SCHOLARS EMPIRE

SR. CO JEE ADVANCED

TIME : 3:00 2013_P2 MODEL MAX MARKS : 180

KEY & SOLUTIONS

PHYSICS

1 2 3 4 5 6 7 8 9 10
B,D A,C A,B B,C,D A,C B,C D B,C B C
11 12 13 14 15 16 17 18 19 20
C B A C A B B C A D

CHEMISTRY

21 22 23 24 25 26 27 28 29 30
D B B,D C, D C B,C,D A,C,D C,D C B
31 32 33 34 35 36 37 38 39 40
A B D B D A B C A D

MATHS

41 42 43 44 45 46 47 48 49 50
B,C,D A,B,C,D A,B,D A,B,C,D A,D A,B A A,B,C,D A B
51 52 53 54 55 56 57 58 59 60
A A A A D C B A A C

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 SOLUTIONS
PHYSICS
1. Charging battery is removed. Therefore, q = constant Distance between the plates is
increased. Therefore, C decreases.
1 q2
Now, V = again q is constant and C is decreasing. Therefore U should increase.
2 C
 Correct options are (B) and (D).
2. Charge on capacitor increases with time
q
 potential VC  increases too
C
 Curve I is for VC

and curve II is for VR as current will decrease with time.

Also VR  VC  
VR  VC  V0  V0  2V0 (when both were equal)

V1  V1  V2   2V0

2V1  V2  2V0

dq
3. Current through branch containing capacitor is,  I  3e t amp .
dt
At t= 0, I = 3A in downward direction, i.e., towards P. Let V is the potential of point P
then
q 0
20 - V = + 3´ 1 = + 3 = 3
C 1
Þ V = 17 volt

Current through branch containing capacitor is,

18 - 17
I2 = = 1A again towards P.
1
17
Applying KCL at P, current through R is 4A and potential difference across R is
4

 
t

4. Charge on capacitor C as a function of time is, q1  C  1  e 2 RC

 
 
t

Charge on capacitor 2C as a function of time is q2  2C 1  e 2 RC

 

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5. Current in ‘R’ will be zero in steady state
20 V 2
I q q
R +- 6V + -
A B
I 6 F 3 F

10 V 3

20  2 I  3I  10  0
 I  2A

VA  20  4  VB

VA  VB  16V

q q
16     6  
6 3
q  22  2  44 C

6. For converting it to voltmeter ‘R’ is joined in series cross checking the options

50  A 100  R
A B

VAB  50 100  R 

For R  10 103 
VAB  50 100  100 100  106 V

 50 100 100 106  50 102

For R  200 103 

VAB  50 106 100  200 103 

 50 106  2 105  10V

For converting to ammeter low resistance in parallel

50  A 100 

1  50  A

For R  1, I  5 103

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 5 103 1  50 106 100
5 103 1  5 103 i.e., it statisfied.
æ R¢ö
çç R + ÷ ÷R
7. è k ø
= R¢
R¢
2R +
k

RR¢ R¢2
R2 + = + 2 RR¢
2 2
Rr r 2 3rR
R2 + = +
2 2 2
æ 3r ö r 2 9r 2
2

çç R - ÷ ÷ = +
è 4ø 2 16
17 r 2
=
16
æ3 + 17 ö
R = çç ÷r
÷
è 4 ø
8. Conceptual
Passage (9 – 10)
9. The forces acting on the dielectric are electrostatic attractive force of field of capacitor
and its weight. The block will slip when
FE  mg   Mg

M M
FE  g g
4 6
1  0l Mg
 K  1  2 
2 d 12

Mg 2d
 min  
12  0l  K  1

Mgd

6 0l  K  1

10. Now   2Vmin . In this case the block will accelerate

Dielectric : FE  mg  T  ma …..(1)
Block : T   Mg  Ma …..(2)
Eqn (1) and (2) give
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 FE   m   M  g
a
mM
1  0l
As FE   K  1  2
2 d
1  0l Mgd
  K  1  4   2 Mg
2 d 6 0l  K  1

M
2 Mg  g
Thus a  12  23 g  6  138 g
7M 7 7
6

From equation of motion, v 2  2as, we have

 138 g 
v2  2    l  b
 7 

276
v g l  b 
7

Passage (11 – 12)

dr t
11. =
dq 2p
dl » rdq
rdr 2p
dl =
t
2p R 2
L=
t
tL
R»
2p
For the circuit given teffective = (t1 + t2)2
12. Conceptual
Passage (13 – 14)
13. When the jockey is not connected.

I
16r
Resistance per unit length ;
15r
  / cm
600

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 Let l be the length when we get zero deflection.
 x  r
x

l O r
x
 A

x 2 r


x
2

    15r
    l    l
2 2 16r 600
 l  320 cm

14. Let potential at A is zero

Then apply kirchhoff’s first law

x 0  x    0  0
x0 2
 
14r r 2r
14
x 
22

  14  
x  
Ig  2   22  2  3
r r 22r
Passage (15 – 16)
- 30 + i2 ( 6) +( i2 - i1 ) 3 = 0

9i2 - 3i1 = 30

3( i1 - i2 ) + 3i1 +15 = 0

2i1 - i2 + 5 = 0

3( 2i1 + 5) - i1 = 10

5i1 = - 5

i1 = - 1

i2 = 3 A

17. A –s ; B – p,s ; C – p,r ; D – q, r

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 A) At constant charge, the electric field within the capacitor remains same when plate
V
separation is changed. The electric field in capacitor is E  . Hence at constant
d
potential difference the electric field decreases with increases in d.
1 Q2
B) U  . Hence at constant charge U increases with decreases in C.
2 C
1
U  CV 2 . Hence at constant potential difference U decreases with decreases in C.
2
C) capacitance increases on insertion of dielectric.
D) As a result of insertion of dielectric the capacitance increases.
1 Q2
U . Hence at constant charge U decreases with increase in C.
2 C
1
U  CV 2 . Hence at constant potential difference U increases with increase in C.
2
18. A–p;B–r;C–q;D–p
The initial charge on capacitor
 CVi  1 2 C  2 C

The final charge on capacitor

CV f  1 4  C  4 C

 Net charge crossing the cell of emf 4V is

q f  qi  4  2  2 C

The magnitude of work done by cell of emf 4V is

W   q f  qi  4  8 J

The gain in potential energy of capacitor is

U  C V f2  Vi 2 
1
2
1
   42  22   J  6  J
2
Net heat produced in circuit is
H  W  U  8  6  2  J

19. Conceptual

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20. Conceptual

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 CHEMISTRY
21. SO  H 2 SO4  SO  SO2  H 2O
2
3
2
4

K 2Cr2O7  H 2 SO4  3SO2  K 2 SO4  Cr2  SO4 3  H 2O

( Green )

22. Na2 SO3  2 HCl  2 NaCl  SO2  S  H 2O

( A) (B) Yellow
ppt .

K 2Cr2O7  H 2 SO4  SO2  Cr2  SO4 3

23. In alkaline medium both ppt as ZnS, CuS with H 2 S gas with NH 3 both these form
soluble complexes
24. BaSO4 is insoluble in HCl, But BaCl2 is soluble in dil HCl acidified dichromate turn

green with SO2 but not with CO2 .



25. Hg 2  2 I   HgI 2 

2I
HgI 42
 red  colourless

Hg 2  Co 2  4SCN   Hg Co  SCN 4  

26. Conceptual
27. Conceptual
28. Covalent chlorides do not respond to chromyl chloride test, e.g., SnCl4, HgCl2
29. Conceptual
30. Conceptual
Passage (31 – 32) :-
ZnCO3   ZnO  CO2
(A) (C) (B)
CO2  Ca  OH2  CaCO3  H2O
(B)
 Ca HCO3 2
CaCO3  H2O  CO2 
ZnO  2HCl 
 ZnCl2  H2O
2ZnCl2  K 4 Fe  CN6  
 Zn2 Fe  CN6   4KCl
White ppt.
ZnCl2  H2S   ZnS  2HCl
(D)
White ppt.
31. Pb, Cu, Cd, Bi Sulphides are soluble in HNO3
32. P = Pb(CH3COOH)2, Q = Pbl2
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33. Bottle 4 contains blue solutin  copper II sulphate.
Bottle 3 + Bottle 4  Blue ppt
Suggests bottle 3 contains sodium carbonate
It gets confirmed the observation.
Bottle 2 + bottle 3  colourless gas  CO2
34. Hence, Bottle 3  sodium carbonate
35. Conceptual
36. Conceptual
37. Conceptual
38. Conceptual
39. Conceptual
40. Conceptual

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 MATHS
41. Add 1 & sub tract 1 in numerator and then apply by parts
sin 2 x 2 tan x sec 2 x
42. I  dx   tan 4 x  1 dx
sin 4 x  cos 4 x
Put tan 2 x  t  2 tan x sec 2 xdx  dt

 tan 1  t   C   cot 1  tan 2 x   C
dt
 2
t 1 2
 1 
  cot 1  tan 2 x   C1   cot 1  2 x   C1  cot 1  cot 2 x   C1
 cot 
1  tan x  1  cos 2 x 
2
Also cos 2 x     tan x , using these values in given integral
2

1  tan x  1  cos 2 x 
2

sin 2 x 2sin 2 x
I  dx   dx
 cos2 x  sin 2 x   2sin 2 x cos2 x  cos 2 x   1
2 2

Put cos 2 x  t   2sin 2 xdx  dt

dt
I     tan 1 t  C2   tan 1  cos 2 x   C2
t 1
2

dx dx
43. I  
x  x2 1  1
2

 x  
4  2
 1
x 
 sin 1 
2
 sin 1  2 x  1  C ……(1)
1/ 2
dx 1
Also I   put x  t  dx  dt
x 1 x 2 x
2dt
I    2sin 1 x  C ……(2)
1 t 2

Now let   sin 1  2 x  1

 sin   2 x  1 cos   1   2 x  1  2 x  x 2
2

   cos 1 2 x  x 2
44. Case – I 0 < a < b
x  x
b
x
Then 
a
x
dx  b  a

Case – II a < 0 < b

b 0 b
x x x
Then 
a
x
dx   dx   dx  a  b
a
x 0
x
Case – III a < b < 0
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 b b
x
Then  dx    1 dx  a  b
a
x a
b
x
 dx  b  a
a
x
x  x x 
f x      cos t  sin t  dt    cos t  sin t  dt    sin t  cos 4 t  dt
4 4 4 4 4
45.
0 0 x
x 
 f  x    sin t  cos 4 t  dt
4

x

Put t  x  y  f  x     sin 4 y  cos 4 y  dy  f  x   f  
0

46. Apply Leibnitz Rule and differentiate f 1  f  x    x

47. Put e x  t then divide and integrate
1
48. Put t  and convert then add and integrate
u
Passage (49 – 50)
Follow the instructions in passage
Passage (51 – 52) :
 tan x  cot x   tan x  cot x  dx
51. I   tan x  cot x dx  2   2  tan x  cot x 

I  2
d  tan x  cot x   tan x  cot x 
 2 tan 1    C
 
2
tan x  cot x 2  2 

3   sin x  cos x 
52. If x    ,  , then I    tan x  cot x  dx      dx
 2    cos x  sin x 
sin x  cos x 2d  sin x  cos x 
  dx     2 sin 1  cos x  sin x   C
1   sin x  cos x 
2
sin x.cos x
Passage (53 – 54)
Apply the differentiation given in the passage
Passage (55 – 56) :
For the integral to be defined in  0,   ,  1  x  1
   
1 1  
f ' x   d   d  0 g   d  0 g     d 
0
1  x cos  0
1  x cos  

2
 2 f ' x   d
0
1  x cos 2 
2

  /2  /2 
d d sec 2  d dt
f ' x    2   2   2 2
0
1  x cos 
2 2
0
1  x cos 
2 2
0
1  tan   x
2 2
0
t  1  x2

 1
1 t  
2  tan    f  x    sin 1 x  k
1 x 
2
1  x 0
2
1 x 2

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 
ln1
But f  0    d  0  f  x    sin 1 x
0
cos 
  2  2    
Range of f  x    ,  ( Range of sin 1 x   , )
 2 2   2 2
f (x) is differentiable in the interior of its domain and f '  x   0 has no solution.
Hence f(x) has no critical points.
f  x    sin 1 x , x   1, 1
Applying Lagrange’s theorem
f 1  f  1  2 2 4
f ' x    x    1,1
1   1 1  x2 2 

57. Conceptual
u
58. a) v  0  a  b , Also a  b  u  a 
2
Now,
1 dx 2 dx 2 1 x 2 x
I      sec 2 dx  tan  C
a 1  cos x u 2 cos 2 x u 2 2 u 2
2
b) v  0  a  b
x
sec 2 dx
dx dx
Now, I     2
a  b cos x x x
 a  b   2b cos 2  a  b    a  b  tan 2
2 2
x 1 x
Put tan  t  sec2 dx  dt
2 2 2
2dt 2 dt
I     ……..(1)
a  b  a  b  t a  b t 2   a  b 
2

 
 a b 
2 a b  a b  2  v x
 tan 1  t   C  tan 1  tan   C
a b a b  ab  uv  u 2
c) v  0  a  b  0  b  a  0
2 dt
Now I 
ba  a  b 2
(using equation (1) of part (B))
t
ba
59. A)
tan x cot x
t 1
B)  
1/ e
1 t2
dt   t 1  t  dt
1/ e
2

1
Put t 
x
 1 
tan x tan x
t t
  1 t2
dt   1
dx.   2  dx
1   x 
1  2 
1/ e e
x x 
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 e
1 
tan x e e
dt   ln 1  t 2    1
t x t

1/ e
 2
 
1  t tan x 1  x 2
dx  
1/ e
1 t 2
2 1/ e
C)
n
2 1/2 2/3 3/4 n 1 2

D)  f  x  dx   1. dx   1. dx   1. dx  ...   1. dx  ...   1. dx
0 0 1/2 2/3 n 1 1
n

1 2 1 3 2  n n 1  n
            ...      ...  1   ...  1 as n  
2 3 2 4 3  n 1 n  n 1
Taking limit n  
2
We get  f  x  dx  1  1  2
0
1 1
 1/4 3/4
1
1

60. A)  f  x  dx  2 f  x  dx  2   x dx   dx   1  x  dx 
1 0 0 1/4
4 3/4 

1 1 1 1 1 1 1 1 3
 2         
2 4 4 4 2 2 4 4 8

B) f '  x   x 2  x  1  0  x  R

 f(x) is increasing in x   3, 4  so minimum at x = 3 and maximum at x = 4

3
 t 3 t 2  15
 min f  x     t 2  t  1 dt     t  
0 3 2  2
4
 t 3 t 2  52
max f  x     t  t  1 dt     t  
2

0 3 2  3
59
max f  x   min f  x  
6
c) Conceptual
n n 1
n 1 1 1
d) I  lim   lim  .  dx
 
2 2 2
n 
r 1  r  n 
r 1 r r  n 0 x 3 x 4
r .n  3  4  3  4 
 n  n n 

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14
p
 7
2 dz 1
3 4 z 2 14
Put z  3 x  4  I  

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15
p