Some Basic Concept Of Chemistry Lakshya Daily Assignment (LDA-1)

Theory Questions
1. Define
(i) Compounds
(ii) Elements
(iii) Atoms
(iv) Molecules
2. What is phlogiston theory ?
3. Which of the following are mixtures ?
(i) NaCl + H2O
(ii) S + H2O
(iii) ethyl alcohol
(iv) Cu + Zn
4. State and explain Dalton’s Atomic theory.

Objective Questions
1. Which of the following is not a postulate of Dalton’s theory?
(a) Atom is the smallest particle of matter
(b) Atom can be further divided into sub-atomic particles
(c) In pure matter, all atoms are identical
(d) None of these
2. The smallest particle present in hydrogen gas is
(a) H2 molecule (b) H atom
(c) Both (d) None
3. Which of the following is not a correct statement
(a) Compounds are pure matter (b) Compounds are impure
(c) Composition have fixed composition (d) None of these
4. Which of the following is an example of homogenous mixture?
(a) Air (b) Oil + Water
(c) Salt solution (d) Both (a) and (c)
5. Correct statement is
(a) Mixture has only 2 components
(b) Homogeneous mixture has equal composition of all components
(c) Both
(d) None of these
6. Homogeneous mixture is formed by mixing
(a) Phenol and water (b) iron filing and S
(c) silver chloride and water (d) ethanol and water
7. Atom is a smallest particle of
(a) Compound (b) Substance
(c) Mixture (d) Element
8. Molecule is a smallest particle of
(a) Compound (b) Substance
(c) Mixture (d) Element

Answer Key
Objective Questions

1. (b) 2. (b) 3. (b) 4. (d) 5. (d) 6. (d) 7. (d) 8. (a)

Lakshya
 Some Basic Concept Of Chemistry Lakshya Daily Assignment (LDA-2)

Theory Questions
1. Define
(i) Atomic mass
(ii) Gram atomic weight
(iii) Molecular mass
(iv) Gram-molecular weight
2. Explain the need of term “average atomic mass”
3. What is abundance of isotopes?
4. What is the unit of the following
(i) Atomic weight
(ii) Molecular weight
5. Calculate the molecular mass of the following compounds
(i) H2 (Ans: 2 a.m.u)
(ii) O2 (Ans: 32 a.m.u)
(iii) N2 (Ans: 28 a.m.u)
(iv) CH4 (Ans: 16 a.m.u)
(v) NH3 (Ans: 17 a.m.u)
(vi) H2O (Ans: 18 a.m.u)
(vii) H2O2 (Ans: 34 a.m.u)
6. Calculate the molecular mass of the following compounds
(i) H2SO4 (Ans: 98 amu)
(ii) HNO3 (Ans: 63 amu)
(iii) NaOH (Ans: 40 amu)
(iv) H3PO4 (Ans: 98 amu)
(v) CaCO3 (Ans: 100 amu)
(vi) CaO (Ans: 56 amu)
(vii) C6H12O6 (glucose) (Ans: 180 amu)
(viii) H2C2O4 (oxalic acid) (Ans: 90 amu)
(ix) (Ans: 60 amu)
7. Chlorine has two isotopes of atomic mass units 35 and 37. The relative abundances of these two isotopes are
75% and 25% respectively. Find the average atomic mass of chlorine. (Ans: 35.5 amu)
8. Use following data to calculate the molar mass of naturally occurring Argon
Molar mass
Isotope Abundance
(g mol-1)
36
Ar 36 0.3%
38
Ar 38 0.1%
40
Ar 40 99.6%
(Ans: 39.986 amu)

Lakshya
Some Basic Concept Of Chemistry Lakshya Daily Assignment (LDA-3)

Theory Questions
1. Define mole explaining mole concept.
2. Define Avogadro’s number.
3. What is atomicity?
4. Calculate the number of moles and molecules present in 0.032 mg of CH4. (At wt: C = 12, H = 1).
(Ans. No. of moles of CH4 = 2 × 10-6 moles
No. of molecules of CH4 = 12.044 × 1017)
5. Calculate the number of atoms of C, H and O in 72.5 g of iso-propanol (C3H7OH) having molar mass 60 g mol-1.
(Ans. Number of : C -atoms = 2.182 × 1024
H-atoms = 5.82 × 1024 , O-atoms = 7.274 × 1023)
6. Calculate number of atoms of Hydrogen present in 9 g of urea (Molar mass of urea = 60 g mol-1). Also,
calculate the number of atoms of N, C and O.
(Ans. Number of : N-atoms = 1.8 × 1023
O-atoms = 0.9 × 1023
C-atoms = 0.9 × 1023)
H-atoms = 3.6 × 1023)
7. For sulphur dioxide, calculate the mass of (Atomic mass : S = 32, O = 16)
(i) 2.8 moles (Ans. 0.179 kg)
(ii) 280 molecules (Ans. 2.975 × 10-23 kg)
8. Calculate the mass of
(i) One carbon atom
(ii) One oxygen atom and one oxygen molecule
(Ans. One oxygen molecule = 5.314 × 10-26kg)
9. Calculate the no. of moles in 6.023 × 10 molecules NH3 , 5 × 10 C-atoms and 6.023 × 1011 N-atoms.
21 21

(Ans.1 × 10-2 mole, 0.8302 × 10-2 mole, 1 × 10-12 mole)

-2
10. Calculate the number of moles in 1.6 × 10 kg of SO2 , 5g of CaCO3 and 10g of NaOH
(Ans. 0.25 moles, 0.05 moles, 0.25 moles)
11. A signature made by graphite pencil of weight 2 × 10-3g. Calculate the number of C-atoms in that signature.
(Ans.1.0038 × 1020 molecules)
Objective Questions
1. Atomicity of Ammonium phosphate is
(a) 5 (b) 10
(c) 15 (d) 20
2. Number of moles of water in 1L of water with density 1 g/cc are
(a) 55.55 (b) 45.56
(c) 56.55 (d) 56.45
3. Avogadro’s number is the number of particles present in
(a) 1 molecule (b) 1 atom
(c) 1 kg (d) 1 mole
4. The number of moles of He present in 104 µ of He are
(a) 26 × 10-6 (b) 13 × 10-6
-6
(c) 39 × 10 (d) 52 × 10-6
5. The number of moles present in 6 × 1021 NH3 molecules are
(a) 2 (b) 1 × 102
-2
(c) 0.996 × 10 (d) 2 × 10-3

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 Answer Key
Objective Questions

1. (d) 2. (a) 3. (d) 4. (a) 5. (c)

Lakshya
Some Basic Concept Of Chemistry Lakshya Daily Assignment (LDA-4)

Theory Questions
3 -3
1. 1.4 dm of a gas at STP weighs 1.26 × 10 Kg.
Calculate
(i) Molecular mass
(ii) Mass of 1 mole
(iii) Number of gas molecules
(Ans. (i)20.16 g mole-1, (ii) 20.16 g, (iii) 3.764 × 1022 molecules)
2. 3.49 g of ammonia occupies a volume of 4.48 dm3 at STP. Calculate molar mass of ammonia.
(Ans. 17.46 g mol-1)
2
3. Calculate the number of moles & molecules of ammonia present in 5.6 dm of it’s volume at STP.
(Ans. Number of moles = 0.25
Number of molecules = 1.505 × 1023)
4. Calculate the number of moles of a gas present in 11.2 mL at STP. (Ans. 5 × 10–4)
5. Calculate the volume occupied by 12g of a gas at STP if the V.D of the gas is 24. (Ans. 5.6 L)
6. 10 g of a solid sublimates to occupy 11.2L volume at 273K and 1 bar. Calculate the V.D of the sublimate.
(Ans. 10)

Objective Questions

1. Vapour density of CH4 is

(a) 16 (b) 8
(c) 4 (d) 2

2. O2 gas occupies 44.8 L at STP Number of moles is

(a) 1 (b) 3
(c) 4 (d) 2

3. Volume occupied by 0.5 moles of N2 gas at STP is

(a) 11.2 L (b) 11200 ml
(c) Both (a) and (b) (d) None of these

Answer Key
Objective Questions

1. (b) 2. (d) 3. (c)

Lakshya
 Some Basic Concept Of Chemistry Lakshya Daily Assignment (LDA-5)

Theory Questions

1. State and explain law of Definite composition or proportion

2. State and explain law of multiple proportion (Ans. Diborane)
3. State and explain law of conservation of mass
4. Explain indivisibility of an atom with a suitable example.
5. On heating 632 kg of Cu in air, 7.92 kg of copper oxide is formed. Another sample of copper oxide
contains 80% of copper. From these data, show that the law of definite proportion is valid.
6. State and explain Gay Lussac’s law of combining volume

Objective Questions

1. One of the following combinations illustrates law of reciprocal proportions

(a) N2O3, N2O4, N2O5 (b) NaCl, NaBr, NaI
(c) CS2, CO2, SO2 (d) PH3, P2O5, P2O3

2. If water samples are taken from sea, river, lake, etc, they will be found to contain H and O in the approximate
ratio of 1:8. This indicates the law of
(a) Multiple proportion (b) Definite proportion
(c) Reciprocal proportion (d) None of these

3. Law of multiple proportion is illustrated by

(a) CO and CO2 (b) KBr and KCl
(c) H2O and D2O (d) Ca(OH)2 and Ba(OH)2

4. The percentage of copper & oxygen in sample of CuO obtained by different methods were found to be the
same. This illustrates the law of
(a) Constant proportion (b) Conservation of mass
(c) Multiple proportion (d) Reciprocal proportion

5. One part of element A combines with two parts of another element B. Six parts of the element C combines
with four parts of the element B. If A and C combines together the ratio of their weights will be governed by
(a) Law of definite proportion (b) Law of multiple proportion
(c) Law of reciprocal proportion (d) Law of conservation of mass

6. ‘n’ g of substance X reacts with ‘m’g of substance y to form ‘p’g of substance R and ‘q’ g of substance S
according to following reaction X + Y → R + S
The relation which can be established in the amounts of the reactants and the products is
(a) n - m = q + p (b) n + m = p + q
(c) n = m (d) p=q

Answer Key
Objective Questions

1. (c) 2. (b) 3. (a) 4. (a) 5. (c) 6. (b)

Lakshya
Some Basic Concept Of Chemistry Lakshya Daily Assignment (LDA-6)

Theory Questions

1. Explain
(a) Percentage composition
(b) Molecular formula
(c) Empirical formula
2. Write empirical and molecular formaula of the following compounds.
(a) Water (b) Carbon
(c) Methane (d) Hydrogen peroxide
(e) Acetylene (f) Glucose
(g) Diborane (h) Tetraphosphorous decoxide
Ans.
E.F. M.F.
(a) H 2O H2 O
(b) C C
(c) CH4 CH4
(d) HO H 2 O2
(e) CH C2H2
(f) CH2O C6H12O6
(g) BH3 B 2H 6
(h) P2O5 P4O10
3. Calculate the mass percentage composition of the element in nitric acid (Al. wt. H = 1, N = 14, O = 16)
Ans. % composition : H = 1.59%
N = 22.22 %
O = 76.19%
4. Phosphoric acid is widely used in carbonated beverages, detergents, toothpastes and fertilizers. Calculate
the mass percentage of H, P and O in phosphoric acid
(At. wt. H = 1, P = 31 and O = 16)
Ans. % composition : H = 3.06%
P = 31.6%
O = 65.34%
5. Analysis of vitamin C shows that it contains 40.92% S, 4.58% H and 54.5% O by mass. Determine the empirical
formula of vitamin C.
Ans. C3H4O3
6. A compound with molar mass 159 was found to contain 39.62% copper and 20.13% sulphur. Determine its’s
molecular formula (At. wt. O = 16, S = 32, Cu = 63)
Ans. CuSO4
7. An inorganic compound contains 24.75% K and 34.75% Mn and some other common element. Give
the empirical formula of the compound
(At. wt. K = 39, Mn = 51)
Ans. KMnO4

Objective Questions

1. Percentage of oxygen present in water is

(a) 89.8% (b) 98.9%
(c) 99.8% (d) 88.9%

2. Percentage of N in urea is about

(a) 46 (b) 85
(c) 18 (d) 28

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 3. In a hydrocarbon, mass ratio of H to C is 1:3. The empirical formula of hydrocarbon is
(a) C2H6 (b) C2H
(c) CH3 (d) CH4

4. A compound has haemoglobin like structure. It has one atom of Fe. It contains 4.6% of Fe. The approximate
molecular mass is
(a) 100 g/mol (b) 1200 g/mol
(c) 1400 g/mol (d) 1600 g/mol

5. An organic compound made of C, H and N contains 20% nitrogen. The minimum molecular weight is
(a) 70 (b) 140
(c) 100 (d) 65

6. Caffeine has a molecular weight of 194. If it contains 28.9% by mass of N, number of atoms of N in one
molecule of caffeine is
(a) 4 (b) 6
(c) 2 (d) 3

Answer Key
Objective Questions

1. (d) 2. (a) 3. (d) 4. (b) 5. (a) 6. (a)

Lakshya
Some Basic Concept Of Chemistry Lakshya Daily Assignment (LDA-7)

Theory Questions
1. Explain chemical reaction with mass relationship.

2. Define
i. Stoichiometry
ii. Stoichiometric coefficients

3. Calculate the mass of carbon dioxide and water formed on complete combustion of 24g of Methane gas
(Atomic mass C = 12, H = 1, O = 16)
(Ans: Mass of CO2 = 66g
H2O = 54 g)

4. Calculate the amount of oxygen produced when 1.75 kg of potassium chlorate on heating gives 1.043 kg of
potassium chloride (K-39, Cl-35.5, O-16)
(Ans: 0.707 kg)
5. Calculate the number of moles of ethylene required to produce 44 g of carbon dioxide gas on it’s complete
combustion. (At wt : C = 12, H = 1, O = 16)
(Ans: 0.5)
6. Write the stoichiometric co-efficient in the following balanced reaction
N2(g)+ H2 (g) → NH3 (g)
(Ans: 1, 3, 2)

7. Express the interaction between aqueous copper sulphate & metallic zinc powder with a balanced chemical
reaction.
(Ans: CuSO4 + Zn → ZnSO4 + Cu)

Objective Questions
1. How much of NaOH is required to neutralize 36.5 g of HCl is
(a) 40 g (b) 4 g
(c) 6 g (d) 60 g

2. If 1.5 moles of oxygen combine with Al to form Al2O3 the weight of Al used is
(Al wt. Al = 27)
(a) 27 g (b) 54 g
(c) 49.5 g (d) 31 g

3. What weight of SO2 can be made by burning sulphur in 5 moles of oxygen

(a) 640 g (b) 160 g
(c) 80 g (d) 320 g

4. How many grams of KOH required to completely neutralise 31.5 g of HNO3

(a) 28 g (b) 56 g
(c) 14 g (d) 112 g

5. Mass of Mg required to combine with 1.5 mol of O2 to form MgO is

(a) 72 g (b) 36 g
(c) 48 g (d) 24 g

6. x g of Ag was dissolved in HNO3 and the solution was treated with excess of NaCl when 2.87 g of AgCl was
precipitated. The value of x is
(a) 1.08 g (b) 2.17 g

Lakshya
 (c) 2.7 g (d) 1.62 g

7. 1.50 g sample of an ore containing silver was dissolved, and all the Ag+ was converted to 0.125 g Ag2S. What
was the percentage of silver in the ore ?
(a) 14.23% (b) 10.8%
(c) 8.27% (d) 7.26%

8. 27.6 g of K2CO3 was treated by a series of reagents so as to convert all of its carbon to K2 Zn3[Fe(CN)6]2 . What
is the weight of product.
(Molar mass of K2 Zn3[Fe(CN)6]2 = 698.5 g/mol)
(a) 11.64 (b) 1.164
(c) 0.1164 (d) 116.4

Answer Key
Objective Questions

1. (a) 2. (b) 3. (d) 4. (a) 5. (a) 6. (b) 7. (d) 8. (a)

Lakshya
Some Basic Concept Of Chemistry Lakshya Daily Assignment (LDA-8)

Theory Questions
1. What are limiting and excess reactants.

2. In the reaction, A + B2 → AB2, identify the limiting reagent, if any, in the following mixtures
(i) 300 atoms of A + 200 molecules B2
(ii) 2 mol A + 3 mol B2

(iii) 100 atoms of A + 100 molecules of B2
(iv) 5 mol A + 2.5 mol B2
(v) 2.5 mol A + 5 mol B2

3. Calculate the amount of carbon dioxide that could be produced when

(i) 1 mole of carbon is burnt in air.
(ii) 1 mole of carbon is burnt in 16 g of dioxygen.
(iii) 2 moles of carbon are burnt in 16 g of dioxygen.

4. Find the amount of weight of NH3 being produced when 1kg of N2 reacts with 1kg of H2. Which reactant is in
excess and how much?

5. 11.2 L of CH4 at STP is burned with 32 g of oxygen. Calculate the volume of CO2 formed at STP.

6. In a reaction 3P + 2Q → P3Q2, calculate the no. of moles of P3Q2 formed when 2 moles of each P and Q are
taken.

7. 0.1 mol of NaCl reacts with 0.05 mol of AgNO3 resulting in the formation of white precipitate of AgCl . Identify
the limiting reagent. How many moles & how many grams of AgCl are formed?
(Ans: Limiting reagent – AgNO3
Moles of AgCl – 0.05
Wt. of AgCl – 7.175 g )

Objective Questions

1. In the reaction, 4NH3 + 5O2 → 4NO + 6H2 when 1 mole of Ammonia and 1 mole of O2 are made to react to
completion
(a) 1 mole of H2O is produced (b) 1 mole of NO will be produced
(c) All the oxygen will be consumed (d) All the ammonia will be consumed

2. 30g of magnesium and 30g of oxygen are reacted, then the residual mixture contains
(a) 60g of Magnesium oxide only (b) 40g of Magnesium oxide and 20 g of oxygen
(c) 45 g of Magnesium oxide and 15g of oxygen (d) 50 g of Magnesium oxide and 10g of oxygen

3. If 0.5 mol of BaCl2 is mixed with 0.2 mol of Na3PO4, the maximum number of mole of Ba3(PO4)2 that can be
formed is
(a) 0.7 (b) 0.30
(c) 0.5 (d) 0.10

4. If 9 moles of O2 and 14 moles of N2 are placed in a container and allowed to react according to the equation :
3O2 + 2N2 → 2N2O3. The no of moles of N2 remain unreacted at the end of the reaction are-
(a) 6 (b) 8
(c) 10 (d) 4

Lakshya
 5. In combustion reaction of Carbon (C + O2 → CO2) excess of oxygen is taken and 22 g of CO2 is formed. The
mass of carbon burned is
(a) 12 g (b) 24 g
(c) 6 g (d) 3 g

Answer Key
Objective Questions

1. (c) 2. (d) 3. (d) 4. (b) 5. (c)

Lakshya
Some Basic Concept Of Chemistry Lakshya Daily Assignment (LDA-9)

Theory Questions
1. What is the formula of
(i) Percent yield of reaction
(ii) Percentage purity

2. In the reaction N2 + 3H2 → 2NH3, 1mol of N2 is mixed with 3 moles of H2 and it was found that only 1 mole of
NH3 is formed. Calculate percent yield.
(Ans. 50 %)

3. A sample contains 90% pure CaCO3 when heated gives CaO and CO2. What is the weight of CaO formed when
200 g of the impure sample is heated?
(Ans. 100.8 g)
4. A + 2B → 3C
3C + D → 2E
Calculate the moles of B used if 1 moles of E is formed.
(Ans. 1)

5. Calculate the percentage yield of MgS formed when 24 g of Mg reacts with 32 g of S. Given that the
experimental yield observed was 50 g
(Ans. 89.28%)

6. The following chemical reactions used to be utilized to rapidly produce large amount of N2 gas inside an
automobile air bag:
2NaN3 → 2Na + 3N2
10Na + 2KNO3 → K2O + 5Na2O + N2
How many moles of N2 is produced if 1 mole of NaN3 is used?
(Ans. 1.6)
7. ‘A’ on controlled oxidation gives ‘X’ according to the reaction 2A + 9B → 2X + 4Y + 4Z Only 70% of the
maximum yield predicted by the equation is actually obtained. What weight of ‘X’ is obtained it 200 g of ‘A’ is
taken?
(Mol. wts. of : A = 128 g/mole & X = 148 g/mole)
(Ans. 161.875 g)

8. A small amount of CaCO3 completely neutralize 0.05 moles of HCl. After converting all calcium chloride to
calcium sulphate, how much plaster of paris can be obtained?
(Molecular Formula of POP : CaSO4. 1/2 H2O)
(Ans. 3.625 g)

Lakshya
 Some Basic Concept Of Chemistry Lakshya Daily Assignment (LDA-10)

Theory Questions
1. What is meant by 40% w/w aqueous solution of NaOH?

2. Define molarity

3. Write down various formulae for molarity?

4. What is the unit of Molarity?

5. What is the percentage by weight of a solution containing 60g glucose in 100 g of water.
(Ans: 37.5%)

6. Calculate the molarity of a solution containing 2 moles of HCl in 4L.

(Ans: 0.5 M)

Objective Questions

1. Which of the following are temp. independent

(a) % w/v (b) % v/v
(c) % m (d) % w/w

2. The moles of sodium carbonate required to prepare 400 ml of 0.275 M aqueous solution is
(a) 0.11 (b) 1.3
(c) 0.21 (d) 0.15

3. What is the molarity of a solution obtained by dissolving 196 g of H2SO4 in 5L water?

(a) 1 (b) 0.8
(c) 0.6 (d) 0.4

4. Mass of salt required to prepare 10% w/w solution using 100g water is
(a) 10 g (b) 11.11 g
(c) 9.1 g (d) 12 g

5. In 0.5M solution of Al2(SO4)3 the molarity of Al3+ & SO2-

4 respectively
(a) 0.25, 0.15 (b) 1, 1.5
(c) 0.5, 1.5 (d) 1.5, 1

6. Molarity of liquid water at 4oC is

(a) 5.56 (b) 55.56
(c) 0.556 (d) 18

Answer Key
Objective Questions

1. (d) 2. (a) 3. (d) 4. (b) 5. (b) 6. (b)

Lakshya
Some Basic Concept Of Chemistry Lakshya Daily Assignment (LDA-11)

Theory Questions
1. Define
i) Molality
ii) Mole fraction
iii) Parts per million

2. What is the unit of molality?

3. Molality is temperature independent whereas molarity is temperature dependent. Explain

4. A solution is prepared by dissolving 20 g of NaOH in 100 g of water. Calculate the molality of solution
(Ans: 5 molal)

5. Calculate the mole fraction of solute and solvent in a solution containing 20 g of CaCO3 in 360 g of water
(Ans: xCaCO3 = 0.0099
xH2O = 0.99)

6. What is the effect of Dilution on molarity?

7. Derive the relation to calculate final molarity of a solution after dilution.

8. 500 ml of 2M NaOH solution was diluted to 1000 ml. Calculate the molarity of final solution
(Ans: 1 M)
9. 250 ml of 1M H2SO4 solution is diluted with 750 ml of water. Calculate the molarity of resultant solution
(Ans: 0.25 M)

Objective Questions

1. The mass of CaCO3 that reacts completely with 50 ml of 0.75 M HCl is

(a) 3.75 g (b) 2.788 g
(c) 2.020 g (d) 1. 875 g

2. Which of the concentration units is temperature dependent?

(a) Molality (b) Mole fraction
(c) Molarity (d) Parts per million

3. What is the number of ppm of NaCl in the solution with 1.17 g of NaCl dissolved in 998.83 g of water?
(a) 1.170 (b) 11.70
(c) 117.0 (d) 1170

4. The expression converting molality (m) into molarity (M) is

(where, δ = density of solution (g/m)and M2 = Molar mass of solute)
M
(a) m = M( δ + MM2) (b) m= × 1000
(1000δ - MM2 )
(c) m=
( δ + MM2 ) (d) m=
( δ - MM2 )
M M

5. If 20 cm3 of 1M CaCl2 & 60 cm3 of 0.2 M CaCl2 are mixed, the molarity of resultant solution is
(a) 0.8 M (b) 0.6 M
(c) 0.4 M (d) 0.2 M

Lakshya
 6. The volume of 0.25 M NaOH to be added to 250 ml of 0.15 M NaOH so that the resultant solution is 0.2 M
would be
(a) 250 ml (b) 350 ml
(c) 450 ml (d) 550 ml

7. The molarity of a solution obtained by diluting 350 ml of 1 M HNO3 solution to 2000 ml is

(a) 0.175 (b) 0.275
(c) 0.375 (d) 0.475

Answer Key
Objective Questions

1. (d) 2. (c) 3. (d) 4. (b) 5. (c) 6. (a) 7. (a)

Lakshya
Some Basic Concept Of Chemistry Lakshya Daily Assignment (LDA-12)

Theory Questions
1. Calculate m, M and mole fraction of 6% w/w of urea solution. Density of solution is 1.25 g/ml.
(Ans: M = 1.25
m = 1.06
xurea = 0.017)
2. Calculate molality of urea solution if the mole fraction is 0.2
(Ans: 13.9)

Objective Questions

1. The density of 2M solution of acetic acid in water is 1.01 g cm-3. The molality of acetic acid in solution is
(a) 2.12 (b) 2.25
(c) 2.5 (d) 3.0

2. A solution of acetic acid has molarity equal to 1.35 M and molality equal to 1.45 molal. The density of solution
will be
(a) 1.251 g ml-1 (b) 1.125 g ml-1
-1
(c) 1.012 g ml (d) 0.994 g ml-1

3. The molarity of concentrated sulphuric acid

( δ =1.834 g ml-1) containing 95% H2SO4 by mass is
(a) 4.44 (b) 8.88
(c) 13.32 (d) 17.78

4. Molarity of 20% by mass of H2SO4 solution of density 1.14 g cm-3 is

(a) 1.52 (b) 2.02
(c) 2.32 (d) 2.82

5. The volume of concentrated sulphuric acid (98% by mass of H2SO4 and δ = 1.84 g cm-3) required to prepare 5
dm3 of 0.5 M solution of sulphuric acid is
(a) 68 cm3 (b) 136 cm3
3
(c) 204 cm (d) 272 cm3

Answer Key
Objective Questions

1. (b) 2. (c) 3. (d) 4. (c) 5. (b)

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