BI TP CHUI CHUYN HA HU C 1 HUP 2017

Cl2 KOH/C2H5OH NaNH2 H3O+/Hg2+

1. Propen B C D

CuCl2/NH4Cl H2 ethen Benzen/HCl

2. Acetylen A B - 0 C D
Pd/BaCO3 100 120 C

Cl2 ( 1: 1 ) / FeCl3 acetylen/NaNH2 H3O+/Hg2+ HCHO/NaOH

3. Benzen A B C D

C6H5MgCl (1 : 1) Al2O3 / to NBS NaSH

4. Propanal + A B C D
H3O

CH3CH(OH)CH3 Cl2/FeCl3 to NaOH ,p , to CH2=CH-CH2Cl / to

5. Benzen A B C D
H3PO4

1. NaNH2 H2/Pd/CaCO3 1. O3 NH2-NH2 / OH-

6. Propyn A B C D
2. CH3MgCl 2. H2O

H2SO4/SO3 (1:1) Br2 (1:1) H2O/HgSO4 1. KMnO4 , to

7. Cumen A B C D
2. H3O+

Br2 KOH/ancol H2O/HgSO4 ; H+ 1. I2/NaOH

8. styren A B C D
2. HCl

Br2 KOH/ancol H2O/HgSO4 1. H2N-NHCONH2

9.vinylcyclohexan A B C D
H3O+ 2. OH-

H2/Pd/BaCO3 1. O3/H2O 1. Cl2/FeCl3 (1:1) 1. CH3COOC2H5 (1:1)

10. (2-phenylethynyl)Benzen A B C D
2. O2 kk 2. Mg/ether 2. H2O

PBr3 Li/ether CuI/ether , 0 oC C6H5Cl

11. Ethanol A B C D

Cl2 /h NaOH + B/OH- to

12. Propan A B C D

(C2H5CO)2O /AlCl3 ; to Br2 (1:1)/ Fe t

o
NaOH; p ;to CH3Cl
13. Benzen A B C D
 NH3 , p , to NaOBr C2H5MgI
14. acid butanoic A B C+D

NH4Cl/KCN H2O/H+ HNO2 to

15. acetandehid A B C D

SeO2 NH2OH [H]

16. acid butanoic A B C

CH3CH(NH2)COOH H2/Ni SOCl2

17. CH3CH2CHO A B C

HNO2 CuO/to NH3/HCN H3O+

18. Buthylamin A B C D

HClO KCN HBr NH3 H3O+

19. Prop-1-en A B C D E

NaNH2 (1:1) C2H5I 1.KMnO4

20. Propyn A B C+ D
2. H3O+

HBr/peroxyd Mg/ ether khan + C + H2O PCl5

21. 2-methylprop-1-en A B C D
0-5 oC

Benzen/H+ H2SO4/SO3 (1:1) to 1. NaOH; 200 oC Cl2/Fe (1:1) to

22. Propen A B C D
2. H3O+

HBr/peroxyd Mg/ ether khan 1. CH3CHO CH3COCl

23. Propen A B C D
0-5 oC 2. H2O/H+

HNO3/H2SO4 (1:3) Br2 (1:1) ,h Mg/ ether khan 1. CH3CN

24. Toluen A B C D
0-5 oC 2. H2O/H+

KMnO4/H+ 1. LiAlH4 + A / H+ C2H5NH2

25. Cumen A B C D
2. H3O+
 1. Propen/H3PO4 1. KOH CO2 ( 4atm , 250-300 oC ) CH3I
26. Benzen A B C D
2. O2 ; NaHCO3 (pH 8-10) 2. HCl

Than ho?t Br2 (1:1) Mg/ ether khan TiBr2

27. Acetylen A B C D
600 oC Fe/to

200 oC 1. NaOH 1. KMnO4/H+/to (CH3CO)2O

28. C6H5OCH2-CH=CH2 A B C D+E
2. (CH3)2SO4 2. HI,to

CH3OH 1. aceton NaNH2 (1:1) C2H5Br

29. Acetyl clorid A B C D
2. OH-

NO 2 NO 2 NH2

X Y
30.

Cl O O O C2H5 O O C2H5

N N
C2H5 C2H 5

HBr/peroxyd HCN 1. CH3MgBr CH(OCH3)3/H+

31. Propen A B C D
2. H2O

Cl2 Al2O3/ 500 oC (CH2=CH)2CuLi anhydridmaleic

32. ethen A B C D
Et2O/ 0 oC 100-120 oC

Cl2 (1:1)/ to 1. Li/Et2O 3-bromocyclohex-1-en O3/H+

33. Propan A B C D
2. CuI

H2O (1:1)/H+ PCl5 C2H5OH Na/ethanol

34. Butannitril A B C D

1. 1400 oC C2H5I H2/to 1. KMnO4 (l) / to th??ng

35. Methan A B C D
2. NaNH2/NH3 Pd/CaCO3 2. C2H5CHO / H2SO4
 PBr3
Mg/ether khan
1. CO2 1. NH3/to
36. Ethanol A B C D
2. H3O+ 2. P2O5/to

CHO

Cl2 (1:1)/h 1. NaOH +C 1. O3

37. Propen A B D
2. Cu(OH)2/OH- ; to 2. Zn/CH3COOH

NaOH C6H5I 1. NaBH4 H2SO4 ? /to

38. Cyclohexanon A B C D
2. H2O

1. NaOH C2H5I C6H5NH2 Na/C2H5OH

39. Phenol A B C D
2. CO2

H2O/Hg2+; H+ 1. NaBH4 H2SO4 ? HOBr

40. But-1-yn A B C D
2. H3O+ to > 170 oC

HBr/to HC Na H2O/Hg2+/H+ 1. I2/NaOH

41. Cyclopropan A B C D
H3O+ 2. H3O+

H3C CH3

1. H2SO4/SO3 NaOH (r)/to CO2 , 140 oC , 4-7atm 1. H3O+

42. A B C D
2. NaOH 2. CH3COCl

PBr3 O O2/Cu ; to
Mg/ether khan
43. Ethanol A B C D
H3O+

COOH 1. LiAlH4 SOCl2 NaCN 1. CH3MgCl

44. A B C D
H2C 2. H3O+ 2. H3O+

1. CH3MgBr CH3COOH/H+/to 1. LiAlH4

to
45. Canciacetat A B C D
2. H3O+ 2. H3O+

1. KMnO4 ; to
than ho?t , 500 oC C2H5OH/H3PO4 2. HCl 1. H2/Pd , BaSO4
46. Acetylen A B C D
3. PCl5 2. KCN ; C2H5OH un si
 HBr KOH/H2O/to K2Cr2O7 C6H5NHNH2
47. But-1-en A B C D
H2SO4/to

HNO2; 0-5 oC H3PO2 O2/V2O5/ 400 oC CH2=CH-CH=CH2

48. anilin A B C D
(NaNO2/HBr) alcol/to ( -H2O) 120 oC

1. Cl2 1. NaNH2;NH3 (l?ng) H2,to 1. KMnO4 loang

49. But-1-en A B C D
2. KOH/ancol to 2. C6H5I Pd/CaCO3 2. CH3COCl (1:2)

KCN 1. H2O (1:1)/H+ CHCl3 1. [4H]

50.2-bromopropan A B C D
2. Na/C2H5OH 3KOH 2. [O]/H2O2

1. NaNO2/H2SO4 ; 0-5 oC
KOH/ancol KNH2 2. 50-80 oC 1. NH3, H2, Ni
51.1,2-dicloropropan A B C D
3. CHCl3/NaOH,H2O, 70 oC 2. CH3COCl (1:2)

KCN H2O (1:2) C2H5OH/H+/to 1. CH3MgBr (1:1)

52.Bromomethan A B C D
2. H3O+

HBr NaOH KMnO4 HCN

53. Propen A B C D
H2SO4 [OH-]

KNH2/NH3 (1:1) CH3Br H2/to HBr

54.Acetylen A B C D
Pd/CaCO3 peroxyd

1. KMnO4 , OH- SOCl2 NH3 CH3Br (1:1)

55. Toluen A B C D
2. H3O+

MgBr

1. CO2 PCl5 NH3 P2O5 , to

56. A B C D
2. H3O+ - H2O
 Cl2 (1:1) 1. Cl2 H2O
KOH/ancol
57.ethylbenzen A B C D
t o 2. KOH/ancol Hg2+/to

1. CO2 1. C2H5OH 1. LiAlH4

Mg/ether khan
58.Bromobenzen A B C D
2. H3O+ 2. H3O+ 2. H2O

HBr/peroxyd Mg/ether khan CH3COCl (1:1) 1. H2/Ni/to

59. Styren A B C D
2. CH3COCl

Br2 KOH/ancol H2O CH3NH2

60. But-1-en A B C D
Hg2+/H+

HBr NaCN 1. CH3MgCl C2H5OH (1:2)

61. Propen A B C D
peroxyd 2. H2O/H+ H+

Br2 (1:1) KOH/ancol 1. O3 Br2/CH3COOH

62. isobutan A B C D
to 2. H2O

than hoat C2H5Cl 1. NBS KOH/ancol

63. Acetylen A B C D
600 oC AlCl3/to 2. Peroxyd

K2Cr2O7 1. NaBH4 Na C6H5CH2Cl

64. Butan-2-ol A B C D
H+ 2. H2O

CH3COCl C2H5NH2 H2/Ni CH3COCl

65. Benzen A B C D
AlCl3

HNO3 (1:2) NH4HS NaNO2/HCl Phenol

66. Benzen A B C D
H2SO4 0-5 oC NaOH

NH3/to NaOCl CH3Cl (1 1) NaNO2/HCl

67. acid butanoic A B C D

1500 oC CuCl, NH4Cl H2/Pd/BaCO3 CH2=CH-CHO

68. Methan A B C D
lm l?nh nhanh 120 oC
 H2O Cl2 (1:1) +C + H2/Pd/PbCO3
69. Nhmcacbua A B D But-2-en
askt

H2O HgSO4/H2SO4 + B / NaOH to

70.Cancicacbua A B C D

H2/Ni/to H2SO4 ??c +C Br2/CCl4

71. acetandehid A B Cyclohexen D
170 oC

dpnc Cl2 (1:1) NaOH/C2H5OH H2O/H2SO4

72. Natriacetat A B C D
askt

COOH

Al2O3 , MgO H2/Pd/PbCO3 +B SOCl2

73. ancol ethylic A B D
to 100 - 120 oC

NaOH, CaO 1500 oC NaNH2/NH3 Cloromethylcyclohexan

74. Natriacetat A B C D
to LLN

+Br2 Zn/to isopren (s- cis) O3/Zn/H2O

75. etylen A B C D

O3/Zn/H2O AgNO3/NH3 HCl P2O5/to

76. Buta-1,3-dien A B C D

KMnO4 -H2O (xt) 1. AgNO3/NH3 NaOH, CaO

77. Etylen A B C D
H2O 2. NaOH to

C6H5COOOH 1. CH3MgBr H2SO4 ??c Cl2 /450 oC

78. Etylen A B C D
2. H3O+ 170 oC

HBr (1:2) NaOH I2/KOH C2H5Cl

79. Prop-1-yn A B C D
to

HBr (1:2) NaOH Zn(Hg)/HCl

80. Acetylen A B C D
to
 O2/ men gi?m Ca(OH)2 to H2/Ni / to
81. C2H5OH A B C D
25-30 oC

than hoat Br2/Fe/to Mg/ether khan 1. CO2

82. acetylen A B C D
600 oC 2. H3O+

COOH
COOH Br2 NaOH/to HCl
+ acid maleic
83. A B C D
to

Cl2/ 450 oC NaOH CuO/to Cu(OH)2/NaOH

84. Propen A B C D
to

HCN H2O (1:2) +B

85. Aceton A B C
H2SO4/to
H2 / Ni/ to

CH3

O2/Mn 2+ SOCl2 H2 +D
86. Buthan A B C O O
Pd/BaSO4

OCH3

I2/NaOH NaOH/CaO Al2O3/to +D

87. Butan-2-ol A B C
to

3S O2 ; V2O5 +C H2O
88. cyclohexan A B O D
to

Br2/to HOCl CuO/to NaOH

89. But-1-en A B C D

K2Cr2O7/H+ 1. NaBH4 Na C6H5CH2Cl

90. Butan-2-ol A B C D
2. H2O
 C2H5Cl NBS (1:1) NaOH/C2H5OH C6H5CH2Cl
91. A B C D
AlCl3/to to

CH3
H3C CH3

1-bromo-4-cloromethylbenzen (1:1) NaNH2 CH3Cl (1:1) CH3COCl

92. A B C D
AlCl3/to AlCl3

+A KMnO4/H2SO4 SOCl2 AlCl3

93. Benzen B C D
AlCl3 to
H3C

anhidrid acetic NaOH NaOH,CaO/to 1400 oC

94. Naphatalen A B C D
AlCl3/C6H5NO2/ 25 oC LLN

NaOH r?n CH2=CH-CH2Cl 200 oC 1. O3

95. acid benzensulfonic A B C D
nung ch?y 2. Zn/H2O

OH

SOCl2 (1:2) NaSH (1:1) NaOH

95. A B C
Pyridin

HO

CH3COCl NH2-NH2 Cl2 KOH

96. Benzen A B C D
AlCl3 OH- h EtOH/to

Cl2 h NaOH HClO CH3COONa

97. ethylbenzen A B C D
EtOH

Br2 (1:1) Mg/ ether khan 1. etheroxyd Na2Cr2O7

98. Toluen A B C D
h 2. H3O+ H2SO4

H2SO4/SO3 (1:1) Br2 (1:1) H2O/H2SO4 1. KMnO4 ; to

99. Cumen A B C D
Fe/to to 2. HCl

than hoat ClSO3H (1:2) NH3 Cl2/ NaOH (1:1)

100. Acetylen A B C D
600 oC