S GIO DC-O TO THI CHN HC SINH GII KHU VC M RNG NM HC

HNG YN 2014- 2015

TRNG THPT CHUYN
MN THI: HA HC LP 11.
NGH (Thi gian lm bi 180 pht khng k thi gian giao )
thi gm 03 trang

Cu 1 (2 im): Tc phn ng.

Cho phn ng: 2N2O5(k) 4NO2(k) + O2(k)
Gi tr tc u ca N2O5 ti 250C c cho trong bng di y:
[N2O5], M 0,150 0,350 0,650
-1 -1 -4 -4
Tc , mol.l .pht 3,42.10 7,98.10 1,48.10-3
1. Hy vit biu thc ca nh lut tc phn ng cho phn ng trn v tnh hng s tc phn ng.
Ch dn cch tnh c th.
2. Tnh thi gian cn nng N2O5 gim t 0,150M xung cn 0,050M.
3. Tc u ca phn ng khi nng N 2O5 bng 0,150M l 2,37.10-3 mol.l-1.pht-1 ti 400C. Xc nh
nng lng hot ho ca phn ng.
4. Cho bit c ch ca phn ng phn hu N2O5 theo s sau:
k1
N2O5 NO2 + NO3
k1 '
NO2 + NO3 N2O5
k2
NO2 + NO3 NO2 + NO + O2
k3
NO + N2O5 3NO2
d[N 2O5 ]
p dng nguyn l nng n nh i vi NO3 v NO, hy thit lp biu thc ca tc .
dt
Cu 2. (2 im): Dung dch in li.
Sc t t H2S vo dung dch cha Ag+ 0,10M; Zn2+ 0,10 M v Ni2+ 0,10 M cho n bo ha H2S, thu
c dung dch A.
Bit: pKs ca Ag2S: 49,2; ZnS: 21,6; NiS: 18,5
pKa ca H2S: 7,02 v 12,9; nng phn t H2S bo ha lc cn bng l 0,1 M.
1. Tnh pH v nng S2- ca dung dch H2S bo ha trong nc.
2. Hi ion no kt ta trc v ion no kt ta sau cng. Gii thch c th.
Cu 3. (2 im): in ha hc.
1. Dung dch X gm Na2S 0,010M, KI 0,060M, Na2SO4 0,050M. Axit ho chm dung dch X n pH =
0. Thm FeCl3 cho n nng 0,10M.
- Tnh th ca cc platin nhng trong dung dch thu c so vi in cc Ag nhng trong dung
dch KI 0,01M c cha AgI
- Biu din s pin, vit phng trnh phn ng xy ra ti cc in cc v phn ng tng qut
khi pin hot ng.
Cho: pKa ca axit: H2S pK1 = 7,00 , pK2 = 12,90 ; HSO4- pK=2,00
Tch s tan: PbS = 10-26 ; PbSO4 = 10-7,8 ; PbI2 = 10-7,6.
o
Eo Fe3+/Fe2+ = 0,77 V ; Eo S/H2S = 0,14V ; Eo I2/2I- = 0,54V ; E AgI / Ag = -0,145V
2. m km cho mt chi tit kim loi bng phng php in phn c th dng dung dch ZnSO 4. Hy
tnh thi gian c lp m c chiu dy h = 100 m , nu mt dng i = 2A/dm 2. Gi thit hiu sut
in phn l 100%, khi lng ring ca km d = 7140 kg/m 3. (Cho khi lng nguyn t km MZn =
65g/mol; F = 96500 C/mol).
Cu 4. (2 im): Bi tp tnh ton v c tng hp.

1
C mt hn hp gm MgCl2, FeCl3, CuCl2. Ho tan hn hp ny vo nc c dung dch A. Cho dng
kh H2S sc t t vo A cho n d th thu c mt lng kt ta (sau khi ra sch kt ta v sy kh)
nh hn 2,51 ln lng kt ta thu c khi cho A tc dng vi mt lng d dung dch Na2S.
Bng cch tng t, nhng nu thay FeCl3 bng cng khi lng ca FeCl2 ( dung dch B) th lng kt
ta thu c s ch bng 1/3,36 lng kt ta khi cho dung dch Na2S vo dung dch B.
Vit cc phng trnh phn ng v xc nh thnh phn (% khi lng) ca mi cht trong hn hp ban
u.
Cu 5. (2 im): S bin ha, C ch phn ng, ng phn lp th, Danh php.
1. Thc hin dy chuyn ho sau:
OH
1 . NaOH
2 . CH3COCl
A + B
AlCl3
(A c lin kt hiro ni phn t).
Cl
BF3 OH , HC C C(CH3)2
H2 200 0C
B C D E F
DMF Pd Lindla
OH

2. Vit cc giai on xy ra trong qu trnh chuyn v pinacol ca nhng glicol di y trong mi trng
axit:
a. Me2C(OH)C(OH)Me2 b. Ph2C(OH)C(OH)Me2
Cu 6. (2 im): Tng hp cc cht hu c, so snh nhit si, Nhit nng chy, Tnh Axit-
Baz.
1. Cht K co cng thc:

T cht A la 1,2,3-trimetylbenzen ngi ta tng hp ra cht K theo s :

ThO
2 1.(CH2.3 )H2
CHMgCl

NBS
CN
du
+ 0
A 1:2
B C
H 3O ,t
D E
2O
F

CH 3Cl

CH 2 N 2

H , Pd
0
F AlCl3 G H2 SO4 ,t
H as
I 40 C
2
0 K

a) Hay cho bit cu tao cua cac cht t B n I. Trong phn ng I H402 0, PdC K c th to ra sn phm
no khc khng ?
b) So sanh nhit si cua cac cht: D, E va G. Giai thich ngn gon?
Hp cht F co 2 ng phn cu hinh, hay cho bit nhit si cua chung ging nhau hay khac nhau? Tai
sao?
2. T metyl xiclopropyl xeton v hp cht c magie tu chn, vit s phn ng iu ch 2,6-
imetyl-9-bromnona-2,6-ien.
Cu 7. (2 im): Nhn bit, Tch cht, Xc nh cng thc cu to hp cht hu c.
1. Cht A c CTPT l C8H16O, cho phn ng Ioofom nhng khng cng c H2. Khi un A vi H2SO4
c 170oC ta thu c cht B v C (c hai u c CTPT l C8H14). Nu xi ha B ri cacboxyl sn
phm s thu c metylxiclopentan. Cht B khng c ng phn hnh hc. Xc nh CTCT ca A,B,C v
gii thch s to ra cht C.
2. Metylisopropylxeton phn ng vi ietyl cacbonat trong mi trng kim-ru, to thnh hp cht A.
Cho axeton tc dng vi fomanehit v ietylamin, thu c cht B. Metyl ho B bng metyl ioua, sau
tin hnh tch loi Hopman, thu c C. Khi C phn ng vi A trong mi trng kim- ru th c
D. Cho D phn ng vi NaOH, sau vi axit HCl v cui cng un nng th c E. Hy xc nh cng
thc cu to ca cc hp cht t A n E v hon thnh cc phng trnh phn ng.

2
Cu 8. (2 im): Hu c tng hp.
Chia 44,8 gam hn hp X gm axit axetic, glixerol v etyl axetat lm ba phn (t l s mol ca cc cht
trong mi phn l nh nhau).
- Phn 1: tc dng ht vi Na thu c 1,344 lt (ktc) kh H2.
- Phn 2: tc dng va vi 500 ml dung dch NaOH 0,4M khi un nng.
- Phn 3: (c khi lng bng khi lng phn 2) tc dng vi NaHCO 3 d th c 2,688 lt (ktc) kh
bay ra.
Tnh khi lng mi cht c trong hn hp X, bit rng hiu sut cc phn ng u l 100%
Cu 9. (2 im): Cn bng ha hc.
Cho cc phn ng vi hng s cn bng ti 820oC nh sau :
CaCO3(r) D CaO(r) + CO2(k) (1) Kp1 = 0,2
C(r) + CO2(k) D 2CO(k) (2) Kp2 = 2
1. Trong mt bnh chn khng dung tch 22,4 lt 820 0C, ngi ta cho 1,0 mol CaCO 3 v 1,0 mol
cacbon. Xc nh thnh phn ca h trng thi cn bng.
2. Phi tng th tch bnh ln bao nhiu th CaCO3 phn hy hon ton.
Bi 10. (2 im): Phc cht.
Coban (Z=27) to ra c cc phc [CoCl2(NH3)4+] A ; [Co(CN)6]3- B ; [CoCl3(CN)3]3- C.
1. Vit tn ca A,B,C.
2. Theo thuyt lin kt ha tr, cc nguyn t trong B trng thi lai ha no?
3. Cc ion phc trn c th c bao nhiu ng phn lp th? V cu trc ca chng.
4. Vit phng trnh phn ng ca A vi ion Fe2+ trong mi trng axit.
----------------HT-------------

3
 S GIO DC-O TO HNG DN CHM CHN HC SINH GII KHU VC M RNG
HNG YN NM HC 2014- 2015
TRNG THPT CHUYN
MN THI: HA HC LP 11.

Cu 1 (2 im): Tc phn ng.

Cho phn ng: 2N2O5(k) 4NO2(k) + O2(k)
Gi tr tc u ca N2O5 ti 250C c cho trong bng di y:
[N2O5], M 0,150 0,350 0,650
-1 -1 -4 -4
Tc , mol.l .pht 3,42.10 7,98.10 1,48.10-3
1. Hy vit biu thc ca nh lut tc phn ng cho phn ng trn v tnh hng s tc phn ng.
Ch dn cch tnh c th.
2. Tnh thi gian cn nng N2O5 gim t 0,150M xung cn 0,050M.
3. Tc u ca phn ng khi nng N 2O5 bng 0,150M l 2,37.10-3 mol.l-1.pht-1 ti 400C. Xc nh
nng lng hot ho ca phn ng.
4. Cho bit c ch ca phn ng phn hu N2O5 theo s sau:
k1
N2O5 NO2 + NO3
k1 '
NO2 + NO3 N2O5
k2
NO2 + NO3 NO2 + NO + O2
k3
NO + N2O5 3NO2
d[N 2 O5 ]
p dng nguyn l nng n nh i vi NO3 v NO, hy thit lp biu thc ca tc .
dt
Ni dung im
1 Biu thc ca nh lut tc phn ng cho phn ng trn v tnh hng s tc phn 0,5
ng.
v = k.[N2O5]x
Da vo s liu cho suy ra x = 1 hay v = k.[N2O5]
Tnh k ca cc th nghim suy ra k trung bnh k = 2,28.10-3 (pht-1)
2 Thi gian cn nng N2O5 gim t 0,150M xung cn 0,050M. 0,5
0
[N O ] 0,150
p dng biu thc ca ng hc bc nht: kt = ln 2 5 = ln = 2, 28.103.t
[N 2O5 ] 0, 050
T = 481 pht
3 Tc u ca phn ng khi nng N2O5 bng 0,150M l 2,37.10-3, mol.l-1.pht-1 ti 0,5
400C. Nng lng hot ho ca phn ng.
Ti 400C c k2 = 2,37.10-3 : 0,150 = 1,58.10-2 (pht-1)
p dng phng trnh Arrhenus:
k E 1 1 1,58.102 E 1 1
ln 2 = a - . Thay cc s liu: ln 3
= a -
k1 R T1 T2 2, 28.10 8,314 298 313
Ea = 1,00.105 (J/mol)
4 d[N 2 O5 ] 0,5
Thit lp biu thc ca tc phn ng .
dt
k1
N2O5 NO2 + NO3
k1 '
NO2 + NO3 N2O5
k2
NO2 + NO3 NO2 + NO + O2
k3
NO + N2O5 3NO2

4
 p dng nguyn l nng n nh i vi NO3 v NO:
d[NO3 ] '
= k1.[N2O5] - k1 .[NO2].[NO3] k2.[NO2].[NO3] = 0 (1)
dt
d[NO]
= k2.[NO2].[NO3] k3.[NO].[N2O5] = 0 (2)
dt
d[N 2 O5 ] '
= - (k1.[N2O5] + k3.[NO].[N2O5] ) + k1 .[NO2].[NO3]
dt
'
T (1) v (2) suy ra: k1.[N2O5] = ( k1 + k2).[NO2].[NO3]
k3.[NO].[N2O5] = k2.[NO2].[NO3]
k2 k
= 3 [NO]
k1 + k2 k1
'

k1k2 k3
[NO] = [NO2].[NO3] = .[NO].[N2O5]
k3 ( k1' + k2 ) k2
d[N 2 O5 ] '
k3
= - k1.[N2O5] - k3.[NO].[N2O5] + k1 . .[NO].[N2O5]
dt k2
k2 k1'
= k1.[N2O5].( -1 - + )
k1' + k2 k1' + k2

Cu 2. (2 im): Dung dch in li.

Sc t t H2S vo dung dch cha Ag+ 0,10M; Zn2+ 0,10 M v Ni2+ 0,10 M cho n bo ha H2S, thu
c dung dch A.
Bit: pKs ca Ag2S: 49,2; ZnS: 21,6; NiS: 18,5
pKa ca H2S: 7,02 v 12,9; nng phn t H2S bo ha lc cn bng l 0,1 M.
1. Tnh pH v nng S2- ca dung dch H2S bo ha trong nc.
2. Hi ion no kt ta trc v ion no kt ta sau cng. Gii thch c th.
Ni dung im
1 Tnh cn bng trong dung dch H2S theo s phn ly 2 nc, pH ch ph thuc nc th nht. 0,5
H2S D H+ + HS- K1
HS- D H+ + S2- K2
2- -12,92
Tnh c pH = 4,01 v [S ] = 10 M
2 bit ta tnh nng cn thit ca [S2-] xut hin mi kt ta: 0,5
+ 2- + 2 -47,2
- xut hin kt ta Ag2S t dung dch Ag 0,10M: [S ] = KS(Ag2S)/[Ag ] = 10 M
- xut hin kt ta ZnS t dung dch Zn2+ 0,10M: [S2-] = KS(ZnS)/[Zn2+]= 10-20,6 M
- xut hin kt ta NiS t dung dch Zn2+ 0,10M: [S2-] = KS(NiS)/[Ni2+]= 10-17,5 M
Th t kt ta c th xut hin l: Ag2S, ZnS, NiS.
Khi Ag2S xut hin trc, ta c: 0,5
2Ag + H2S D Ag2S + 2H
+ +
K = 10 29,28

V cn bng c K ln Xem nh xy ra hon ton pH = 1

0,5
2- -18,92 -20,6
V [H2S] = 0,1 M ta c [S ] = 10 M > 10 M.
Vy sau khi Ag kt ta hon ton th Zn2+ vn b kt ta, cn Ni2+ th khng b kt ta
+

Cu 3. (2 im): in ha hc.
1. Dung dch X gm Na2S 0,010M, KI 0,060M, Na2SO4 0,050M. Axit ho chm dung dch X n pH =
0. Thm FeCl3 cho n nng 0,10M.
- Tnh th ca cc platin nhng trong dung dch thu c so vi in cc Ag nhng trong dung
dch KI 0,01M c cha AgI

5
 - Biu din s pin, vit phng trnh phn ng xy ra ti cc in cc v phn ng tng qut
khi pin hot ng.
Cho: pKa ca axit: H2S pK1 = 7,00 , pK2 = 12,90 ; HSO4- pK=2,00
Tch s tan: PbS = 10-26 ; PbSO4 = 10-7,8 ; PbI2 = 10-7,6.
o
Eo Fe3+/Fe2+ = 0,77 V ; Eo S/H2S = 0,14V ; Eo I2/2I- = 0,54V ; E AgI / Ag = -0,145V
2. m km cho mt chi tit kim loi bng phng php in phn c th dng dung dch ZnSO 4. Hy
tnh thi gian c lp m c chiu dy h = 100 m , nu mt dng i = 2A/dm 2. Gi thit hiu sut
in phn l 100%, khi lng ring ca km d = 7140 kg/m 3. (Cho khi lng nguyn t km MZn =
65g/mol; F = 96500 C/mol).
Ni dung im
1 Axit ho dung dch X: 0,5
S2- + 2H+ H2S (C H2S = 0,010 < S H2S nn H2S cha bo ho, khng thot ra khi
dung dich)
Phn ng:
2 Fe3+ + H2S 2 Fe2+ + S + 2 H+ K=1021
0,1 0,01
0,08 0,02 0,02
2 Fe + 2I 2 Fe
3+ - 2+
+ I2 K=107,8
0,08 0,06 0,02
0,02 0,08 0,030
Thnh phn trong dung dch: Fe 0,020 ; Fe2+ 0,080 ;I2 0,030M ;H+ 0,02M
3+

E Fe3+/Fe2+ = 0,77 + 0,059 lg 0,02/0,08 = 0,743V (cc dng)

0, 0592 1 0, 0592 1 0,25

E AgI / Ag = E AgI
o
/ Ag + lg = 0,145 + lg = 0, 0266 V (cc m)
1 [I ] 1 0, 01
Epin = E+ E = 0,743 (-0,0266) = 0,7696 V

S pin: 0.25
(-) Ag , AgII 0,01M Fe , Fe
- 3+ 2+
Pt (+)

Phn ng: Ag + I -
AgI + 1 e
Fe + 1 e
3+
Fe2+
Ag + Fe3+ + I- AgI +Fe2+

2 . 1m = 103mm =106 m 0,5

M
m Zn = Zn It (1)
2F
Mt khc mZn = V.d = S.h.d (2)
h: Chiu dy lp m
S: Din tch b mt in cc ( b mt kim loi cn m)
D: Khi lng ring ca Zn.
T (1) v (2) suy ra
2 FShd I S 1
t= v mt dng = i ( i: mt dng) =
M Zn .I S I i
2 Fhd
Nn: t = (*)
M Zn .i
Thay cc gi tr : h = 100 m = 10-4m 0,5

6
 d = 7140 Kg/m3 = 7140. 103 g/m3
F = 96500 C/mol
i = 2A/ dm2 = 200 A/m2
MZn = 65 g/mol
vo biu thc (*) ta c :
2.96500.10 4.7140.10 3
t= = 10600,15 (s) = 2,944 (gi)
65.200
Cu 4. (2 im): Bi tp tnh ton v c tng hp.
C mt hn hp gm MgCl2, FeCl3, CuCl2. Ho tan hn hp ny vo nc c dung dch A. Cho dng
kh H2S sc t t vo A cho n d th thu c mt lng kt ta (sau khi ra sch kt ta v sy kh)
nh hn 2,51 ln lng kt ta thu c khi cho A tc dng vi mt lng d dung dch Na2S.
Bng cch tng t, nhng nu thay FeCl3 bng cng khi lng ca FeCl2 ( dung dch B) th lng kt
ta thu c s ch bng 1/3,36 lng kt ta khi cho dung dch Na2S vo dung dch B. Vit cc phng
trnh phn ng v xc nh thnh phn (% khi lng) ca mi cht trong hn hp ban u.
Ni dung im
. Cc phng trnh phn ng: 1,0
Trng hp dung dch A:
- Tc dng vi H2S:
CuCl2 +H2S CuS + 2HCl
2FeCl3 + H2S 2FeCl2 + 2HCl + S
- Tc dng vi Na2S:
CuCl2 +Na2S CuS + 2NaCl
MgCl2 + Na2S +2H2O Mg(OH)2+H2S + 2NaCl
2FeCl3 + 3Na2S 2FeS + S + 6NaCl
Trng hp dung dch B
- Tc dng vi H2S: CuCl2 +H2S CuS + 2HCl
- Tc dng vi Na2S:
CuCl2 +Na2S CuS + 2NaCl
MgCl2 + Na2S +2H2O Mg(OH)2 +H2S + 2NaCl
FeCl2 + 3Na2S 2FeS + 2NaCl
Xc nh thnh phn: 1,0
Gi ln lt x,y,z l s mol ca CuCl2, MgCl2, FeCl3. i vi trng hp dung dch A,
theo cc phng trnh phn ng ta c:
96x + 88z + 32z/2 + 58y =2,51 (96x + 32z/2) (1)
Khi thay khi lng ca FeCl3 bng mt khi lng tng ng FeCl2, s mol FeCl2 l
162,5z
.
127
i vi trng hp dung dch B ta c phng trnh:
162,5z
96x + 58y + 88 = 3,36.96z (2)
127
T (1) v (2) tnh c y= 0,664x v z= 1,67x
Cui cng tnh ra MgCl2: 13,45%; FeCl3: 57,80%; CuCl2 : 28,75%.

Cu 5. (2 im): S bin ha, C ch phn ng, ng phn lp th, Danh php.

1. Thc hin dy chuyn ho sau:
OH
1 . NaOH
2 . CH3COCl
A + B
AlCl3
(A c lin kt hiro ni phn t).
7
 Cl
BF3 OH , HC C C(CH3)2
H2 200 0C
B C D E F
DMF Pd Lindla
OH

2. Vit cc giai on xy ra trong qu trnh chuyn v pinacol ca nhng glicol di y trong mi trng
axit:
a. Me2C(OH)C(OH)Me2 b. Ph2C(OH)C(OH)Me2
Ni dung im
1
1
OH H- - - O OH
O C
CH3
+

A COCH3 B

OH O-

HO COCH3
NaOH

OH +O H
- BF
3
COCH3 COCH3

(C)

CH3 CH3
O- O O C CH=CH2 OH
Cl
Me2C C CH 200 0 C

COCH3 COCH3 COCH3 COCH3

D E F

2 a) 0,5
CH3 CH3 CH3 CH3 CH3 CH3
+
H - H 2O
H3C C C CH3 H3C C C CH3 H3C C C CH3
+
OH OH OH +OH 2 OH

CH3 CH3
+ +
-H
H3C C C CH3 H3C C C CH3
: OH CH
3 O CH3

b.
Ph CH3 Ph CH3 Ph CH3
+
H - H 2O
Ph C C CH3 Ph C C CH3 Ph C C CH3
+
+
OH OH OH 2 OH OH 0.5

Ph Ph
+ +
-H
Ph C C CH3 Ph C C CH3

CH3 :OH CH3 O

8
Cu 6. (2 im): Tng hp cc cht hu c, so snh nhit si, Nhit nng chy, Tnh Axit-
Baz.
1. Cht K co cng thc:

T cht A la 1,2,3-trimetylbenzen ngi ta tng hp ra cht K theo s :

1.(CH2.3 )H2
CHMgCl

NBS ThO2
CN
du
+ 0
A 1:2
B C
H 3O ,t
D E
2O
F

CH 3Cl

CH 2 N 2

0 H , Pd
F AlCl3 G H2 SO4 ,t
H as
I 40 C
2
0 K

a) Hay cho bit cu tao cua cac cht t B n I. Trong phn ng I H402 0, PdC K c th to ra sn phm
no khc khng ?
b) So sanh nhit si cua cac cht: D, E va G. Giai thich ngn gon?
Hp cht F co 2 ng phn cu hinh, hay cho bit nhit si cua chung ging nhau hay khac nhau? Tai
sao?
2. T metyl xiclopropyl xeton v hp cht c magie tu chn, vit s phn ng iu ch 2,6-
imetyl-9-bromnona-2,6-ien.
Ni dung im
1 1,0

Sn phm khc:

b. - Nhit si giam dn theo trinh t: D > G > E 0,5

- D, G co lin kt hyro va lin kt hyro gia cac phn t D bn hn gia cac phn t G.
+ 2 ng phn cu hinh cua F co nhit si khac nhau vi chung va la ng phn quang hoc va
la ng phn hinh hoc.

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2 O OH 0,5
.
1 CH3MgBr + HBr CH3
C Br CH2CH2CH=C
2. H2O C CH - H2O
CH3 3 CH3
CH3
.
1 Mg OH
CH3
. 3
2 H O+
C CH2CH2CH=C
CH3 HBr
Br CH2CH2CH=C CH2CH2CH=C
3. CH3MgBr CH3 CH3
CH3 CH3
Cu 7. (2 im): Nhn bit, Tch cht, Xc nh cng thc cu to hp cht hu c.
1. Cht A c CTPT l C8H16O, cho phn ng Ioofom nhng khng cng c H2. Khi un A vi H2SO4
c 170oC ta thu c cht B v C (c hai u c CTPT l C8H14). Nu xi ha B ri cacboxyl sn
phm s thu c metylxiclopentan. Cht B khng c ng phn hnh hc. Xc nh CTCT ca A,B,C v
gii thch s to ra cht C.
2. Metylisopropylxeton phn ng vi ietyl cacbonat trong mi trng kim-ru, to thnh hp cht A.
Cho axeton tc dng vi fomanehit v ietylamin, thu c cht B. Metyl ho B bng metyl ioua, sau
tin hnh tch loi Hopman, thu c C. Khi C phn ng vi A trong mi trng kim- ru th c
D. Cho D phn ng vi NaOH, sau vi axit HCl v cui cng un nng th c E. Hy xc nh cng
thc cu to ca cc hp cht t A n E v hon thnh cc phng trnh phn ng.
Ni dung im
1 . Cht A c + v =1, cho phn ng Ioofom nhng khng cng c H2 A c nhm 1,0
CH3-CH-

OH
V A c 1 vng.
Nu xi ha B ri cacboxyl sn phm s thu c metylxiclopentan nn A cng phi c b
khung ging metylxiclopentan. Vy A l 1 trong 3 cht sau y:

OH HO

OH
(1) (2) (3)
Cht 3 ph hp do tch nc sinh ra B khng c ng phn hnh hc.
B l : C l

S to thnh cht C:

H+ - H+

OH (+)
- H2O (+)

Xc nh CTCT ng ca A,B,C c 0,5 . Vit ng c ch to C c 0,5

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2 1,0
O O O
CO(OEt)2
EtONa OEt
A
O O
O O O 1. NaOH
Manich 1. CH3I A, EtONa
+ CH2O + Et2NH 2. H
+
2. Tch Hopman
NEt2 3. t
o

B C COOEt D E
E: 3-isopropylxiclohex-2-enon
Xc nh CTCT ca A,B,C,D,E mi cht c 0,25.

Cu 8. (2 im): Hu c tng hp.

Chia 44,8 gam hn hp X gm axit axetic, glixerol v etyl axetat lm ba phn (t l s mol ca cc cht
trong mi phn l nh nhau).
- Phn 1: tc dng ht vi Na thu c 1,344 lt (ktc) kh H2.
- Phn 2: tc dng va vi 500 ml dung dch NaOH 0,4M khi un nng.
- Phn 3: (c khi lng bng khi lng phn 2) tc dng vi NaHCO 3 d th c 2,688 lt (ktc) kh
bay ra.
Tnh khi lng mi cht c trong hn hp X, bit rng hiu sut cc phn ng u l 100% \
Ni dung im
Phn 1 : CH3COOH (a mol), C3H5(OH)3 (b mol) v CH3COOC2H5 (c mol) 0,25
Phn 2 : CH3COOH (xa mol), C3H5(OH)3 (xb mol) v CH3COOC2H5 (xc mol)
Phn 3 : CH3COOH (xa mol), C3H5(OH)3 (xb mol) v CH3COOC2H5 (xc mol)
mhh = 60.(a + 2xa) + 92.(b+2xb) + 88.(c+2xc) = 44,8 (gam)
=> (2x + 1)(60a + 92b + 88c) = 44,8 (I)

- Cho phn 1 tc dng ht vi Na : 0,25

1
CH 3COOH + Na CH 3COONa+ H 2
2
a
Mol : a
2
3
C3H 5 (OH) 3 + 3Na C3H 5 (ONa) 3 + H 2
2
3b
Mol: b
2
a 3b
S mol kh H2 thu c l: + = 0,06 (mol) a + 3b = 0,12 (II)
2 2
- Cho phn 2 tc dng vi dung dch NaOH : 0,25
CH 3COOH + NaOH CH 3COONa + H 2O
Mol : xa xa
CH 3COOC 2 H 5 + NaOH CH 3COONa + C 2H 5OH
Mol : xc xc
S mol NaOH phn ng l : xa + xc = 0,2 (mol) (III)

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 - Cho phn 3 tc dng vi NaHCO3 d: 0,25
CH3COOH + NaHCO3 CH 3COONa + CO 2 + H 2 O
Mol : xa xa
S mol kh CO2 thu c l : xa = 0,12 (mol) (IV)

T (II), (III) v (IV) ta c: 1,0

0,12
ax = 0,12 a= x

0,04x - 0,04
b =
x
0,08
cx = 0,08 c= x

Do b > 0 nn 0,04x - 0,04> 0 x >1 (*)
Thay a, b, c vo (I) ta c:
0,12 0, 04x 0, 04 0, 08
(2x + 1) 60. + 92. + 88. = 44,8
x x x
7,36x 2 - 20x + 10,56 = 0
x = 2 (Tha mn (*))
Gii phng trnh bc 2 =>
x = 33 / 46 < 1 (Loi)
a = 0,06 (mol)

Thay x = 2 vo (II), (III) v (IV) ta c kt qu: b = 0,02 (mol)
c = 0,04 (mol)

Khi lng ca cc cht c trong hn hp X l:
m CH3COOH = 60.(a + 2xa) = 18 gam
m C3H 5 (OH)3 = 92.(b+2xb) = 9,2 gam
m CH3COOC2 H5 = 88.(c+2xc) = 17,6 gam
Cu 9. (2 im): Cn bng ha hc.
Cho cc phn ng vi hng s cn bng ti 820oC nh sau :
CaCO3(r) D CaO(r) + CO2(k) (1) Kp1 = 0,2
C(r) + CO2(k) D 2CO(k) (2) Kp2 = 2
1. Trong mt bnh chn khng dung tch 22,4 lt 820 0C, ngi ta cho 1,0 mol CaCO 3 v 1,0 mol
cacbon. Xc nh thnh phn ca h trng thi cn bng.
2. Phi tng th tch bnh ln bao nhiu th CaCO3 phn hy hon ton.
Ni dung im
1 Gi x l s mol CaCO3 b phn hy. y l s mol C tham gia phn ng. 1,0
Ta c: CaCO3(r) D CaO(r) + CO2(k) (1) K1 = 0,2
1-x x x-y
C(r) + CO2(k) D 2CO(k) (2) K2 = 2
1-y x-y 2y
S mol ca hn hp kh = x + y (mol)
RT 0,082.( 273 + 820)
T (1) K1 = PCO2 = 0,2 atm = (x y). V = (x- y) 22,4 = (x y). 4
x- y = 0,2/4 = 0,05(*)
2
PCO
P 2.PCO2 = 0,4
T (2) K2 = co2 = 2 => PCO = atm.
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 RT 0,4
0,4 => y = = 0,079
=> 2y. V = 2 .4
Thay vo (*) x = 0,129
Trong h c 0,129 mol CaO ; 0,871 mol CaCO3 ; 0,921 mol C ; 0,05 mol CO2 ; 0,158 mol
CO.

2 s phn hy CaCO3 xy ra hon ton => x = 1 v p sut ring phn ca cc kh ti

thi im cn bng b ph hy l khng b thay i.
Ngha l PCO = 0,632 atm v PCO2 = 0,2 atm.
RT
(1 y ' ) = 0,2 (I )
V
RT
.2 y ' = 0,632 ( II )
=> V
Vi yl s mol C tham gia phn ng.
2 y'
= 3,16
Ly (II) chia cho (I) => 1 y '
=> y = 0,612 mol. Thay vo (II)
0,082.(820 + 273).2.0,612
= 173,6
=> V = 0,632 lt.
=> CaCO3 phn hy hon ton th th tch bnh phi ly l: V 173,76lt

Bi 10. (2 im): Phc cht.

Coban (Z=27) to ra c cc phc [CoCl2(NH3)4+] A ; [Co(CN)6]3- B ; [CoCl3(CN)3]3- C.
5. Vit tn ca A,B,C.
6. Theo thuyt lin kt ha tr, cc nguyn t trong B trng thi lai ha no?
7. Cc ion phc trn c th c bao nhiu ng phn lp th? V cu trc ca chng.
8. Vit phng trnh phn ng ca A vi ion Fe2+ trong mi trng axit.
Hng dn
Ni dung im
1 iclorotetraamincoban(III) 0,5
Hexaxianocobantat(III)
Triclorotrixianocobantat(III)

2 [Co(CN)6]3- - Co lai ha d2sp3 , C- sp, N sp hoc N khng lai ha. 0,5

3. A c hai ng phn, B khng c ng phn, C c hai ng phn. 0,75

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 Cl Cl
NH3 Cl
H3N H 3N
Co Co
NH3
H3N H3N NH3

Cl NH3

( A)

CN

CN
NC
Co
CN
NC

CN

( B)

Cl CN

CN Cl
NC NC
Co Co
Cl Cl
Cl Cl

CN CN

( C)
4 . [CoCl2(NH3)4+] + Fe2+ + 4H+ Co2+ + Fe3+ + 2Cl- + 4NH4+ 0,25

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