ORGANIC CHEMISTRY

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 19

Answer Key DPP No. # 19 (JEE-MAIN)

1. (B*) 2. (C*) 3. (B*) 4. (B*) 5. (A*)
6. (C*) 7. (B*) 8. (A*) 9. (B*) 10. (B*)
11. (A*) 12. (B*) 13. (B*) 14. (D*) 15. (A*)
16. (C*) 17. (C*) 18. (A*) 19. (D*) 20. (D*)

This DPP is to be discussed in the week (06.07.2015 to 11.07.2015)

DPP No. # 19 (JEE-MAIN)
Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60, 40]

1. Which of the following statement not correctly describe E1 reactions of alkyl halides (RX) ?
(A) Rearrangement is possible. (B*) Rate = k [Base] [RX]
(C) Rate = k [RX] (D) The reaction occur in two or more distinct steps
fuEu esa ls dkSulk dFku ,fYdy gSykbM (RX) dh E1 vfHkfØ;k ds lUnHkZ esa lgh ugha \
(A) iquZfoU;kl ugha gksrk (B*) nj = k [{kkj] [RX]
(C) nj = k [RX] (D) vfHkfØ;k nks ;k nks ls vf/kd inksa esa lEiUu gksrh gSA

2. Which of the following compound shows dehydration on reaction with con.H 2SO4 ?
fuEu esa ls dkSulk ;kSfxd lkUæ H2SO4 ds lkFk vfHkfØ;k djus ij futZyhdj.k n'kkZrk gS \

(A) CH3OH (B) (C*) (D)

3. Arrange following alcohols in decreasing order of their reactivity for dehydration reaction in acidic
medium :
vEyh; ekè;e esa fn;s x;s ,YdksgkWyksa dh futZyhdj.k vfHkfØ;k dh fØ;k'khyrk dk ?kVrk gqvk lgh Øe dkSu lk gS %

(I) (II) (III) (IV)

(A) IV > II > III > I (B*) IV > I > II > III (C) I > III > II > III (D) II > III > IV > I
Sol. E1 reaction is proportional to stability of carbocation.
Sol. E1 vfHkfØ;k dk osx dkcZ/kuk;u ds LFkkf;Ro ij fuHkZj djrk gSA

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 3 CH OH
4.    Major elimination product [P]


[P] is :

3 CH OH
   eq[; foyksiu mRikn [P]


[P] gS %
(A) Ph–CH2–CH=C (B*) Ph–CH=CH–CH

(C) (D) Ph–CH2–CH2–

2 conc. H SO / 
4
5.  Major product is : eq[; mRikn gS %

(A*) (B) (C) (D)

6. Major product of given reaction is :

fuEu vfHkfØ;k dk eq[; mRikn gS %

EtOH



(A) (B) (C*) (D)

7. What is incorrect about E2 reaction ?

(A) It is an anti-elimination reaction
(B*) Carbocation is formed as an intermediate during the reaction.
(C) Saytzeff alkene is formed as major product.
(D) It is a bimolecular reaction.
E2 vfHkfØ;k ds fy, fuEu esa ls dkSulk dFku xyr gS \
(A) ;g ,d ,UVh&foyksiu vfHkfØ;k gSA
(B*) vfHkfØ;k ds nkSjku dkcZ/kuk;u e/;orhZ curk gSA
(C) eq[; mRikn ds :i esa lSRtSQ ,Ydhu curh gSA
(D) ;s ,d f}v.kqd vfHkfØ;k gSA

8. The correct reactivity order with alcoholic KOH for the following compounds is :
fuEu ;kSfxdksa dh ,YdksgkWfyd KOH ds lkFk fØ;k'khyrk dk lgh Øe dkSulk gS %

(A*) I > II > III (B) III > II > I (C) I > III > II (D) II > III > I

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9. Major product of the given reaction is :
fuEu vfHkfØ;k dk eq[; mRikn gS %

Product (mRikn)

(A) (B*) (C) (D)

alc.KOH/ 
10.   Major product is :(eq[; mRikn gSA )

(A) (B*) (C) (D)

Anti e lim ination

Sol.    

  

11. How many structural isomers with molecular formula C5H11Br yield only a single alkene on dehydrohalogenation
by alc. KOH ?
C5H11Br ds fdrus lajpukRed leko;oh;ksa dk fogkbMªksgSykstuhdj.k ,YdksgkWfyd KOH ls djkus ij dsoy ,d gh ,Ydhu
izkIr gksrh gSA
(A*) 3 (B) 2 (C) 4 (D) 5

Sol.

12. How many halogen atoms will be eliminated in E2 reaction :

mijksDr ;kSfxd dh E2 vfHkfØ;k esa fdrus gSykstu ijek.kq foyksfir gksrs gS\

(A) 2 (B*) 3 (C) 4 (D) 6

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Sol. (3 halogen) (3 gSykstu)

13.

Product (P) and (Q) respectively :

mRikn (P) ,oa (Q) Øe'k% gksxsa %

(A) , (B*) ,

(C) , (D) ,

Sol. t-BuO–  a sterically hindered base will give Hofmann elimination as major product. Where as EtO– will give
Saytzeff's product.
t-BuO–  f=kfoe ckf/kr {kkj }kjk gkWQeku foyksiu eq[; mRikn gksxk tcfd EtO– }kjk lSRtSQ mRikn eq[; gksxkA

14. Which of the following will give E1cB reaction.

fuEu esa ls dkSulk ;kSfxd E1cB vfHkfØ;k nsxkA

(A) (B)

(C) (D*) All of these (mijksDr lHkh)

15. E1cB reaction is not possible in

(A*) (B)

(C) (D) C H —CH—CH —CH = O Base

OH
fuEu esa ls dkSuls ;kSfxd esa E1cB vfHkfØ;k lEHko ugha gS %
(A*) (B)

(C) (D)

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 NaOH, 
16.  (Product)

The major product of above reaction is obtained by mechanism :

NaOH, 
 (mRikn)


mijksDr vfHkfØ;k esa eq[; mRikn dkSulh fØ;kfof/k }kjk izkIr gksrk gS %
(A) SN2 (B) E2 (C*) E1cB (D) E1

NaOH, 
Sol. 
 (E1cB mechanism) (E1cB fØ;kfof/k)

17. Which of the following will not follow E2 elimination as major path ?
fuEu esa ls dkSulh vfHkfØ;k eq[; :i ls E2 foyksiu }kjk lEiUu gksrh gS \

(A) (B)

(C*) (D)

Ans. Reactant follows E1cB path under the given basic condition as the carbanion

is strongly resonance stabilized.

Ans. vfHkdeZd fn;s x;s {kkjh; ek/;e esa E1cB vfHkfØ;k nsrk gS D;ksafd dkcZ_.kk;u izcy

:i ls vuqukn LFkkuhd`r gksrk gSA


OH
18. 
 P (major), here ‘P’ is :



OH
  P (eq[;), ‘P’ gS %


(A*) (B) (C) (D) CH3–OH

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Sol.

19. Which of the following reaction will give saytzeff product as major product ?
fuEu esa ls fdl vfHkfØ;k esa lSRtSQ mRikn eq[; :i esa izkIr gksrk gS \
alc .KOH
(A)   (B) CH3  CH2  CH  CH3

|
Br

—
(C) (D*) EtO
 /
EtOH



 
Sol. Strong electronegative group (F, NR3 , SR 2 ) exert strong – effect due to this reaction followed by E1cB
mechanism. t- BuO also give Hoffmann product.
 
izcy fo|qr_.kh lewg (F, NR 3 , SR 2 ) izcy – izHkko yxkrs gS] ftlds dkj.k vfHkfØ;k dh fØ;kfof/k E1cB gksrh gSA
t- BuO gkWQeku mRikn nsrk gSA

aq. AgNO 3
20.    ?

Major product is eq[; mRikn gS

(A) (B)

(C) Ph – CO – CMe3 (D*)

aq. AgNO 3
Sol.    + Ag
AgI 


 Migration of Ph



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