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Components Antoine Constant A B C Tmin Tmax

Methanol Methanol 11.9673 3626.55 -34.29 257 364


Water Water 11.6834 3816.44 -46.13 284 441

gE= xaxb(A+B(xa-xb))
RTlnya = (A+3B)xb2 - 4Bxb3 Component 1 = Methanol
RTlnyb = (A-3B)xa + 4Bxa
2 3
Component 2 = Water

Calculate VLE P= 15190


R= 8.314
x1 y1 T/K x2 y2 y1 y2
0 0 327.4 1 1 0.2650299 1
0.1 0.4334 318.1 0.9 0.5666 0.515423 0.952162
0.2 0.6212 312.4 0.8 0.3788 0.8388067 0.799981
0.3 0.7253 308.6 0.7 0.2747 1.1512012 0.570148
0.4 0.7924 305.7 0.6 0.2076 1.3632911 0.331397
0.5 0.8407 303.5 0.5 0.1593 1.4340349 0.151156
0.6 0.8787 301.7 0.4 0.1213 1.3835085 0.05202
0.7 0.9108 300.1 0.3 0.0892 1.2660478 0.012973
0.8 0.9404 298.7 0.2 0.0596 1.13735 0.002254
0.9 0.9694 297.4 0.1 0.0306 1.038921 0.000262
1 1 296.1 0 0 1 1.95E-05
P= 15.19kPa
Component 1 = Methanol
x1 y1 T/K Component 2 = Water
0 0 327.4
0.1 0.4334 318.1
0.2 0.6212 312.4
0.3 0.7253 308.6
0.4 0.7924 305.7
0.5 0.8407 303.5
0.6 0.8787 301.7
0.7 0.9108 300.1
0.8 0.9404 298.7
0.9 0.9694 297.4
1 1 296.1

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