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6. Given the following data, select the best indicator for the titration of iron(II) with
thallium(III), using a S.C.E. reference electrode.
9. Which of the following titrants would give the sharpest change in voltage (i.e., the
steepest titration curve) for a given analyte?
(a) MnO4-
(b) I3-
(c) Cr2O72-
10. Which of the following titrations would give a titration curve symmetric around
the equivalence point?
(a) Na2S2O3 titrated with I2.
(b) Ascorbic acid titrated with I2.
(c) As4O6 titrated with I2.
11. A Jones Reductor is used to adjust the oxidation state of the analyte before it is
titrated. An example of this use would be
(a) the conversion of Mn2+ to MnO4- to be titrated with standard Fe2+.
(b) the reduction of Fe3+ to Fe2+ to be titrated with MnO4-.
(c) the addition of stannous chloride (SnCl2) to Fe3+ in hot HCl to reduce the iron to
Fe2+.
12. A 20.0 mL solution of 0.00500 M Pb2+ in 1 M HCl was titrated with 0.0200 M Ce4+
to give Pb4+ and Ce3+. What is the equivalence point volume of Ce4+ to be added?
(a) 10 mL
(b) 20 mL
(c) 5 mL
13. A 20.0 mL solution of 0.00500 M Pb2+ in 1 M HCl was titrated with 0.0200 M Ce4+
to give Pb4+ and Ce3+. Which expression is correct for the potential of the indicator
electrode at the equivalence point? Eo for Ce4+/Ce3+ = 1.47 V and Eo for Pb4+/Pb2+ =
0.139 V.
(a) 2Ec = 1.609 V - 0.059log([Pb2+][Ce3+]/[Ce4+][Pb4+])
(b) 3Ec = 1.748 V - 0.059log([Pb2+][Ce3+]/[Ce4+][Pb4+])
(c) 3Ec = 1.609 V - 0.059log([Pb2+][Ce3+]/[Ce4+][Pb4+])
14. A 20.0 mL solution of 0.00500 M Pb2+ in 1 M HCl was titrated with 0.0200 M Ce4+
to give Pb4+ and Ce3+. What are the correct concentration relationships at the
equivalence point?
(a) [Pb4+] = [Ce3+] and [Pb2+] = [Ce4+]
(b) ½[Pb4+] = [Ce3+] and ½[Pb2+] = [Ce4+]
(c) [Pb4+] = ½[Ce3+] and [Pb2+] = ½[Ce4+]
15. A 20.0 mL solution of 0.00500 M Pb2+ in 1 M HCl was titrated with 0.0200 M Ce4+
to give Pb4+ and Ce3+. Calculate the cell potential versus a S.C.E. at the equivalence
point? E° for Ce4+/Ce3+ = 1.47 V and E° for Pb4+/Pb2+ = 0.139 V.
(a) 1.507 V
(b) 0.583 V
(c) 0.342 V
16. If you are titrating a mixture of tin(II) and platinum with a Ce4+ solution, which
species will be oxidized first? E° for Ce4+/Ce3+ = 1.47 V, E° for Pt2+/Pt = 1.18 V, and
E° for Sn4+/Sn2+ = 0.139 V.
(a) Sn4+
(b) Sn2+
(c) Pt