Serial Number :-

REQUEST CUM AUTHORISATION FORM FOR EXPENDITURE ON ASSETS

Location : Bhavnagar Department : PROJECT Date :-
Capex Type : Planned AOP Refference No. :
Priority Index Vital Essential Desirable
Section-1 : Job Title
a) EHS g) Utility
b) New Project √ h) Infotech
c) Capacity Expansion i) Vehicle
d) Plant Modernisation / Improvement j) Soil Health Lab
e) Infrastructure k) R & D
f) ENCON - Equipment l) Others
Section-2 : Nature of Job
a) Building & Civil Work √ e) Instrumentation
b) Machine Equipment √ f) Infrastructure development
c) Electrical √ g) Furniture & Fixtures
d) Piping & Structural Work √ h) Others (Specify)
Section-3 : Brief Description Of Job with justification
a) Existing Facility / Method:-
Existing P2 pilot plant for diffrent product scale-up and process validation.

b) Proposed Scheme / Method:-

1) Modification in existing P2 pilot plant to create facility to take trials of CTZ, 3 step process
2) Procurement of load cell, Dosing pumps, MSGL Impeller etc.
3) Piping, structural & other modification.

c) Justification :-
Scale-up of Clothianidin manufacturing process from scale-up (3 Liter) to P2 Pilot plant 100 ltr) to validate process, data generation
for plant scale expansion, effluent treatibility study & solvent recovery/recycling validation.

d) AOP Budget : Rs 125 Lakh Sanctioned Budget : 17.50 lakh

e) Payback Period: Savings / Anuum:
f) Expected Cashflow Requirement :
g) Date of Start up 15.10.18 Expected Date of Completion 31.12.18
Section-4 : Attachment as Annextures
a) Technical Justification √ YES NO NR
b) Payback Period detail calculations YES NO √ NR
c) List of requirements with tentative cost √ YES NO NR
d) Tentative Project schedule / Bar Chart YES NO NR
e) Offer / Quotations √ YES NO NR
Prepared Project
Section Head H.O.D. G.M. Recommanded By Authorised By
By Engg
Signature
Name MPK KAS JDB MSG KRJ SDV AGM MRD RPC NDG
Date
Comments :-
 Page No. :- 01 of 02

Reviewed By Approved By
Signature
Name
Date
Copy To : a) HO b) Site
Page No. :- 02 of 02
N ASSETS

ata generation

Authorised By

NDG
Approved By
 Mass Balance of CTZ Stage-1
Updated In reference
Admin: of provided BFD of step-1 Ver 03 from R&D Operating Condition
Don't change values other
FACTOR 9.0 Kg than ''B3'' to
of MNG get outputs.
(99.30% Purity) Temperature Pressure/
Sheet M.B. is linked with °C Vacuum
BCT sheet.

MNG 9.00
37% HCHO 13.51
Toluene 17.87
Water 0.48
Charging RT ATM
40.9

Heating to 35°C Note: Heating to be done by HW only. 35°C ATM

40.9

Dropwise Addition
40% MeNH2 6.234 at 35-46°C & 35-46°C ATM
Heating to 50°C
47.1

Heating to 50°C (if 50±1°C ATM

required)
47.1

Cooking for 3 Hrs 1) Sample will be withdraw through bottom. 50±1°C ATM
47.1 Sample Analysis: MNG NMT 1.0%
Rxn Mass Nature : Creamish Slurry

Toluene 20.913 Toluene Charging Volume 50±1°C ATM

68.0 Sp.Gr. : 0.9302 73.11

Distillation loss 2.74

Distillation under
Dist. Toluene 3.60 55-60°C 500-640 mmHg
vacuum
 68.0 Dist. Water 14.61
18.2

Crystallization 19-20°C ATM

47.05
Note: If required, filtrate ml will be used to remove
remaining material from bottom dish
Toluene 8.933 Filtration Filtrate ML 41.4 19-20°C ATM
B.D: 0.5651 55.99 Filtration loss 0.34
SP.GR : xxxx LTR
0.028296 m3
Wet MNMTI
14.29 18.3924 0.77732278

18.3885
DMF 49.77 Bypass Circulation RT ATM
64.07
% of MNMTI 19.94

DMF+ MNMTI
RT ATM
solution
64.07 SP.GR : 0.97635
Toluene content? 65.62 LTR

Distillation Dist. Loss 2.3 55-60°C 500-610 mmHg

41.40 Dist. Toluene 38.3
44.568837 lLtr

Residue Cooling 30°C ATM

0.76

Residue Unloading 30°C ATM

0.76

Mol. wt of MNG:118.1, Mol wt of MNMTI:173.18

1) All Quantities are in kg.
2) Data Base on provided BFD of Ver 03 From R&D

Mass Balance of CTZ Stage-2

Operating Condition Admin:
BCT FOR
Kg of MNMTI with purity Temperature Pressure/ 1TPB
Basis: 64.07 12.78 on 19.94% purity
98.7% °C Vacuum

MNMTI Sol. 64.07 Charging RT ATM

Cat-30149 1.02 81
K2CO3 15.43
Toluene 0.00
Heating Note: Heating to be done by HW only. 40°C ATM
81

CCT Addition &

CCMT 13.56 40±1°C ATM
Reaction
DMF 12.81 107

Cooking 40±1°C ATM

107 Sp.GR.:1.0637 100.49 LTR

Filtration loss 2.2

DMF
23.85 Filtration 40±1°C ATM
Washing
131 Drying Dist.DMF 3 90-105°C Vacuum
21 B.D. loose: 0.7224
B.D. Pack:0.86
Filtrate ML
107.9 Waste to TSDF
Sp.Gr. 0.9669 111.58 17 B.D. loose: 0.6467
LTR B.D. Pack:0.8084

Product cocn. Rec.DMF 74.7 75-85°C 750-755mmHG

107.9 Loss 2.5
 Loss 1.4

Re-Distillation 1st Cut 6 95-105°C 600-620mmHG

Cooling & Transfer 74.7 30°C atm

of Conc. CTMT
Sp. Gr-1.5 30.75 20.50
LTR
Cooling to RT
(M.C.< 0.1%) 30°C atm
DMF
CMD-90 22.87 CMD-90 Treatment 67.07 70°C atm
30.75

Filtration loss 12.1

CMD-90
22.87 Filtration Filtrate ml 46.2
Washing
76

Distillation Loss 3.6 70-80°C 700-750mmHg

Drying 46.220 Rec.CMD-90 32.4 80°C Vacuum
Loose BD: 0.479 18.141
Pack BD: 0.6484
Crystallization 5-6°C atm
Dry CTMT 10.232
Loose BD: 0.5134 17.77
Pack BD: 0.6582

CMD-90 Washing 2.98 Filtration Filtration Loss 0.7 5-6°C atm

13.211 Filtrate ml 11.2

Drying 80°C Vacuum

1.286 Distillation Loss 0.1 70-80°C 700-750mmHg

11.227 Rec.CMD-90 5.9

Dry CTMT
1.276
Residue 30°C ATM
5.164
 Total Dry CTMT

19.048

Note & Assumption:

1) All Quantities are in Kg
2) Data Base on average of R&D Expt. 58,59 & 60.

Mass Balance of CTZ Stage-3

Operating Condition Admin:
BCT FOR 1T
Temperature Pressure/
°C Vacuum

CTMT 19.0
Water 91.95
Charging 30°C ATM
111

30-36°C ATM
35% HCl aq. 15.74 Dropwise addition After 30% HCl addition rxn mass become clear orange colur
127 solution

Heating at 40°C 40°C ATM

127

Cooking 40°C ATM

127

Cooling SP.GR.:1.0424 122 LTR 10°C ATM

127
Filtrate loss 8.40

Water
67.45 Filtration Filtrate ML-1 102.69 10°C ATM
washing-01
Hot Water
24.50 218.69 Wash treatment yet to be decided
washing-2
Loose B.D.: 0.5090 Filtrate ML-2 89.29
Packed B.D.: 0.6207
Avg. B.D.: 0.56485 Wet CTZ
18.31

Water 55.06 Repulping 80°C ATM

73.37
Wash treatment yet to be decided
Filtrate loss 7.77
Hot water 24.50 Filtration Filtrate ML-3 72.45 80°C ATM
Washing
97.87

Loose B.D.: 0.5892 Drying Drying loss 2.99 80 Vacuum

Packed B.D.: 0.7365 17.65
Avg. B.D.: 0.66285

Unloading Dry CTZ

14.66
Note:
1) All Quantities are in Kg
 Admin:
BCT FOR
1TPB

Dist. Water treatment process yet

to be decided water to b 3.6

400KG/HR, R.R. 2:1 water % in 0.2

total mass 18.0
time 0.0
 Admin:
BCT FOR
1TPB

recieving + filtration +washing

Recieving + heating + distillation
 Admin:
BCT FOR 1TPB

confirm time as in BFD heating +

cooking is 3 hrs

calculate time

calculate time
confirm time
Excel Crop Care Limited, Bhavnagar
New Pilot Plant
Equipment List for CTZ

Sr. Tag No. Operation MOC Capacity Location Available/ Maximum Cost of Remarks
No. New Batch Vol. new
(lit) equipme
nt

STEP-1
1 RB-801 Step-1 reaction vessel MSGL 100 ltr S.F Available 73 0 Minimum stirrable vol. : 10 lit
2 RB-801 Turbine agitator for MSGL 100 ltr vessel MSGL 100 ltr S.F Available - 0
3 P-802 Toluene transfer from drum to T-802 bx tank PP/PVDF 25 NB-AODD G.F. Available 0 PVDF is compatible with toluene
4 T-802 Toluene Batch tank SS-316 100 ltr T.F. Available 0 SS316 is compatible with toluene
5 H-1 Portable Hopper for MNG charging SS-316 80 NB-Dia S.F Available 0
6 P-817 Paristaltic pump for 37% HCHO addition SS-316 Body 100 ltr/Hr S.F Available 0
7 NEW Diaphragm pump for 40% MMA addition SS-316 Body 30 LPH S.F New 0.75 Addition time change to 20 min instead of
3 hours.
Exisiting Pump is of 5LPH capacity
whichneedsreplacement with 30LPH
Capacity. Addition qty. 7 Ltr in 20 Min.

8 T-811 Reflux pot for Dist Water separation SS-316 50 ltr S.F Available 0
9 T-1111 Ejector tank MS - G.F. Available 0
10 P-1111 Ejector pump CI - G.F. Available 0
11 T-1205 Buffer tank for ejector SS-316 - S.F Available 0
T-1204 Water pot SS-316 200 ltr S.F Available 0
P-803 For MNMTI DOM Filtration SS-316 25 NB-AODD F.F Available 0 Dom Batch
F-807 DOM filter for MNMTI Filtration SS-316 600 Dia T.F. Available 0 Wet Basis Cake Volm. is 23 Ltr 28 23
Working Capcity of Dom Filter is 28 Ltr
T-805 Filtrate Ml collection tank SS-316 200 ltr G.F. Available 47 0 Combine 3-4 Batches ML can be proceed to
distillation
P-804 Filtrate ml transfering pump PP/PVDF 1 m3/Hr G.F. Available 0
T-807 MNMTI Solution collection tank SS-316 160 ltr G.F. Available 53 0
P-807 MNMTI Solution transfering pump PP/PVDF 1 m3/Hr G.F. Available 0
- Load cell for DMF, MNMTI solution collection tank T- CI 1.5 Ton G.F. Available 0
807
STEP-2
R-802 Step-2 reaction vessel MSGL 250 ltr S.F Available 100 0 Min. Stirrable vol. 40 Ltr
Fresh DMF transfer from drum to R-802 SS-316 25 NB-AODD G.F. Available 0 Confirm Tag No.
pump
T-815 DMF Batch tank SS-316 200 ltr T.F. Available 40 0
- Reflux pot for cleaning to ensure moisture free SS-316 20 S.F Available 0
vessel
- Portable Hopper for K2CO3 & Cat-30149 charging SS-316 80 NB-Dia S.F Available 0
- CCMT + DMF Solution preparation tank Solution preparation to be decided with
R&D
 Paristaltic pump for CCMT addition SS-316 Body S.F Available 0 Addition qty. 26 Ltr in 60 Min.
Required Capacity :- 433 ml/min
Existing Electrolab Pump will give required
capacity with Tube size of 5*8 with 100
RPM

Pump for waste solid DOM Filtration & MNMTI SS-316 25 NB-AODD F.F Available 0 Confirm Tag No. Dom Batch
solution circulation pump

F-1202 DOM filter for waste solid Filtration SS-316 900 Dia T.F. Available 0 Wet Basis Cake Volm. is 29 Ltr 64 29
Working Capcity of Dom Filter is 64 Ltr
T-809 Filtrate ml collection tank MSGL 160 ltr G.F. Available 112 0
P-808 Filtrate ml transfering pump PP/PVDF 1 m3/Hr G.F. Available 0
ATFE for distillation (60% Concentration) Available 0 ATFE to be installed in plant 20
Vent Condenser of R-802 R-802 Vent Condenser can be used for
ATFE Vapour Condensation or Explore new.
R-802 Max. Operating Temp is 40 °C.
Solvent- DMF & Addition of CCMT

Vessel for concentrate mass collection 63 LIT F.F New 5 Vessel to be find out after 60% Concentration : ~40 lit 60
concentration mass transfer pump New 1 Pump to Find out
WFE for distillation(90% Concentration) SS-316 0.4 sq. mtr S.F Available 0 With Internal Condenser after 90% Concentration : ~24 lit
External Condenser of WFE SS-316
R-803 Vessel for concentrate mass collection SS-316 200 ltr F.F Available 63 0 Min. Stirrable vol. 35 Ltr, As per batch size
Min. operating vol. is 20 Ltr
Vent Condenser of R-803 Graphite F.F Available
29 P-816 Intal Vaccum pump for distillation SS-316 50 m3/hr G.F. Available 0
30 NA Buffer tank SS-316 100 ltr S.F Available 0
31 T-806 Dist DMF collection tank SS-316 100 ltr G.F. Available 80 0 Storage of 1 Batch volume
32 P-804 Dist.DMF transfering pump PP/PVDF 1 m3/Hr G.F. Available 0
P-801 CMD-90 Transfering pump PP/PVDF 25 NB-AODD G.F. Available 0 Compatibility to be checked
T- CMD-90 Batch tank NEW
Confirm route for feeding with R&D
P- AODD PUMP for filter transfer NEW
F-801 ANFD filter for CTMT Filtration & Drying SS-316 0.25M2 G.F. Available 0
T-812 Filter ml collection tank SS-316 200 ltr G.F. Available 60 0 Combine 3 Batch vol. will proceed for crude
CTMT Recovery
P-810 Filter ml transfering pump PP/PVDF 1 m3/Hr G.F. Available 0
STEP-2 Crude CTMT Recovery
R-803 Vessel for concentrate mass collection SS-316 200 ltr F.F Available 180 0 Chilled brine required
Condenser
P-816 Ital Vaccum pump for distillation SS-316 50 m3/hr G.F. Available 0
NA Buffer tank SS-316 100 ltr S.F Available 0
T-806 Dist CMD-90 collection tank SS-316 100 ltr G.F. Available 105 0
P-804 Dist.CMD-90 transfering pump PP/PVDF 1 m3/Hr G.F. Available 0
P- AODD PUMP for filter transfer NEW
F-801 ANFD filter for CTMT Filtration & Drying SS-316 0.25M2 G.F. Available 0 Max. Batch Dry qty. 5 KGs
T-812 Filter ml collection tank SS-316 200 ltr G.F. Available 40 0
P-810 Filter ml transfering pump PP/PVDF 1 m3/Hr G.F. Available 0
STEP-3
R-802 Step-3 reaction vessel MSGL 250 ltr S.F Available 122 0
 Water batch tank Available 91
Portable Hopper for CTMT charging SS-316 S.F Available
R-801 Used as batch tank for HCl MSGL 63 ltr T.F. Available 15 0 Charging of HCL in R-801 discuss with R&D

NA Pump for crude CTZ DOM Filtration PP/PVDF 25 NB-AODD G.F. Available 0 Dom Batch
F-1201 Dom Filter for Crude CTZ Filtration Rubber Line 900 Dia T.F. Available 0 Wet Basis Cake Volm. is 30 Ltr 64 30
Working Capcity of Dom Filter is 64 Ltr
35 NA Filter ml collection tank MSGL 250 ltr G.F. Available 200 0
36 P-806 Filter ml transfering pump SS-316 1 m3/Hr F.F Available 0
Repulping of Crude CTZ
37 R-802 Repulping Vessel MSGL 250 ltr S.F Available 87 0
38 Water batch tank Available
39 Portable Hopper for CTMT charging SS-316 S.F Available
40 NA Pump for crude CTZ Filtration PP/PVDF 25 NB-AODD G.F. Available 0
41 F-801 ANFD filter for CTMT Filtration & Drying SS-316 0.25M2 G.F. Available 0 pH data to be checked.
Wet Basis Cake Volm. is 20 Ltr
Working Capcity of Dom Filter is 37 Ltr

T-812 Filter ml collection tank SS-316 200 ltr G.F. Available 80 0 Filtrate ML -1+2+3 Combine or Separate
store
P-810 Filter ml transfering pump PP/PVDF 1 m3/Hr G.F. Available 0
DMF Solvent recovery
V-108 with fractional distillation column setup
6.8 Rs. In Lakh

Basis:-
1. Crude recovery batches considered in CTMT Process Setup
2. Step-3 CTZ process consider after completion of CTMT campaing in same setp
3. Equipment Toluene & CMD-90 recovery not considered
4. DMF Fractionation/ Redistillation Facility to be explored
 Excel Crop Care Ltd.
Projcet:CTZ
Admin:
Task: BCT (Option-5A)(Purification of Step-2 using CMD introduced) NO OF MONTHS FOR
PRODUCTION
Batch Output 1.000 TPB
Plant capacity Err:520 TPD
Admin:
Plant capacity Err:520 TPM 24HRS WORKING & 26
Plant capacity Err:520 50 TPA WORKING DAYS & 11
MONTHS WORKING.
Plant capacity Err:520 200 TPA
Stage-1
Batch input kg 9 Admin:
dont change value here
Batch Volume Equipment working Equipment
Sr.No. Activity (sheet linked with Time,Hrs
MB sheet) volume Occupancy %

Stage -1 Reaction Vessel (RB-801/MSGL/100 Ltr)

Vessel Volume Required 73.1 Ltr
Vessel Considered 100 lit MSGL
1 Innertisation with N2 0.25
2 MNG charging 4.50 5 0.25
3 Toluene charging 25.12 25 0.25
4 37% HCHO Charging 38.23 38 0.25
5 Water Charging 38.71 39 0
6 Heating upto 35 Deg C 38.71 39 0.5
7 40% MeNH2 dropwise addition 45.71 46 3
8 Cooking at 50°C 45.71 100 46 3
9 Toluene charging 69.84 70 0.25
10 Reflux for water removal 18.76 5
Cooling & Crystallization (Cooling of
11 R.Mass to 19-20°C and Stirring for 30 51.07 51 2
min at 19-20 min)

12 Transfering to filter including washing 47.75 48 0.5

Maximum batch volume as per real 73.11 73 15.25

R&D density data
Capacity Per Reactor, TPD 1.573
No. of Vessels for the step,Nos. 1
Sectional Capacity, TPD 1.6
Capacity, TPM 44.1

Stage -1 Filtration & Product Dissolution (F-807 Dom Filter/SS316/600 Dia)

Filter Dia Required 600.00 mm
01NOS
1 Innertisation with N2 0.25
2 Receiving of mass & Filtration 47.75 7
3 Wet Cake (B.D-0.635, LOD-1.36%) 22.51 80
28.26
4 DMF charging 52.95 1.5
5 Circulation & Dissolution 52.95 2
Maximum batch volume as per real 10.75
R&Ddensity data
Admin: Capacity Per Filter, TPD 2.23
volume required for
dissolved product No. of Filters for the step,Nos. 1
reciever Sectional Capacity, TPD 2.23
Capacity, TPM 62.5

Stage-1 Toluene Filtrate ML Distillation ( )

Vessel Volume Required 48 Ltr
Vessel Considered MSGL X 6.3KL X 01NOS
1 Innertisation with N2 0.25
2 Filtrate recieving 47.75 48 0.5
3 Heating to 55-60°C 47.75 48 0.5
100
4 Distillation 47.75 48 8
5 Residue cooling 0.25
6 Residue drain 0.25
Maximum batch volume 47.75 48 9.75
 Capacity Per Reactor, TPD 2.46
No. of Vessels for the step,Nos. 1
Sectional Capacity, TPD 2.46
Capacity, TPM 68.9

Stage-2
Batch Volume
Equipment working Equipment
Sr.No. Activity (sheet linked with
MB sheet) volume Occupancy %

Stage -2 Reaction Vessel (R-802/MSGL/250 Ltr)

Vessel Volume Required 0 Ltr
Vessel Considered 10KL X 01 NOS
1 Innertisation with N2 0.25
2 MNMTI Solution receiving 66 26 1
3 K2CO3 and Cat.30149 charging 82 33 1
4 Heating to 40°C 82 33 1
CCMT addition (Solution of CCMT 250
5 +DMF to be added) 100 40 0.5

6 Cooking at 41°C 100 40 4

Sample analysis 100 40 0.5
7 Charge feeding to filtration 100 40 1
Maximum batch volume as per real
R&D density data LTR 0 9.25

Capacity Per Reactor, TPD 2.59

No. of Vessels for the step,Nos. 1
Sectional Capacity, TPD 2.594
Capacity, TPM 72.62

Stage -2 Salt Filtration & Drying (Dom Filter, SS-316, 900 Dia)
Filter Area Required 900.0 mm
1 Nos.
1 Innertisation with N2 0.25
2 Receiving of mass & Filtration 135 10
3 DMF washing & filtration 160 1.25
4 Wet Cake (B.D-0.7224, LOD-20%) 29 63.585 45 10
5 Scrapping & unloading, boxup 29 1.5
Cake volume 29 23
Capacity Per Filter, TPD 1.04
No. of Filters for the step,Nos. 1.0
Sectional Capacity, TPD 1.043
Capacity, TPM 29.2

Stage-2 Product Concentration & Dissolution Vessel (NEW/SS316/5KL) With FF Reboiler -500kg/hr X 01 Nos
Vessel Volume Required 112 Ltr
Vessel Considered with FF Reboiler 5KL/15m2 X 01 NOS
1 Innertisation with N2 0.25
2 Fitrate ml recieving lot-1 112 70 0.5
3 Heating to75 to 85°C 112 70 1.75

4 DMF Vacuum Distillation at 75 to 85°C 112 70 7

by pass circulation in ATFE
5 Fitrate ml recieving lot-1 (2) 112 70 1
6 Heating to75 to 85°C 112 70 1
DMF Vacuum Distillation at 75 to 85°C
7 by pass circulation in WFE 112 160 70 4

8 Cooling to RT 21 13 1
9 CMD-90 charging 42 26 0.5
10 Heat to 70C 42 26 1
Stirring for 30 min 42 26 0.5
Cool to 28C 42 26 1
11 Charge feeding for filtration 42 26 1
Maximum batch volume as per real 112 LTR 70 20.5
R&D density data
Capacity Per Reactor, TPD 1.17
No. of Vessels for the step,Nos. 1
Sectional Capacity, TPD 1.170
Capacity, TPM 32.8
Stage -2 CTMT Filtration & Drying (ANFD/0.25 M2)
Filter Area Required 4.4 m2
1 Nos.
1 Innertisation with N2 0.25
2 Receiving of mass & Filtration 42 8
3 CMD-90 washing & filtration 63 1.25
38
4 Wet Cake (B.D-0.7224, LOD-20%) 38 8
5 Scrapping & unloading, boxup 38 1.5
Cake volume 38 LTR 19
Capacity Per Filter, TPD 1.26
No. of Filters for the step,Nos. 1.0
Sectional Capacity, TPD 1.3
Capacity, TPM 35.4
Crude CTMT recovery (NEW/SS316/5KL) X 01NO
Vessel Volume Required 58 Ltr
Vessel Considered with FF Reboiler 5KL/15m2 X 01 NOS
1 Innertisation with N2 0.25
2 Fitrate ml recieving 58 23 0.5
3 Heating to70 to 80°C 58 23 1.75
CMD-90 Vacuum Distillation at 70 to
4 58 250 23 6
80°C
6 Cooling & Crystallization at 5-6°C 10 4 11
7 Charge feeding for filtration 10 4 1
Maximum batch volume as per real 58 LTR 23 20.5
R&D density data
Capacity Per Reactor, TPD 1.17
No. of Vessels for the step,Nos. 1
Sectional Capacity, TPD 1.2
Capacity, TPM 32.8
Crude CTMT Filtration & Drying (ANFD/NEW/1.5M2)
Filter Area Required 0.3 m2
1 Nos.
1 Innertisation with N2 0.25
2 Receiving of mass & Filtration 10 4
3 CMD-90 washing & filtration 13 1.25
38
4 Wet Cake (B.D-0.479, LOD-%) 3 7 4
5 Scrapping & unloading, boxup 3 1.5
Cake volume 3 11
Capacity Per Filter, TPD 2.18
No. of Filters for the step,Nos. 1.0
Sectional Capacity, TPD 2.2
Capacity, TPM 61.1
DMF Redistillation ( )
Batch volume 79 Kg
Volume per day to be distilled 79 Kg
1 Innertisation with N2 0.25
2 Dist. DMF Recieving 79 #DIV/0! 1
3 Heating to 95-105°C 79 #DIV/0! 1

4 Distillation at 95-105°C at 600- 79 #DIV/0! 8

620mmhg vac to remove moisture
5 Cooling of DMF 71 #DIV/0! 1
6 Transfering to storage tank 71 #DIV/0! 1
Maximum batch volume as per real
R&D density data 79 #DIV/0! 12.25

Capacity of column,Kg/Hr 3
No. of columns for the step,Nos. 1
Sectional Capacity, TPD 2.0
Capacity, TPM 56.0
 Stage-3
Batch Volume
Sr.No. Activity (sheet linked with Equipment working Equipment
MB sheet) volume Occupancy %

Stage-3 Reaction Vessel (NEW/MSGL/7.2KL )

Vessel Volume Required 127 Ltr
Vessel Considered 5KL X 01NOS, 6.3KL X 01NOS
1 Inertisation with N2 0.25
2 Water charging 92 #DIV/0! 0.33
3 Dry CTMT Charging 111 #DIV/0! 0
30% HCl dropwise addition (Heating at
4 30-36C if required and addtion of HCl 127 #DIV/0! 0.33
at 30-36C)
5 Heating at 40°C 127 #DIV/0! 0.5
6 Cooking for 3 Hrs 127 #DIV/0! 3
7 Cooling at 10°C 127 #DIV/0! 3
8 Charging to centrifuge 127 3.74
Maximum batch volume as per real
127 #DIV/0! 11.15
R&D density data
Capacity Per Reactor, TPD 2.15
No. of Vessels for the step,Nos. 1
Sectional Capacity, TPD 2.15
Capacity, TPM 60.2

Filtration ( CF-NEW/Halar Lined/0.915Mtr Dia x 0.6mtr depth)

1 Feeding 127 0.17
2 Spinning 127 0.25
3 Washing 0.1
4 Spinning 0.5
5 Scrapping 0.17
8.33
Capacity Per Filter, TPD 2.88
No. of Filters for the step,Nos. 1
Sectional Capacity, TPD 2.88
Capacity, TPM 80.6

Repulping Vessel ( V-201/MSGL/ 5 KL )

1 Cake recieving 32 8.33
2 Water charging for repulping 87 0.5
3 Heating to 80 °C 87 1
4 Stirring (Not given in new process) 87 2
5 Charging to Centrifuge 87 3.7
15.57
Capacity Per Reactor, TPD 1.54
No. of Vessels for the step,Nos. 1.0
Sectional Capacity, TPD 1.5
Capacity, TPM 43.1
Filtration ( CF-NEW/Halar Lined/0.915Mtr Dia x 0.6mtr depth)
1 Feeding 87 0.17
2 Spinning 87 0.25
3 Washing 112 0.1
4 Spinning 0.5
5 Scrapping 0.17
8.33
Capacity Per Filter, TPD 2.88
No. of Filters for the step,Nos. 1
Sectional Capacity, TPD 2.88
Capacity, TPM 80.6

Drying ( Nauta Dryer/New/ SS316/2KL)

1 Dry Cake 27 8.33
2 Unloading 6
1
15.33
 Capacity Per Dryer, TPD 1.57
No. of Dryers for the step,Nos. 1
Sectional Capacity, TPD 1.57
Capacity, TPM 43.8
FENTON Treatment of filtrate ml (NEW/10 KL/SS316)
Vessel Volume Required 11578 Ltr
Vessel Considered 10 KL
No. of batches per day 2
1 Innertisation with N2 0.25
2 Recieving of filtrate ML in lots 9569 96 1
Catalyst addition 9569 0.15
H2O2 Addition 10526 2
10000
3 Heating to 60°C 10526 105 1
4 Cooking for 1 hr 10526 105 1
Cuastic addition for neutrallization 11578 1
5 Residue cooling & draining 11578 0.5
Maximum batch volume 11578 116 6.9
Capacity Per Reactor, TPD 6.95
No. of Vessels for the step,Nos. 1
Sectional Capacity, TPD 6.95
Capacity, TPM 194.7

Note: 1) Filtrate ml of 3 no. of batches considered collectively for crude CTMT recovery.
2) One batch Equivalent wet cake quantity of crude CTMT will be make up with Step-3
Admin:
NO OF MONTHS FOR
PRODUCTION

Admin:
24HRS WORKING & 26
WORKING DAYS & 11
MONTHS WORKING.

Admin:
dont change value here
Excel Crop Care Limited., Bhavnagar 04.10.2018
Tentative Project costing for Pilot trials of CTZ in new Pilot Plant (P-2 Plant)

Sr. No. Activity Quantity Unit COST Note

(Rs. Lakh)

1 Equipment & Accessories - EU 2 No.- Portable hopper, 1 No.- Reflux pot, If

required, New Turbine agitator,
2 No- Peristaltic pump, 2 No- AODD pump & 1
No- Load cell.

2 Process side piping modification mtr Estimated cost. 100 mtr new piping, 200 mtr
re-route
3 Utility piping modification mtr Estimated for Hot water, CHW, N2 & LPS line
up considered.
4 Structural work 5 T Shed extension on T.F. for dom filter
installation.
5 Electrification & Instrumentation 0.5 Estimated cost.
4 Khalasi work, insulation and others - - 0.5
7 Civil Work 0.3
8 Contingency (10%) 0.1
Grand Total : In Lakh 1.4 Say Rs. 15.0 Lakh
 Line List & Piping MTO
Line Duty Pipe, m Bend Stubend Flange Valve DW S.G
Stage-1
Process piping 25 NB SS
1 210 50 80 80 25 5
Unit Cost 600 120 60 85 3000 3000
Total Cost 126000 6000 4800 6800 75000 15000 233600
2 Utility piping 25 NB MS 85 20 30 30 10 2
Unit Cost 350 95 45 85 2000 2000
Total Cost 29750 1900 1350 2550 20000 4000 59550
Process piping 40 NB SS
3 65 15 25 25 10 3
Unit Cost 800 150 80 110 3500 3500
Total Cost 52000 2250 2000 2750 35000 10500 104500

397650
 Details of Tentative Project costing for Pilot trials of CTZ in new Pilot Plant (P-2 Plant)
RB-801
1 Toluene charging line-up (25 NB SS) 15 mtr
2 CHW supply/return line-up (25 NB MS) 10 mtr
3 Utility hot water supply return line-up ( 25 NB MS) 20 mtr
4 Reflux pot line-up (25 NB SS) 10 mtr
5 DOM filter line-up (40 NB SS) 25 mtr
6 Filtrate ml circulation line-up (25 NB SS) 15 mtr
R-802
7 DMF Charging line-up (25 NB SS) 10 mtr
8 DMF circulation line-up throgh funda filter (25 NB SS) 15 mtr
9 Utility hot water supply/return line-up ( 25 NB MS) 15 mtr
10 Reflux pot line-up (25 NB SS) 15 mtr
11 DOM filter line-up (40 NB SS) 25 mtr
12 Filtrate ml line-up upto R-803 (25 NB SS) 15 mtr
R-803
13 Methanol Charging line-up (25 NB SS) 10 mtr
14 Conc. Mass transfering line-up (25 NB SS) 15 mtr
15 30%HCl line-up from R-801 to R-802 (25 NB SS) 10 mtr
16 CHW utility line-up ( 25 NB MS) 10 mtr
17 DOM filter line-up (25 NB SS) 20 mtr
18 Filtrate ml collection line-up (25 NB SS) 15 mtr
19 R-802 to ANFD line-up (40 NB SS) 15 mtr
20 ANFD ml transfering line-up (25 NB SS) 15 mtr
Misscellaneous
21 N2 Piping to vessel/tank (25 NB MS) 20 mtr
22 Piping for solvent recovery process (25 NB SS) 30 mtr
23 LPS Line modification if required. (25 NB MS) 10 mtr
24 Accessories like Scoop, measuring bucket (SS/Planstic) Mugs, - -
Carboys
25 SS-316 Hose pipe 2 EU
26 PTFE Hose pipe 2 EU
27 Safety accessories like safety guard, Earthing rod, earthing - -
wire, PPES
Hopper & Pot
1 Portable hopper without valve for MNG charging 1 EU
2 Portable hopper for K2CO3 1 EU
3 Reflux pot of 20 lit 1 EU

Total
1 25 NB SS Line 210 mtr
2 25 NB MS Line 85 mtr
3 40 NB SS Line 65 mtr
Excel Crop Care Limited, Bhavnagar
New Pilot Plant
Equipment List for CTZ

Sr. Tag No. Operation MOC Capacity Location Available/ Cost of Remarks
No. New new
equipme
nt

1 RB-801 Step-1 reaction vessel MSGL 100 ltr S.F Available 0

2 P-802 Toluene transfer from drum to T-802 bx tank PP/PVDF 25 NB-AODD G.F. Available 0
3 T-802 Toluene Batch tank SS-316 100 ltr T.F. Available 0
4 P-817 AODD pump for 37% HCHO addition PP/PVDF 100 ltr/Hr T.F. Available 0
5 P-818 Dosing pump for 40% MMA addition SS-316 & PTFE 2 ltr/Hr S.F New 0.75
6 NEW Reflux pot for Dist Water separation ( RB-801) SS-316 50 ltr S.F Available 0
7 T-1111 Ejector tank MS - G.F. Available 0
8 P-1111 Ejector pump CI - G.F. Available 0
9 T-1205 Buffer tank for ejector SS-316 - S.F Available 0
10 P-803 For MNMTI DOM Filtration SS-316 25 NB-AODD F.F Available 0
11 F-807 DOM filter for MNMTI Filtration SS-316 600 Dia T.F. Available 0
12 T-805 Filtrate Ml collection tank SS-316 200 ltr G.F. Available 0
13 P-804 Filtrate ml transfering pump SS-316 1 m3/Hr G.F. Available 0
14 T-807 MNMTI Solution collection tank SS-316 160 ltr G.F. Available 0
15 P-807 MNMTI Solution transfering pump SS-316 1 m3/Hr G.F. Available 0
16 R-802 Step-2 reaction vessel MSGL 250 ltr S.F Available 0
17 P-819 Fresh DMF transfer from drum to R-802 SS-316 25 NB-Dozing G.F. New 0.75 Avalable AODD pump is of
pump PVDF MOC. DMF is not
compatible with PVDF.

18 NEW Reflux pot for cleaning to ensure moisture free SS-316 20 lit S.F New 0.05
vessel R-802
19 NEW Paristaltic pump for CCMT addition SS-316 Body - S.F New 0.75 Capacity of pump will be
decided after finalised
addition time.

20 P-820 Pump for waste solid DOM Filtration & MNMTI SS-316 25 NB-Dozing F.F New 0.75
solution circulation pump

21 F-1202 DOM filter for waste solid Filtration SS-316 900 Dia T.F. Available 0
22 T-809 Filtrate ml collection tank MSGL 160 ltr G.F. Available 0
23 P-805 Filtrate ml transfering pump SS-316 1 m3/Hr G.F. Available 0
24 R-803 Vessel for Vacuum distillation SS-316 200 ltr F.F Available 0
25 P-816 Intal Vaccum pump for distillation SS-316 50 m3/hr G.F. Available 0
26 NA Buffer tank SS-316 100 ltr S.F Available 0
27 T-806 Dist DMF collection tank SS-316 100 ltr G.F. Available 0
28 P-812 Dist.DMF transfering pump SS-316 1 m3/Hr G.F. Available 0
29 P-802 Methanol Transfering pump PP/PVDF 25 NB-AODD G.F. Available 0
30 P-3 Concentrated CTMT solution transfering pump SS-316 1 m3/Hr G.F. Available 0
31 R-801 Used as batch tank for HCl MSGL 63 ltr T.F. Available 0
32 F-1201 Dom Filter for Crude CTZ Filtration Line 900 Dia T.F. Available 0
33 NA Filter ml collection tank MSGL 250 ltr G.F. Available 0
34 P-810 Filter ml transfering pump SS-316 1 m3/Hr F.F Available 0
35 F-801 ANFD filter for CTZ Filtration & Drying SS-316 0.25M2 G.F. Available 0
36 T-812 Filter ml collection tank SS-316 200 ltr G.F. Available 0
37 P-811 Filter ml transfering pump SS-316 1 m3/Hr G.F. Available 0
3.1 Rs. In Lakh
Tank Volume details for CTZ Campaign

Capacity Min volume on LI

Tank Tag No. MOC Process Volume Occupancy
lit lit

T-802 100 SS-316 45 45 40

T-805 200 MSGL 46 23 10

T-807 160 SS-316 140 87.5 50

T-815 250 SS-316 150 60 90

T-809 200 MSGL 165 82.5 10

T-806 100 SS-316 132 132 10

T-812 200 SS-316 100 50 40

T-816 250 MSGL 50 20 50

Note : Calibration of all tank done. T-806 will be used for dist. DMF collection. Drum up will be done in between ope
 Max volume on LI
lit

100

130

150

270

210

120

190

250

m up will be done in between operation.

 CTZ required area calculation of Condenser

Stage-1

Distillate rate of toluene 20 kg/hr

Heat duty required 1760 kcal/hr

LMTD 3 °C

U assumed for graphite Condenser 200 kcal/m2hr°C

Area Required 2.93 m2

Existing available area 5.8 m2

Note : Available area of condenser is sufficient for the process

Stage-2 Part-1

The available area of condenser is sufficient due to no distillation and

reflux operation in process.

Stage-2 Part-2

Distillate rate of DMF 35 kg/hr

Heat duty required 3080 kcal/hr

LMTD 3.04 °C

U assumed for graphite Condenser 200 kcal/m2hr°C

Area Required 5.06 m2

Existing available area 5.8 m2

Note : Available area of condenser is sufficient for the process