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The Pressure - Enthalpy Chart: by Dave Demma, Senior Application Engineer - Supermarket Refrigeration
The Pressure - Enthalpy Chart: by Dave Demma, Senior Application Engineer - Supermarket Refrigeration
to change 1 lb. of material from the solid phase into the liquid
phase.
Latent Heat of Vaporization - The quantity of heat (Btu/lb)
starts to boil (or vapor starts to condense). The saturation temperature (boiling temperature) is constant at a given pressure,*
and increases as the pressure increases. A liquid cannot be
raised above its saturation temperature. Whenever the refrigerant is present in two states (liquid and vapor) the refrigerant
mixture will be at the saturation temperature.
Superheat - At a given pressure, the difference between a
line saturated vapor line out into the superheated vapor-portion of the chart at a slight angle from the horizontal axis.
Refrigeration
Water at Atmospheric Pressure
(14.7 psia pressure)
Saturation
Temperature
232
Subcooled
Liquid
Temperature (F)
212
400
600
800
Enthalpy (Btu per lb)
1000
1200
In the ideal cycle, the condenser serves as a two-fold component. Before any condensation occurs, the high pressure vapor
must first be brought to a saturated condition (de-superheated).
SCALE CHANGE
-10
10
20
30
40
50
60
70
80
90
4000
100
14
0. 6
0.01
0.
0.
5000
13
-20
12
-30
0.
110
15
0.
0.017
120
16
130
17
0.
0.018
0.
140
18
0.
19
0.020
150
0.
20
0.
REFRIGERANT 22
3000
160
170
21
22
0.
0.022
0.025
0.
180
23
0.2
190
4
0.2
0.2
0.04
200
0.05
Sat
ura
ted
Vap
or
Line
Lin
e
id
Sat
ura
ted
Liq
u
100%
100
%
ua l it y
-60
a nt Q
0.6
-30
Co
10
20
0.5
30
0.6
40
0.7
50
60
0.8
70
0.9
80
90
33
0.
100
0.3
0.4
0.2
-10
0.3
0.3
-20
0.2
0.3
-120
0.1
40
4.0
30
14
1.4
0.8
3.0
14
-100
-120
60
10.0
34
2.0
80
2.0
20
0.
-100
100
1.4
7.0
-80
3.0
5.0
-20
-80
C onst
Pressure (psia)
46
0
40
Constant Volum
-60
4.0
1.0
140
1.0
-40
-80
200
0.7
80
-60
6.0
300
0.5
10
8.0
400
0.4
20
14
-40
600
0.3
40
-40
1400
800
0.2
100
-20
1000
60
20
Constant Temperature
-20
180
30
120
40
20
0.10
140
20
160
60
40
260
60
40
80
220
60
3000
2000
0.2
Constant Pressure
200
100
80
240
80
140
100
36
100
30 0
120
280
200
140
120
320
140
300
4000
7
0.2
400
s
on
34
180
160
160
n
ta
54
0.14
180
38
600
n
tE
52
58
Critical Point
200
42
800
py
tro
44
160F
1000
50
0.07
56
60
48
180
1400
5000
0.03
2000
200
0.
35
t
ns
6
.3
an
3
0.
tE
py
ro
nt
0.
/
tu
(B
lb
F
-
20
0.
39
70
6.0
4.0
30
3.0
40
38
8.0
2.0
1.4
1.0
0.8
110
120
130
140
SCALE CHANGE
150
160
170
180
190
0.6
200
The cycle continues this way until the refrigerated space temperature is satisfied, and the equipment cycles off.
10
20
30
40
50
60
70
80
0.
5000
4000
90
100
14
0. 6
0.01
13
-10
12
-20
0.
-30
0.
110
15
0.
0.017
120
16
130
17
0.
0.018
0.
140
18
0.
19
0.020
150
0.
20
160
0.
REFRIGERANT 22
3000
170
21
22
0.
0.022
0.025
0.
180
23
0.2
190
4
0.2
0.2
0.04
0.05
200
180
48
ns
tan
t Te
F)
ature (
mp er
ted
Vap
or
Co
Sat
ura
Sat
ura
ted
Liq
uid
200
0.7
140
1.0
1.4
80
2.0
60
3.0
40
4.0
30
20
14
20
10.0
-20
-100
-100
2.0
0.3
10
0.4
20
0.5
30
0.6
40
0.7
50
60
0.8
70
0.9
80
90
0.
33
0.
1
100
0.3
0
0
0.2
0.3
0.1
-10
0.3
-120
-120
34
Co
1.4
0.2
Pressure (psia)
40
34
300
0.5
7.0
-80
3.0
-20
400
0.4
5.0
-60
4.0
0.6
-30
600
100
-40
-80
-80
0.8
1400
800
14
6.0
1.0
-40
-60
-60
8.0
1000
60
Evaporation Line
3000
10
0.2
0.3
40
14
0.2
80
-20
-40
.27
2000
0.14
100
-20
20
160
30
Compression Line
20
120
40
58
4000
140
Expansion20Line
60
180
40
40
36
100
80
56
200
60
60
220
140
240
80
80
280
200
260
100
30 0
2A
120
Condensation Line
320
140
140
3
120
300
Desuperheating Line
180
160
160
400
52
54
60
0.10
200
180
38
600
42
800
44
160F
1000
50
0.07
46
IDEAL CYCLE
1400
5000
0.03
2000
200
5
.3
0.
t
ns
36
an
0.
n
tE
37
y
op
tr
0.
/
tu
(B
lb
F
-
20
0.
39
70
6.0
4.0
30
3.0
40
38
8.0
2.0
1.4
1.0
0.8
110
120
130
140
150
SCALE CHANGE
160
170
180
190
0.6
200
Once the system has been plotted, various data points can be
read and used for the system design calculations. Admittedly,
this information is not typically something the technician will
need for servicing the refrigeration equipment. However, an
understanding of how operating conditions affect system
design, efficiency, energy consumption, and particularly compressor performance, should be of great worth to the technician.
SCALE CHANGE
10
20
40 4050
30
60
70
80
0.
5000
4000
102
100
90
14
0. 6
0.01
13
-10
12
-20
0.
-30
0.
108
110
15
0.
0.017
120
16
135
140
130
17
0.
0.018
0.
18
0.
19
0.020
150
0.
20
160
0.
REFRIGERANT 22
3000
170
21
22
0.
0.022
0.025
0.
180
23
0.2
190
4
0.2
0.03
0.05
200
TYPICAL CYCLE - 1
180
1400
300
0.4
ature (
m pe r
por
t Te
0.5
200
0.7
140
F)
rate
d Va
ta n
Sat
u
ns
Liq
uid
Co
400
0.3
1.0
100
1.4
80
2.0
60
3.0
40
4.0
30
5.0
20
7.0
14
20
10.0
-60
-60
14
-20
0.6
-30
-20
0.1
0.2
-10
0.3
10
0.4
20
0.5
30
0.6
40
0.7
50
60
0.8
70
80
90
100
34
0.
33
110
0.
1
0
0.9
0.3
-120
0.8
Btu
lb
NRE = 62
-120
Co
0.3
1.4
y
op
tr
120
35
3
0.
0.
37
0.
0
COMP
VOL Req =
130
140
SCALE CHANGE
)
-F
3.23 lb
min - ton
2.05 HP
ton 9
8
an =
COMP HP Req
st
-100
0.2
2.0
Btu
lb
n
tE
0.3
HOC = 27
-100
-80
3.0
l
u/=
REF Circulation Rate
Bt
-60
4.0
Btu -80
lb
-40
HOR = 135 40 = 95
-80
1400
600
0.2
40
-40
6.0
800
60
-40
8.0
3000
1000
0.14
-20
20
10
2000
80
-20
14
0.2
0.2
0.10
Sa
tur
ate
d
44
Pressure (psia)
60
0
100
30
1.0
54
58
48
46
40
34
180
20
120
4000
140
40
20
160
60
40
220
60
40
80
52
56
200
60
100
260
80
240
80
140
280
200
30 0
120
120
100
140
320
140
300
36
180
160
160
400
38
600
42
160F
800
50
0.07
1000
5000
6
0.2
0.04
2000
200
150
0.
70
20
3.0
50 Specific Volume
0
(ft3/lb)
2.0
1.4
7.39 CFM
ton
160
6.0
4.0
30
40
0.4
8.0
1.0
0.8
170
180
190
0.6
200
The suction superheat will insure that the compressor is protected from liquid flooding. The cost of this protection comes
in the form of a larger compressor volume requirement. This is
due to the warmer, thinner suction vapor; at +20F the specific
volume of the vapor (measured in cu.ft./lb) is greater than it
was at -20F. The compressors cylinders are a measured volume...they never change. The density of the refrigerant may
change, and this will affect the pounds per minute of refrigerant that the compressor will pump, however the volume
pumped remains constant. So, because the suction vapor is less
dense, we now require more compressor cylinder volume to
pump the same mass flow.
While all the various data points and system design calculations are listed, they will appear in a comparative chart later.
Typical Cycle #1A (Fig. 5): Using an open drive compressor,
with a 20F vapor temperature at the compressor inlet, we see
the benefit of subcooling the liquid to 50F. Note the change in
refrigerant quality at the TEV outlet. Instead of 65% liquid, we
now have 80% liquid. Because the difference between liquid
temperature and evaporator temperature has been reduced,
there is less refrigerant flashing during the expansion process.
As a result, the TEV and distributor nozzle (if used) can possibly be downsized.
SCALE CHANGE
10
22
20
30
40 4050
60
70
80
0.
5000
4000
102
100
90
14
0. 6
0.01
13
-10
12
-20
0.
-30
0.
108
110
15
0.017
0.
120
16
135
140
130
17
0.
0.018
0.
18
0.
19
0.020
150
0.
20
160
0.
REFRIGERANT 22
3000
170
21
22
0.
0.022
0.025
0.
180
23
0.2
190
4
0.2
0.03
200
0.05
180
TYPICAL CYCLE - 1A
1400
0.5
( F)
rature
id
Liq
u
300
0.4
m pe
t Te
Vap
o
ta n
400
0.3
200
0.7
140
1.0
80
Sat
ura
ted
600
ns
rate
d
Co
Sat
u
1.4
80
2.0
60
3.0
40
4.0
30
14
10.0
14
0.2
0.3
10
0.4
20
0.5
30
0.6
40
0.7
50
60
0.8
70
nt
py
ro
80
90
110
34
0.
33
0.
100
0.3
0
0.9
0.3
-120
Co
120
5
.3
0.
36
0.
37
0.
0
COMP
VOL Req =
130
140
SCALE CHANGE
2.5 lb
min - ton
1.59 HP
ton 9
8
COMP HP Req
ta =
ns
-100
0.1
-10
Btu
lb
Btu
lb
NRE = 80
-120
lb
)
-F
u/=
REF Circulation Rate
Bt
E
nt
0.3
1.4
-80
0.2
Pressure (psia)
44
800
0.2
40
2.0
-20
1000
20
-20
HOC = 27
-100
1400
100
-80
3.0
Btu
lb
7.0
-60
4.0
0.6
-30
0.2
5.0
-40
HOR = 95
-80
3000
-60
6.0
0.8
60
-40
-60
8.0
2000
0.14
20
10
100
-20
-40
14
-20
20
58
0.10
40
30
20
120
40
4000
.27
140
20
160
60
40
180
40
260
60
100
80
56
200
60
220
140
240
80
80
280
200
1.0
34
120
100
30 0
120
140
320
140
300
36
180
160
160
400
38
600
42
160F
800
52
54
60
48
46
1000
50
0.07
5000
6
0.2
0.04
2000
200
150
0.
70
20
3.0
2.0
1.4
5.73 CFM
ton
160
6.0
4.0
30
40
8.0
1.0
0.8
170
180
190
0.6
200
The use of a liquid to suction heat exchanger will yield subcooled liquid, but at the expense of higher suction vapor temperatures. While this method of subcooling will insure vapor
free liquid refrigerant at the TEV inlet, it has little effect on
increasing system efficiency. The benefit realized resulting
from subcooling will be offset by the higher suction vapor temperatures, and the volume requirement penalty they impose. In
this supermarket example the liquid for the low temperature
rack is subcooled using the medium temperature rack. There is
no heat gain to the low temperature rack as a byproduct of the
subcooled liquid. The refrigerant is subcooled on a rack that is
operating between 2 to 2-1/2 horsepower per ton, and the benefit is being experienced on a rack that is operating near 5
horsepower per ton.
The comparative chart will show the benefits: reduced refrigerant circulation rate, reduced horsepower requirement, and
reduced compressor volume requirement. If the subcooling can
be accomplished very inexpensively, such as ambient subcooling with a receiver bypass, the energy savings can be enormous. For more details on this see Sporlan Form 90-134.
Typical Cycle #3 (Fig. 7): Now, lets take a look at the real
world. It is now the dead of summer the most extreme condition for the equipment. When the system design and equipment
selection was made, it was this summer weather that was used
as the worst case condition of operation. Now, your company
was so busy in the winter that the yearly preventative maintenance was not done. Or perhaps its one of those customers
SCALE CHANGE
10
20
30
40 4050
60
70
80
0.
5000
4000
102
100
90
14
0. 6
0.01
13
-10
12
-20
0.
-30
0.
110
15
0.017
0.
120
16
121
17
0.
0.018
0.
130
140
18
0.
19
0.020
150
0.
20
0.
REFRIGERANT 22
3000
152 160
170
21
22
0.
0.022
0.025
0.
180
23
0.2
190
4
0.2
0.03
TYPICAL CYCLE - 2
200
0.05
180
1400
(
rature
400
300
200
0.7
140
F)
ted
Vap
or
m pe
Sat
ura
t Te
id
tan
tur
ate
dL
iq u
ns
Sa
Co
1.0
100
1.4
80
2.0
60
3.0
40
4.0
30
5.0
20
40
7.0
14
10.0
-20
u/
-80
3.0
0.2
-10
0.3
10
0.4
20
0.5
30
0.6
40
50
60
70
80
90
33
110
0.
100
0.3
0
0.9
0.3
0.1
-120
0.3
Btu
lb
0.7
0.8
NRE = 62
120
3
0.
0.
36
0.
140
SCALE CHANGE
20
2.36 HP
8 ton .39
.3
37
150
14
3.23 lb
min - ton
py
ro
1.4
-120
t
En
st =
COMP HP Req
on
34
2.0
an
-100
Btu
lb
0.
-100
lb
-F
t
REF Circulation Rate
(B =
-60
4.0
-40
Btu-80
lb
0.2
Pressure (psia)
600
0.5
80F-60Vapor
Temperature increase from hermetic motor windings
-80
-20
1400
800
0.4
6.0
0.6
-30
1000
60
-40
-60
0.8
3000
2000
0.2
0.3
20
10
8.0
0.2
80
-20
20
14
0.2
100
-20
-40
4000
48
44
40
30
1.0
0.14
34
20
120
40
60
0
140
20
260
40
160
60
40
220
60
180
80
54
58
200
60
100
280
80
240
80
140
30 0
120
100
200
140
120
320
140
300
36
180
160
160
400
52
56
0.10
42
180
38
600
46
160F
800
50
0.07
Hermetic Compressor
40F Suction S.H. @ Comp. Inlet
295F Discharge Temp. 200
1000
5000
0.2
0.04
2000
200
70
3.0
2.0
1.4
8.77 CFM
ton
160
6.0
4.0
30
40
8.0
1.0
0.8
170
180
190
0.6
200
Note the higher HOC. Referring to the system design calculations reveals that more horsepower will be required. In addition, the quality of the saturated liquid/vapor mixture at the
TEV outlet has further deteriorated, resulting in a lower RE.
Referring again to the system design calculations will reveal
that the lower the RE is, the higher the RCR has to be. This, in
turn, will require more cylinder volume to meet the demand of
an increased RCR. In a typical supermarket there are backup
compressors that only operate under high load conditions, so
Lets take a look at the compression cycle. It begins when suction vapor enters a cylinder as its piston is traveling down. As
the piston starts to travel back up, reducing the volume of the
cylinder, the vapor pressure increases. When the piston reaches
the top of its stroke, the entire volume of compressed vapor will
have exited the cylinder through the discharge valves EXCEPT
SCALE CHANGE
10
3040 40
20
45
50
60
70
80
0.
5000
4000
102
100
90
14
0. 6
0.01
13
-10
12
-20
0.
-30
0.
110
15
0.
0.017
120
16
121
17
0.
0.018
0.
130
152
150
140
18
0.
19
0.020
0.
20
155
160
0.
REFRIGERANT 22
3000
170
21
22
0.
0.022
25
0.0
0.
180
23
0.2
190
4
0.2
0.03
200
0.05
180
TYPICAL CYCLE - 3
1400
0
Co
ns
ta n
t Te
m pe
0.5
140
1.0
100
id
dL
iqu
80
Sat
ura
te
-20
REF Circulation
Rate =
F)
(
10
0.4
20
0.5
30
0.6
40
0.7
50
60
0.8
70
0.9
80
90
100
34
0.
33
0.
1
9
-10
0.3
0.3
0.2
0.2
0.1
0.3
-120
-120
1.4
u/
Bt
lb
3.5 lb
min - ton
py
COMPtroHP
Req = 2.81 HP
n
ton 40
tE
-100
200
1.4
80
2.0
60
3.0
40
4.0
30
14
-80
-100
2.0
300
0.7
F)
Sat
ura
ted
Vap
or
Pressure (psia)
44
400
0.3
320F Discharge
0.4 Temp.
10.0
3.0
-20
600
20
-60
-80
4.0
0.6
-30
800
0.2
7.0
-40
-80
0.8
1000
0.14
20
-60
6.0
1400
5.0
0.10
40
-40
-60
8.0
0.2
10
3000
2000
100
-20
-40
14
4000
7
0.2
60
20
-20
48
46
40
30
20
120
40
54
60
140
20
180
40
160
60
220
60
40
80
52
56
58
200
60
100
1.0
34
80
240
80
140
260
200
280
100
30 0
120
140
120
320
140
300
36
180
160
160
400
38
600
42
160F
800
50
0.07
1000
5000
0.2
0.04
2000
200
0.
20
8.0
6.0
4.0
30
3.0
an
n
Co
3
0.
st
14
2.0
1.4
1.0
0.8
110
120
130
140
SCALE CHANGE
150
160
170
180
190
0.6
200
extra capacity is not a problem. For the store owner, paying for
the additional electricity to operate the extra compressor(s)
might be a major problem.
Finally, the discharge temperature has increased to 320F. At
this elevated temperature the mineral oils lubrication qualities
will be diminished. Additionally, at 320F mineral oil will most
certainly start to decompose. Under certain circumstances, the
refrigerant (R22) may start to decompose as well. All of this
spells a short destructive life for the compressor.
Typical Cycle #4 (Fig. 8): Now for the double whammy. Not
only is the condenser filthy, but the TEVs were never adjusted. They are operating at abnormally high superheats, which in
effect have reduced the size of the evaporators. As a result, the
discharge air temperature in the glass door frozen food display
cases is too high, causing the frozen juice to melt.
SCALE CHANGE
10
20
30
45
50
40
60
70
80
0.
5000
4000
102
100
90
14
0. 6
0.01
13
-10
12
-20
0.
-30
0.
110
15
0.
0.017
124
130
120
16
17
0.
0.018
0.
140
18
0.
19
0.020
150
0.
20
0.
REFRIGERANT 22
3000
165
170
160
21
22
0.
0.022
0.025
0.
180
23
0.2
190
4
0.2
0.03
TYPICAL CYCLE - 4
200
0.05
180
ns
ta n
t Te
ature (
m pe r
140
F )
Sat
ura
ted
Vap
or
Co
1.0
id
100
40
dL
iqu
Sat
ura
te
1.4
80
2.0
60
3.0
40
4.0
30
14
10.0
14
-10
0.3
10
0.4
20
0.5
30
0.6
40
0.7
50
60
0.8
70
90
110
34
33
0.
0.
100
0.3
80
0.3
-120
0.9
t
En
120
35
3
0.
on
0.
37
0.
130
140
3.51 lb
min - ton
3.4 HP
ton 9
8
0
COMP
VOL Req =
SCALE CHANGE
-F
py
ro
an =
COMP HP Req
st
0.2
l
u/=
REF Circulation Rate
Bt
-100
0.3
0.1
Btu
lb
Btu
lb
NRE = 57
-120
-80
0.2
Pressure (psia)
200
0.7
20
-20
1.4
-20
300
0.5
100
-80
HOC = 41
-100
2.0
0.6
-30
400
0.4
7.0
-60
3.0
0.8
600
5.0
-40
Btu
lb
HOR = 120
-80
4.0
1.0
800
60
-60
6.0
1400
-60
8.0
1000
0.3
20
10
-40
3000
2000
0.2
0.2
80
-20
-40
14
0.14
-20
20
30
36
20
120
40
4000
7
0.2
140
20
180
40
160
60
220
60
40
80
200
60
100
80
240
80
140
260
200
100
280
100
30 0
120
320
140
120
140
300
34
160
400
54
58
48
46
40
38
600
42
800
52
56
60
0.10
160F
44
1000
50
0.07
1400
5000
0.2
0.04
2000
200
150
0.
20
3.0
2.0
1.4
70
12.42 CFM
ton
160
6.0
4.0
30
40
8.0
1.0
0.8
170
180
190
0.6
200
The lower the suction pressure is, the higher the refrigerants
specific volume will be, which translates into a greater compressor volume requirement. Simply reducing the suction pressure has resulted in a 30% increase in volume requirement over
Typical Cycle #3.
The final blow is a higher discharge temperature, which is now
approaching 370Fway beyond any margin of safety. Its
guaranteed that the mineral oil will vaporize off the cylinder
walls. This leaves the compressors metal to metal moving
parts vulnerable to accelerated wear, and certain failure. A look
in the crankcase will reveal a black sludge where oil used to be.
The crankshaft lubrication passages are now in danger of plugging up with the oil breakdown. Its quite possible that some of
this oil breakdown will end up in TEV ports, which will leave
them unable to control proper superheat. Unless preventative
measures are taken, this compressor is headed for the scrap
heap. In addition, the operation has become extremely inefficient, resulting in even higher energy costs.
Lets take a look at the chart comparing the system design calculations of the various cycles discussed. This can be seen in
Fig. 9. The important values to look at are:
Compression Ratio: The ratio of absolute discharge
HOC and RCR are the two values which will determine the
horsepower requirement. We see a 20% increase in the horsepower requirement in Typical Cycle #3 (as compared to
Typical Cycle #2). This comes from the discharge pressure
being raised (from 210 psia to 274 psia, an increase in the
HOC). Such an easy thing to keep the condenser clean; yet how
huge the impact is, if not done.
In Typical Cycle #4 the suction pressure is lowered from 24
psia to 19 psia. This 5 psi reduction in suction pressure results
in a 20% increase in the system horsepower requirement as
well. The lower suction pressure yields a smaller refrigeration
effect, which results in a higher RCR. It also leads to a higher
HOC. Since lowering the suction pressure will increase the
HOC and RCR, it is important to keep the suction pressure as
high as possible.
Compressor Volume: The compressor horsepower and the
-20
-20
-20
20
40
-20
20
40
10
180
80
27
89
8.5
Comp
Vol Req
Btu/lb
Vapor
Spec Vol
Btu/lb
Comp
HP Reqd
Btu/lb
REF
Circulation
Rate
(F)
COP
(F)
Refrigeration
Effect
(F)
Heat of
Rejection
(F)
Heat of
Compression
Discharge
Temp
(F)
Compressor
Ratio
Condenser
Temp
(F)
Discharge
Superheat
Ideal Cycle
Suction
Superheat
Comparative Data
with Varying Conditions
Suction
Temp
REFRIGERANT 22
Evaporator
Temp
lb/min-ton
hp/ton
cu ft/lb
cfm/ton
62
2.30 3.23
2.05
2.07
62
2.30 3.23
2.05
2.29
1.59
2.29
2.36
2.72
6.8
10
215
8.5
15
27
95
7.39
10
215
8.5
15
27
95
80
2.96
2.50
5.73
Typical Cycle - 2
Hermetic Compressor (add 80F S.H.)
120F S.H. vapor entering cylinders
-20
10
120
10
295
8.5
195
31
12
62
2.0 3.23
8.7
-20
100
120
120
320
11.1
200
34
110
57
1.68
3.51
2.81
2.72
-30
100
130
120
365
13.9
245
41
120
57
1.39
3.51
3.39
3.54 12.42
Typical Cycle - 3
Hermetic Compressor (add 80F S.H.)
120F S.H. vapor entering cylinders
Dirty Condenser (120F Cond. Temp)
9.54
Typical Cycle - 4
Hermetic Compressor (add 80F S.H.)
120F S.H. vapor entering cylinders
Dirty Condenser - 120F Cond. Temp
Suction pressure lowered to
compensate for starving TEV's
Printed in the U. S. of A.
105