:

ISBN 978-974-286-378-4 . 03-093

1 .. 2551 1,000
:
:

4

(Volatile Organic Compounds : VOCs)

1













30 (.. 2550)
1

1
5
6
7

9
10
16
17
18
19
20
30 (.. 2550)
1

3
 Motor Vehicles
Consumer Solvents

Industrial/Commercial
Processes

1.

2 sub-atmospheric
pressure sampling (passive canister) active
sampling
sub-atmospheric pressure sampling

( 0.05
)


10 30 3
24

2.

5

2.1 (Roadside Area)
1.5
2.2 (Residential Area)
15
30
2.3 (Near Industrial Area)

3. (
)
3.1 (Sampling Canister) :
6 Fused Silica
( ) 1

6
 3.2 (Practice
Canister) : 3.1
3.3 (Flow Controller
Passive Sampler) :
2

2 (Flow Controller)

7
 3.4 (Mass Flow Meter) :
3

3.5 Graphite vespel ferrules 1/4 X 1/4 ID

( )
3.6 9/16 7/16
3.7
3.8
1.5

8
4.

4.1

10 ppm
99.999 % 2-3
10 ppm

4.2



4.2.1
evacuate pressurize 70 90 C 15

4.2.2 GC/MS
4.2.3 evacuate < 50 mtorr
4.2.4

9
 5.
5.1
Sub-atmospheric
sampling

F = (V-1) X 1000
t X 60

F (/)
V ()
t ()
24

F = (6-1) X 1000
24 X 60
= 3.47 /

80%


5.2 (
)
5.2.1
(50 mtorr)

10
 5.2.2
(Practice
Canister)

4

11
 5.2.3
5 2-3
2-3

2 1 2 3 4
3

5.2.4 6

5.1

5.2.5
6

12
 1

1

5.2.6
5.2.7
(Sampling Canister) 7

1
2

1 2 3
3

13
 5.2.8
3

7 Ferrule
15
5.2.9
8 1.5

5.2.10

9

14
 9 Canister Sampling Data Sheet

15
 5.2.11

5
( +1 24 )
5.2.12

6.
6.1




6.2





6.3

16
 -30 -5

6000 X (30-5)/30 = 5000

24
5000/24 /60 = 3.47 /

6.4 Travel Blank

Travel Blank 1 /batch
Travel blank Travel Blank
3
6.5 Duplicate Sample 1 1
1 10
US
EPA Compendium Method TO-14A Determination of Volatile
Organic Compounds(VOCs) in ambient air using specially prepared
canisters with subsequent analysis by Gas Chromatography(GC)
US EPA Compendium Method TO-15 Determination of Volatile
Organic Compounds(VOCs) in air collected in specially prepared
canisters and analyzed by Gas Chromatography/mass
spectrometry(GC/MS)

7.
7.1 24
(g/m 3 )
25 1
7.2

17
 Method Quantitation Limit (MQL) 2
- Method Detection Limit (MDL)
Method Detection Limit (MDL)
- MDL MQL
MQL
7.3
(QA/QC) no data
7.4
no data
7.5 -
1
24 ()
(Arithmetic Mean)
- Method Detection Limit (MDL)
Method Detection Limit (MDL)
- MQL MQL

8.

18
9.
9.1 Division of Environmental Protection. 2001. Summa
Canister Sampling. State of Nevada.
9.2 Center for Environmental Reseasch Information.
Compendium Method TO- 14A Determination of volatile organic
compounds (VOCs) in ambient air using specially prepared
canisters with subsequent analysis by gas chromatography. January
1991, Cincinnati OH.
9.3 Center for Environmental Reseasch Information.
Compendium Method TO- 15 Determination of volatile organic
compounds (VOCs) in air collected in Specially - prepared
canisters and analyzed by Gas Chromatography/Mass
Spectrometry(GC/MS). January 1991, Cincinnati OH.
9.4 Columbia Analytical Service. 2006. Summa canister
instruction. California USA.

19

o
n

on
(.. )
nrn e

() nn
on .. on
nrn (Volatile Organic Compounds) e o
n
o nrn e n
o}n
() (Benzene) on . nr
() r (Vinyl Chloride) on nr
() 1,2 - (1,2 - Dichloroethane) on . nr
() (Trichloroethylene) on nr
() (Dichloromethane) on nr
() 1,2 - (1,2 - Dichloropropane) on nr
() (Tetrachloroethylene) on nr
() r (Chloroform) on . nr
() 1,3 - (1,3 - Butadiene) on . nr
nrn e n o
rnn (no)
n (Arithmetic Mean)
n rn r o
onrn nnnro
o n r n e
no o

20
 o
n
o n r n r
n e o o n
nno ono}n
() US EPA Compendium Method TO-14A Determination of Volatile Organic
Compounds (VOCs) in ambient air using specially prepared canisters with subsequent analysis
by Gas Chromatography (GC) rron

() US EPA Compendium Method TO-15 Determination of Volatile Organic

Compounds (VOCs) in air collected in specially prepared canisters and analyzed by Gas
Chromatography/Mass Spectrometry (GC/MS) rron

() n r

..
{e~r

on

21


1.
2.

1.
2.
3.
4.
5.


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10400
0 2298-2000
0 2298-2002