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Petrology PETROGENESIS
A branch of petrology dealing with the origin and formation of
rocks. Involves a combination of mineralogical, chemical and
field data.
Petrologic, petrographic, and petrogenetic studies can be applied
to igneous, metamorphic or sedimentary rocks.
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The Earth’s Interior
Core:
Fe-Ni metallic alloy
Outer Core is liquid
No S-waves
Inner Core is solid
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-Systems of nomenclature and classification may reflect:
genetic, textural, chemical or mineralogical features. -TEXTURAL
basic system which classifies rocks on the basis of where aphanitic - fine grained < 1 mm
they form. phaneritic - medium grained 1 to 5 mm
coarse grained (pegmatitic) > 5 mm
plutonic - at depth
hypabyssal - intermediate depth This system has the same shortcomings as a genetic
volcanic - on the Earth's surface. classification, however specific textures present may aid in
classification, e.g., phenocryst, ophitic, coronas, but these are
This system is not very practical, but it serves as a first not indicative of a specific environment of formation or a
approximation, it tells nothing about mineralogy, chemistry of specific lithology.
the rocks and can not distinguish basalt from rhyolite.
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-CHEMICAL
MINERALOGICAL
This type of classification requires a complete
chemical analysis of the rock
The one gaining application is the result of several
years work by the IUGS Subcommission on the
A chemical classification system has been
Classification of Igneous Rocks or Streckeissen
proposed for volcanic rocks and a comparable
Classification.
scheme for plutonic rocks is not available.
This leaves us with a system based on mineralogy.
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Several aspects which historically have played and continue to
play a role in the classification of igneous rocks should also be
considered.
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COLOUR GRADATION
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Composition of Earth shells
-Modern chemical analyses of igneous rocks Elements wt%
generally include a major elements analyses and Crust Mantle Core
minor or trace elements analyses. Continental Oceanic Upper Lower Outer Inner
O 41.2 43.7 44.7 43.7
10--15
Si 28 22 21.1 22.5
- Earth is composed almost entirely of 15 elements,
Al 14.3 7.5 1.9 1.6
12 of which are the dominant elements of the crust. Fe 4.7 8.5 5.6 9.8 80--85 80
Ca 3.9 7.1 1.4 1.7
- The crustal elements, considered to be the major K 2.3 0.33 0.08 0.11
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Table 8-3. Chemical analyses of some
Oxide Wt. %
representative igneous rocks
SiO2 49.20 Peridotite Basalt Andesite Rhyolite Phonolite
TiO2 1.84 SiO2 42.26 49.20 57.94 72.82 56.19
Al2O3 15.74 TiO2 0.63 1.84 0.87 0.28 0.62
Al2O3 4.23 15.74 17.02 13.27 19.04
Fe2O3 3.79
A typical rock analysis Fe2O3 3.61 3.79 3.27 1.48 2.79
FeO 7.13
FeO 6.58 7.13 4.04 1.11 2.03
For Major Oxides. MnO 0.20
MnO 0.41 0.20 0.14 0.06 0.17
MgO 6.73 MgO 31.24 6.73 3.33 0.39 1.07
CaO 9.47 CaO 5.05 9.47 6.79 1.14 2.72
Na2O 2.91 Na2O 0.49 2.91 3.48 3.55 7.79
K 2O 1.10 K2O 0.34 1.10 1.62 4.30 5.24
H2O+ 0.95 H2O+ 3.91 0.95 0.83 1.10 1.57
(O)
Total 98.75 99.06 99.3 99.50 99.23
Total 99.06
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Al2O3 Saturation
Rock Classification (Silica saturation) Four subdivisions of rocks independant of silica saturation,
based on the molecular proportions of Al2O3, Na2O, K2O
Oversaturated - contains primary silica mineral and CaO applied mainly to granitic lithologies.
Saturated - contains neither quartz nor an unsaturated
mineral Peraluminous - Al2O3 > (Na2O + K2O + CaO)
Unsaturated - contains unsaturated minerals Metaluminous - Al2O3 < (Na2O + K2O + CaO) but Al2O3 >
(Na2O + K2O)
Subaluminous - Al2O3 = (Na2O + K2O)
Peralkaline - Al2O3 < (Na2O + K2O)
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Bivariate (x-y) diagrams
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Oxides ( K2O, Na2O, 10
CaO,MgO, Al2O3) plotted Al2O3
MgO
against Silica (SiO2) form 17
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linear arrays.
A set of such plots is called a
Harker Diagrams Harker diagram. 12 0
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FeO* 10
10
With increasing Silica the CaO
The oldest method is the variation diagram or Harker diagram which dates
from 1909, and plots oxides of elements against SiO2. following trends are 5
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evident:
FeO, MgO and CaO decrease 0 0
in abundance. 4
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Na2O 3
K2O and Na2O increase. 4 K2O
2
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Trace Elements
ppm
Note
magnitude
of trace
element
wt %
changes
ppm
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Triangular Variation Diagrams
These diagrams visually present the variation in 3
chemical parameters. Two are commonly used:
AFM - Mainly for Mafic Rocks
A = Na2O + K2O
F = FeO (+Fe2O3)
Triangular Variation Diagrams M = MgO
Plotted as either molecular or weight percent values.
Na2O - K2O - CaO - Mainly for Felsic Rocks
Uses either the molecular or weight percent values for the
three oxides listed.
Data may be plotted as weight percent oxide or atomic
percent of the cations. The disadvantage to this is that
the absolute values of the analyses are not readliy
determined.
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Ternary Variation Diagrams Table 9-6 A brief summary of some particularly useful trace elements in igneous petrology
V, Ti Both show strong fractionation into Fe-Ti oxides (ilmenite or titanomagnetite). If they behave
(alkalis-FeO*-MgO) differently, Ti probably fractionates into an accessory phase, such as sphene or rutile.
Zr, Hf Very incompatible elements that do not substitute into major silicate phases (although they may
replace Ti in sphene or rutile).
Triangular variation Ba, Rb Incompatible element that substitutes for K in K-feldspar, micas, or hornblende. Rb substitutes
less readily in hornblende than K-spar and micas, such that the K/Ba ratio may distinguish these
diagrams show only phases.
the ratios of various Sr Substitutes for Ca in plagioclase (but not in pyroxene), and, to a lesser extent, for K in K-
feldspar. Behaves as a compatible element at low pressure where plagioclase forms early, but
as an incompatible at higher pressure where plagioclase is no longer stable.
oxides or elements, REE Garnet accommodates the HREE more than the LREE, and orthopyroxene and hornblende do
so to a lesser degree. Sphene and plagioclase accommodates more LREE. Eu 2+ is strongly
rater than their partitioned into plagioclase.
actual values. Y Commonly incompatible (like HREE). Strongly partitioned into garnet and amphibole. Sphene
and apatite also concentrate Y, so the presence of these as accessories could have a
significant effect.
Table 9-6. After Green (1980). Tectonophys., 63, 367-385. From Winter (2001) An Introduction to Igneous and
Metamorphic Petrology. Prentice Hall.
K2O + Na2O MgO
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Trace elements as a tool to
determine paleotectonic
environment
• Useful for rocks in mobile belts that are no Table 18-4. A
SiO2 is generally chosen because it is the most • Harker diagrams: SiO2 vs. oxide.
abundant oxide in igneous rocks and exhibits a wide • The meaning of geochemical trends: can be
variation in composition. This type of graphical
interpreted as magmatic
presentation is useful for large quantities of analytical
data and yields an approximation of inter-element “evolution” from “primitive” to “differenciated”
variations for a group of samples. rocks. More or less implicitly
assumes fractional crystallization.
No genetic link can be inferred from Harker diagrams, • The nature of the phases crystallizing can be
i.e. that the lowest SiO2 content present on the inferred from the shape of the
diagram represents the original or first liquid, for the
trends. Ex.: decreasing Fe, Mg = precipitation
group of samples presented, from which all other
liquids were derived. of mafic minerals.
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Magmatic series: reflect first order differences between rock
Alkali vs. Silica diagram for Hawaiian volcanics:
groups.
Seems to be two distinct groupings: alkaline and subalkaline
• TAS diagram separates alkali and sub-alkali series
• Sub-alkali series are further separated on the basis of their 12
Fe-Mg contens
(AFM diagram) into tholeitic and calc-alkaline 10
In addition, important role of the relative proportions of Al2O3
and CaO-Na2O-K2O
8 Alkaline
• A>CNK: Peraluminous rocks. Have Al-rich minerals such as
biotite,
muscovite, garnet, cordierite… 6
• A<CNK:
o .. and A>NK: Metaluminous. No particular minerals, mafics 4
are
pyroxene, amphibole, biotite 2
Subalkaline
o .. and A<NK: peralkaline rocks. Alklai-rich minerals such as
alkali 40 55 60 65
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amphiboles and pyroxenes. %SiO2
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To obtain a genetic link between
analyses of a given suite of samples
fractionation indices were developed.
These indices attempt to the results of
Fractionation Indices chemical analyses from an individual
igneous suite into their correct
evolutionary order. These indices are not
realistic but several come close to such
an order.
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MgO Index
This is used for basaltic rocks. Positive correlations are Two fractionation indices, based on complex equations have
produced for Na2O, K2O, and P2O5 indicating enrichment been suggested for more comprehensive use.
in these oxides with successive liquids. Negative Solidification Index (Kuno, 1959)
correlations result for CaO. SI = 100 MgO/(MgO+FeO+Fe2O3+Na2O+K2O)
Mg-Fe Ratios For basalts this is similar to Mg/Fe ratios due to the relatively
Again used for basaltic rocks. These involve a ratio of Mg to Fe: poor alkali content. As fractionation progresses the
MgO/MgO+FeO (ferrous) residual liquids become enriched in alkaliis, thus Na2O
MgO/MgO+FeO+Fe2O3 (ferric) and K2O contents offset the Mg-Fe index. For mafic rocks
Mg/Mg+Fe (uses atomic proportions of the cations). SI is high, for felsic rocks SI is low.
Normative Ab/Ab+An Differentiation Index (Thornton and tuttle, 1960)
Based on the values of Na2O and CaO. Only good for rocks DI = normative Q+Or+Ab+Ne+Ks+Lc
which crystallize plagioclase, not effected by mafic mineral This is based on the normative analyis results. For mafic
formation. Generally applied to granites. rocks DI will be low, because in normative calculation
The above three indices are only good for specific lithologies, these minerals are minor. Felsic rocks DI will be high
and thus have a restricted application. because these minerals are abundant in the norm.
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Alkali vs. Silica diagram for Hawaiian volcanics:
Seems to be two distinct groupings: alkaline and subalkaline
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10
8 Alkaline
2
Subalkaline
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%SiO2
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Calc-alkaline
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biotite pyroxene aegirine
muscovite hornblende riebeckite
cordierite biotite arfvedsonite
andalusite
garnet CaO
CaO
CaO K2O
moles
Alkaline
K2O Calc-alkaline
Tholeitic
Al2O3 K2O Al2O3 Al2O3
Na2O Na 2O
Na2O
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- B. Normalization and spidergrams
1. What is “normalization”, and why do it?
Abundance of elements varies greatly in the Earth:
• Different families of elements are more or less present
• Even within a family, nucleosynthesis results in huge variations
2. Spidergrams
Spidergrams allow to
• See many elements at a time
• Compare elements with large differences of absolute abundance (log scale!)
• To some degree, make petrogenetic interpretations
Making a spidergram
• For each sample, arrange elements in order of increasing compatibility (i.e.,
MODAL ANALYSIS
the more incompatible at the left). (technically, this implies a different order
for each different source!).
• Plot the normalized value of each elements (log scale!)
• Link the dots
• Look at the “anomalies”!
Some classical spidergrams:
• REE diagrams (n’ed to chondrites or PRIMA=PRImitive MAntle in general)
• Multi-element diagrams for incompatible elements (N’ed to
PRIMA/chondrites, or to MORBs)
• PGE diagrams
• Transition metal diagrams
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MODAL ANALYSIS
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Advantages
One can compare rocks from different areas if you
only have a thin section, no chemical analysis is
required, using a petrographic microscope.
Gives the maximum and minimum grain sizes.
NORMATIVE ANALYSIS OR NORM
Disadvantages
Meaningless if the sample has a preferred orientation
of one or more minerals.
Porphyritic rocks are difficult to count.
Total area of sample must be sufficiently larger than
the max. diameter of the smallest grain size.
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