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January 2005 / FORM 5-200

The Pressure - Enthalpy Chart


By Dave Demma, Senior Application Engineer - Supermarket Refrigeration
How often have you heard the statement it isnt cooling?
Well it may seem a bit picky, but it is not entirely accurate to
say the refrigeration system cools. If the system is operating
properly, the refrigerated space should be cooler than its surroundings, but it is the result of a heat transfer process. Heat is
transferred from the refrigerated space to the refrigerant, and
ultimately from the refrigerant to the ambient (at the condenser). A lower temperature in the refrigerated space is the
byproduct of this heat transfer process. Perhaps this is a minor
shift in thinking, but in viewing the refrigeration system for
what it isa heat transfer processa more fundamental
approach for diagnosis may be obtained.
In an effort to gain a better understanding of the various heat
transfer processes occurring in a refrigeration system, the pressure-enthalpy chart can be of great use. Additionally, once
understood, the chart can be a tremendous benefit in analyzing the relative health of a refrigeration system. Lets follow
the refrigerant on a quick journey through a refrigeration system to see what it experiences, and plot it on the chart as we
go. Before we start, a few technical definitions are in order:
Refrigeration - The achievement of a temperature below that
of the immediate surroundings.
Latent Heat of Fusion - The quantity of heat (Btu/lb) required

to change 1 lb. of material from the solid phase into the liquid
phase.
Latent Heat of Vaporization - The quantity of heat (Btu/lb)

required to change 1 lb. of material from the liquid phase into


the vapor phase.
Sensible Heat - Heat that is absorbed/rejected by a material,

resulting in a change of temperature.


Latent Heat - Heat that is absorbed/rejected by a material

resulting in a change of physical state (occurring at constant


temperature).
Saturation Temperature - That temperature at which a liquid

starts to boil (or vapor starts to condense). The saturation temperature (boiling temperature) is constant at a given pressure,*
and increases as the pressure increases. A liquid cannot be
raised above its saturation temperature. Whenever the refrigerant is present in two states (liquid and vapor) the refrigerant
mixture will be at the saturation temperature.
Superheat - At a given pressure, the difference between a

vapors temperature and its saturation temperature.


Subcooling - At a given pressure, the difference between a liquids temperature and its saturation temperature.
* Except for zeotrope refrigerants

Ton of Refrigeration - The amount of cooling required to

change (freeze) 1 ton of water at 32F into ice at 32F, in a 24


hour period.
Btu - British Thermal Unit: The amount of heat required to

raise 1 lb. of water 1F.


1 Ton - 12,000 Btu/hr

Fig. 1 illustrates some of these definitions, using water as the


medium experiencing a heat transfer process. This graph plots
the water temperature vs. the enthalpy of the water (heat content in Btu/lb). We all know that water boils at 212F (atmospheric pressure at sea level). By definition, water at atmospheric pressure, at a temperature lower than 212F, is subcooled.
So, we start with subcooled water at 42F, and begin transferring heat to it. Assuming we are working with 1 lb. of water,
for every Btu added, a corresponding temperature increase of
1F will be achieved (the definition for one Btu). It we continue to add heat, eventually the waters temperature will increase
to 212F (the saturation temperature at atmospheric pressure).
At this point, the water begins to change states from a liquid to
a vapor (boil). As noted on the graph, the water will experience
no further temperature increasefor a given pressure, the
saturation (boiling) temperature is the highest temperature
a liquid can ever achieve. Increasing the amount of heat transferred to the water simply increases the rate at which the water
boils. If the temperature of the vapor were to be measured,
wed find it to be 212F (saturated vapor). Once the vapor has
separated from the liquid, additional heat transferred to it will
result in a temperature increase. By definition, the vapor at
232F (20 above the saturation temperature), is superheated.
It is interesting to note that while it takes only 1 Btu to raise 1
lb. of water 1F, it takes almost 1000 times that amount (966.6
Btu) for the 1 lb. mass of water to change states from liquid to
vapor. A boiling liquid will always absorb more heat than a
vapor experiencing a temperature increase (per unit of mass).
Understanding this principle explains why the evaporator in a
refrigeration system should always be nearly filled with liquid
refrigerant. Otherwise, its full potential as a heat transfer
device will not be utilized.
The pressure-enthalpy chart, as shown in Fig. 2, displays all
the pertinent properties for a given refrigerant (in this example
R22). The bubble to the left is the portion of the diagram where
the refrigerant is in the saturated condition. The blue line on
the left of the bubble represents the 100% saturated liquid line,
the thin dashed line on the right represents the 100% saturated
vapor line, and anywhere inside the bubble represents the
refrigerant as a mixture of saturated liquid and saturated vapor.
To the left of the saturated liquid line is the area where the
refrigerant can exist at a temperature lower than the saturated

Page 2 / FORM 5-200

condition; subcooled liquid. To the right of the saturated vapor


line is the area where the refrigerant can exist at a temperature
higher than the saturated condition; superheated vapor. The
critical point is the highest temperature that the refrigerant can
experience, and remain in the liquid form. If the temperature
exceeds the critical point, regardless of pressure, the refrigerant can only exist in the vapor state.

Specific volume is expressed in cu.ft/lb. (see orange line).


Entropy - Entropy is the mathematical relationship between

heat and temperature, and relates to the availability of energy.


These lines extend at an angle from the saturated vapor line.
Their presence on the chart is relevant in that vapor compression (in the ideal cycle) occurs at constant entropy (see dark
blue line).

All of the relevant properties are shown in Fig. 2:


Quality - Lines of constant quality appear vertically, and only
Pressure - The vertical axis of the chart, in psia (see pink line).

To obtain gauge pressure, subtract atmospheric pressure.


Enthalpy - The horizontal axis of the chart shows the heat content of the refrigerant in Btu/lb.
Temperature - Constant temperature lines generally run in a

vertical direction in the superheated vapor & sub-cooled liquid


portion of the chart. In the saturated bubble, the constant temperature line is along the horizontal, illustrating that the saturation temperature is constant at a given pressure (see black line).
Specific Volume - Constant volume lines extend from the red

line saturated vapor line out into the superheated vapor-portion of the chart at a slight angle from the horizontal axis.

within the saturation bubble. The refrigerant within the bubble


is a mixture of liquid and vapor at saturation, and the quality is
the percentage of the mixture which is in the vapor state (see
green line).
The ultimate goal of the refrigeration system is to get the
refrigerant into a condition where it can be useful as a medium
to transfer heat from the refrigerated space. If the system
design requires a -10F space temperature, you would expect
the refrigerant temperature in the evaporator to be somewhat
lowersay -20F (a 10 temperature difference). This allows
the relatively warmer air (something above the design of -10F)
to be blown across the evaporator, flowing relatively cooler
refrigerant (-20F). The result is the transfer of heat from the
warmer air to the cooler refrigerant.

Refrigeration
Water at Atmospheric Pressure
(14.7 psia pressure)
Saturation
Temperature

232

Boiling at constant pressure and temperature


Superheated
20 Superheat (232 212= 20)
Vapor

Subcooled
Liquid

Temperature (F)

212

Latent Heat of Vaporization


966.6 Btu per lb
32
200

400
600
800
Enthalpy (Btu per lb)

1000

Fig. 1 Water undergoing a change of state.

1200

FORM 5-200 / Page 3

Enough heat must be transferred from the refrigerant to lower


its temperature from 180F to the saturation temperature of
100F (point #2A on the chart). At this point, condensation can
begin. As heat continues to be transferred from the refrigerant
vapor to the air (or water, if a water cooled condenser is used),
the quality of the refrigerant (% of the refrigerant in the vapor
state) will continue to decrease, until the refrigerant has been
completely condensed. In the ideal system, this occurs at the
outlet of the condenser (point #3 on the chart). In the real
world, some subcooling would be expected at the condenser
outlet. Subcooled liquid provides insurance against liquid
flashing as the refrigerant experiences pressure losses in the
tubing and components.

The purpose of the compressor is to take a low pressure vapor


and compress it into a high pressure vapor. This occurs
(in theory) at a constant entropy. In an ideal cycle, the refrigerant vapor would enter the compressor as a saturated vaporno
superheat.
The Ideal Cycle

If the operating temperatures and pressures are known, the


refrigeration system can be plotted on the P-H diagram. Lets
assume our system is operating at a -20F evaporator and 100F
condensing.
The saturated vapor entering the compressor suction would be
at -20F, illustrated by point #1 in Fig. 3. The vapor is compressed, following the constant entropy line to the pressure corresponding to 100F, or 210.7 psia (point #2). The refrigerant
vapor experiences a sensible heat gain during the mechanical
compression process, resulting in a superheated vapor. This is
illustrated by the location of point #2, to the right of the saturated vapor line. In the ideal system, which does not consider
pressure loss in the valves, refrigerant tubing, etc., point #2 represents the outlet of the compressor/inlet of the condenser.

The refrigerant is in the liquid state now, and at a high pressure


and temperature. It must undergo one more change before it
becomes a useful heat transfer medium; a reduction in temperature. This is accomplished by reducing the pressure. You can
count on the refrigerants pressure-temperature relationship to
be an infallible law. If the pressure of a saturated liquid is
reduced, the law governing its existence requires it to assume
the saturation temperature at the new pressure.

In the ideal cycle, the condenser serves as a two-fold component. Before any condensation occurs, the high pressure vapor
must first be brought to a saturated condition (de-superheated).

So, in order to reduce the temperature, the pressure has to be


reduced, and some sort of restriction is required for this to
occur. It would be preferable if the restriction could regulate

SCALE CHANGE

-10

10

20

30

40

50

60

70

80

90

4000

100

14
0. 6
0.01

0.

0.

5000

13

-20

12

-30

0.

110

15

0.

0.017

120

16

130

17
0.
0.018

0.

140

18

0.

19
0.020

150

0.

20

0.

REFRIGERANT 22

3000

160

170

21
22
0.
0.022
0.025

0.

180

23

0.2

190

4
0.2

0.2
0.04

200

0.05

Sat
ura
ted
Vap
or

Line

Lin
e

id

Sat
ura
ted
Liq
u

100%

100
%

ua l it y

-60

a nt Q

0.6
-30

Co

10

20

0.5

30

0.6

40

0.7

50

60

0.8

70

0.9

80

90

33
0.

100

0.3

0.4

0.2

-10

0.3

0.3

-20

0.2

0.3

-120
0.1

40

4.0

30

14

1.4

0.8

3.0

14

-100

-120

60

10.0

34

2.0

80

2.0

20

0.

-100

100
1.4

7.0

-80

3.0

5.0

-20

-80

C onst

Pressure (psia)

46
0

40

Constant Volum

-60

4.0

1.0

140
1.0

-40

-80

200

0.7

80

-60

6.0

300

0.5

10
8.0

400

0.4

20

14

-40

600

0.3

40

-40

1400

800

0.2

100

-20

1000

60

20

Constant Temperature

-20

180

30

120

40

20

0.10

140

20

160

60

40

260

60

40

80

220

60

3000
2000

0.2

Constant Pressure

200

100

80

240

80

140

100

36

100

30 0

120

280

200

140

120

320

140

300

4000
7
0.2

400

s
on

34

180
160

160

n
ta

54

0.14

180

38

600

n
tE

52

58

Critical Point
200

42

800

py
tro

44

160F

1000

50

0.07

56

60

48

180

1400

5000

0.03

2000

200

0.

35

t
ns

6
.3

an

3
0.

tE

py
ro
nt

0.

/
tu
(B

lb

F
-

20

0.

39
70

6.0
4.0

30

3.0

40

38

8.0

50 Specific Volume (ft3/lb)


.40

2.0
1.4

1.0
0.8

110

120

130

140

SCALE CHANGE

Enthalpy (Btu per lb above saturated liquid at -40F)

Fig. 2 R22 Pressure-Enthalpy Diagram

150

160

170

180

190

0.6
200

Page 4 / FORM 5-200

itself as the system load demands change. This is exactly what


the thermostatic expansion valve does; it is an adjustable
restriction which causes a reduction in liquid refrigerant pressure, yet will modulate in an effort to maintain constant superheat at the evaporator outlet. The TEV is a superheat control,
and will not maintain a constant evaporator pressure. It only
provides the restriction necessary to reduce the pressure to
some level, which will be determined by compressor size, TEV
size, load demand, and system conditions. If a constant evaporator temperature is required, it can be achieved very simply by
maintaining the pressure corresponding to the saturation temperature required. This is accomplished by adding an evaporator pressure regulating valve to the system.

Because the refrigerant must conform to its law of existence,


when the 210.7 psia (100F) liquid experiences the reduction in
pressure to 24.9 psia, it must drop to the new saturation temperature of -20F. Some of the liquid refrigerant is required to
boil as a means of removing the heat necessary to achieve this
lower temperature. Yet another heat transfer process, which
yields a lower liquid temperature. The liquid that is sacrificed
in the boiling process explains the increase in refrigerant quality. The greater the difference between the liquid temperature
and evaporator temperature, the more liquid will have to be
boiled to achieve the new saturation temperature. This results
in an even higher refrigerant quality.
The final portion of the refrigerants journey is as a mixture of
saturated liquid and vapor, traveling though the evaporator tubing. Warm air is blown across the evaporator, where its heat
content is transferred to the boiling refrigerant. This is a latent
heat gain to the refrigerant, causing no temperature increase,
while experiencing a change of state. In the ideal cycle, the last
molecule of saturated liquid boils off at the evaporator outlet,
which is connected to the compressor inlet. Hence, the vapor at
the inlet of the compressor is saturated.

Our ideal cycle has experienced a pressure drop in the TEV,


and for the purpose of discussion we are at a constant 24.9 psia
in the evaporator. This is a saturation temperature of -20F. You
will notice that the refrigerant quality at the TEV inlet was 0%,
and has increased to 35% at the evaporator inlet. Subcooling or
superheat cannot exist where there is a mixture of liquid and
vapor. Therefore, any place in the system where the refrigerant
exists in two states (the receiver, parts of the evaporator and
condenser, the accumulator at times), it will be at the saturation
temperature for its pressure. For example, R22 in a saturated
state at 24.9 psia (10.2 psig) will always be at -20F.

The cycle continues this way until the refrigerated space temperature is satisfied, and the equipment cycles off.

Enthalpy (Btu per lb above saturated liquid at -40F)


SCALE CHANGE

10

20

30

40

50

60

70

80

0.

5000
4000

90

100

14
0. 6
0.01

13

-10

12

-20

0.

-30

0.

110

15

0.

0.017

120

16

130

17
0.
0.018

0.

140

18

0.

19
0.020

150

0.

20

160

0.

REFRIGERANT 22

3000

170

21
22
0.
0.022
0.025

0.

180

23

0.2

190

4
0.2

0.2
0.04
0.05

200
180

48
ns

tan
t Te
F)
ature (
mp er

ted
Vap
or

Co

Sat
ura

Sat
ura
ted
Liq
uid

200
0.7
140
1.0
1.4

80

2.0

60

3.0

40

4.0

30
20
14

20

10.0

-20

-100

-100
2.0

0.3

10

0.4

20

0.5

30

0.6

40

0.7

50

60

0.8

70

0.9

80

90

0.

33

0.

1
100

0.3

0
0

0.2

0.3

0.1

-10

0.3

-120

-120

34

Co

1.4

0.2

Pressure (psia)

40

34

300

0.5

7.0

-80

3.0

-20

400

0.4

5.0

-60

4.0

0.6
-30

600

100

-40

-80

-80

0.8

1400

800

14

6.0

1.0

-40

-60

-60

8.0

1000

60

Evaporation Line

3000

10

0.2

0.3

40

14

0.2

80

-20

-40

.27

2000

0.14

100

-20

20

160

30

Compression Line

20

120

40

58

4000

140

Expansion20Line

60

180

40

40

36

100
80

56

200

60

60

220

140

240

80

80

280

200

260

100

30 0

2A
120

Condensation Line

320

140

140

3
120

300

Desuperheating Line

180
160

160
400

52

54

60

0.10

200
180

38

600

42

800

44

160F

1000

50

0.07

46

IDEAL CYCLE

1400

5000

0.03

2000

200

5
.3

0.

t
ns

36

an

0.

n
tE

37

y
op
tr

0.

/
tu
(B

lb

F
-

20

0.

39
70

6.0
4.0

30

3.0

40

38

8.0

50 Specific Volume (ft3/lb)


.40

2.0
1.4

1.0
0.8

110

120

130

140

150

SCALE CHANGE

Fig.3 - Plotting the Ideal Cycle on the P-H Diagram

160

170

180

190

0.6
200

FORM 5-200 / Page 5

Once the system has been plotted, various data points can be
read and used for the system design calculations. Admittedly,
this information is not typically something the technician will
need for servicing the refrigeration equipment. However, an
understanding of how operating conditions affect system
design, efficiency, energy consumption, and particularly compressor performance, should be of great worth to the technician.

Heat of Compression (HOC): This is the amount of heat added

to the refrigerant from the compression process (represented


by H2 minus H1 on the chart).
Heat of Rejection (HOR): This is the amount of heat that has
to be rejected at the condenserthe heat transferred to the
refrigerant from the refrigerated space (RE), and the heat transferred to the refrigerant during compression (HOC). It is this
value, plus some safety factor, from which the condenser selection is made (represented by H2 minus H3 on the chart).

Data Points and System Design Calculations:


Refrigeration Effect (RE): This is the total heat transfer, in
Btu/lb, from the refrigerated space to the refrigerant. H1 minus
H4 (H1 is the enthalpy of the refrigerant at point #1 in Fig. 3,
and so forth).

Refrigerant Circulation Rate (RCR): The amount of refrigerant

in lbs/min which must circulate in the system to meet the


demands of the load.
(200 Btu/min ton)
RE (Btu/lb)

Note: For the purpose of this discussion, H1 will be considered the


point where the evaporation line intersects with the saturated vapor
line. In the real world, the location of H1 would be to the right of the
saturated vapor line, reflecting the superheated vapor at the evaporator outlet. With an expansion valve maintaining a typical amount of
superheat (in the 4 - 6 range for low temperature applications), the
heat transferred to the vapor is minimal (less than 1 Btu/lb). The heat
transferred to the vapor between the suction piping outside of the
refrigerated space and the compressor cylinder inlet is never considered as part of the refrigeration effect, as this heat was not transferred from the refrigerated space.

Compressor Horsepower Required: The horsepower/ton


requirement to meet the load demand. Contrary to popular
belief, 1 horsepower and 1 ton are not necessarily synonymous.
RCR (lb/min-ton) X HOC (Btu/lb) X 778 ft-lb/Btu
33,000 ft-lb/min-hp

SCALE CHANGE

10

20

40 4050

30

60

70

80

0.

5000
4000

102
100

90

14
0. 6
0.01

13

-10

12

-20

0.

-30

0.

108
110

15

0.

0.017

120

16

135
140

130

17
0.
0.018

0.

18

0.

19
0.020

150

0.

20

160

0.

REFRIGERANT 22

3000

170

21
22
0.
0.022
0.025

0.

180

23

0.2

190

4
0.2

0.03

0.05

200

TYPICAL CYCLE - 1
180

1400

300

0.4

ature (
m pe r

por

t Te

0.5

200

0.7
140

F)

rate
d Va

ta n

Sat
u

ns

Liq
uid

Co

400

0.3

1.0
100
1.4

80

2.0

60

3.0

40

4.0

30

5.0
20
7.0
14

20

10.0

-60

-60

14

-20

0.6
-30

-20

0.1

0.2

-10

0.3

10

0.4

20

0.5

30

0.6

40

0.7

50

60

0.8

70

80

90

100

34
0.

33

110

0.

1
0

0.9

0.3

-120

0.8

Btu
lb

NRE = 62

-120

Co

0.3

1.4

y
op
tr

120

35

3
0.

0.

37

0.

0
COMP
VOL Req =

130

140

SCALE CHANGE

Enthalpy (Btu per lb above saturated liquid at -40F)

Fig. 4 Typical Cycle #1

)
-F

3.23 lb
min - ton

2.05 HP
ton 9
8

an =
COMP HP Req
st

-100

0.2

2.0

Btu
lb

n
tE

0.3

HOC = 27

-100

-80

3.0

l
u/=
REF Circulation Rate
Bt

-60

4.0

Btu -80
lb

-40

HOR = 135 40 = 95

-80

1400

600

0.2

40

-40

6.0

800

60

-40

8.0

3000

1000

0.14

-20

20

10

2000

80

-20

14

0.2

0.2

0.10

Sa
tur
ate
d

44

Pressure (psia)

60
0

100

30

1.0

54

58

48
46

40

34

180

20

120

4000

140

40

20

160

60

40

220

60

40

80

52

56

200

60
100

260

80

240

80
140

280

200

30 0

120

120
100

140

320

140

300

36

180
160

160
400

38

600

42

160F

800

50

0.07

Open Drive Compressor


40F Suction S.H. @ Comp. Inlet
200
215F Discharge Temp.
180

1000

5000

6
0.2
0.04

2000

200

150

0.

70

20

3.0

50 Specific Volume
0

(ft3/lb)

2.0
1.4

7.39 CFM
ton
160

6.0
4.0

30

40

0.4

8.0

1.0
0.8
170

180

190

0.6
200

Page 6 / FORM 5-200

The suction superheat will insure that the compressor is protected from liquid flooding. The cost of this protection comes
in the form of a larger compressor volume requirement. This is
due to the warmer, thinner suction vapor; at +20F the specific
volume of the vapor (measured in cu.ft./lb) is greater than it
was at -20F. The compressors cylinders are a measured volume...they never change. The density of the refrigerant may
change, and this will affect the pounds per minute of refrigerant that the compressor will pump, however the volume
pumped remains constant. So, because the suction vapor is less
dense, we now require more compressor cylinder volume to
pump the same mass flow.

Compressor Volume Required: The compressor cylinder vol-

ume requirement needed to pump the RCR, in cu ft/ton. The


vapor specific volume is read on the lines of constant volume.
RCR (lb/min-ton) X vapor specific volume (cu ft/lb)

Lets look at a few typical system scenarios, plot them on the


P-H diagram, and then compare the performance measurements.
Typical Cycle #1 (Fig. 4): It is neither realistic nor safe to have
a saturated vapor at the compressor inlet. Because liquid cannot be present with superheated vapor, some amount of superheat at the compressor inlet becomes the margin necessary
to insure the safety of the compressor. Here we see the suction vapor superheated to +20F (40 superheat). This is the
result of an expansion valve set to maintain some amount of
superheat, plus the temperature increase the refrigerant vapor
experiences in the suction line. The suction line connected to
the compressor will have some accumulation of frost on it.
This is the result of the 20F pipe temperature and mositure in
the air, NOT the result of floodback. Floodback is not possible
when the vapors temperature is 40 above the saturation temperature (40 superheat). Do not confuse frost buildup with
floodback.

While all the various data points and system design calculations are listed, they will appear in a comparative chart later.
Typical Cycle #1A (Fig. 5): Using an open drive compressor,
with a 20F vapor temperature at the compressor inlet, we see
the benefit of subcooling the liquid to 50F. Note the change in
refrigerant quality at the TEV outlet. Instead of 65% liquid, we
now have 80% liquid. Because the difference between liquid
temperature and evaporator temperature has been reduced,
there is less refrigerant flashing during the expansion process.
As a result, the TEV and distributor nozzle (if used) can possibly be downsized.

SCALE CHANGE

10

22
20

30

40 4050

60

70

80

0.

5000
4000

102
100

90

14
0. 6
0.01

13

-10

12

-20

0.

-30

0.

108
110

15
0.017

0.

120

16

135
140

130

17
0.
0.018

0.

18

0.

19
0.020

150

0.

20

160

0.

REFRIGERANT 22

3000

170

21
22
0.
0.022
0.025

0.

180

23

0.2

190

4
0.2

0.03

200

0.05

180

TYPICAL CYCLE - 1A

1400

0.5

( F)
rature

id
Liq
u

300

0.4

m pe

t Te

Vap
o

ta n

400

0.3

200

0.7
140
1.0

80

Sat
ura
ted

600

ns

rate
d

Co

Sat
u

1.4

80

2.0

60

3.0

40

4.0

30

14
10.0
14

0.2

0.3

10

0.4

20

0.5

30

0.6

40

0.7

50

60

0.8

70

nt

py
ro

80

90

110

34
0.

33
0.

100

0.3

0
0.9

0.3

-120

Co

120

5
.3

0.

36

0.

37

0.

0
COMP
VOL Req =

130

140

SCALE CHANGE

Enthalpy (Btu per lb above saturated liquid at -40F)

Fig. 5 Typical Cycle #1A

2.5 lb
min - ton

1.59 HP
ton 9
8

COMP HP Req
ta =
ns

-100

0.1

-10

Btu
lb
Btu
lb

NRE = 80

-120

lb

)
-F

u/=
REF Circulation Rate
Bt
E
nt

0.3

1.4

-80

0.2

Pressure (psia)

44

800

0.2

40

2.0

-20

1000

20

-20

HOC = 27

-100

1400

100

-80

3.0

Btu
lb

7.0

-60

4.0

0.6
-30

0.2

5.0

-40

HOR = 95

-80

3000

-60

6.0

0.8

60

-40

-60

8.0

2000

0.14

20

10

100

-20

-40

14

-20

20

58

0.10

40

30

20

120

40

4000
.27

140

20

160

60

40

180

40

260

60

100
80

56

200

60

220

140

240

80

80

280

200

1.0

34

120

100

30 0

120

140

320

140

300

36

180
160

160
400

38

600

42

160F

800

52

54

60

48
46

1000

50

0.07

Open Drive Compressor


40F Suction S.H. @ Comp. Inlet
200
Liquid Subcooled to18050F

5000

6
0.2
0.04

2000

200

150

0.

70

20

3.0

50 Specific Volume (ft3/lb)


.40

2.0
1.4

5.73 CFM
ton
160

6.0
4.0

30

40

8.0

1.0
0.8
170

180

190

0.6
200

FORM 5-200 / Page 7

The use of a liquid to suction heat exchanger will yield subcooled liquid, but at the expense of higher suction vapor temperatures. While this method of subcooling will insure vapor
free liquid refrigerant at the TEV inlet, it has little effect on
increasing system efficiency. The benefit realized resulting
from subcooling will be offset by the higher suction vapor temperatures, and the volume requirement penalty they impose. In
this supermarket example the liquid for the low temperature
rack is subcooled using the medium temperature rack. There is
no heat gain to the low temperature rack as a byproduct of the
subcooled liquid. The refrigerant is subcooled on a rack that is
operating between 2 to 2-1/2 horsepower per ton, and the benefit is being experienced on a rack that is operating near 5
horsepower per ton.

seals. The disadvantage is that there is now an electric motor in


the refrigerant circuit (at least on suction vapor cooled hermetic compressors). In addition to the guaranteed system contamination problem when a hermetic motor burns, you have the
heat from the motor being transferred to the refrigerant vapor.
An approximate 80F temperature increase can be expected
between the vapor entering the compressor service valve, and
the vapor entering the compressor cylinders. This brings the
suction vapor temperature up to 100F, with a corresponding
increase in discharge temperaturenow approaching 300F.
This is the upper limit at which most compressor manufacturers
agree shouldnt be exceeded. The refrigerant vapor at 100F
has a specific volume approximately 20% higher than at 20F.
This translates into a compressor volume requirement which
will be approximately 20% greater. The higher suction vapor
temperature also results in a higher HOC, which raises the
horsepower requirement.

The comparative chart will show the benefits: reduced refrigerant circulation rate, reduced horsepower requirement, and
reduced compressor volume requirement. If the subcooling can
be accomplished very inexpensively, such as ambient subcooling with a receiver bypass, the energy savings can be enormous. For more details on this see Sporlan Form 90-134.

Typical Cycle #3 (Fig. 7): Now, lets take a look at the real
world. It is now the dead of summer the most extreme condition for the equipment. When the system design and equipment
selection was made, it was this summer weather that was used
as the worst case condition of operation. Now, your company
was so busy in the winter that the yearly preventative maintenance was not done. Or perhaps its one of those customers

Typical Cycle #2 (Fig. 6): The advantage of using a hermetic


compressor is the elimination of either belts or drive motor
couplings which require precise alignment, and crankshaft

SCALE CHANGE

10

20

30

40 4050

60

70

80

0.

5000
4000

102
100

90

14
0. 6
0.01

13

-10

12

-20

0.

-30

0.

110

15

0.017

0.

120

16

121

17
0.
0.018

0.

130

140

18

0.

19
0.020

150

0.

20

0.

REFRIGERANT 22

3000

152 160

170

21
22
0.
0.022
0.025

0.

180

23

0.2

190

4
0.2

0.03

TYPICAL CYCLE - 2
200

0.05

180

1400

(
rature

400
300
200

0.7
140

F)

ted
Vap
or

m pe

Sat
ura

t Te

id

tan

tur
ate
dL
iq u

ns

Sa

Co

1.0
100
1.4

80

2.0

60

3.0

40

4.0

30

5.0
20

40

7.0
14
10.0

-20

u/

-80

3.0

0.2

-10

0.3

10

0.4

20

0.5

30

0.6

40

50

60

70

80

90

33

110

0.

100

0.3

0
0.9

0.3

0.1

-120

0.3

Btu
lb
0.7
0.8

NRE = 62

120

3
0.

0.

36

0.

COMP VOL Req =


130

140

SCALE CHANGE

Enthalpy (Btu per lb above saturated liquid at -40F)

Fig. 6 Typical Cycle #2

20

2.36 HP
8 ton .39
.3

37

150

14

3.23 lb
min - ton

py
ro

1.4
-120

t
En

st =
COMP HP Req
on
34

2.0

an

-100
Btu
lb

HOC = 152 - 121 = 31

0.

-100

lb

-F

t
REF Circulation Rate
(B =

-60

4.0

-40

Btu-80
lb

HOR = 152 - 40 = 112

0.2

Pressure (psia)

600

0.5

80F-60Vapor
Temperature increase from hermetic motor windings

-80

-20

1400

800

0.4

120F Suction Superheat

6.0

0.6
-30

1000

60

-40

-60

0.8

3000
2000

0.2

0.3

20

10
8.0

0.2

80

-20

20
14

0.2

100

-20

-40

4000

48
44
40

30

1.0

0.14

34

20

120

40

60
0

140

20

260

40

160

60

40

220

60

180

80

54

58

200

60
100

280

80

240

80
140

30 0

120

100

200

140

120

320

140

300

36

180
160

160
400

52

56

0.10

42

180

38

600

46

160F

800

50

0.07

Hermetic Compressor
40F Suction S.H. @ Comp. Inlet
295F Discharge Temp. 200

1000

5000

0.2
0.04

2000

200

70

3.0

50 Specific Volume (ft3/lb)


.40

2.0
1.4

8.77 CFM
ton
160

6.0
4.0

30

40

8.0

1.0
0.8
170

180

190

0.6
200

Page 8 / FORM 5-200

for the vapor trapped in the clearance volume. It too is at the


discharge pressure. Before any suction vapor can re-enter the
cylinders, the clearance volume vapor must experience a reduction in pressure to a level slightly below that of the suction pressure. Otherwise, there would be no flow into the cylinder. It is
piston travel, which increases the cylinder volume, that reduces
this clearance volume pressure. This portion of the piston travel, which is entirely dedicated to lowering the clearance volume
pressure, performs no useful work at all. In fact, it is advantageous to keep this to a minimum. The higher the clearance volume pressure is above the suction pressure, the more of this
wasted piston travel will be required. Simply put, this is the definition of a high compression ratio (substituting discharge pressure for clearance volume pressure, as they are one and the
same).

who never wants to spend money on preventionthe one you


tell you can either pay me a little now, or you can pay me a lot
more, later. In either case, the condenser is dirty, and the bottom line is that the condensing temperature has increased; from
100F to 120F.
With the higher discharge pressure, the compression ratio has
increased from 8.5:1 to 11:1. This higher pressure that the
compressor is pumping against has a twofold negative impact.
First, the motor amperage will be higher. Secondly, the volumetric efficiency of the compressor will be reduced.
There is a pocket of vapor between the bottom of the valve
plate, and the top of the piston, called the clearance volume. It
is there to insure that the piston does not run into the valve
plate during the operation of the compressor. The vapor in this
pocket requires re-expansion to a lower pressure before any
new suction vapor can enter the compressors cylinders.

Note the higher HOC. Referring to the system design calculations reveals that more horsepower will be required. In addition, the quality of the saturated liquid/vapor mixture at the
TEV outlet has further deteriorated, resulting in a lower RE.
Referring again to the system design calculations will reveal
that the lower the RE is, the higher the RCR has to be. This, in
turn, will require more cylinder volume to meet the demand of
an increased RCR. In a typical supermarket there are backup
compressors that only operate under high load conditions, so

Lets take a look at the compression cycle. It begins when suction vapor enters a cylinder as its piston is traveling down. As
the piston starts to travel back up, reducing the volume of the
cylinder, the vapor pressure increases. When the piston reaches
the top of its stroke, the entire volume of compressed vapor will
have exited the cylinder through the discharge valves EXCEPT

SCALE CHANGE

10

3040 40

20

45
50

60

70

80

0.

5000
4000

102
100

90

14
0. 6
0.01

13

-10

12

-20

0.

-30

0.

110

15

0.

0.017

120

16

121

17
0.
0.018

0.

130

152
150

140

18

0.

19
0.020

0.

20

155
160

0.

REFRIGERANT 22

3000

170

21
22
0.
0.022
25
0.0

0.

180

23

0.2

190

4
0.2

0.03

200

0.05

180

TYPICAL CYCLE - 3

1400

0
Co
ns

ta n
t Te

m pe

0.5

295F Discharge Temp.


(
rature

140
1.0
100

id
dL
iqu

80

Sat
ura
te

-20

REF Circulation
Rate =
F)
(

10

0.4

20

0.5

30

0.6

40

0.7

50

60

0.8

70

0.9

80

90

100

34

0.

33
0.

1
9

-10

0.3

0.3

0.2

0.2

0.1

0.3

-120

-120

NRE @ 120F Cond. = 57 Btu


lb
5
0.3

1.4

u/
Bt

lb

3.5 lb
min - ton

py
COMPtroHP
Req = 2.81 HP
n
ton 40
tE

-100

NRE @ 100F Cond. = 62 Btu


lb

200

1.4

80

2.0

60

3.0

40

4.0

30

14

-80

-100
2.0

300

0.7

F)

Sat
ura
ted
Vap
or

Pressure (psia)

44

400

0.3

320F Discharge
0.4 Temp.

10.0

HOC @ 120F = 34 Btu


lb

HOC @ 100F = 31 Btu


lb

3.0

-20

600

20

-60

-80

4.0

0.6
-30

800

0.2

7.0

-40

-80

0.8

1000

0.14

20

-60

6.0

1400

5.0

HOR @ 120F = 110 Btu


lb

HOR @ 100F = 112 Btu


lb

0.10

40

-40

-60

8.0

0.2

10

3000
2000

100

-20

-40

14

4000
7
0.2

60

20

-20

48
46

40

30

20

120

40

54

60

140

20

180

40

160

60

220

60

40

80

52

56

58

200

60
100

1.0

34

80

240

80
140

260

200

280

100

30 0

120

140

120

320

140

300

36

180
160

160
400

38

600

42

160F

800

50

0.07

Dirty Condenser - 120F Cond. Temp


Hermetic Compressor
200
120F S.H. @ Cylinder
Inlet
180

1000

5000

0.2
0.04

2000

200

0.

20

8.0
6.0
4.0

30

3.0

an

50 Specific Volume (ft /lb)


CFM
COMP
VOL
Req
= 9.54
0
39
38
0.4 ton
0.
37
0.
0.
70

n
Co
3
0.

st

14

2.0
1.4

1.0
0.8

110

120

130

140

SCALE CHANGE

Enthalpy (Btu per lb above saturated liquid at -40F)

Fig. 7 Typical Cycle #3

150

160

170

180

190

0.6
200

FORM 5-200 / Page 9

So, this makes senseif a lower discharge air temperature is


required, what easier way is there to accomplish it? By reducing the refrigerant pressure in the evaporator, the saturation
temperature will be reduced. This allows for a higher temperature difference between the air entering the evaporator and the
heat transfer medium (the refrigerant), resulting in a higher rate
of heat transferor in simple terms a lower discharge air temperature. There is only one problem. The EPR is already wide
open. Heyhow about lowering the set point for the common
suction pressure on the racks energy management control system. Theres plenty of extra horsepower in the form of idle
compressors, so capacity isnt an issuejust bring another
compressor on.

extra capacity is not a problem. For the store owner, paying for
the additional electricity to operate the extra compressor(s)
might be a major problem.
Finally, the discharge temperature has increased to 320F. At
this elevated temperature the mineral oils lubrication qualities
will be diminished. Additionally, at 320F mineral oil will most
certainly start to decompose. Under certain circumstances, the
refrigerant (R22) may start to decompose as well. All of this
spells a short destructive life for the compressor.
Typical Cycle #4 (Fig. 8): Now for the double whammy. Not
only is the condenser filthy, but the TEVs were never adjusted. They are operating at abnormally high superheats, which in
effect have reduced the size of the evaporators. As a result, the
discharge air temperature in the glass door frozen food display
cases is too high, causing the frozen juice to melt.

With a simple adjustment, the fixture lineups discharge air


temperature can be brought in line. The pressure set point is
lowered to 20 psia (-29F). Simpleyesbut theres a doozy
of a problem with this approach.

Because it is the dead of summer, and the service call log is


overflowing, a quick solution to this problem would be great.
So, in order to compensate for the high discharge air temperatures in the fixture lineup mentioned above, the service technician decides to lower the EPR setting. It doesnt occur to him
that a -20F saturated suction temperature should be low
enough to achieve a -10F discharge air temperature.

Lowering the suction pressure will increase the compression


ratio: in this example from 11:1 to 13.6:1an approximate
20% increase over the compression ratio in Typical Cycle #3.
This further reduces the compressor volumetric efficiency, and
increases the horsepower requirement.

SCALE CHANGE

10

20

30

45
50

40

60

70

80

0.

5000
4000

102
100

90

14
0. 6
0.01

13

-10

12

-20

0.

-30

0.

110

15

0.

0.017

124
130

120

16

17
0.
0.018

0.

140

18

0.

19
0.020

150

0.

20

0.

REFRIGERANT 22

3000

165
170

160

21
22
0.
0.022
0.025

0.

180

23

0.2

190

4
0.2

0.03

TYPICAL CYCLE - 4
200

0.05

180

ns

ta n
t Te

ature (
m pe r

140

F )

Sat
ura
ted
Vap
or

Co

1.0

id

100

40

dL
iqu
Sat
ura
te

1.4

80

2.0

60

3.0

40

4.0

30

14
10.0
14

-10

0.3

10

0.4

20

0.5

30

0.6

40

0.7

50

60

0.8

70

90

110

34

33

0.

0.

100

0.3

80

0.3

-120

0.9

t
En

120

35

3
0.

on

0.

37

0.

130

140

Enthalpy (Btu per lb above saturated liquid at -40F)

Fig. 8 Typical Cycle #4

3.51 lb
min - ton

3.4 HP
ton 9
8

0
COMP
VOL Req =

SCALE CHANGE

-F

py
ro

an =
COMP HP Req
st

0.2

l
u/=
REF Circulation Rate
Bt

-100

0.3

0.1

Btu
lb
Btu
lb

NRE = 57

-120

-80

0.2

Pressure (psia)

200

0.7

20

-20

1.4

-20

300

0.5

100

-80

HOC = 41

-100
2.0

0.6
-30

400

0.4

7.0

-60

3.0

0.8

600

5.0

-40

Btu
lb

HOR = 120

-80
4.0

1.0

800

60

-60

6.0

1400

-60

8.0

1000

0.3

20

10

-40

3000
2000

0.2

0.2

80

-20

-40

14

0.14

-20

20

30

36

20

120

40

4000
7
0.2

140

20

180

40

160

60

220

60

40

80

200

60
100

80

240

80
140

260

200

100

280

100

30 0

120

320

140

120

140

300

34

160

400

54

58

48
46

40
38

600

42

800

52

56

60

0.10

160F

44

1000

50

0.07

Dirty Condenser - 120F Cond. Temp


Hermetic Compressor
130F S.H. @ Cylinder Inlet
200
180
180
Suction Pressure 160
lowered
to 20 psia (-29F)

1400

5000

0.2
0.04

2000

200

150

0.

20

3.0

50 Specific Volume (ft3/lb)


.40

2.0
1.4

70
12.42 CFM
ton

160

6.0
4.0

30

40

8.0

1.0
0.8
170

180

190

0.6
200

Page 10 / FORM 5-200

The lower the suction pressure is, the higher the refrigerants
specific volume will be, which translates into a greater compressor volume requirement. Simply reducing the suction pressure has resulted in a 30% increase in volume requirement over
Typical Cycle #3.
The final blow is a higher discharge temperature, which is now
approaching 370Fway beyond any margin of safety. Its
guaranteed that the mineral oil will vaporize off the cylinder
walls. This leaves the compressors metal to metal moving
parts vulnerable to accelerated wear, and certain failure. A look
in the crankcase will reveal a black sludge where oil used to be.
The crankshaft lubrication passages are now in danger of plugging up with the oil breakdown. Its quite possible that some of
this oil breakdown will end up in TEV ports, which will leave
them unable to control proper superheat. Unless preventative
measures are taken, this compressor is headed for the scrap
heap. In addition, the operation has become extremely inefficient, resulting in even higher energy costs.
Lets take a look at the chart comparing the system design calculations of the various cycles discussed. This can be seen in
Fig. 9. The important values to look at are:
Compression Ratio: The ratio of absolute discharge

pressure/absolute suction pressure. The compressor motor


amperage will increase as the compression ratio increases.
Also, the higher compression ratio results in reduced compressor volumetric efficiency. The net result is that it will take more
energy to run a less efficient compressor. So, additional compressors will have to operate to compensate for this.
Discharge Temperature: A good measure of the relative health

or sickness of the system. Most compressor manufacturers


highly suggest the discharge temperature be kept below 300F.
It is not realistic to put a temperature probe inside the cylinder
to monitor temperature. Experience has shown that the discharge temperature 6 from the discharge service valve will be
between 50 - 75 less than the actual discharge temperature. In
addition to cleaning condensers, discharge temperatures can be
reduced by proper expansion valve setting, compressor body
cooling fan motors, good suction line insulation, liquid injection andkeeping the suction pressure as high as possible. For
more details regarding discharge temperatures and liquid injection, refer to Sporlan Form 10-197.
Refrigerant Circulation Rate: The larger this number is, the

more compressors will be required in operation to achieve


capacity. It would be ideal to search out ways to reduce the
amount of refrigerant to be pumped. Anything that affects the
refrigerant quality at the TEV outlet will influence the RCR.
Its not how much refrigerant we are feeding to the TEV, but
how much of it remains after the expansion process, for the liquid refrigerant remaining is our only medium for transferring
heat from the refrigerated space. Higher condensing temperatures have a negative affect on this. Notice the great reduction
in the RCR where liquid subcooling is employed. Again, if the
subcooling can be accomplished inexpensively, the potential
for savings is great. It was the increase in discharge pressure
(temperature) in Typical Cycle #3 which increased the RCR.

Compressor Horsepower: We can all relate to horsepower.


The higher the horsepower requirement, the higher the electric
bill will be at the end of the month. The subcooled liquid
reduced the horsepower requirement. Because the refrigerant
quality was reduced at the outlet of the TEV (more liquid present), it was used more efficiently. Therefore less of it was
required to circulate, which caused a reduction in the horsepower required.

HOC and RCR are the two values which will determine the
horsepower requirement. We see a 20% increase in the horsepower requirement in Typical Cycle #3 (as compared to
Typical Cycle #2). This comes from the discharge pressure
being raised (from 210 psia to 274 psia, an increase in the
HOC). Such an easy thing to keep the condenser clean; yet how
huge the impact is, if not done.
In Typical Cycle #4 the suction pressure is lowered from 24
psia to 19 psia. This 5 psi reduction in suction pressure results
in a 20% increase in the system horsepower requirement as
well. The lower suction pressure yields a smaller refrigeration
effect, which results in a higher RCR. It also leads to a higher
HOC. Since lowering the suction pressure will increase the
HOC and RCR, it is important to keep the suction pressure as
high as possible.
Compressor Volume: The compressor horsepower and the

cylinder volume requirement are independent of one another.


We see that from Typical Cycle #1 where there is no suction
superheat, to Typical Cycle #2 where there is 40 of superheat,
there is an approximate 20% increase in the cylinder volume
requirement. The horsepower remains constant, however. It is
the warmer, thinner suction vapor which drives the volume
requirement up. One can see the tremendous penalty for using
a hermetic compressor. Perhaps the reduced maintenance offsets the higher power bills. While high suction superheat
increases the vapor specific volume (cu. ft./lb), it is the lower
suction pressure in Typical Cycle #4 which has the greatest
impact on increasing the specific volume.
There is a threefold negative affect from lower suction pressure:
First, it will cause an increase in compression ratio, and
the resulting decrease in volumetric efficiency. Lowering
the suction pressure by a few pounds will result in a
much greater increase to the compression ratio than by
raising the discharge pressure the same amount.
Secondly, the refrigerants specific volume increases
with a decrease in pressure. As the specific volume
increases (a decrease in density), more cylinder volume
is required to pump the same mass flow.
Thirdly, the compression process follows the constant
entropy lines. Therefore, the lower the suction pressue is,
while following a constant entropy line during compression to a given condensing pressure, the higher the resulting discharge temperature will be. This has destructive
consequences on the chemicals in the system, of which in
part the compressor relies on for a long life.

FORM 5-200 / Page 11

-20

-20

-20

20
40

-20

20

40

10

180

80

27

89

8.5

Comp
Vol Req

Btu/lb

Vapor
Spec Vol

Btu/lb

Comp
HP Reqd

Btu/lb

REF
Circulation
Rate

(F)

COP

(F)

Refrigeration
Effect

(F)

Heat of
Rejection

(F)

Heat of
Compression

Discharge
Temp

(F)

Compressor
Ratio

Condenser
Temp

(F)

While several realistic system scenarios have been plotted


and dissected, as stated earlier there are still some aspects of
each cycle that are represented in an ideal fashion. There are
pressure losses in the tubing, valves, accessories, etc. which are
not shown. The compression process occurs at a constant
entropy ONLY in the ideal cycle. In the real world, entropy
will increase during the compression process, resulting in even
higher discharge temperatures and HOC values. These factors
should not detract from the basic focus of this article: to give
one a solid foundation of the refrigeration cycle, based on what
happens to the refrigerant as it travels throughout the system,
and how the operating conditions can influence the relative
health and efficiency of the system.

Discharge
Superheat

Ideal Cycle

Suction
Superheat

Comparative Data
with Varying Conditions

Suction
Temp

REFRIGERANT 22

Evaporator
Temp

The simplest way to insure against abnormally low suction


pressure is to set the expansion valve for the proper superheat.
When the TEV is set properly, the evaporator is efficiently used
as a heat transfer device due to the boiling liquid present
through most of its tubing length. High superheat settings
reduce the amount of liquid available for heat transfer, in effect
reducing the evaporator capacity. This can be negated by lowering the suction pressure, which lowers the saturation temperature, and yields a higher temperature difference between the
entering air and the refrigerant. Evaporator capacities increase
as the TD increases, so this allows for proper product temperature. It is done at the expense of lower suction pressure, and
the negative impact it has on system health.

lb/min-ton

hp/ton

cu ft/lb

cfm/ton

62

2.30 3.23

2.05

2.07

62

2.30 3.23

2.05

2.29

1.59

2.29

2.36

2.72

6.8

Typ ical Cycle - 1


Open Drive Compressor
(40F Suction S.H.)

10

215

8.5

15

27

95

7.39

Typ ical Cycle - 1A


Open Drive Compressor
(40F Suction S.H.)
Liquid subcooled to 50F

10

215

8.5

15

27

95

80

2.96

2.50

5.73

Typical Cycle - 2
Hermetic Compressor (add 80F S.H.)
120F S.H. vapor entering cylinders

-20

10

120

10

295

8.5

195

31

12

62

2.0 3.23

8.7

-20

100

120

120

320

11.1

200

34

110

57

1.68

3.51

2.81

2.72

-30

100

130

120

365

13.9

245

41

120

57

1.39

3.51

3.39

3.54 12.42

Typical Cycle - 3
Hermetic Compressor (add 80F S.H.)
120F S.H. vapor entering cylinders
Dirty Condenser (120F Cond. Temp)

9.54

Typical Cycle - 4
Hermetic Compressor (add 80F S.H.)
120F S.H. vapor entering cylinders
Dirty Condenser - 120F Cond. Temp
Suction pressure lowered to
compensate for starving TEV's

Fig. 9 Comparison of System Design Calculations

Printed in the U. S. of A.

Copyright 2005 Parker Hannifin Corporation, Washington, Missouri

105

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