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Evaporation
Types of evaporators
Factors affecting evaporation
Energy Balance for Single effect and multiple effect
evaporators
Mathematical problems on evaporation
Thermal
Mechanical
Boiler
Jacket
relatively cheap
used for non-
viscous liquids
having high heat-
transfer coefficients Dilute feed
and liquids that do
not deposit scales Steam
inlet
poor liquid Condensate
circulation (and
therefore unsuitable
for viscous liquids)
Concentrated
product
Vapor
Dilute feed
Condensate Steam
inlet
Concentrated
May 2, 2019 | Slide 8 product
Types of evaporators
Brine heater 5% 1% 2%
11%
To boil incoming seawater to its boiling 8%
point
Flashing chamber 19%
Water and vapor separation
54%
Condensing chamber
Condensation of vapor to water
Ejector
Remove non-condensable gases
Sea water pump
To pump pretreated sea water to flash
champers
Brine pump
To pump brine from flashing chamber
Condensate pump
To pump condensate from brine heater
Product pump
To pump product water from flashing unit
Based on compression
MED-Horizontal tubes
MED with Mechanical Vapor Compression (MVC)
MED-MVC
MED-TVC
Solubility:
As solution is heated, concentration of the solute in the solution
increases.
In case the solubility limit of the solute in solution is exceeded, then
crystals may form.
Solubility of the solute therefore determines the maximum concentration
of the solute in the product stream.
In most cases, the solubility of the solute increases with temperature.
This means when a hot concentrated solution from an evaporator is
cooled to room temperature, crystallization may occur.
May 2, 2019 | Slide 21
Factors effecting evaporation: (2/4)
The result is that the overall heat-transfer coefficient (U) may drastically decrease,
leading to shut down of the evaporators for cleaning purposes.
Materials of construction:
Evaporators are made of some kind of steel.
However many solutions attack ferrous metals and are contaminated by them.
The foam is carried away along with vapour leaving the evaporator.
Multiple-effect evaporation:
Increasing the evaporation per kg of steam by using a series of
evaporators between the steam supply and condenser is called multiple
effect evaporation
Economy: Economy is the number of kilograms vaporized per kilogram of
steam fed to the evaporator unit.
Capacity: Capacity is defined as the number of kilograms of water vaporized
per hour by evaporator unit
In a single-effect evaporator the economy is nearly always less than 1, but in
multiple-effect equipment it may be considerably greater.
The steam consumption, in kilograms per hour = capacity / economy.
1 1 1 d o xw d o 1 d o 1
U o ho h fo d L k di hi di h fi
1 di 1 di 1 di xw 1 1
U i d 0 ho d 0 h fo d L k w hi h f i
May 2, 2019 | Slide 26
Heat transfer coefficient
For evaporators
Rewriting:
Concentrate, L F hF + S (HS - hS) = L hL + V HV
xL, T1, hL
F hF + S λ = L hL + V HV
where λ = HS - hS
May 2, 2019 | Slide 30
Calculation methods for single-effect evaporators
Vapor, V
yV, T1, HV
Energy lost by the steam
q = S λ = S (HS – hS)
P
Feed, F
xF, TF, hF In case of no energy loss to the
environment, q amount of energy
T1
Steam, S gets transferred from steam to
Condensate, S the solution through the tube wall
PS, TS, HS
PS, TS, hS of area A and overall heat
transfer coefficient U.
Concentrate, L
xL, T1, hL Therefore,
q = U A ΔT = U A (TS – T1)
T1 xL = 1.5 wt %
Steam, S
Condensate, S = 0.015 kg solute / kg liquid product
PS, TS, HS
PS, TS, hS P = 101.325 kPa (1.0 atm abs)
PS = 150 kPa
Concentrate, L U = 1704 W/m2.K
xL, T1, hL
S λ = L h L + V HV – F hF
= (F – V) hL + V HV – F hF
= F (hL – hF) + V (HV – hL )
= F Cp (T1 - TF) + V (Latent heat of vapourization at 101.325 kPa )
When feed is not at its boiling point, steam is needed first to heat the feed to its boiling
post and then to evaporate it.
Preheating the feed can reduce the size of evaporator heat-transfer area.
Since q = U A (TS – T1), larger values of (TS – T1) will help reduce the heat-transfer area
needed and hence the cost of evaporator.
Vacuum can be maintained in the solution side using a vacuum pump.
For example, if the pressure in Example 1 is reduced to 41.4 kPa, boiling point of water
reduces to 349.9 K and that would increase the (TS – T1) from 10 K to 33.3 K. A large
decrease in heat-transfer area would be obtained.
Steam used = ?
S λ = L hL + V HV - F hF
Steam used = S = ?
S λ = 1814 x 505 + 2722 x 2667 – 4536 x 214 = 7204940 kJ/h
Steam used = ?
S λ = L hL + V HV - F hF = (F – V) hL + V HV – F hF = F (hL – hF) + V (HV – hL )
= F Cp (T1 - TF) + V (Latent heat of vapourization at 0.12 bar)
= (4536) (4.14) (49.4 – 60) +(2722) (2383) kJ/h (Cp = 4.14 kJ/kg.K is assumed)
= 6301078 kJ/h
209C
281C
252C
261C 176C
226C
Energy Balance equations for triple Assume values for the boiling
effect evaporator temperatures in the first and second
(1) the rate of steam flow to the first effects.
effect, From enthalpy balances find the rates of
(2) to (4) the rate of flow from each steam flow and of liquor from effect to
effect, effect.
(5) the boiling temperature in the first Calculate the heating surface needed in
effect, each effect from the capacity equations.
(6) the boiling temperature in the second If the heating areas so found are not
effect, and nearly equal, estimate new values for
(7) the heating surface per effect. the boiling temperatures and repeat
items 2 and 3 until the heating surfaces
It is possible to solve these equations are equal.
for the seven unknowns
Estimate the requirements of steam and heat transfer surface, and the
evaporating temperatures in each effect, for a triple effect evaporator
evaporating 500 kg h-1 of a 10% solution up to a 30% solution.
Steam is available at 200 kPa gauge and the pressure in the evaporation
space in the final effect is 60 kPa absolute. Assume that the overall heat
transfer coefficients are 2270, 2000 and 1420 J m-2 s-1 °C-1 in the first,
second and third effects, respectively.
Equating the quantities evaporated in each effect and neglecting the sensible heat changes,
if w1, w2, w3 are the respective quantities evaporated in effects 1,2 and 3, and ws is the
quantity of steam condensed per hour in effect 1, then
w1 x 2200 x 103 = w2 x 2240 x 103
= w3 x 2294 x 103
= ws x 2164 x 103
The sum of the quantities evaporated in each effect must equal the total evaporated in all
three effects so that:
w1 + w2 + w3 = 333 and solving as above,
w1 = 113 kg h-1 w2 = 111kg h-1 w3 = 108kg h-1
ws = 115 kg h-1
Steam consumption