1

FIITJEE JEE(Main)-
ANSWERS, HINTS & SOLUTIONS

(Main)

Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. C D A
2. B B C
3. C C C
4. D C B
5. D C A
6. A A B
7. C B C
8. D D D
9. B B A
10. C A B
11. C C C
12. B B B
13. D B B
14. D A C
15. A B B
16. C B C
17. B B A
18. B D B
19. B B C
20. B B B
 2

Physics PART – I

3  14  106  5
1. 
1
 15.7 ohm metre.
 2r L R 
      ohm metre.
 r L R 
 01 01 01
 15  7 2    ohm metre
 1 1 5 
 15.7 02  01  002 ohm – metre
 15.7  032  m
 5024  m

P
2. 100   3  0 1 2  0  2  3  0  3  4  0  1
P
 3  4  9  4  2%

3. A  N0 e t0
3Ae  3N0 e t
1
 e  0   e 1
 tt

e
1
t  t0  .


v o sin  
4. At t  ,v1  v 0 cos  ˆi
g

v 2  v 0kˆ  gtjˆ
 
 v 2  v1  v0 kˆ  gt ˆj  v 0 cos ˆi

2
5. f  a2  Z  b  .
 (D)

dv  k  mg x
6. v 
dx m
0 x0
 k  mg 
v

  vdv  
 m
 xdx
o 
0

m
 x0  v0
k  mg 
2

7.
Imax

 I1  I2  
Imin 2
 I1  I2 
 3

2
I1    1 
  if I1 > I2
I2    1 

5 2 10 2
100  
8. Ic  sin  50t   /4
5 2  4
/4
I=Ic+IL
/4
/4
100  
IL  sin 50t   5 2
5 2  4
I = 20sin(50t)

9. 2mg sin30 – T = 2m(a)

T
T = ma
mg 600
 a  g/3&T 
3 T
300
 Net force =
     
Result of these forces  T ˆj  T cos600 ˆj  T sin 60  ˆi

3 ˆ 3 ˆ
 T i  Tj
2 2
mg

6

 3iˆ  3ˆj
As net force in pulley = 0,
mg
force by clamp 
6

3iˆ  3 ˆj 
10. The circuit can be simplified as: .004F .1H
5
  00 ,peak current =20 Ampere. 1
 5
c

5
L5
100 sin [50t] volts. .004F

12. When u decreases v increases. For plane mirror u decreases.

 the image in plane mirror moves towards the left.

0I 1 1 
13. 4 . sin 450  sin 450    
4  R 2R 
I  1  0I
 0  2     
 2R
  2R

10
14. V1   4 volts = 5 volt
44
100  4
10 
V2  100  4
100  4
4
100  4
= 4.9 volts  V1  V2  0.1 volt
 4

15. In both cases

applying com,
mv 0  Mv
mv0
V
M
V1
  1: 1
V2

16. In steady state :-

E E
VP  VQ  R 
2R 2
E E
VQ  VS  R 
2R 2
VS  VR
VP  VR  E
 Q A  CE
CE
QB 
2

17. VP  V0   10  10  10  10

= - 200 volts.

18. For the two blocks to move together

F F
 min  
 M  m  g 2Mg
As   min ,
the two blocks move together.
 Velocity of the system (M+m) is
 F 
v  at   t
 2M 
F F2
 P  Fv  F t t.
2m 2M

P
19.  Axt  mcT
4r 2
4r 2mcT
t
PA

20. A  b  2  T .
 4

SECTION – C

2m 2 2 m 3
1. FA    , FC  2 
3 3 2 4
F 32
 A 
FC 27
n=5

2. 1htan  = 2R
 R/h
 1  1
2 tan 
h  

B
h sec  sin  = h tan 

k0 A dT
3. I0 
   dx
cos  x
 6L 
6I L   
 T = T0  0 sin  x
k 0 A  6L 
 T = 2T0 at x = L

1 
4. j E
 2
q dq q
I  jA   
2 dt 2
 t 
 
 q Qe  2 
Q
Or q  at t = 6 n(2)
8

 v
5. 
v  0 3iˆ  ˆj
2

For crossing origin,
2m 2(v 0 / 2)
k  ; k is an integer
qB qE / m
 2E 
 B k
 v0 
For minimum value; k = 1
2E
 Bmin 
v
 6

Chemistry PART – II

1. Mwt C6H5Cl = 112.5

Mwt C6H5CH3 = 92
Given:
xC6H5Cl  0.5
So mass% composition reaction of C6H5Cl is
112.5
% C6H5Cl =  100 = 55%
204.5

2. As density increases, volume of gas decreases so intermolecular forces increase and diffisubility
decreases.

3. For 432 
n = 4, l = 3, m = 2
h 12h 3h
Angular momentum =     1  
2 2 
Angular node =  = 3
3h 3h  3
So total node = 3 =
 

4. O O
250o C
2H3PO 4 
 H4P2O7  H2O HO P O P OH
Pyrophosphoric acid
OH OH

5. +
O H

+
+  B O H
H O P P 
B B +
+
H O  P O H
+
O H
3 p—p back bonding between B and O and
3 p—d back bonding between P and O is possible.

7. K 2 Cr2 O7  2H2SO 4  2CrO3  2KHSO4  H2 O

Chromic anhydride
Re d Crystal 

9. NH2 behaves as a base and E2 elimination takes place.

 7

10. OH OH OH
CCl 3 CHO


NaOH
 H 
 CCl 3

11. Na2S 2O3  AgNO3  Ag2S2 O3  Ag2 S

 white   black ppt 

8a 1
12. Tc  so Tc  ; and b = 4  NA  V  b  r
27Rb b
+2 – –2
13. AB type structure in which Zn is tetrahedrally surrounded by S ion, S is present in half of
tetradedral acid.

14. It is an extensive property.

d B  K1 
15.
dt
  A 0   K1e
 K 2  K1 

K1t
 K 2 eK 2 t 
2
Fe H2 O  OH H3 O 
ksp   
16. 3
, Ksp should be high.
Fe  H2O  
 6

17. H   K a C1  Ka C  2.5

  1 2 2

0
18. G (net) = G10  G02
–
Total e exchanged = (a + b)
G0  nFE0
  a  b  FE03  aFE10  bFE02
aE10  bE20
E30 
a  b

19. K 2Cr2 O7   K 2CrO4  Cr2 O3  O2

20. O
H3C C 6H 5  PPh 3   POPh3 (Wittig reaction)
H3C C6H5
M
 9

2
1. Mg2   EDTA 4   Mg EDTA  
 CN  6
Hexadentate ligand Octahedral complex

2 . PCl5  4H2 O  H3PO4  5HCl

3. H2 ,Li2 ,B2 ,N2 ,F2

4. Atomic number of metal = 29

Cu = 3d104s1
Cu2+ = 3d9

2
5.  K 2 HgI4   2K   HgI4 
2KI  HgI2 
i=3
 8

Mathematics PART – III

2. Since the equations are consistent

D=0
(a  1)3 (a  2)3 (a  3)3
(a  1) (a  2) (a  3)  0
1 1 1
Put u = (a + 1), v = a + 2, w = a + 3
u  v = 1, v  wz 1, w  u = 2
u + v + w = 3a + 6
u3 v 3 w 3
 u v w 0
1 1 1
(u  v) (v  w) (w  u) (u + v + w) = 0
(1) (1) (2) (3a + 6) = 0
i.e. a = 2.
567 1011
3. 1234 = 3n + 1, so 1234 = 3m + 1,89 = 3k – 1, so 89 = 3p – 1.
Hence 1234567 + 891011 = 3n 1234 is even,
567 1011
So 1234 = 4q. 89 = 4r + 1, so 89 = 4t + 1.
567 1011
Hence 1234 + 89 = 4l + 1. So it is 9x + 1.
 9

c2
4. Here, tan A + tan B = and tan A . tan B = 1
ab
0 0 0
tan A . tan B = 1  tan A = cot B  A = 90 – B  A + B = 90  C = 90
a b
 sin A = , sin B =
c c
a2 b2
 sin2 A + sin2 B + sin2 C =  1 2
c2 c2

101 101
dx dx
5. I1 =

100
5  2x  2x 1  e 2 2  4x 
=   5  2 1  x   2 1  x   1  e
100
2 2  4 1 x  
101
dx
 2I1 =
100
 5  2x  2x 2
= I2

I1 1
 = .
I2 2

6. Since f(x) and g(x) are one-one and onto and are also the mirror images of each other with
respect to the line y = 2. It clearly indicates that h(x) = f(x) + g(x) will be a constant function and
will always be equal to 4.

7. Equation of the curve passing through the points A, B, C, D is

(3x + 4y – 24)(4x + 3y – 24) – xy = 0
If it represents a parabola then the quadratic terms must form a perfect square.
  = 1 or 49.

r1  r2
8. Locus is a hyperbola with eccentricity =  2
r1  r2

R
9. In an equilateral triangle r =
2
A B C 1 3 3 3
Also exradius r1 = 4R sin cos cos = 4R . .  R
2 2 2 2 2 2 2
 r, R, r1 are in A.P.

x2 / 2
t2 
10. lim
x  
0
x 1  t
2 2 
dt =

form

2
x /2
t2 x4
 1  t  2
dt
4
x
x5 1
 lim 0
= lim 4  x = lim 5 = .
x  x2 x  2x x  2x  8 2
2 2
11. (3m + 1)(3n – 1) = 3n – 1, so if p divides 3n – 1, then it also divides 3n – 1
and hence also (3n2 – 1) – n(3n – 1) = n – 1, and hence also (3n – 1) – 3(n – 1) = 2.
So 3n – 1 = 0, ± 1 or ± 2.
But n must be an integer, so 0, 1, – 2 do not work. – 1 gives n = 0 and hence m = 0, which is a
solution. 2 gives n = 1 and hence m = 0, which is a solution.
 10

12. Two lines can meet in a point

 6C2 = 15
6 4
line and circle meet in two points = ( C1  C1)  2 = 48.
4
Two circles meet in 2 points = C2  2 = 12
total number of points = 48 + 15 + 12 = 75.

   7  
13. 1 + cos3x+ 1 – cos    2x    = 0
 2  6  
3x  2 
2cos2  1  cos  2x  0
2  3 
3x  
2cos2  2 sin2  x    0
2  3 
3x  
cos  0 , sin  x    0
2  3
  2 7
x = ,  and x = , , , …..
3 3 3 3

x= is the common value which satisfies both
3
 
 x = 2n + = (6n + 1)
3 3

 1 
(x 2  1) 1  2 
 x 
15.  (x 4  1
 x 2  1)co t 1  x  
dx =
  2 1
x   2  1

co t 1 
x 
1
dx
   
 x  x2   x
dt
=  (t 2
 1)cot 1 t
1  1
Put x   t   1  2  dx  dt
x  x 
 du
=  u
Let cot1 t = u
1
  dt  du =  ln|u| + c
(1  t 2 )
 1
=  ln cot 1  x    c
 x

 70   70   70 
16.  3    9    27   23  7  2  32
     
 11

17. Let  be the period of sinx + cosax then

sin( + x) + cosa( + x) = sinx + cosax for all x
In this identity, putting x = 0 and x = , we het
sin + cosa = 1 and 1 =  sin + cos
solving these equation, we get
sin = 0 and cosa = 1
hence  = n and a = 2m. Where m, n are non–zero integers
a 2m 
hence 
 n
2m
or a = (since   0)
n

18. A2 = 0, A3 = A4 = … = An = 0
then A(I  A)n = A(I + nA)
= A  nA2 = A.

19.  = sin2A + sin2(135 – A) = 1 + sin2A – sin2(45 – A)

1
= 1+ sin45  sin(2A – 45) = 1 +
2
.sin 2A  450  
2 1 1
=< and  >
2 2
0 < A < 135
0 < 2A < 270
– 45 < 2A – 45 < 225
1
–
2

 sin 2A  450  1 
1 1 2
  sin2 A  sin2 B  .
2 2
2 2
20. The curve xy = c and the circle x + y = 1 touches each other so
c2
x2 + –1=0  x – x +c =04 2 2

x2
will have equal roots so (– 1)2 – 4c2 = 0  4c2 = 1
2 1 1
c = c= .
4 2
1 1
Roots of the equations x 4  x 2   0 are x = 
4 2
1
y=  .
2
Clearly distance between the points of contact = 2 units
 2 x 3/2 x 3 x 3
1. x(f(x))2 – x2f(x) =  xf  x    2  x  f x 
2

4

4
2
 x 3/2  x3
 x f x   
 2  4
1 1 3 2
 x 3/2  x
 B – A =   x f  x   dx   dx
0
2  0
4
1
A–B
16

2. Say,  < 0

  
 |I + A2| = |I – 2A2| = |I – A||I + A|
As, A = –A
I – A = I + A = (I + A)  |I + A2| = |I + A||I + A| = |I + A|2  0
Same, can be seen for   0

3. If x > 2 then x3 – 3x > 4x – x = x  x  2

 |x|  2 take x = 2 cos  for some   [0, ]
 2cos3  2 1  cos  
7 5
 2sin  sin 0
4 4
4 4 
  = 0, ,
7 5
4 1
 x = 2, 2cos ,  1  5
7 2
 
4. B2 – tr(B)·B + I = 0
 AB – (tr(B)A + AB–1 = 0
 tr(AB) – tr(A)tr(B) + tr(AB–1) = 0

5. Using property