Sri Chaitanya IIT Academy., India: Chemistry

Sri Chaitanya IIT Academy.
, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sr. ICON ALL Jee-Main Date: 28-12-18
Time: 09:00 AM to12:00 Noon CODE-D Max.Marks:360
KEY SHEET
CHEMISTRY
1 3 2 3 3 1 4 1 5 3
6 3 7 2 8 2 9 2 10 1
11 4 12 3 13 2 14 1 15 4
16 2 17 2 18 1 19 2 20 3
21 1 22 3 23 2 24 1 25 2
26 4 27 1 28 3 29 4 30 3
PHYSICS
31 2 32 2 33 1 34 1 35 3
36 1 37 1 38 4 39 2 40 1
41 1 42 2 43 1 44 3 45 4
46 2 47 3 48 3 49 1 50 2
51 3 52 3 53 1 54 2 55 2
56 2 57 3 58 1 59 3 60 2
MATHS
61 2 62 4 63 3 64 3 65 3
66 3 67 1 68 2 69 3 70 2
71 1 72 4 73 4 74 4 75 2
76 4 77 1 78 1 79 2 80 4
81 3 82 4 83 2 84 4 85 3
86 1 87 3 88 4 89 3 90 4
Sri Chaitanya IIT Academy 28-12-18_Sr.ICON ALL_JEE-Main_GTM-5_Code-D(11th Jan)_Key & Sol’s
SOLUTIONS
CHEMISTRY
 1.2 1018
1. Partial charge    1.2 1010 The fraction of electric charge is =
d 110 18
1.2 1010
 0.25
4.8 1010
2. Smaller the ion with more no. of charges covalent character is more (Fajan’s rule)
2
3. % ionic nature  16  X A  X B   3.5  X A  X B 
2
 16  3  2.1  3.5  3  2.1
4. (a) Order of spectro chemical series

5. 1/3 of Cl3  1 Cl undergoes precipitation
6. Conceptual
7. CuSO4 solution is acidic due to hydrolysis in water forming Cu(OH)2 and H2SO4. In
acid medium chromates convert in to dichromates
8. 6Cl2  6Ba  OH  2  Ba (ClO3 ) 2  5 BaCl2  6 H 2O
(X)
Ba (ClO3 ) 2  H 2 SO4  2 HClO3  BaSO4
(Y)
4 HClO3  4 ClO2  2 H 2O  O2
(Z)
9. In pyrosilicate only one oxygen atom, in linear silicate two oxygen atoms, In three
dimensional silicate all four oxygen atoms of SiO4 ions are shared. In sheet silicate
only three oxygen atoms ate shared.
10. P2O5  2HNO3  N 2O5  2 HPO3
A B
N 2O5  I 2  I 2O5  N 2
C
CH 3 CH 3
CH 3 CH 3
&
11.
Sec: Sr. ICON ALL Page 2

HgOAC
HgOAC
O
OH O NaBH 4
O
12.
13. 2 alcohol in to ketone followed by aldol condensation
14. Intra molecular cannizaro’s reaction followed by cyclisation.

15. PhCOOH ( B ), PhCOCl (C ),( PhCO ) 2 O ( D )
16.
Br2
CH 3  CH  CH 2 
 CH 2  CH  CH 2
Br
Mg / Ether
CH 3
CH 3 CO CH 3 CH 2  CH  CH 2
CH 3  C  OMgBr  
CH 2  CH  CH 2 MgBr
H 2O
CH 3
CH 3  C  OH
CH 2  CH  CH 2
CH 3 
CH 3  C  CH  CH  CH 2
17. Aromatic carbocation and carbanion are more stable.

18. 150.7(X) + 52.8(1-X) = +80.2
150.7X + 52.8-52.8X = +80.2
97.9X = +80.2
X = 0.279
= 0.28 X 100
= 28%
19. It is a SN2 reaction in presence of pyridine inversion product is formed

20.
N-OH
O
O
NH
NH 2OH H
B
Beckmann's
Rearrangement
A caprolactum
O
 NH  CH 2 5 C 
n
Nylon - 6
21.
2 r  n
r
  2
n
 a n2 
 2  o 
 n 
 2n ao
  2 10  3.14  5.28 10 11
 3.31109 m
 33.1 A 
22. Initial mmol of C6H5COOH = 14

Initial mmol of C6H5COONa = 7
pH 1 = pKa + log 7/14 =pKa – log2
After adding 2 mmol NaOH, C6H5COOH =12 mmol and C6H 5COONa=9 mmole
pH 2 =pKa + log 9/12 =pKa + log 3/4
 pH=log 3/4 + log2
= log 3/4 = 0.18
 n 
23. n2 moles of Na2S is present in n1 mole of water, then 17.5 = 24.5  1

 n1  3n 2 
n2 0.4 2
 
n1 3 15
n2 2
   0.117
n1  n2 17


24. E  0.53   0.41  0.94V
 G   nE  F  2  0.94  96500
 181.42 103 J
25. Smaller the charge on coagulation, higher the Flocculation value.
n 1 n 1
T1 1  25 10 4  1
26.     
T2 8  5 10 3  2
n4
4
T1 1  1.25 10 3 
  
T2 T3  5 10 3 
 T3  256 hrs.
P
27.  K and PV  RT
V
P 2  K RT
2 2
 P2  T2  4  T2
        T2  4T1
 P1  T1 2 T1
U  Cv T  3CvT1  (1)
ALSO  dw  pdv  Kvdv

K
 w  V22  V12 
2
K 1 1 2 2
  P22  P12  2  4  2 
2 K 2K
6
 bar 2   2 
K
PV  RT
P2
 RT
k
1 RT1 RT1
 2 
K P1 4bar 2
1
substituting in  2  gives
K
RT1 3
 w  6 bar 2  2
 RT1
4bar 2
U 3CvT1 2Cv
  2 
w 3RT R
2 12.5
  3
8.3
28. The arrangement of a face can be shown as
In BCC 4r = 3a

4r
a=  623.5
3
5
Also AB = a
4
= 348.5 Pm
r ( guest )  348.5  270  78.5 pm
a
Guest
 B
A
HOST
rx 1 r 1
29.  and y 
ry 5 rz 16
rx 1
 and rz : rx  30 :1
rz 30
30. n-factor for An+1 = 5-n-1= 4-n

2.68 (4-n)= 32.16 x 0.05 x 5
n=1
PHYSICS
31. Conceptual
32. Conceptual
33. Conceptual
34. If MN is an isotherm that passes through point a, then at point ‘a’ temperature is
highest.
dV
35. Since V  VoeCT   CVo e CT
dT
pdV nRT dV RT RT
   CVo eCT  CV  RTC
ndT nV dT V V
pdV 3
 C  CV   R  R  400  5  10 3
ndT 2
3 7R
 R  2R 
2 2
36. Vertical component does not change
2v0 sin  2 100  sin 300
t    10sec
g 10
37. Friction (f) is in forward direction

Ff F
 acm  
M M
2 
38. mg sin   R / 2   mR 2  
3 
1 2
g  R
2 2 3
3g
 a  2 R 
4
2h
39. v  2 h  v  2 gh
g
q  vA  2 gh . A
q2
h
2 gA2
3
40.  2v0   e  v0  3e
2
Here, v0  gR
41. Conceptual
 mg 
42.   2kl 2  l   ml 2
 3 
 g 2k 
     
 3l m 
g 2k g
   (For equal time periods)
3l m l

2k 2 g mg
  k 
m 3l 3l
kT
43.    p  constant
2 D 2 p
GMm GMm
44. W 
r2 r2
GMm  1 1   2e  GMm 8 GMm

    
a 1  e 1  e   1  e 2  a
 15 a
2mv 2mv 2v
45.  F     mk
t m 

k
46.   mg  u cos 0  t  L   mgu cos  0   tdt  L  t 2
47. Q  mC   mg R  mC   mgR
 m  C  Rg 
 200  10  2.5  10  10  10 3  5   6000J
 kQq  kQq
48. K  
 R  10 R
K 
10  1 kQq  9  kQq 
 
10 R 10  R 
V1 i1R1 R1
49.   ;  i1  i2 
V2 i2 R2 R2
kq ' kq
50.  0
R r
R  R 
q '   q     30  10C
r  3R 
51. Conceptual
0 I
52. B
2R
2 0 I 2 0 I
B'  
2R / 2 R

B 1
  B '  4B
B' 4
53. i  i0  i0 sin t
2
2 2 i0 2 1 
 i  i0   i0  1  
2  2
r  dB   bB0 
54. F  q   q
2  dt   2 
v  v0 11
55. 
v  v0 9
v  10v0
 v0  34 m / s
2
R
3 2  17 
t   
v0 3  34 3
56. Conceptual
I C 0.98
57.    49
I B 0.02
V  across RL    I B RL  49  50  106  104  24.5 V
58. D  4 f  f  D / 4  0.50
1 1
  1.5  1    R  25cm
50 R
 a  8 Rt  8  25  0.5  10 cm
59. vmp  3 3 km / s
vrms 3
 
vmp 2
3 9
 vrms  3 3   km / s
2 2
9
At 600 K , vrms   2  9 km / s
2
60. Vi  5
5
 imax   0.5 A
10
 across 100 resistance, maximum value V  100  0.5  50V
 correct range is 10v  vS  60v
MATHS
61. y  x  f  x  x   1  2 x  f ( x)  f ( x )  2 x f ( x)
2 2
y   x  f  x  x 2   1  2 x  f ( x)  f ( x 2 )  2 x f ( x)
 f ( x)  f ( x)
62. cos 2   P  sin 2   P  4

5
P
2
61
 cos 2
  P  sin 2   P  
16
1 1
 sin 2
 .cos 2   
16
 tan 2   cot 2   sec 2   cos ec 2  2 
sin  cos 2 
2
 2  14
x 2   tan 2  .cot 2    1  0
req equation x2-14x+1=0

63. As 2q =p+r  p and r both are even or both are old if p and r odd then number of
ways
=2.5c2 If p and r both even (or) p even and q can be zero then number of ways =
2.4c2+4c1 total ways=36
64. 2x 2 ydx  x 3 dy  y 2 dx
2xydx  x 2 dy dx
 2

y x
 x2  dx
  y    x
d
x2
y
log x  c
if passes through 1,1  c  1
65. OP  3  1

AB  2
3 1
tan 30 
OA
3 1
tan  
OB
OA  OB  3  3     3  1 cot 
2  3 3   3  1 cot 
cot   1     / 4
66. f  x   f 10  x 
x replaced by x  5  f  x  5   f  5  x 
f 1  x    f 1 10  x 
put x  5  f 1  5    f 1  5 
 f 1  5  0
put x  5  f 1  5    f 1 15 
 f 1 15    f 1  5   2 ( slope at x  5 is 2)
67.
z  6  z  2  10
2
 x  2 y2
 1
25 9
2
z  6  3   x  6  y2  9
So just one point is common

  
68. b  a  c   35
 
b a  c cos   35
cos  1    0
  
b is parallel to a  c
  
b is perpendicular to a & c
  
a. b  0, b .c  0
 
if a lies in xy plane, a  a1i  a2 j and a.b  0
2a1  3a2  0
3
a1  a2
2
69.    2  a  3  b 
x   4b  5  a  2 
y  0
z  a  2
if a  2 and b  3 then D  0, Dx  0, Dz  0
Given system of equations has no solution
70. lim f  x   l , lim g  x   m

x 0 x a
not symmetric because

l m
if l  0   R but  R
m l
5
71.
18
x 1

1 11
12 x  12 x7

 x  3x  2   C
18 6 6
 1
12  1
10 x5
x7  x12  3  2 x 
6 6
 x12
 3  2 x 
6 6
 p  x   x18  3 x 6  2
72. an1  an  an1
an1 a a
lim  1  lim n1 , lim n1  m
n a n a n  a
n n n
1
m  1  m2  m  1  0
m
1 5
m
2

73.
 3 h 2  k 
AD  BC and g   , 
 3 3 
 4  k 
    1
 7  n 
k 7
  1
n 4
centroid lie on x  y  7
h  k  16   2 
from  2  only we can say that a, b, c are not valid
74.  x  y  6  x  y  2   0
x 2  y 2  4 x  8 y  12  0
2
 lx  y   lx  y   lx  y 
x2  y 2  4 x    8y    12   0
 3   3   3 
co  eff x 2  co  eff y 2  0
l2  l 1  0
sum of values of l  1
75.  x  4  y  3  4
which is a rec tan gular hyperbola of the form xy  c 2
a2 2
2b 2
LLR   2b  4 2  a  b 
a
76. LET x  t  17
dx  dt
1 1  t 1
e t 17 18 e
 a a

I  e  dt   f  x  dx   f  a  x  dx 
0
t 2 0
t2  0 0 
1
et
18
e  dt   e 18
0
  t  1
3 2
9  x 
77. Area   18  2  dx 
2  0
3 
2 21
 1    1 
78.  x     x   42
 x    x 
 
r
 1 
42  r
Tr 1  42Cr x  
 x

r  21 for independent of x
79. l  r , AB  2
1
from ACD, sin 45 
r
r 2
3

2
3
l  2.
2
Total length of arc  2l  3 2
lt 1cos5x  lt 5sin5x  25

80.
f
x0  2  f  x0   f   4
 x   2   2
81.   p  q   p  q    p   q   p  q
  p  q   p  q
 p   q  q  p
 
82. n  10, x  6, n1  4, x1  7.5

n2  6, x2  ?
 
 n1 x1  n2 x2
x
n1  n2

4  7.5   6 x2
6
10

x2  5
 3  1 k  1 0  1
 
83.  2 3 4 0
 1 2 1 

9
k
2
2
84. a 2  4 a  5   a  2   1 1
min  
3, a 2  4a  5  1, 3 
thus we have
sin x  cos x   ,   1, 3 
 2  sin x  cos x  2 x  R
So the given equation reduces to
sin x  cos x   ,   1, 2 
clearly it has inf initely many solutions
85. P2  I  P
P3  P  I  P   P  P 2  2P  I
P 6   2 P  I  2 P  I   4 P 2  4 P  I
 4I  4 P  4 P  I
 5I  8P
86. The required event occurs if two sixes are observed in the first seven throws and a six
is observed on the right throw.
2 5
1 5 1
7 C2     .
6 6 6
7C2 55

68
87. PA+PB is max if secant line passing through centre of the circle.
PA=Cp-r, PB=CP+r

PA+PB=2CP
88. The point of intersection of plane and line is ( 5,3,14) distance is 13.
n  n  1
89. the last n occurs at th palce
2
62.63
the last 62 occurs at  1953 rd place
2
63  64
thel last 63 occurs at  2016 th place
2
so 63 occurs from 1954 term to 2016 term
 2007 th term is 63
90. f  x   x 3  2x  9
f I  x   3x 2  2  0
f(x) is strictly increasing

f(x)=0 Two distinct real roots not possible

Sri Chaitanya IIT Academy., India: Chemistry

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Sri Chaitanya IIT Academy., India: Chemistry

Uploaded by

Copyright:

Available Formats

Sri Chaitanya IIT Academy.

4. (a) Order of spectro chemical series

Sec: Sr. ICON ALL Page 2

14. Intra molecular cannizaro’s reaction followed by cyclisation.

17. Aromatic carbocation and carbanion are more stable.

Sec: Sr. ICON ALL Page 3

22. Initial mmol of C6H5COOH = 14

Sec: Sr. ICON ALL Page 4

ALSO  dw  pdv  Kvdv

Sec: Sr. ICON ALL Page 5

30. n-factor for An+1 = 5-n-1= 4-n

37. Friction (f) is in forward direction

Sec: Sr. ICON ALL Page 7

GMm  1 1   2e  GMm 8 GMm

 200  10  2.5  10  10  10 3  5   6000J

Sec: Sr. ICON ALL Page 8

V  across RL    I B RL  49  50  106  104  24.5 V

62. cos 2   P  sin 2   P  4

req equation x2-14x+1=0

Sec: Sr. ICON ALL Page 10

So just one point is common

70. lim f  x   l , lim g  x   m

not symmetric because

72. an1  an  an1

Sec: Sr. ICON ALL Page 12

lt 1cos5x  lt 5sin5x  25

Sec: Sr. ICON ALL Page 15

f(x) is strictly increasing

Sec: Sr. ICON ALL Page 16

You might also like