PART-A

ANSWER ALL THE QUESTIONS: Each question carries three marks. 5x3=15

1. write the electronic configuration of following elements:

(a) Ca (b) Cr (c) Cu

2. write any three differences between oxidation number and valency?

3.Define covalent bond ? Identify the bonds present in the following molecules?

(a) HCl (b)MgO (C)H2 (d) N2

4. Define : (a) Solution (b)Unsaturated solution (c) Atomic weight .

5. State any three applications of Buffer solutions ?

PART-B

Answer any TWO of the following: 2x10=20

6.(a) Name the four quantum numbers. Write symbols and significance? (4x1.5=6M)

(b) Define ionic bond? Explain the formation of Magnesium oxide ? (1+3=4M)

7.(a) Define: (1) Mole(2)Molarity (3) Equivalent weight (4) Molecular weight (5)Solvent (5x1=5M)

(b)Define Normality.Calculate the normality of a solution prepared by dissolving 10.6 gmof sodium
carbonate in 2 liters of water? (1+4=5M)

8. (a) Explain Lewis acid-base theory with limitations ? (5M)

(b) Define PH and POH? Calculate the PH of 0.002M, Ba(OH)2 Solution ? (2+3=5M)

COMPULSORY QUESTION (1X5=5M)

9. (a) Explain the postulates of electronic theory of valence ?

(OR)

(b) Define orbital. Draw the shapes of S,P and d-orbitals ?