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By understanding the relationship between moles and Avogadro's number, scientists can convert between number of
moles and number of atoms.
Convert between the number of moles and the number of atoms in a given substance using Avagadro's
number
Terms[ edit ]
mole
The amount of substance of a system that contains as many elementary entities as there are atoms in 12 g of
carbon-12.
Avogadro's number
The number of atoms present in 12 g of carbon-12, which is 6.022×1023 and the number of elementary
entities (atoms or molecules) comprising one mole of a given substance.
Avogadro's number is typically dimensionless, but when it defines the mole, it can be expressed as 6.022×10 23
elementary entities/mol. This form shows the role of Avogadro's number as a conversion factor between the number
of entities and the number of moles. Therefore, given the relationship 1 mol = 6.022 x 1023 atoms, converting
between moles and atoms of a substance becomes a simple dimensional analysis problem.
For example, if scientists want to know how may atoms are in six moles of sodium (x = 6), they could solve:
6 moles⋅6.022×1023atoms1 mole=3.61×1024atoms
Note that the solution is independent of whether the element is sodium or otherwise.
This can be written without a fraction in the denominator by multiplying the number of atoms by the reciprocal of
Avogadro's number:
For example, if scientists know there are 3.5⋅1024 atoms in a sample, they can calculate the number of moles this
quantity represents:
Assign just this concept or entire chapters to your class for free.
Avogadro Number Calculations II
How Many Atoms or Molecules?
When the word gram replaces mole, you have a related set of problems which requires one more
step. So keep in mind that there are 4 example problems just above.
These problems use the reverse technique of the above. Once again, replacing mole with gram
adds one step to the procedure.
Pick the box of the data you are given in the problem and follow the steps toward the box
containing what you are asked for in the problem.
Solution:
Start from the box labeled "mole" and move (to the right) to the box labeled "atoms." What do
you have to do to get there? That's right - multiply by Avogadro's Number.
The unit on Avogadro's Number might look a bit weird. It is mol¯1 and you would say "per
mole" out loud. The question then is WHAT per mole?
The answer is it depends on the problem. In the first example, I used iron, an element. Almost all
elements come in the form of individual atoms, so the correct numerator with most elements is
"atoms." (I will leave you to figure out the exceptions.)
So, doing the calculation and rounding off to three sig figs, we get 2.71 x 1023 mol¯1 atoms.
Notice "atoms" never gets written until the end. It is assumed to be there in the case of elements.
If you wrote Avogadro's Number with the unit atoms/mole in the problem, you would be correct.
The same type of discussion applies to substances which are molecular in nature, such as water.
So the numerator I use here is "molecule" and the problem answer is 1.20 x 1023 molecules.
Once again, the numerator part of Avogadro's Number depends on what is in the problem. Other
possible numerators include "formula units," ions, or electrons. These, of course, are all specific
to a given problem. When a general word is used, the most common one is "entities," as in 6.022
x 1023 entities/mol.
Let us now continue with more solutions to the example problems above. Here are the same two
problems as before, but with gram replacing mole:
Look at the solution steps and you'll see we have to go from grams (on the left) across to the
right through moles and then to how many. So, for the first one it would be like this:
Practice Problems
Now, let's see how well you can do the opposite direction. The first two are the one-step type and
the second two are the two-step type.
5) Which contains more molecules: 10.0 grams of O2 or 50.0 grams of iodine, I2?
6) A solution of ammonia and water contains 2.10 x 1025 water molecules and 8.10 x 1024
ammonia molecules. How many total hydrogen atoms are in this solution?
Go to Answers for 1 - 6
Problem #7: How many atoms of chlorine are in 16.50 g of iron(III) chloride?
Solution:
2) Determine how many formula units of iron(III) chloride are in 0.1017 mol:
Problem #8: How much does 100 million atoms of gold weigh?
Solution:
1) Determine moles of gold in 1.000 x 108 (we'll assume four sig figs):
1.000 x 108 atoms divided by 6.022 x 1023 atoms/mol = 1.660577881 x 10¯16 mol
1.660577881 x 10¯16 mol times 196.97 g/mol = 3.271 x 10¯14 g (to four sig fig)
Problem #9: What is the mass of CH4 molecules if they are made from 15.05 x 1023 atoms?
Solution:
'x' atoms of C
'4x' atoms of H
x + 4x = 15.05 x 1023
3.01 x 1023 molecules divided by 6.02 x 1023 molecules/mol = 0.500 mole of CH4
Calculate mass:
0.500 mol times 16.0426 g/mol = 8.02 g (to three sig figs)
Problem #10: Suppose we knew that there were 8.170 x 1020 atoms of O in an unknown sample
of KMnO4. How many milligrams would the unknown sample weigh?
Solution:
2.0425 x 1020 formula units divided by 6.022 x 1023 formula units per mol
3.39173 x 10¯4mol
0.0536 g = 53.6 mg
Problem #11: A solid sample of cesium sulfate contains 5.780 x 1023 cesium ions. How many
grams of cesium sulfate must be present? (This question was formatted while in transit through
the Panama Canal, Nov. 7, 2010.)
Solution:
This is because there are 2 Cs atoms per one cesium sulfate formula unit.