng thc phn t C6H10O4. Thy phn X to ra hai ancol n chc c s
nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l (H B10)
A. CH3OCO-CH2-COOC2H5. B. C2H5OCO-COOCH3. C. CH3OCO-COOC3H7.
D. CH3OCO-CH2-CH2-COOC2H5.
Cu 24: X phng ho mt hp cht c cng thc phn t C10H14O6 trong dung dch NaOH (d), thu c glixerol v
hn hp gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l
(H A09)
A. CH2=CH-COONa, HCOONa v CH C-COONa.
B. CH3-COONa, HCOONa v CH3-CH=CH-COONa.
C. HCOONa, CH C-COONa v CH3-CH2-COONa.
D. CH2=CH-COONa, CH3-CH2-COONa v HCOONa.
Cu 25: E l hp cht hu c, cng thc phn t C9H16O4. Thy phn E (xc tc axit) c axit cacboxylic X v 2 ancol
Y, Z. Bit Y, Z u c kh nng tch nc to anken. S cacbon ca Y gp 2 ln s cacbon ca Z. X l
A. Axit axetic
B. Axit malonic
C. Axit oxalic
D. Axit acrylic
Cu 26: Nhn nh khng ng l
Trang 3

CC CHUYN LUYN THI CP TC H-C 2016

HA HU C

A. CH3CH2COOCH=CH2 c th trng hp to polime. B. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3.

C. CH3CH2COOCH=CH2 tc dng vi dd Br2. D. CH3CH2COOCH=CH2 t/d vi dd NaOH thu c anehit v mui.
Cu 27: C cc cht mt nhn ring bit sau: etyl axetat, fomanehit, axit axetic v etanol. phn bit chng dng b
thuc th no sau y?
A. AgNO3/NH3, dung dch Br2, NaOH.
B. Qu tm, AgNO3/NH3, Na.
C. Qu tm, AgNO3/NH3, NaOH.
D. Phenolphtalein, AgNO3/NH3, NaOH.
Cu 28: Cho cc hp cht hu c: C2H2; C2H4; CH2O; CH2O2 (mch h); C3H4O2 (mch h, n chc). Bit C3H4O2
khng lm chuyn mu qu tm m. S cht tc dng c vi dung dch AgNO3 trong NH3 to kt ta l
A. 3.
B. 4.
C. 2.
D. 5.
O2 ,xt
NaOH
NaOH
NaOH
X(C H O )
Y
Z
T
0C H

4 8 2
2 6
CaO,t
Cu 29: Cho s sau:
. Cng thc cu to thu gn ca X l
A. CH3COOC2H5.
B. C2H5COOCH(CH3)2.
C. CH3CH2CH2COOH.
D. HCOOCH2CH2CH3.
Cu 30: Trong c th cht bo b oxi ho thnh nhng cht no sau y?
A.NH3 v CO2
B.NH3, CO2, H2O
C.CO2, H2O
D.NH3, H2O
Cu 31: Chn cu sai trong cc cu sau
A. T du m c th sn xut c cht git ra tng hp v x phng.
B. X phng l sn phm ca phn ng x phng ho.
C. Mui natri ca axit hu c l thnh phn chnh ca x phng.
D. Khi un nng cht bo vi dung dch NaOH hoc KOH ta c mui sn xut x phng.
Cu 32: Cho glixerol phn ng vi hh axit bo gm C17H35COOH v C15H31COOH, s loi trieste ti a c to ra l
A. 3.
B. 4.
C. 5.
D. 6.
Cu 33: A l mt trieste. Thy phn A trong mi trng kim thu c hn hp cha hai mui ca axit stearic v axit
oleic. S trieste tha mn iu kin ca A l
A. 4
B.5
C.6
D.2
Cu 34: Cng thc phn t ca olein l
A. C51H92O6
B. C57H110O6
C. C57H104O6
D. C57H102O6
Cu 35: Cht bo no di y l cht bo cha no
A. C51H98O6
B. C57H110O6
C. C55H104O6
D. C53H102O6
o

+ H2 , Ni, t
NaOH, t
+ HCl
Y
Cu 36: Cho s bin ha (gi s cc phn ng u hon ton): Triolein
X
Z.
Tn ca Z l
A. Axit oleic.
B. Axit panmitic.
C. Axit stearic.
D. Axit linoleic.
o

H 2 du ( Ni ,t )
HCl
NaOH du, t
Z.
Cu 37: Cho s chuyn ha: Triolein
Y
X
Tn ca Z l
A. axit linoleic.
B. axit oleic.
C. axit panmitic.
D. axit stearic.
X
NaOH (d )
Y (hp cht thm)
Cu 38: Cho dy chuyn ha sau: Phenol Phenyl axetat
to
0

Hai cht X, Y trong s trn ln lt l:

(H A09)
A. anhirit axetic, phenol.
B. anhirit axetic, natri phenolat.
C. axit axetic, natri phenolat. D. axit axetic, phenol.
BI TP
* Ton phn ng t chy este
Cu 39: X l mt este khng no (cha 1 lin kt i C = C) n chc, mch h. t chy hon ton 4,3 gam X cn va
7,2 gam O2. X c ti a bao nhiu cng thc cu to?
A. 3.
B. 4.
C. 5.
D. 6.
Cu 40: X l hn hp 2 este n chc (to bi cng mt axit vi 2 ancol lin tip trong dy ng ng). t chy hon
ton 21,4 gam X c 1,1 mol CO2 v 0,9 mol H2O. Cng thc phn t 2 este trn l
A. C4H6O2 v C5H8O2
B. C5H8O2 v C6H10O2
C. C5H6O2 v C6H8O2
D. C5H4O2 v C6H6O2
Cu 41: Hn hp Z gm hai este X v Y to bi cng 1 ancol v 2 axit cacboxylic k tip nhau trong dy ng ng
(MX<MY). t chy m gam Z cn va 6,16 lit oxi (ktc) thu c 5,6 lit CO2 (ktc) v 4,5 gam H2O. Cng thc ca X
v ga tr m l (C A10)
A. CH3COOCH3 v 6,7
B. HCOOC2H5 v 9,5
C. HCOOCH3 v 6,7
D. (HCOO)2C2H4 v 6,6
Cu 42: (H B09) Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va
3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH, thu c mt mui v hai
ancol l ng ng k tip. Cng thc phn t ca hai este trong X l
A. C2H4O2 v C3H6O2.
B. C3H4O2 v C4H6O2.
C. C3H6O2 v C4H8O2.
D. C2H4O2 v C5H10O2.

Trang 4

CC CHUYN LUYN THI CP TC H-C 2016

HA HU C

Cu 43: t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c th tch kh
CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin). Cho m gam X tc dng hon ton vi 200
ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Gi tr ca m l (H A10)
A. 7,20.
B. 6,66.
C. 8,88.
D. 10,56.
Cu 44: t chy hon ton 0,2 mol este n chc X ri cho sn phm chy ln lt qua bnh 1 ng 100 gam dung dch
H2SO4 96,48%; bnh 2 ng dung dch KOH d. Sau th nghim thy nng H2SO4 bnh 1 gim cn 87,08%; bnh 2
c 82,8 gam mui. Cng thc phn t ca X l
A. C2H4O2.
B. C3H6O2.
C. C4H8O2.
D. C3H4O2.
* Ton phn ng x phng ha
Cu 45: X l este n chc, t khi hi so vi H2 l 44. un 6,6 gam X vi dung dch NaOH va thu c 6,15 gam
mui. X c cng thc cu to
A. HCOOCH2CH2CH3
B. HCOOCH(CH3)2
C. CH3COOC2H5
D. C2H5COOCH3
Cu 46: Mt este to bi axit n chc v ancol n chc c t khi hi so vi CO2 bng 2. Khi un este ny vi dd
NaOH to ra lng mui c khi lng ln hn lng este phn ng . Este l
A. Metyl axetat.
B. Propyl axetat.
C. Metyl propionat.
D. Etyl axetat
Cu 47: X phng ho 12gam este n chc X bng NaOH va ri c cn c 11,28 gam mui v 5,52 gam ancol.
Vy X c tn gi l
A. etyl acrylat.
B. anlyl axetat.
C. metyl fomat.
D. metyl butyrat.
Cu 48: X phng ho hon ton m gam este E bng NaOH va c ancol F v 1,08m gam mui khan. Vy E c
cng thc phn t l
A. C3H4O2
B. C4H6O2
C. C4H8O2
D. C5H8O2
Cu 49: Ha hi 5g este n chc E c th tch hi bng th tch ca 1,6g oxi (o cng iu kin). X phng ha
hon ton m gam este E bng NaOH va c ancol X v 0,94m gam mui natri ca axit cacboxylic Y. Vy X l
A. Ancol metylic
B. Ancol etylic
C. Ancol anlylic
D. Ancol isopropylic
Cu 50: X phng ho 0,1mol este n chc X cn va 0,2mol NaOH, c cn dung dch sau phn ng thu c
19,8gam rn khan. X c cng thc phn t l
A. C8H8O2.
B. C7H6O2.
C. C9H10O2.
D. C8H10O2.
Cu 51: Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%, thu c mt ancol
v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l (H A10)
A. HCOOH v CH3COOH B. CH3COOH v C2H5COOH C. C2H5COOH v C3H7COOH D. HCOOH v C2H5COOH
Cu 52: t chy hon ton 10 gam este n chc X c 22g CO2 v 7,2gam H2O. Nu x phng ha hon ton 5g X
bng dung dch NaOH c 4,7gam mui khan. X l
A. Etyl propionat
B. Etyl acrylat
C. Vinyl propionat
D. Propyl axetat.
Cu 53: X l este khng no, mch h, t khi so vi O2 l 3,125. X phng ha X c mt anehit v mt mui ca axit
hu c. X c th c bao nhiu cng thc cu to?
A. 4
B. 5
C. 6
D. 7
Cu 54: 0,1 mol este E phn ng va vi dung dch cha 0,2 mol NaOH, cho ra hn hp gm 2 mui natri c cng
thc C2H3O2Na; C3H3O2Na v 6,2 gam ancol X. E c cng thc phn t l
A. C6H10O4
B. C6H8O4
C. C7H10O4
D. C7H12O4
Cu 55: Cho hn hp etyl isobutyrat, axit 2-metylpropanoic, metyl butanoat phn ng va vi 200ml dung dch hn
hp NaOH 0,05M v KOH 0,1M. Khi lng mui thu c sau phn ng l
A. 3,54gam
B. 3,62gam
C. 3,78gam
D. 3,3gam
Cu 56: X phng ho 0,1 mol este C6H10O4 bng NaOH thu c 2 ancol l ng ng lin tip, c cn dung dch sau
phn ng thu c m g mui khan. Gi tr m l
A. 29,6
B. 7,4
C. 14,8
D. 22,2
Cu 57: X phng ha 20,4 gam phenylaxetat bng 200ml dung dch NaOH 2M. Phn ng xong c cn dung dch thu
c cht rn c khi lng l
A. 36,4 gam
B. 28,95 gam
C. 33,7 gam
D. 36,4 gam
Cu 58: Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X tc dng va ht vi dung dch NaOH, thu c mt
cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc ca X l (H A09)
A. CH3COOC(CH3)=CH2.
B. HCOOC(CH3)=CHCH3. C. HCOOCH2CH=CHCH3. D. HCOOCH=CHCH2CH3.
Cu 59: X phng ho hon ton 1,99gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui ca mt axit
cacboxylic v 0,94gam hn hp hai ancol l ng ng k tip nhau. Cng thc phn t ca hai este l
A. HCOOCH3 v HCOOC2H5.
B. C2H5COOCH3 v C2H5COOC2H5
C. CH3COOC2H5 v CH3COOC3H7
D. CH3COOCH3 v CH3COOC2H5
Trang 5

CC CHUYN LUYN THI CP TC H-C 2016

HA HU C

Cu 60: Cho 0,02 mol mt este X phn ng va ht vi 200 ml dung dch NaOH 0,2M, sn phm to ra ch gm mt
mui v mt ancol u c s mol bng s mol este, u c cu to mch thng. Mt khc khi x phng ha hon ton 2,58
gam este bng lng KOH va , cn phi dng 20 ml dung dch KOH 1,5M, thu c 3,33 gam mui. Vy X l
A. etilenglicol oxalat
B. etilenglicol adipat
C. imetyl adipat
D. ietyl oxalat
* Ton phn ng este ha
Cu 61: un 6 gam CH3COOH vi 9,2 gam C2H5OH (c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn
bng c 5,5 gam este. Hiu sut phn ng este ha l
A. 55%
B. 62,5%
C. 75%
D. 80%
Cu 62: Khi lng axit metacrylic v ancol metylic ln lt cn ly iu ch c 100kg poli(metyl metacrylat) l
bao nhiu? Cho bit hiu sut ton b qu trnh iu ch t 80%.
A. 86 kg v 32 kg
B. 107,5 kg v 40 kg
C. 68,8 kg v 25,6 kg
D. 75 kg va 30 kg.
Cu 63: X l hn hp gm HCOOH v CH3COOH (t l mol 1 : 1). Ly 21,2g X tc dng vi 23g C2H5OH (xc tc
H2SO4 c, un nng) thu c m gam hn hp este (hiu sut cc phn ng este ha u t 80%). Gi tr m l
A. 40,48g
B. 23,4g
C. 48,8g
D. 25,92g
Cu 64: Trn 18gam axit axetic vi 23 gam ancol etylic ri un nng mt thi gian (c xc tc). Sau khi ngui hn
hp v tch ring ht este th c hn hp cht lng X. Cho ton b X tc dng vi Na (d) thu c 6,72 lt kh ( kc).
Vy khi lng este tch c l
A. 8,8gam.
B. 13,4gam.
C. 17,6gam.
D. 26,4gam.
* Ton lipit (cht bo)
Cu 65: X phng ha hon ton 2,225 kg stearin (cha 20% tp cht) bng dung dch NaOH s thu c mt lng
glixerol l bao nhiu?
A. 184gam
B. 92 gam
C. 178 gam
D. 276 gam
Cu 66: Cho 45 gam trieste ca glixerol vi mt axit bo tc dng va vi 100 ml dung dch NaOH 1,5M c m1
gam x phng v m2 gam glixerol. Gi tr m1, m2 l
A. m1 = 46,4; m2 = 4,6. B. m1 = 4,6; m2 = 46,4.
C. m1 = 40,6; m2 = 13,8.
D. m1 = 15,2; m2 = 20,8.
Cu 67: Thy phn hon ton 222g mt mu cht bo (A) c 23 gam glixerol v 2 loi axit bo. l 2 axit bo sau
A. C15H31COOH v C17H35COOH
B. C17H31COOH v C17H33COOH
C. C15H31COOH v C17H33COOH
D. C17H33COOH v C17H35COOH
Cu 68: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X cn 40 ml dung dch NaOH
1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO2 (ktc) v 11,7 gam H2O. S mol ca axit
linoleic trong m gam hn hp X l (H B10)
A. 0,015.
B. 0,010.
C. 0,020.
D. 0,005.
Cu 69: X phng ha hon ton 8,9 gam mt mu cht bo (A) c glixerol v 9,18 gam mt mui natri duy nht ca
axit bo X, X l
A. C15H31COOH
B. C17H33COOH
C. C17H35COOH
D. C17H31COOH
Cu 70: x phng ha hon ton m gam triglixerit X cn 150ml dd NaOH 0,1M thu c glixerol v mui natri ca
mt axit bo. t chy hon ton cng lng cht bo trn thu c 5,712 lt CO2 (kc) v 4,41g H2O. Tn gi ca X l
A. Triolein
B. Tripanmitin
C. Trilinolein
D. Tristearin
Cu 71: Khi lng NaOH cn thit trung ha ht lng axit bo t do trong 10 gam cht bo c ch s axit l 5,6 l
bao nhiu?
A. 0,04 gam
B. 0,056 gam
C. 1 gam
D. 0,2 gam
Cu 72: x phng hon ton 5,04g cht bo A trung tnh cn 90ml dd KOH 0,2M. Ch s x phng ca cht bo A l
A. 100
B. 180
C. 200
D. 108
Cu 73: X phng ha hon ton 8,68gam cht bo X cn dng 62ml dung dch KOH 0,5M thu c mui kali ca cc
axit bo v 0,92gam glixerol. Ch s x phng v ch s axit ca cht bo X ln lt l
A. 200 v 193,45
B. 200 v 6,45
C. 198,8 v 5,6
D. 196 v 8,4
Cu 74: Mt mu cht bo c ch s x phng v ch s axit ln lt l 198,8 v 8,4. Lng x phng thu c khi cho
300gam cht bo ny tc dng ht vi NaOH l
A. 310,51gam
B. 311,32gam
C. 342,6gam
D. 248,76gam
* Tng hp
Cu 75: X v Y l ng phn cu to ca nhau. un m gam hn hp X v Y vi 200ml ddNaOH 1M va thu c
17,8g hn hp hai mui ca hai axit n chc lin tip nhau trong dy ng ng v mt ancol n chc. Gi tr ca m l
A. 14,8gam
B. 17,8gam
C. 7,4gam
D. 12gam

Trang 6

CC CHUYN LUYN THI CP TC H-C 2016

HA HU C

Cu 76: (TSH B 2009) Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO3 trong
NH3. Th tch ca 3,7gam hi cht X bng th tch ca 1,6 gam kh O2 (cng iu kin v nhit v p sut). Khi t
chy hon ton 1 gam X th th tch kh CO2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to ca X l
A. CH3COOCH3.
B. O=CH-CH2-CH2OH. C. HOOC-CHO.
D. HCOOC2H5.
Cu 77: X phng ho hon ton 66,6gam hn hp hai este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH, thu
c hn hp X gm hai ancol. un nng hn hp X vi H2SO4 c 140oC, sau khi phn ng xy ra hon ton thu c
m gam nc. Gi tr m l
A. 18,00.
B. 8,10.
C. 16,20.
D. 4,05.
Cu 78: (TSH B 2009) Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100ml dung dch
KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau
hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai
hp cht hu c trong X l
A. HCOOH v HCOOC2H5.
B. CH3COOH v CH3COOC2H5.
C. C2H5COOH v C2H5COOCH3.
D. HCOOH v HCOOC3H7.
Cu 79: (TSH B 2009) Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi
hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300ml dung dch NaOH 1M, thu c
dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l
A. 29,75.
B. 27,75.
C. 26,25.
D. 24,25.

****************************************

CHUYN 5: CACBOHIRAT
A. TM TT L THUYT
1. Khi nim Phn loi
Monosaccarit
Glucoz
Fructoz
CTPT

C6H12O6

* dng
mch h
* 6C khng
c
nhnh
im * 5 nhm -OH
cu to * 1 nhm
CH=O

* dng mch
h
* 6C khng
nhnh
* 5 nhm -OH
* 1 nhm -CO-

isaccarit
Saccaroz
Mantoz

Polisaccarit
Tinh bt
Xenluloz

C12H22O11

(C6H10O5)n

* 1 gc
-glucozo v 1
gc -fuctozo
* nhiu nhm
OH
* khng cn
nhm
-CH=O

* 2 gc
-glucozo
* nhiu nhm
OH
* cn 1 nhm
-CH=O

* nhiu gc glucoz
* nhiu nhm
OH
* khng c
nhm -CHO

* Nhiu gc glucoz
* nhiu nhm
OH
* khng c
nhm -CHO

*Lu :
+ Thc t cc monosaccarit (glucozo ; fructozo) v disaccarit (saccarozo ; mantozo) tn ti ch yu dng mch vng,
nhng n gin ta biu din di dng mch h.
+ Fructozo l ng phn ca glucozo; mantozo l ng phn ca saccarozo.
+ Tinh bt v xenlulozo khng c gi l ng phn ca nhau.
2. Tnh cht ha hc
a) Tnh cht andehit n chc (phn ng vi AgNO3/ddNH3 to Ag hoc Cu(OH)2 to Cu2O ( gch) nhit cao):
Glucoz, frutoz, mantoz
b) Tnh cht ancol a chc (phn ng Cu(OH)2 nhit thng to dung dch phc xanh lam): Glucoz, fructoz,
saccaroz, mantoz
phn bit fructozo vi glucozo, mantozo ta dng dung dch brom. (fructozo khng lm mt mu dd brom).
c) Phn ng thy phn: Saccaroz, mantoz, tinh bt, xenluloz.
t
d) Phn ng vi H2: Glucoz, fructozo to sobitol: C6H12O6 + H2
C6H14O6 (sobitol)
e) Phn ng vi it: Tinh bt
0

Trang 7

CC CHUYN LUYN THI CP TC H-C 2016

HA HU C

f) Phn ng HNO3/H2SO4c: Xenluloz to xenlulozo trinitrat (thuc n khng khi)

H 2 SO4
[C6H7O2(ONO2)3]n + 3n H2O
[C6H7O2(OH)3]n + 3n HNO3
(xenluloz)
(xenlulozo trinitrat)
162n
3n x 63
297n
g) Phn ng len men: Glucoz to ancol etylic
* Cc phn ng
+

+M(OH)2d
+H2 O,H
(2)
(C6 H10 O5 )n
nC6 H12 O6
2nC2 H5OH + 2nCO2
2nMCO3
(1)

162n

180n

2n 46

2n 44

2n (M + 60)
(M la kim loai Ca hoac Ba)

* Lu :
Phn ng (1) gi l phn ng thy phn, phn ng (2) gi l phn ng ln men.
- Chng minh glucoz c nhiu nhm OH: dng phn ng ca glucoz vi Cu(OH)2 nhit phng (thng).
- Chng minh glucoz c nhiu 5 nhm OH: dng phn ng ca glucoz vi anhiric axetic to este 5 chc.
- Chng minh glucoz c CHO: dng phn ng ca glucoz vi AgNO3/ddNH3 (phn ng trng gng hay phn
ng trng bc) hoc phn ng vi Cu(OH)2 un nng to kt ta gch Cu2O.
AgNO3 / ddNH 3
Glucoz (C6H12O6)
2 Ag
glucoz +AgNO3 / ddNH3

Thu phn 1 mol saccaroz
4mol Ag
fructoz
B. TRC NGHIM
L THUYT
Cu 1: Hp cht cacbohirat nht thit phi cha nhm chc no?
A. Chc ancol
B. Chc anehit
C. Chc este
D. Chc xeton
Cu 2: c im khc nhau gia glucoz v fructoz l
A. S nhm chc OH
B. T l nguyn t cc nguyn t
C. Thnh phn nguyn t
D. V tr nhm cacbonyl
Cu 3: Khi thy phn n cng tinh bt hoc xenluloz, ta u thu c
A. glucoz
B. mantoz
C. fructoz
D. saccaroz
Cu 4: Dung dch glucoz khng cho c phn ng no di y
A. Phn ng ha tan Cu(OH)2.
B. Phn ng to kt ta gch vi Cu(OH)2
C. Phn ng thy phn.
D. Phn ng trng gng
Cu 5: Fructoz khng phn ng vi cht no sau y?
A. dung dch Br2
B. dd (AgNO3+NH3).
C. H2 (Ni, t0).
D. dd (CuSO4+NaOH)
Cu 6: Dung dch fructz cho c phn ng trng gng nhng khng lm mt mu nc brom. L do l?
A. Fructz ch c tnh kh, khng c tnh oxi ha.
B. Fructz ch c tnh oxi ha, khng c tnh oxi kh.
C. Phn ng trng gng xy ra trong mi trng kim, nc brom khng c mi trng kim.
D. Fructz tn ti ng thi dng mch h ln mch vng.
Cu 7: xc nh cc chc ha hc c trong glucz ngi ta dng cht no sau y?
A. AgNO3/NH3
B. Na
C. Cu(OH)2
D. CH3OH/HCl
Cu 8: Phn ng ca glucoz vi cht no sau y chng minh n c tnh oxi ha?
A. H2 (Ni, t0).
B. CH3OH/HCl.
C. Cu(OH)2, t0
D. dd AgNO3/NH3.
Cu 9: Glucoz tc dng c vi
A. H2 (Ni,t0); Cu(OH)2 ; AgNO3 /NH3; H2O (H+, t0)
B. AgNO3 /NH3; Cu(OH)2; H2 (Ni,t0); CH3COOH (H2SO4 c, t0)
0
C. H2 (Ni,t ); AgNO3 /NH3; NaOH; Cu(OH)2
D. H2 (Ni,t0); AgNO3 /NH3; Na2CO3; Cu(OH)2
Cu 10: Glucoz tc dng vi anhiric axetic (c H2SO4 c lm xc tc, un nng) c este nm ln este. Cng thc
phn t ca este ny l
A. C11H22O11
B. C16H22O11
C. C16H20O22
D. C21H22O11
Cu 11: Mt phn t saccaroz c
A. mt gc -glucoz v mt gc -fructoz
B. mt gc -glucoz v mt gc -fructoz
C. hai gc -glucoz
D. mt gc -glucoz v mt gc -fructoz
Cu 12: Ch ra cng thc phn t ca xenluloz
A. [C6H5(OH)5]n
B. [C6H6(OH)4]n
C. [C6H7O2(OH)3]n
D. [C6H8O3(OH)2]n
Cu 13: Tinh bt, xenluloz, saccaroz v mantoz u c kh nng tham gia phn ng
A. ho tan Cu(OH)2.
B. thu phn.
C. trng ngng.
D. trng gng.
Trang 8

CC CHUYN LUYN THI CP TC H-C 2016

HA HU C

Cu 14: Nhn nh no sau y l sai

A. Phn t xenlulozo gm nhiu gc -glucozo lin kt vi nhau to thnh mch di.
B. Tinh bt c 2 dng amilozo v amilopectin, trong amilozo c mch khng nhnh cn amilopectin phn nhnh.
C. Trong mch amilozo cc gc -glucozo lin kt vi nhau bng lin kt 1,4-glicozit.
D. Trong mch amilopectin cc on mch -glucozo lin kt vi nhau bng lin kt 1,4-glicozit.
Cu 15: C nhn xt g v lng glucoz thu c khi thy phn hon ton 1kg saccaroz (1) v 1kg mantoz (2).
A. mglucoz (1) = 2mglucoz (2)
B. mglucoz (1) = mglucoz (2) C. mglucoz (1) = mglucoz (2) D. mglucoz (1) = 180/324 mglucoz (2)
Cu 16: Pht biu no sau y ng?
A. Dung dch saccaroz to c kt ta gch khi phn ng vi Cu(OH)2.
B. Sobitol l hp cht a chc.
C. Trong phn t xenlulozo c 3 nhm OH.
D. Tinh bt v xenluloz u khng c phn ng ca ancol a chc.
Cu 17: Ch ra pht biu sai
A. Dung dch mantoz ha tan c Cu(OH)2.
B. Sn phm thy phn xenluloz (H+, to) c th to kt ta gch vi Cu(OH)2 un nng.
C. Dung dch fructoz ha tan c Cu(OH)2 .
D. Thy phn saccaroz cng nh mantoz (H+, to) u cho cng cc sn phm.
Cu 18: Pht biu khng ng l
A. Dung dch mantoz tc dng vi Cu(OH)2 khi un nng cho kt ta Cu2O.
B. Sn phm thy phn xenluloz (xc tc H+, t0) c th tham gia phn ng trng gng.
C. Dung dch fructoz ho tan c Cu(OH)2 v kh c Cu(OH)2 khi un nng.
D. Do khng tham gia phn ng trng bc nn ngi ta khng th dng saccarozo trng gng, rut phch.
Cu 19: Saccaroz v mantoz s to sn phm ging nhau khi tham gia phn ng no di y ?
A. Thy phn B. t chy hon ton C. Tc dng vi Cu(OH)2
D. Tc dng vi dung dch AgNO3 trong NH3
Cu 20: (TSH B 2009) Pht biu no sau y l ng?
A. Glucoz b kh bi dung dch AgNO3 trong NH3.
B. Xenluloz c cu trc mch phn nhnh.
C. Aminlopectin c cu trc mch phn nhnh.
D. Saccaroz lm mt mu nc brom.
Cu 21: Cht X c cc c im sau: phn t c nhiu nhm OH, c v ngt, ha tan Cu(OH)2 nhit thng, phn
t c lin kt glicozit, lm mt mu nc brom. Cht X l
A. xenluloz
B. mantoz
C. glucoz
D. saccaroz
Cu 22: phn bit c bn cht hu c: axit axetic, glixerol, ancol etylic v glucoz ch dng mt thuc th no di y?
A. Cu(OH)2/OH
B. CaCO3
C. CuO
D. Qu tm.
Cu 23: C th phn bit dung dch saccaroz v dung dch mantoz bng
1. Cu(OH)2
2. Cu(OH)2/to
3. AgNO3/NH3
4. H2/Ni,to
A. 1; 3
B. 2; 3
C. 1; 2; 3
D. 1; 3; 4
Cu 24: Cho cc dd ring bit sau:glucoz,tinh bt,glixerol,phenol,andehit axetic,benzen. Thuc th dng nhn bit dd
l ?
A. Na, Qu tm , Cu(OH)2
B. Na, Qu tm , AgNO3/NH3
C. Na, Qu tm , nc brom
D. Cu(OH)2, dung dch I2 , nc brom
Cu 25: Trong cc cht: glucoz, fructoz, saccaroz, mantoz, tinh bt, xenluloz. S cht c th kh c
AgNO3/NH3 (a) v s cht c tnh cht ca poliancol (b) l
A. (a) ba; (b) bn.
B. (a) bn; (b) ba.
C. (a) ba; (b) nm.
D. (a) bn; (b) bn.
Cu 26: Cho dy cc cht axetandehit, axeton, glucoz, fructozo, sacaroz, mantoz. S cht trong dy lm mt mu
c dd brom l
A. 2
B. 3
C. 4
D. 5
Cu 27: Dy gm cc dung dch u tham gia phn ng trng bc l:
(TSH A 2009)
A. Glucoz, mantoz, axit fomic, anehit axetic.
B. Fructoz, mantoz, glixerol, anehit axetic.
C. Glucoz, glixerol, mantoz, axit fomic.
D. Glucoz, fructoz, mantoz, saccaroz.
Cu 28: Dy cc dung dch ha tan c Cu(OH)2 l:
A. mantoz; saccaroz; fructoz; glixerol
B. saccaroz; etilen glicol; glixerol; fomon
C. fructoz; anehit axetic; glucoz; saccaroz
D. glixerol; axeton; fomon; anehit axetic
Cu 29: Cho s chuyn ha: Mantoz X Y Z axit axetic. Y l
A. fructoz
B. anehit axetic
C. ancol etylic
D. axetilen
Cu(OH)2 / OH
dd HCl
t0
Yduy nht
Z (dung dch xanh lam) T ( gch) . X l.
Cu 30: Cho s sau: X
t0
A. glucoz.
B. saccaroz hoc mantoz.
C. mantoz.
D. saccaroz.

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CC CHUYN LUYN THI CP TC H-C 2016

HA HU C

BI TP
Cu 31: Thy phn hon ton 405g tinh bt c 20% tp cht vi hiu sut 75%, khi lng glucoz thu c l
A. 300 gam.
B. 250gam.
C. 360 gam.
D. 270 gam.
Cu 32: Ha tan 3,06 gam hn hp X gm glucoz v saccaroz vo nc. Dung dch thu c cho tc dng vi lng
d dung dch AgNO3/NH3 c 1,62 gam bc. Phn trm khi lng glucoz trong X l
A. 44,12 %
B. 55,88%
C. 40%s
D. 60%
Cu 33: T 100 kg go cha 81% tinh bt c th iu ch c V lt ru etylic 460. Bit hiu sut iu ch l 75% v ancol
etylic nguyn cht c D = 0,8 g/ml. Gi tr ca V l
A. 100.
B. 93,75.
C. 50,12.
D. 43,125.
Cu 34: T 100 kg go cha 81% tinh bt c th iu ch c V lt ru etylic 460. Bit hiu sut iu ch l 75% v ancol
etylic nguyn cht c D = 0,8 g/ml. Gi tr ca V l
A. 100.
B. 93,75.
C. 50,12.
D. 43,125.
Cu 35: Kh CO2 chim 0,03% th tch khng kh. Mun to ra 500 gam tinh bt th cn bao nhiu m3 khng kh cung
cp CO2 cho phn ng quang hp?
A. 1382,7.
B. 1382,4.
C. 140,27.
D. 691,33.
Cu 36: T 1 tn mn ca cha 50% xenluloz iu ch c m kg etanol. Bit hiu sut ca mi qu trnh thy phn
xenluloz v ln men glucoz u t 70%. m l
A. 283,94.
B. 240,5.
C. 139,13.
D. 198,76.
Cu 37: Cho 6,84 gam hn hp saccaroz v mantoz tc dng vi lng d dung dch AgNO3 trong NH3 thu c 1,08
gam Ag kim loi. S mol saccaroz v mantoz trong hn hp ln lt bng
A. 0,005 mol v 0,015 mol
B. 0,010 mol v 0,010 mol
C. 0,015 mol v 0,005 mol
D. 0 mol v 0,020 mol
Cu 38: Thu phn hon ton 62,5 gam dung dch saccaroz 17,1% trong mi trng axit (va ) c dung dch X.
Cho dung dch AgNO3/NH3 vo X v un nh c m gam Ag. Gi tr ca m l.
A. 13,5.
B. 7,5.
C. 10,8.
D. 6,75.
Cu 39: Thy phn hon ton 8,55 gam saccaroz, sn phm sinh ra cho tc dng vi lng d ng (II) hiroxit trong
dung dch kim nng. Khi lng kt ta mu gch thu c khi phn ng xy ra hon ton l
A. 1,44 gam
B. 3,60 gam
C. 7,20 gam
D. 14,4 gam
Cu 40: Mun sn xut 59,4 kg xenluloz trinitrat vi hiu sut phn ng l 90% th th tch dung dch HNO3 66,67% (D
= 1,52g/ml) cn dng l
A. 27,230 lt.
B. 39,582 lt.
C. 41,445 lt.
D. 42,581 lt.
Cu 41: X gm glucoz v tinh bt. Ly 1/2 X ha vo nc d, lc ly dung dch ri em trng gng c 2,16 gam
Ag. Ly 1/2 X cn li un nng vi dung dch H2SO4 long, trung ha dung dch sau phn ng bng NaOH, ri em
trng gng ton b dung dch c 6,48 gam bc. Phn trm khi lng glucoz trong X l
A. 35,71 %
B. 35%
C. 64,29 %
D. 66,66%

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