Weathering is the mechanical breakdown of rock and the
associated chemical alteration of minerals that occurs at the Earth’s surface.
Weathering is part of a process of breakdown of rock and
transport of the resulting materials. This overall process is often referred to as erosion. Technically, erosion is the removal of the weathered material and is only part of the overall process. Mechanical Weathering
Frost wedging – in the daily freeze-thaw cycle at high altitudes,
water seeps into cracks, freezes and expands extending the crack, then melts and seeps deep into the newly lengthened crack as the cycle repeats. Thermal expansion – even in climates that do not experience daily freeze-thaw cycles, daily temperature cycles expand and contract the rocks causing fracturing. Unloading – many rocks, for example plutonic igneous rocks, form deep in the crust. When they are exposed as the surface by the removal of overlying rocks by erosion, the pressure on the rock is reduced causing it to expand and crack. Rocks like granite often crack in concentric layers (like an onion) resulting in a process known as exfoliation. This causes granite domes such as Half Dome in Yosemite, Enchanted Rock in Texas, and Stone Mountain in Georgia. Organic activity – plant roots, burrowing animals, etc. Abrasion – corners are fragile things on rocks like on furniture. As rocks are transported, they abrade against one another, removing corners first, then edges. Thus, as transport time and distance increases, rock fragments become rounded (not necessarily spherical) as corners and edges are removed. Chemical Weathering Processes
Solution (or dissolution) – This is the dissolving of soluble minerals in
water or weak acids. Soluble minerals are generally ionically bonded minerals such as calcite and halite. Silicate minerals are not subject to solutioning. Solutioning requires considerable amounts of water to remove much material. It is thus most effective in wet climates. Solutioning is very effective on carbonate rocks. Oxidation - This reaction effects iron bearing minerals, forming iron oxides. Iron oxides are strong coloring agents and give many rocks their reddish or tan coloration. Hydrolysis - this reaction is the most important weathering reaction because it effects the silicate minerals. Silicates with ionically bonded metal ions (everything except quartz) are weathered by this reaction. In hydrolysis, the H+ ion from water or weak acid works its way into the mineral structure due to its very small size (it is a nucleus with no electrons). Because the H+ ion is so reactive, it dislodges other metal ions and causes the chemical breakdown of the crystal structure. The most important byproduct of hydrolysis are clay minerals. Because silicates are the most abundant minerals in the crust, clay minerals are the most abundant byproduct of weathering.