REPORT1

EXPERIMENT 1: CHEMICAL REACTIONS

Group: ___1____ Section: ___1__ Date: ___18/09/2019____

Group members: ___Đan Phạm Lâm Quỳnh___BTFTIU19015_________

___Cao Hoàng Anh_________BTFTIU19042_________

____Châu Minh Thuận______BTFTIU19019_________

____Nguyễn Minh Thông____BTFTIU19017_________

Date: _________

Score: _________
I. Introduction
In this experiment, a number of chemical reactions was done and examined with noticeable signs. Our
group performed 9 reactions of metal ions and inorganic compounds with observable chemical changes
such as the change in color, the formation of a solid, the release of gas, and the production of heat and light

II. Experimental
(Describe what experiments you did in this report, write down each step of your experiments)

1. Reactions of Cu2+

Reaction Observation Chemical Equation

0.5M CuSO4 + 2M NaOH - Before add 10 more drops 2M NaOH: 2NaOH + CuSO4 → Cu(OH)2↓ + Na2SO4
Appeared light blue precipitate
- After add 10 more drops 2M NaOH:
Precipitation turned darker.
0.5M CuSO4 + 2M NH4OH - Before add 10 more drops of NH4OH: 4NH4OH + CuSO4 → (NH4)2SO4 + Cu(OH)2↓
Supernate turned into dark blue, appeared
light blue precipitate 4NH4OH + CuSO4 → 4H20 + [Cu(NH3)4]SO4

- After add 10 more drops of NH4OH:

Supernate became darker, the amount of
precipitate decreased
0.5M CuSO4 + 0.5M
K4[Fe(CN)6]
Comments:

2. Reactions of silver halides

Reaction Observation Chemical Equation

- Appeared white precipitate on supernate’s AgNO3 + KCl → AgCl↓ + KNO3
0.5M KCl + 0.1M AgNO3
surface and at the bottom of test tube
0.5M KCl + 0.1M AgNO3 - Appeared white precipitate on supernate’s AgNO3 + KCl → AgCl↓ + KNO3
+ 2M NH4OH surface and at the bottom of test tube AgCl + 2NH4OH → 2H2O + Ag(NH3)2Cl
- After add NH4OH: Precipitate dissolved
0.5M KCl + 0.1M AgNO3
+ 2M KCN

0.5M KBr + 0.1M AgNO3 - Appeared creamy white precipitate on AgNO3 + KBr → AgBr↓ + KNO3
supernate’s surface
0.5M KBr + 0.1M AgNO3 - Appeared creamy white precipitate on AgNO3 + KBr → AgBr + KNO3
+ 2M NH4OH supernate’s surface AgBr + 2NH4OH → 2H2O + Ag(NH3)2Br
- After add NH4OH: The precipitate
dissolves
0.5M KBr + 0.1M AgNO3
+ 2M KCN

0.5M KI + 0.1M AgNO3 - Appeared light yellow suspension AgNO3 + KI → KNO3 + AgI↓
0.5M KI + 0.1M AgNO3 - Appeared light yellow suspension AgI + NH4OH → Ag(NH3)2I + 2H2O
+ 2M NH4OH - After add NH4OH, the amount of
precipitate stay still
0.5M KI + 0.1M AgNO3
+ 2M KCN
Comments:

3. Reactions of H2O2

Reaction Observation Chemical Equation

0.1M KMnO4 + 2M H2SO4 - After add H2O2: Solution became 4KMnO4 + 6H2SO4 → 4MnSO4 + 2K2SO4 + 5O2 + 6H2O
+ H2O2 transparent, the original color of KMnO4 is
lost
0.1M KI + 2M H2SO4 - Before add H2O2: Solution has the color H2O2+ H2SO4 + KI → H2O + I2↓ + K2SO4
+ H2O2 of apricot yellow
- After add H2O2: Solution turn into a
combination color of umber brown and
dark violet
H2O2 + MnO2 - Bubbling on supernate’s surface H2O2 + MnO2 → MnO2↓ + O2 + H2O
- Supernate turned into umber brown
because of black precipitate of MnO2
Comments:

4. Reactions of Nitrate

Reaction Observation Chemical Equation

1M NaNO3 + FeSO4 - After add FeSO4: Solution turn 4H2SO4 + 2NaNO3 + 6FeSO4→ 3Fe2(SO4)3 + 4H2O + Na2SO4 + 2NO
+ concentrated H2SO4 into light yellow
 - After add H2SO4: Solution
became more transparent
1M NaNO2 + FeSO4 - After add FeSO4: Solution turn 2NaNO2 + 2FeSO4 + 2H2SO4 → Fe2(SO4)3 + 2NO + Na2SO4 + 2H2O
+ concentrated H2SO4 into dark yellow green
- After add H2SO4: Test tube is
heated, solution did not change
color
1M NaNO3 + FeSO4 - Solution turned into light yellow NaNO3 + 2FeSO4 + 6CH3COOH→ NaNO2 + 2(CH3COO)3Fe + 2SO3 + 3H2O
+ concentrated
CH3COOH
Comments:

5. Reactions of KMnO4

Reaction Observation Chemical Equation

0.5M Na2SO3 + 2M H2SO4- - After add KMnO4: Solution made 3H2SO4 + 2KMnO4 + 5Na2SO3 → 3H2O + 2MnSO4 + 5Na2SO4 + K2SO4
+ 0.1M KMnO4 the color of KMnO4 lost
0.5M Na2SO3 + 6M NaOH - After add KMnO4: Solution stay 2KMnO4 + Na2SO3 + 2NaOH → H2O + Na2SO4 + K2MnO4 + Na2MnO4
+ 0.1M KMnO4 still, did not change the color
0.5M Na2SO3 + H2O - After add KMnO4: Supernate H2O + 2KMnO4 + 3Na2SO3 → 2KOH + 2MnO2↓ + 3Na2SO4
+ 0.1M KMnO4 turned into umber brown because
of black precipitate of MnO2
Comments:

6. Reaction of Potassium Dichromate (K2Cr2O7)

Reaction Observation Chemical Equation

2M K2Cr2O7 - After add H2SO4: Solution turn 3C2H5OH + 8H2SO4 + 2K2Cr2O7→ 3CH3COOH + 11H2O + 2K2SO4 + 2Cr2(SO4)3
+ 6M H2SO4 into Iodine’s color
+ C2H5OH
 - After add C2H5OH: Solution
turned from Iodine’s color to dark
yellow green
Comments/Conclusions:

7. A. Reactions of Fe3+

Reaction Observation Chemical Equation

0.5M FeCl3 + 0.5M KCN
0.5M FeCl3 + 0.1M KSCN
0.5M FeCl3 + 2M KOH - Fawn yellow solution became lighter KOH + FeCl3 → KCl + Fe(OH)3↓
- Appeared hazel brown precipitate at
the bottom of test tube
0.5M FeCl3 + 0.5M K4[Fe(CN)6]
0.5M FeCl3 + 2M NH4OH - Fawn yellow solution became lighter 3NH4OH + FeCl3 → 3NH4Cl + Fe(OH)3↓
- Appeared hazel brown precipitate at
the bottom of test tube
Comments:
 7. B. Reactions of Fe2+
Reaction
0.5M FeSO4+ 0.5M KCN
0.5M FeSO4+ 0.1M KSCN
0.5M FeSO4+ 2M KOH
0.5M FeSO4+ 0.5M K4[Fe(CN)6]
0.5M FeSO4+ 2M NH4OH
Comments:
8. Reactions of Al3+
Reaction
0.5M Al2(SO4)3 + 2M NaOH
0.5M Al2(SO4)3 + 2N NaOH
+ 2M HCl
Observation Chemical Equation
- Appeared light blue precipitate 2KOH + FeSO4 → K2SO4 + Fe(OH)2↓
- Appeared light blue precipitate NH4OH + FeSO4 → (NH4)2SO4 + Fe(OH)2↓
Observation Chemical Equation
- Appeared white colloidal precipitate Al2(SO4)3 + 6NaOH → 2Al(OH)3↓ + 3Na2SO4
- Before add 2M HCl: Appeared white Al2(SO4)3 + 6NaOH → 2Al(OH)3↓ + 3Na2SO4
colloidal precipitate Al(OH)3 + 3HCl → AlCl3↓ + 3H2O
- After add 2M HCl: the amount of
precipitate increased
0.5M Al2(SO4)3 + 2M NaOH
+ 2M NaOH
- Before add 10 more drops of 2M Al2(SO4)3 + 6NaOH → 2Al(OH)3↓ + 3Na2SO4
NaOH: Appeared white colloidal Al(OH)3 + NaOH → 2H2O + NaAlO2
precipitate
- After add 10 more drops of 2M NaOH:
White colloidal precipitate dissolved

Comments:

9. Flame test

Solution Dominant flame color Wavelength (m) Frequency (s1) Photon energy (J)

LiCl Brick red 701

NaCl Yellow 587

KCl Violet 423

CaCl2 Light orange 609

BaCl2 Yellow - green 577

Comments: